CN107352806A - Print glass ink coloured glass powder and its preparation method and application - Google Patents
Print glass ink coloured glass powder and its preparation method and application Download PDFInfo
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- CN107352806A CN107352806A CN201710696288.4A CN201710696288A CN107352806A CN 107352806 A CN107352806 A CN 107352806A CN 201710696288 A CN201710696288 A CN 201710696288A CN 107352806 A CN107352806 A CN 107352806A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
- C03C3/066—Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Wood Science & Technology (AREA)
- Glass Compositions (AREA)
Abstract
The invention provides a kind of coloured glass powder and its preparation method and application, preparation method provided by the invention is by by the Bi of 50~70 parts by weight2O3, the SiO of 5~20 parts by weight2, the B of 5~30 parts by weight2O3, the Al of the ZnO of 5~10 parts by weight and 1~5 parts by weight2O3Mixing, heating, obtains glass metal；Then the glass metal quenching is formed into glass particle again, ball milling obtains parent glass powder；Finally the colouring agent of 2~6 parts by weight and aforementioned base glass powder are mixed, and high-energy ball milling successively, shaping, again sintering, ball milling, obtain coloured glass powder, wherein, the present invention is by selecting the glass powder of specific composition to be mixed with colouring agent so that obtained coloured glass powder low temperature fusible, and it is bright in luster, hardly possible is decolourized, and then cause the glass ink prepared can sintered molten at a lower temperature, acid or alkali environment under not fugitive color high with the bond strength of glass basis.
Description
Technical field
The invention belongs to coloured glass powder field, more particularly to a kind of printing glass ink with coloured glass powder and its
Preparation method and application.
Background technology
Glass ink is mainly formulated by glass powder, colouring agent and varnish three parts, applied to decoration glass of automobile
Glass, plate glass, low-expansion glass vessel, hollow vessels are included in the preparation of cosmetic bottle, drink bottles etc., wherein, glass
Glass powder is the important component of glass ink.Glass ink melts generation liquid phase in sintering process, with glassware table
Face phase counterdiffusion makes ink be combined closely with glass.Therefore, on the premise of glassware is not damaged, the sintering temperature of ink is reduced
Degree has great importance.
Glass heats up sintering after printing, be printed onto the ink of glass surface can be fixedly arranged on glass formed it is bright and colourful
Decorative pattern, different color demands can be met by adding different colouring agents.Glass ink colouring agent mainly has two kinds：Have
Machine colouring agent and inorganic colourant.Toner is easily thermally decomposed during sintering, causes ink consolidation after stain effect
Fruit is undesirable, easy to change or colour fading, so as to limit the application of glass ink；Inorganic colourant mainly has an iron oxide, cadmium sulfide,
Cobalt aluminate, chromium oxide etc., from the point of view of in mechanism, glass powder and inorganic colourant will reach melting before glassware softening
State, dense system is formed inside glassware therewith so as to diffuse into, reach larger bond strength.But inorganic coloring
The fusing point of agent is universal higher, in the sintering procedure of glass ink, because coloring agent particle is difficult to melt during low-temperature sintering,
The liquid phase of glass powder melting generation can only be relied on to coat and bond it, cause the glass ink after solidification that color occurs
Phenomena such as damp uneven, and easy to fall off.
Therefore it provides a kind of adhesive force is strong, the glass ink of uniform coloring is the current technical issues that need to address.
The content of the invention
In view of this, the technical problems to be solved by the invention are to provide a kind of printing glass ink coloured glass powder
Body and its preparation method and application, glass powder low temperature fusible provided by the invention, and the ink being prepared with the powder
Color is uniform, and adhesive force is strong, not deinking.
The invention provides a kind of coloured glass raw powder's production technology, including：
1) by the Bi of 50~70 parts by weight2O3, the SiO of 5~20 parts by weight2, the B of 5~30 parts by weight2O3, 5~10 parts by weight
ZnO and 1~5 parts by weight Al2O3Mixing, heating, obtains glass metal；
2) the glass metal quenching for obtaining step 1) forms glass particle, and ball milling obtains parent glass powder；
3) colouring agent of 2~6 parts by weight and the parent glass powder of step 2) are mixed, successively by high-energy ball milling, into
Type, again sintering, ball milling, obtain coloured glass powder.
Preferably, the Bi in the step 1)2O3For 55~65 parts by weight, SiO2For 10~15 parts by weight, B2O3For 10~
25 parts by weight, ZnO are 7~9 parts by weight, Al2O3For 2~3 parts by weight.
Preferably, the heating-up temperature in the step 1) is 1300~1400 DEG C.
Preferably, the quenching in the step 2) obtains glass particle for glass metal is poured into quenching in deionized water.
Preferably, the ball milling in the step 2) is the parent glass powder by glass particle ball milling into 300~500 mesh.
Preferably, the ratio of grinding media to material of high-energy ball milling is (8~12) in the step 3): 1.
Preferably, the colouring agent is inorganic colourant.
Preferably, the temperature of sintering is 600~750 DEG C in the step 3).
Present invention also offers a kind of coloured glass powder, it is prepared by parent glass powder and colouring agent；
The parent glass powder includes：Bi2O350~70 parts by weight；
Present invention also offers a kind of glass ink, including coloured glass powder of the present invention and varnish.
Compared with prior art, the invention provides a kind of coloured glass powder and its preparation method and application, the present invention
The preparation method of offer is by by the Bi of 50~70 parts by weight2O3, the SiO of 5~20 parts by weight2, the B of 5~30 parts by weight2O3, 5~
The ZnO of 10 parts by weight and 1~5 parts by weight Al2O3Mixing, heating, obtains glass metal；Then the glass metal quenching is formed again
Glass particle, ball milling obtain parent glass powder；Finally the colouring agent of 2~6 parts by weight and aforementioned base glass powder are mixed,
And high-energy ball milling successively, shaping, again sintering, ball milling, coloured glass powder is obtained, wherein, the present invention is by selecting specific composition
Glass powder mixed with colouring agent so that obtained coloured glass powder low temperature fusible, and bright in luster, hardly possible are decolourized, and then
So that the glass ink prepared can sintered molten at a lower temperature, it is high with the bond strength of glass basis, under acid or alkali environment not
Fugitive color；Test result indicates that the softening temperature of coloured glass powder provided by the invention is less than 600 DEG C, tinting strength, tinting power is standard
The 101~105% of sample, and obtained ink resistance to acids and bases, water resistance are prepared, adhesive force is strong, difficult for drop-off, can meet glass oil
The extensive use of ink.In addition, coloured glass raw powder's production technology provided by the invention is simple and easy, cost is cheap, product matter
Measure excellent, suitable large-scale production.
Brief description of the drawings
Fig. 1 is the DSC collection of illustrative plates of glass powder prepared by the embodiment of the present invention 1.
Embodiment
The invention provides a kind of coloured glass raw powder's production technology, including：
1) by the Bi of 50~70 parts by weight2O3, the SiO of 5~20 parts by weight2, the B of 5~30 parts by weight2O3, 5~10 parts by weight
ZnO and 1~5 parts by weight Al2O3Mixing, heating, obtains glass metal；
2) the glass metal quenching for obtaining step 1) forms glass particle, and ball milling obtains parent glass powder；
3) colouring agent of 2~6 parts by weight and the parent glass powder of step 2) are mixed, successively high-energy ball milling, shaping, burnt
Knot, again ball milling, obtain coloured glass powder.
According to the present invention, the Bi of the invention by 50~70 parts by weight2O3, the SiO of 5~20 parts by weight2, 5~30 parts by weight
B2O3, the Al of the ZnO of 5~10 parts by weight and 1~5 parts by weight2O3Mixing, heating, obtains glass metal；Wherein, the Bi2O3It is preferred that
For 55~65 parts by weight, more preferably 60~62 parts by weight；The SiO2Preferably 10~15 parts by weight；The B2O3Preferably
10~25 parts by weight, more preferably 15~20 parts by weight；The ZnO is preferably 7~9 parts by weight, more preferably 8 parts by weight；Institute
State Al2O3Preferably 2~4 parts by weight, more preferably 2.5~3 parts by weight；The present invention does not have particular/special requirement to the method for mixing, this
Hybrid mode known to field, the present invention are preferably mixed evenly by ball milling：, will also be mixed after mixing in the present invention
Compound heating makes its melting, obtains glass metal；The temperature of the heating is preferably 1300~1400 DEG C；The heating and thermal insulation time is preferred
For 30~60min, more preferably 40~50min；Wherein, the present invention does not have particular/special requirement, this area to the method for heating melting
Mixture is preferably placed in crucible by the method for known heating melting, the present invention, and fusing is heated in Muffle furnace, described
The programming rate for heating fusion process is 8~12 DEG C/min, more preferably 10~11 DEG C/min.
According to the present invention, the glass metal quenching that the present invention obtains step 1) forms glass particle, and ball milling obtains basic glass
Glass powder；The present invention does not have particular/special requirement to the method for quenching, and the mode well known in the art for glass metal quenching is excellent
Anthology invention pours into obtained glass metal in deionized water, its quick quenching is formed glass particle, the glass that will be obtained
Grain drying, ball milling, produces parent glass powder；The mesh number of the glass powder is preferably 300~500 mesh, more preferably 400
Mesh.
According to the present invention, the present invention also mixes the colouring agent of 2~6 parts by weight and the parent glass powder of step 2), according to
It is secondary to pass through high-energy ball milling, shaping, again sintering, ball milling, obtain coloured glass powder.Wherein, the colouring agent is preferably inorganic
Toner, more preferably iron oxide, cadmium sulfide, the one or more in cobalt aluminate and chromium oxide；The dosage of the colouring agent is preferred
For 3~5 parts by weight, more preferably 4 parts by weight；The Ball-milling Time of the high-energy ball milling be 24~36 hours, more preferably 28~
30 hours；The rotating speed of the ball mill of the high-energy ball milling is 300~600r/min；Ratio of grinding media to material is preferably (8~12): 1.
After high-energy ball milling, the pressed by powder that ball milling is obtained is molded, and is put into Muffle furnace and is sintered, and enters mixture
One step alloying；Wherein, the present invention does not have particular/special requirement to the method for shaping, well known in the art to can be used for what powder was molded
Powder is preferably placed on compressing in metal die by method, the present invention；In the present invention, the temperature of the sintering is preferred
For 600~750 DEG C, the time of the sintering is preferably 0.5~2 hour.
After sintering, the present invention also by the product cooling after sintering, it is broken, in ball milling, obtain coloured glass powder, its
In, the cooling is preferably furnace cooling；The present invention does not have particular/special requirement to broken method, well known in the art to can be used for
The broken method of solid particle；The present invention does not have particular/special requirement to the mode of ball milling, and ball grinding method well known in the art is equal
Can, product is preferably milled to 300~500 mesh in the present invention, is more preferably milled to 400 mesh.
Present invention also offers a kind of coloured glass powder, it is prepared by preparation method of the present invention, the present invention
The coloured glass powder low temperature fusible of the preparation method preparation of offer and bright in luster, hardly possible decolouring.
Present invention also offers a kind of glass ink, including coloured glass powder of the present invention and varnish；This hair
The glass ink of bright offer has excellent resistance to acids and bases, water resistance, and adhesive force is strong, difficult for drop-off, can meet glass ink
Extensive use.
Coloured glass raw powder's production technology provided by the invention is by by the Bi of 50~70 parts by weight2O3, 5~20 weight
The SiO of part2, the B of 5~30 parts by weight2O3, the Al of the ZnO of 5~10 parts by weight and 1~5 parts by weight2O3Mixing, heating, obtains glass
Glass liquid；Then the glass metal quenching is formed into glass particle again, ball milling obtains parent glass powder；Finally by 2~6 parts by weight
Colouring agent and the mixing of aforementioned base glass powder, and high-energy ball milling, shaping, again sintering, ball milling successively, obtain coloured glass powder
Body, wherein, the present invention carries out high energy ball again by selecting the glass powder of specific composition to be mixed with colouring agent after mixing
Mill, sintering are mixture alloys so that obtained coloured glass powder low temperature fusible, and it is bright in luster, hardly possible is decolourized, and then is made
The glass ink that must be prepared can sintered molten at a lower temperature, it is high with the bond strength of glass basis, be not easy under acid or alkali environment
Fade；In addition, coloured glass raw powder's production technology provided by the invention is simple and easy, cost is cheap, good quality of product, fits
Close large-scale production.
It is clearly and completely described below in conjunction with the technical scheme of the embodiment of the present invention, it is clear that described implementation
Example only part of the embodiment of the present invention, rather than whole embodiments.It is common based on the embodiment in the present invention, this area
The every other embodiment that technical staff is obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
Embodiment 1
Glass ink low temperature fusible red glass raw powder's production technology is printed, is comprised the following steps：
(1) it is calculated in mass percent, by 60% Bi2O3, 10% SiO2, 20% B2O3, 7% ZnO, 3%
Al2O3Mixing, ball milling；
(2) mixed uniformly raw material is placed in corundum crucible, it is molten to be warming up to 1400 DEG C of heating in 10 DEG C/min of Muffle furnace
Change, be incubated 30 minutes, obtain the glass metal of uniform component；
(3) glass metal melted is poured into deionized water, its quick quenching is formed glass particle；Take out drying,
It is milled to 400 mesh and obtains parent glass powder；
(4) it is calculated in mass percent, 4% iron oxide is mixed with above-mentioned parent glass powder, high-energy ball milling 30h, makes it
Mechanical alloying；
(5) by the powder of ball milling mixing in metal die it is compressing, the glass style of shaping is then put into Muffle
650 DEG C are warming up to 10 DEG C/min in stove, is incubated 0.5h, further alloying；
(6) room temperature is cooled to, is crushed, is milled to 400 mesh and obtains glass ink low temperature fusible red glass powder.
The red glass powder being prepared is analyzed, differential thermal point is carried out under the conditions of heating rate is 10 DEG C/min
Analysis, as a result see Fig. 1, Fig. 1 is the DSC collection of illustrative plates of glass powder prepared by the embodiment of the present invention 1, it can be seen that red glass
The softening temperature of glass powder is 584.7 DEG C；By relatively being drawn with shading criteria sample, red glass powder tinting strength, tinting power of the invention
For the 102% of standard sample；It can be seen that red glass powder softening temperature is low, coloring effect is good.
Red glass powder prepared by embodiment 1 mixes to (wherein, varnish passes through 1%~5wt%'s with varnish
Ethyl cellulose, the dispersant of 15%~30wt% terpinol and 0.1%~5wt% and surplus levelling agent mixed preparing obtain
To), glass ink is obtained, the performance of the glass ink to obtaining detects, and the results are shown in Table 1；
Table 1
As it can be seen from table 1 the glass ink that coloured glass powder produced by the present invention is prepared to obtain have it is excellent resistance to
Acid-base property, water resistance, adhesive force is strong, difficult for drop-off, can meet the extensive use of glass ink.
Embodiment 2
Glass ink low temperature fusible yellow glass raw powder's production technology is printed, is comprised the following steps：
(1) it is calculated in mass percent, by 65% Bi2O3,10% SiO2,15% B2O3,7% ZnO, 3%
Al2O3 is mixed, ball milling；
(2) mixed uniformly raw material is placed in corundum crucible, it is molten to be warming up to 1400 DEG C of heating in 10 DEG C/min of Muffle furnace
Change, be incubated 30 minutes, obtain the glass metal of uniform component；
(3) glass metal melted is poured into deionized water, its quick quenching is formed glass particle；Take out drying,
It is milled to 400 mesh and obtains parent glass powder；
(4) it is calculated in mass percent, 3% cadmium sulfide is mixed with above-mentioned parent glass powder, high-energy ball milling 30h, makes it
Mechanical alloying；
(5) by the powder of ball milling mixing in metal die it is compressing, the glass style of shaping is then put into Muffle
600 DEG C are warming up to 10 DEG C/min in stove, is incubated 0.5h, further alloying；
(6) room temperature is cooled to, is crushed, is milled to 400 mesh and obtains glass ink low temperature fusible yellow glass powder.
The yellow glass powder being prepared is analyzed, differential thermal point is carried out under the conditions of heating rate is 10 DEG C/min
Analysis, the results showed that, the softening temperature of the yellow glass powder of embodiment 2 is 565.5 DEG C；By compared with the shading criteria sample
Go out, tinting strength, tinting power of the invention is the 104% of standard sample；It can be seen that yellow glass powder softening temperature is low, coloring effect is good.
Yellow glass powder prepared by embodiment 2 mixes to (wherein, varnish passes through 1%~5wt%'s with varnish
Ethyl cellulose, the dispersant of 15%~30wt% terpinol and 0.1%~5wt% and surplus levelling agent mixed preparing obtain
To), glass ink is obtained, the performance of the glass ink to obtaining detects, and the results are shown in Table 2；
Table 2
From table 2 it can be seen that the glass ink that coloured glass powder produced by the present invention is prepared to obtain have it is excellent resistance to
Acid-base property, water resistance, adhesive force is strong, difficult for drop-off, can meet the extensive use of glass ink.
Embodiment 3
Glass ink low temperature fusible blue tinted glass raw powder's production technology is printed, is comprised the following steps：
(1) it is calculated in mass percent, by 55% Bi2O3,10% SiO2,25% B2O3,7% ZnO, 3%
Al2O3 is mixed, ball milling；
(2) mixed uniformly raw material is placed in corundum crucible, it is molten to be warming up to 1400 DEG C of heating in 10 DEG C/min of Muffle furnace
Change, be incubated 30 minutes, obtain the glass metal of uniform component；
(3) glass metal melted is poured into deionized water, its quick quenching is formed glass particle；Take out drying,
It is milled to 400 mesh and obtains parent glass powder；
(4) it is calculated in mass percent, 5% cobalt aluminate is mixed with above-mentioned parent glass powder, high-energy ball milling 30h, makes it
Mechanical alloying；
(5) by the powder of ball milling mixing in metal die it is compressing, the glass style of shaping is then put into Muffle
720 DEG C are warming up to 10 DEG C/min in stove, is incubated 0.5h, further alloying；
(6) room temperature is cooled to, is crushed, is milled to 400 mesh and obtains glass ink low temperature fusible blue tinted glass powder.
The blue color glass powder being prepared is analyzed, differential thermal is carried out under the conditions of heating rate is 10 DEG C/min
Analysis, the results showed that, the softening temperature of the blue tinted glass powder of embodiment 3 is 593.2 DEG C；By compared with the shading criteria sample
Go out, tinting strength, tinting power of the invention is the 101% of standard sample；It can be seen that blue tinted glass powder softening temperature is low, coloring effect is good.
Blue tinted glass powder prepared by embodiment 3 mixes to (wherein, varnish passes through 1%~5wt%'s with varnish
Ethyl cellulose, the dispersant of 15%~30wt% terpinol and 0.1%~5wt% and surplus levelling agent mixed preparing obtain
To), glass ink is obtained, the performance of the glass ink to obtaining detects, and the results are shown in Table 3；
Table 3
From table 3 it can be seen that the glass ink that coloured glass powder produced by the present invention is prepared to obtain have it is excellent resistance to
Acid-base property, water resistance, adhesive force is strong, difficult for drop-off, can meet the extensive use of glass ink
Embodiment 4
Glass ink low temperature fusible green glass raw powder's production technology is printed, is comprised the following steps：
(1) it is calculated in mass percent, by 60% Bi2O3,10% SiO2,20% B2O3,7% ZnO, 3%
Al2O3 is mixed, ball milling；
(2) mixed uniformly raw material is placed in corundum crucible, it is molten to be warming up to 1400 DEG C of heating in 10 DEG C/min of Muffle furnace
Change, be incubated 30 minutes, obtain the glass metal of uniform component；
(3) glass metal melted is poured into deionized water, its quick quenching is formed glass particle；Take out drying,
It is milled to 400 mesh and obtains parent glass powder；
(4) it is calculated in mass percent, 3% chromium oxide is mixed with above-mentioned parent glass powder, high-energy ball milling 30h, makes it
Mechanical alloying；
(5) by the powder of ball milling mixing in metal die it is compressing, the glass style of shaping is then put into Muffle
650 DEG C are warming up to 10 DEG C/min in stove, is incubated 0.5h, further alloying；
(6) room temperature is cooled to, is crushed, is milled to 400 mesh and obtains glass ink low temperature fusible green glass powder.
The green glass powder being prepared is analyzed, differential thermal point is carried out under the conditions of heating rate is 10 DEG C/min
Analysis, the results showed that, the softening temperature of the green glass powder of embodiment 4 is 580.5 DEG C；By compared with the shading criteria sample
Go out, tinting strength, tinting power of the invention is the 103% of standard sample；It can be seen that green glass powder softening temperature is low, coloring effect is good.
Green glass powder prepared by embodiment 4 mixes to (wherein, varnish passes through 1%~5wt%'s with varnish
Ethyl cellulose, the dispersant of 15%~30wt% terpinol and 0.1%~5wt% and surplus levelling agent mixed preparing obtain
To), glass ink is obtained, the performance of the glass ink to obtaining detects, and the results are shown in Table 4；
Table 4
From table 4, it can be seen that the glass ink that coloured glass powder produced by the present invention is prepared to obtain have it is excellent resistance to
Acid-base property, water resistance, adhesive force is strong, difficult for drop-off, can meet the extensive use of glass ink
The explanation of above example is only intended to help the method and its core concept for understanding the present invention.It should be pointed out that pair
For those skilled in the art, under the premise without departing from the principles of the invention, the present invention can also be carried out
Some improvement and modification, these are improved and modification is also fallen into the protection domain of the claims in the present invention.
Claims (10)
1. a kind of coloured glass raw powder's production technology, including：
1) by the Bi of 50~70 parts by weight2O3, the SiO of 5~20 parts by weight2, the B of 5~30 parts by weight2O3, 5~10 parts by weight
ZnO and 1~5 parts by weight Al2O3Mixing, heating, obtains glass metal；
2) the glass metal quenching for obtaining step 1) forms glass particle, and ball milling obtains parent glass powder；
3) colouring agent of 2~6 parts by weight and the parent glass powder of step 2) are mixed, successively by high-energy ball milling, shaping, burning
Knot, again ball milling, obtain coloured glass powder.
2. preparation method according to claim 1, it is characterised in that the Bi in the step 1)2O3For 55~65 weight
Part, SiO2For 10~15 parts by weight, B2O3For 10~25 parts by weight, ZnO is 7~9 parts by weight, Al2O3For 2~3 parts by weight.
3. preparation method according to claim 1, it is characterised in that heating-up temperature in the step 1) for 1300~
1400℃。
4. preparation method according to claim 1, it is characterised in that the quenching in the step 2) is to pour into glass metal
Quenching obtains glass particle in deionized water.
5. preparation method according to claim 1, it is characterised in that the ball milling in the step 2) is by glass particle ball
Wear into the parent glass powder of 300~500 mesh.
6. preparation method according to claim 1, it is characterised in that the ratio of grinding media to material of high-energy ball milling is (8 in the step 3)
~12): 1.
7. preparation method according to claim 1, it is characterised in that the colouring agent is inorganic colourant.
8. preparation method according to claim 1, it is characterised in that the temperature of sintering is 600~750 in the step 3)
℃。
9. a kind of coloured glass powder, is prepared by parent glass powder and colouring agent；
10. a kind of glass ink, including coloured glass powder and varnish described in claim 9.
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| CN201710696288.4A CN107352806B (en) | 2017-08-14 | 2017-08-14 | Colored glass powder for printing glass ink and preparation method and application thereof |
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|---|---|---|---|
| CN201710696288.4A CN107352806B (en) | 2017-08-14 | 2017-08-14 | Colored glass powder for printing glass ink and preparation method and application thereof |
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| CN107352806B CN107352806B (en) | 2020-12-15 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117264A (en) * | 2007-06-29 | 2008-02-06 | 上海晶采建材厂 | Process for making glass mosaic |
| KR20090025857A (en) * | 2007-09-07 | 2009-03-11 | 대주전자재료 주식회사 | Pb-free colored dielectric glass composition for pdp |
| CN101717196A (en) * | 2009-01-05 | 2010-06-02 | 四川虹欧显示器件有限公司 | Lead-free glass composition, preparation method and plasma display device using same |
| CN102044395A (en) * | 2010-12-09 | 2011-05-04 | 东南大学 | Method for directly preparing two-layer electrode by one-time silk-screen printing and used slurry thereof |
| CN105062215A (en) * | 2015-09-02 | 2015-11-18 | 江苏大学 | Bismuth-oxide-base red pigment for glass digital inkjet printing and preparation method thereof |
| CN106082682A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass air brushing bismuth silicon boron system's low-melting-point nano glass dust suspension and preparation method |
-
2017
- 2017-08-14 CN CN201710696288.4A patent/CN107352806B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117264A (en) * | 2007-06-29 | 2008-02-06 | 上海晶采建材厂 | Process for making glass mosaic |
| KR20090025857A (en) * | 2007-09-07 | 2009-03-11 | 대주전자재료 주식회사 | Pb-free colored dielectric glass composition for pdp |
| CN101717196A (en) * | 2009-01-05 | 2010-06-02 | 四川虹欧显示器件有限公司 | Lead-free glass composition, preparation method and plasma display device using same |
| CN102044395A (en) * | 2010-12-09 | 2011-05-04 | 东南大学 | Method for directly preparing two-layer electrode by one-time silk-screen printing and used slurry thereof |
| CN105062215A (en) * | 2015-09-02 | 2015-11-18 | 江苏大学 | Bismuth-oxide-base red pigment for glass digital inkjet printing and preparation method thereof |
| CN106082682A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass air brushing bismuth silicon boron system's low-melting-point nano glass dust suspension and preparation method |
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