CN107352806B - Colored glass powder for printing glass ink and preparation method and application thereof - Google Patents
Colored glass powder for printing glass ink and preparation method and application thereof Download PDFInfo
- Publication number
- CN107352806B CN107352806B CN201710696288.4A CN201710696288A CN107352806B CN 107352806 B CN107352806 B CN 107352806B CN 201710696288 A CN201710696288 A CN 201710696288A CN 107352806 B CN107352806 B CN 107352806B
- Authority
- CN
- China
- Prior art keywords
- glass
- weight
- parts
- glass powder
- ball milling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
- C03C3/066—Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Wood Science & Technology (AREA)
- Glass Compositions (AREA)
Abstract
The invention provides colored glass powder and a preparation method and application thereof, wherein the preparation method comprises the step of adding 50-70 parts by weight of Bi2O35 to 20 parts by weight of SiO25 to 30 parts by weight of B2O35 to 10 parts by weight of ZnO and 1 to 5 parts by weight of Al2O3Mixing and heating to obtain molten glass; then quenching the glass liquid to form glass particles, and performing ball milling to obtain basic glass powder; and finally, mixing 2-6 parts by weight of a coloring agent with the basic glass powder, and sequentially performing high-energy ball milling, molding, sintering and ball milling to obtain the colored glass powder, wherein the colored glass powder is prepared by selecting the glass powder with a specific composition to be mixed with the coloring agent, so that the obtained colored glass powder is fusible at a low temperature, bright in color and difficult to decolor, and further the prepared glass ink can be sintered and fused at a low temperature, has high bonding strength with a glass substrate and is difficult to fade in an acid-base environment.
Description
Technical Field
The invention belongs to the field of colored glass powder, and particularly relates to colored glass powder for printing glass ink and a preparation method and application thereof.
Background
The glass ink is mainly prepared from three parts of glass powder, a colorant and varnish, and is applied to the preparation of decorative automobile glass, flat glass and low-expansion glassware, hollow utensils comprise cosmetic bottles, beverage bottles and the like, wherein the glass powder is an important component of the glass ink. The glass ink is melted to generate a liquid phase in the sintering process, and the liquid phase and the surface of the glass product are mutually diffused to enable the ink to be tightly combined with the glass. Therefore, the sintering temperature of the ink is reduced to have important significance on the premise of not damaging the glass product.
The glass is heated and sintered after being printed, the ink printed on the surface of the glass can be solidified on the glass to form colorful decorative patterns, and different coloring agents are added to meet different color requirements. There are two main types of glass ink colorants: organic colorants and inorganic colorants. The organic colorant is easy to be thermally decomposed in the sintering process, so that the coloring effect of the solidified ink is not ideal, and the solidified ink is easy to discolor or fade, thereby limiting the application of the glass ink; the inorganic colorant mainly comprises iron oxide, cadmium sulfide, cobalt aluminate, chromium oxide and the like, and in terms of mechanism, the glass powder and the inorganic colorant are in a molten state before the glass product is softened, so that the glass powder and the inorganic colorant are diffused into the glass product to form a compact system with the glass product, and the glass product achieves higher bonding strength. However, the inorganic colorant has a generally high melting point, and in the firing process of the glass ink, since colorant particles are difficult to melt in the low-temperature sintering process, the colorant particles can only be coated and bonded by a liquid phase generated by melting of glass powder, so that the cured glass ink has the phenomena of uneven color, easy falling and the like.
Therefore, the technical problem to be solved is to provide the glass ink with strong adhesion and uniform coloring.
Disclosure of Invention
In view of the above, the technical problem to be solved by the present invention is to provide a colored glass powder for printing glass ink, a preparation method and an application thereof.
The invention provides a preparation method of colored glass powder, which comprises the following steps:
1) 50 to 70 parts by weight of Bi2O35 to 20 parts by weight of SiO25 to 30 parts by weight of B2O35 to 10 parts by weight of ZnO and 1 to 5 parts by weight of Al2O3Mixing and heating to obtain molten glass;
2) quenching the glass liquid obtained in the step 1) to form glass particles, and performing ball milling to obtain basic glass powder;
3) mixing 2-6 parts by weight of a colorant with the basic glass powder in the step 2), and sequentially performing high-energy ball milling, molding, sintering and ball milling again to obtain colored glass powder.
Preferably, Bi in the step 1)2O355 to 65 parts by weight of SiO210 to 15 parts by weight of B2O310 to 25 parts by weight of ZnO, 7 to 9 parts by weight of Al2O32 to 3 parts by weight.
Preferably, the heating temperature in the step 1) is 1300-1400 ℃.
Preferably, the quenching in the step 2) is to pour the molten glass into deionized water for quenching to obtain glass particles.
Preferably, the ball milling in the step 2) is to ball mill the glass particles into basic glass powder of 300-500 meshes.
Preferably, the ball-material ratio of the high-energy ball milling in the step 3) is (8-12) to 1.
Preferably, the colorant is an inorganic colorant.
Preferably, the sintering temperature in the step 3) is 600-750 ℃.
The invention also provides colored glass powder which is prepared from the basic glass powder and a colorant;
the basic glass powder comprises: bi2O350-70 parts by weight;
the invention also provides glass ink which comprises the colored glass powder and the varnish.
Compared with the prior art, the invention provides the colored glass powder and the preparation method and the application thereof, and the preparation method provided by the invention is characterized in that 50-70 parts by weight of Bi are added2O35 to 20 parts by weight of SiO25 to 30 parts by weight of B2O35 to 10 parts by weight of ZnO and 1 to 5 parts by weight of Al2O3Mixing and heating to obtain molten glass; then quenching the glass liquid to form glass particles, and performing ball milling to obtain basic glass powder; finally, 2-6 parts by weight of colorant and the basic glass powder are mixed, and high-energy ball milling, molding, sintering and ball milling are sequentially carried out to obtain the glass powderThe colored glass powder is prepared by mixing the glass powder with specific composition with a coloring agent, so that the obtained colored glass powder is fusible at low temperature, bright in color and difficult to decolor, and further the prepared glass ink can be sintered and fused at low temperature, has high bonding strength with a glass substrate and is difficult to decolor in an acid-base environment; experimental results show that the softening temperature of the colored glass powder is less than 600 ℃, the tinting strength is 101-105% of that of a standard sample, and the prepared ink is acid-alkali resistant, water resistant, strong in adhesive force, not easy to fall off, and capable of meeting the wide application of glass ink. In addition, the preparation method of the colored glass powder provided by the invention is simple and feasible, has low cost and excellent product quality, and is suitable for large-scale production.
Drawings
FIG. 1 is a DSC chart of the glass powder prepared in example 1 of the present invention.
Detailed Description
The invention provides a preparation method of colored glass powder, which comprises the following steps:
1) 50 to 70 parts by weight of Bi2O35 to 20 parts by weight of SiO25 to 30 parts by weight of B2O35 to 10 parts by weight of ZnO and 1 to 5 parts by weight of Al2O3Mixing and heating to obtain molten glass;
2) quenching the glass liquid obtained in the step 1) to form glass particles, and performing ball milling to obtain basic glass powder;
3) mixing 2-6 parts by weight of a colorant with the basic glass powder in the step 2), and performing high-energy ball milling, molding, sintering and ball milling in sequence to obtain colored glass powder.
According to the invention, 50-70 parts by weight of Bi2O35 to 20 parts by weight of SiO25 to 30 parts by weight of B2O35 to 10 parts by weight of ZnO and 1 to 5 parts by weight of Al2O3Mixing and heating to obtain molten glass; wherein, said Bi2O3Preferably 55 to 65 parts by weight, more preferably 60 to 62 parts by weight; the SiO2Preferably 10 to 15 parts by weight; b is2O3Preferably 10 to 25 parts by weight, more preferably 15 to 20 parts by weight; the ZnO is preferably 7-9 parts by weight, and more preferably 8 parts by weight; the Al is2O3Preferably 2 to 4 parts by weight, more preferably 2.5 to 3 parts by weight; the mixing method of the invention has no special requirements, and the mixing method known in the field can be used, and the invention preferably adopts ball milling to mix uniformly: in the invention, after the mixing is finished, the mixture is heated and melted to obtain molten glass; the heating temperature is preferably 1300-1400 ℃; the heating and heat preservation time is preferably 30-60 min, and more preferably 40-50 min; the mixture is preferably placed in a crucible and heated and melted in a muffle furnace, and the heating speed in the heating and melting process is 8-12 ℃/min, more preferably 10-11 ℃/min.
Quenching the glass liquid obtained in the step 1) to form glass particles, and performing ball milling to obtain basic glass powder; the quenching method has no special requirement, the method can be used in all known modes for quenching glass liquid in the field, preferably, the method pours the obtained glass liquid into deionized water to rapidly quench the glass liquid to form glass particles, and the obtained glass particles are dried and ball-milled to obtain basic glass powder; the mesh number of the glass powder is preferably 300-500 meshes, and more preferably 400 meshes.
According to the invention, 2-6 parts by weight of colorant and the basic glass powder in the step 2) are mixed, and the colored glass powder is obtained through high-energy ball milling, molding, sintering and ball milling. Wherein, the colorant is preferably an inorganic colorant, and more preferably one or more of iron oxide, cadmium sulfide, cobalt aluminate and chromium oxide; the amount of the colorant is preferably 3 to 5 parts by weight, and more preferably 4 parts by weight; the ball milling time of the high-energy ball milling is 24-36 hours, and more preferably 28-30 hours; the rotating speed of the high-energy ball mill is 300-600 r/min; the preferred ratio of the ball material to the material is (8-12) to 1.
After the high-energy ball milling is finished, pressing and molding the powder obtained by ball milling, and sintering the powder in a muffle furnace to further alloy the mixture; the invention has no special requirement on the forming method, and any method which is known in the field and can be used for powder forming can be adopted, and the invention preferably puts the powder into a metal mould for compression forming; in the invention, the sintering temperature is preferably 600-750 ℃, and the sintering time is preferably 0.5-2 hours.
After sintering, the sintered product is cooled, crushed and ball-milled to obtain colored glass powder, wherein the cooling is preferably furnace cooling; the method for crushing is not particularly required, and any method which is known in the art and can be used for crushing solid particles can be adopted; the ball milling method has no special requirement on the ball milling mode, the ball milling method known in the field can be adopted, and the ball milling of the product is preferably to 300-500 meshes, and more preferably to 400 meshes.
The invention also provides colored glass powder which is prepared by the preparation method provided by the invention, and the colored glass powder prepared by the preparation method provided by the invention is fusible at low temperature, bright in color and difficult to decolor.
The invention also provides glass printing ink which comprises the colored glass powder and the ink mixing oil; the glass printing ink provided by the invention has excellent acid and alkali resistance and water resistance, is strong in adhesive force, is not easy to fall off, and can meet the wide application of the glass printing ink.
The preparation method of the colored glass powder provided by the invention comprises the step of adding 50-70 parts by weight of Bi2O35 to 20 parts by weight of SiO25 to 30 parts by weight of B2O35 to 10 parts by weight of ZnO and 1 to 5 parts by weight of Al2O3Mixing and heating to obtain molten glass; then quenching the glass liquid to form glass particles, and performing ball milling to obtain basic glass powder; and finally, mixing 2-6 parts by weight of a coloring agent with the basic glass powder, and sequentially performing high-energy ball milling, molding, sintering and ball milling to obtain the colored glass powder, wherein the colored glass powder is obtained by selecting the glass powder with a specific composition to be mixed with the coloring agent, and performing high-energy ball milling and sintering again after mixing to obtain a mixture for alloyingThe glass powder is easily melted at low temperature, has bright color and is difficult to decolor, so that the prepared glass ink can be sintered and melted at low temperature, has high bonding strength with a glass matrix and is difficult to fade in an acid-base environment; in addition, the preparation method of the colored glass powder provided by the invention is simple and feasible, has low cost and excellent product quality, and is suitable for large-scale production.
The following will clearly and completely describe the technical solutions of the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The preparation method of the low-temperature fusible red glass powder for the printing glass ink comprises the following steps:
(1) calculated by mass percentage, 60 percent of Bi2O310% of SiO220% of B2O37% of ZnO, 3% of Al2O3Mixing and ball-milling uniformly;
(2) placing the uniformly mixed raw materials in a corundum crucible, heating the corundum crucible to 1400 ℃ at a temperature of 10 ℃/min in a muffle furnace, and carrying out heat preservation for 30 minutes to obtain glass liquid with uniform components;
(3) pouring the melted glass liquid into deionized water, and rapidly quenching to form glass particles; taking out, drying and ball-milling to 400 meshes to obtain basic glass powder;
(4) mixing 4% of ferric oxide and the basic glass powder in percentage by mass, and performing high-energy ball milling for 30 hours to mechanically alloy the mixture;
(5) pressing and molding the ball-milled mixed powder in a metal mold, then putting the molded glass sample into a muffle furnace, heating to 650 ℃ at a speed of 10 ℃/min, preserving heat for 0.5h, and further alloying;
(6) cooling to room temperature, crushing, and ball milling to 400 meshes to obtain the low-temperature fusible red glass powder for the glass ink.
The prepared red glass powder is analyzed, differential thermal analysis is carried out under the condition that the temperature rising rate is 10 ℃/min, the result is shown in figure 1, figure 1 is a DSC (differential scanning calorimetry) spectrum of the glass powder prepared in the embodiment 1 of the invention, and the softening temperature of the red glass powder is 584.7 ℃ as can be seen from the figure; compared with a coloring standard sample, the coloring power of the red glass powder is 102 percent of that of the standard sample; therefore, the red glass powder has low softening temperature and good coloring effect.
Mixing the red glass powder prepared in example 1 with varnish (wherein the varnish is prepared by mixing 1-5 wt% of ethyl cellulose, 15-30 wt% of terpineol, 0.1-5 wt% of dispersant and the balance of leveling agent) to obtain glass ink, and detecting the performance of the obtained glass ink, wherein the results are shown in table 1;
TABLE 1
As can be seen from Table 1, the glass ink prepared from the colored glass powder prepared by the invention has excellent acid and alkali resistance, water resistance and strong adhesive force, is not easy to fall off, and can meet the wide application of the glass ink.
Example 2
The preparation method of the low-temperature fusible yellow glass powder for printing glass ink comprises the following steps:
(1) mixing 65% of Bi2O3, 10% of SiO2, 15% of B2O3, 7% of ZnO and 3% of Al2O3 in percentage by mass, and performing ball milling uniformly;
(2) placing the uniformly mixed raw materials in a corundum crucible, heating the corundum crucible to 1400 ℃ at a temperature of 10 ℃/min in a muffle furnace, and carrying out heat preservation for 30 minutes to obtain glass liquid with uniform components;
(3) pouring the melted glass liquid into deionized water, and rapidly quenching to form glass particles; taking out, drying and ball-milling to 400 meshes to obtain basic glass powder;
(4) mixing 3% of cadmium sulfide and the basic glass powder in percentage by mass, and performing high-energy ball milling for 30 hours to mechanically alloy the cadmium sulfide and the basic glass powder;
(5) pressing and molding the ball-milled mixed powder in a metal mold, then putting the molded glass sample into a muffle furnace, heating to 600 ℃ at a speed of 10 ℃/min, preserving heat for 0.5h, and further alloying;
(6) cooling to room temperature, crushing, and ball milling to 400 meshes to obtain the low-temperature fusible yellow glass powder for the glass ink.
The yellow glass powder obtained by the preparation was analyzed, and differential thermal analysis was performed at a temperature rise rate of 10 ℃/min, and the result showed that the softening temperature of the yellow glass powder of example 2 was 565.5 ℃; the tinting strength of the invention was 104% of the standard as compared to a tinted standard; therefore, the yellow glass powder has low softening temperature and good coloring effect.
Mixing the yellow glass powder prepared in example 2 with varnish (wherein the varnish is prepared by mixing 1-5 wt% of ethyl cellulose, 15-30 wt% of terpineol, 0.1-5 wt% of dispersant and the balance of leveling agent) to obtain glass ink, and detecting the performance of the obtained glass ink, wherein the results are shown in table 2;
TABLE 2
As can be seen from Table 2, the glass ink prepared from the colored glass powder prepared by the invention has excellent acid and alkali resistance, water resistance and strong adhesive force, is not easy to fall off, and can meet the wide application of the glass ink.
Example 3
The preparation method of the low-temperature fusible blue glass powder for the printing glass ink comprises the following steps:
(1) mixing 55% of Bi2O3, 10% of SiO2, 25% of B2O3, 7% of ZnO and 3% of Al2O3 in percentage by mass, and performing ball milling uniformly;
(2) placing the uniformly mixed raw materials in a corundum crucible, heating the corundum crucible to 1400 ℃ at a temperature of 10 ℃/min in a muffle furnace, and carrying out heat preservation for 30 minutes to obtain glass liquid with uniform components;
(3) pouring the melted glass liquid into deionized water, and rapidly quenching to form glass particles; taking out, drying and ball-milling to 400 meshes to obtain basic glass powder;
(4) mixing 5% of cobalt aluminate and the basic glass powder in percentage by mass, and performing high-energy ball milling for 30 hours to mechanically alloy the cobalt aluminate and the basic glass powder;
(5) pressing and molding the ball-milled mixed powder in a metal mold, then putting the molded glass sample into a muffle furnace, heating to 720 ℃ at a speed of 10 ℃/min, preserving heat for 0.5h, and further alloying;
(6) cooling to room temperature, crushing, and ball milling to 400 meshes to obtain the low-temperature fusible blue glass powder for the glass ink.
The obtained blue glass powder was analyzed, and differential thermal analysis was performed at a temperature increase rate of 10 ℃/min, and the result showed that the softening temperature of the blue glass powder of example 3 was 593.2 ℃; compared with a coloring standard sample, the coloring power of the invention is 101% of that of the standard sample; therefore, the blue glass powder has low softening temperature and good coloring effect.
Mixing the blue glass powder prepared in example 3 with varnish (wherein the varnish is prepared by mixing 1-5 wt% of ethyl cellulose, 15-30 wt% of terpineol, 0.1-5 wt% of dispersant and the balance of leveling agent) to obtain glass ink, and detecting the performance of the obtained glass ink, wherein the results are shown in table 3;
TABLE 3
As can be seen from Table 3, the glass ink prepared from the colored glass powder prepared by the invention has excellent acid and alkali resistance, water resistance, strong adhesive force and difficult shedding, and can meet the wide application of the glass ink
Example 4
The preparation method of the low-temperature fusible green glass powder for printing glass ink comprises the following steps:
(1) mixing 60% of Bi2O3, 10% of SiO2, 20% of B2O3, 7% of ZnO and 3% of Al2O3 in percentage by mass, and performing ball milling uniformly;
(2) placing the uniformly mixed raw materials in a corundum crucible, heating the corundum crucible to 1400 ℃ at a temperature of 10 ℃/min in a muffle furnace, and carrying out heat preservation for 30 minutes to obtain glass liquid with uniform components;
(3) pouring the melted glass liquid into deionized water, and rapidly quenching to form glass particles; taking out, drying and ball-milling to 400 meshes to obtain basic glass powder;
(4) mixing 3% of chromium oxide and the basic glass powder in percentage by mass, and performing high-energy ball milling for 30 hours to mechanically alloy the chromium oxide and the basic glass powder;
(5) pressing and molding the ball-milled mixed powder in a metal mold, then putting the molded glass sample into a muffle furnace, heating to 650 ℃ at a speed of 10 ℃/min, preserving heat for 0.5h, and further alloying;
(6) cooling to room temperature, crushing, and ball milling to 400 meshes to obtain the low-temperature fusible green glass powder for the glass ink.
The green glass powder obtained by the preparation was analyzed, and differential thermal analysis was performed at a temperature rise rate of 10 ℃/min, and the result showed that the softening temperature of the green glass powder of example 4 was 580.5 ℃; the tinting strength of the invention is 103% of that of the standard as determined by comparison with a tinted standard; therefore, the green glass powder has low softening temperature and good coloring effect.
Mixing the green glass powder prepared in example 4 with varnish (wherein the varnish is prepared by mixing 1-5 wt% of ethyl cellulose, 15-30 wt% of terpineol, 0.1-5 wt% of dispersant and the balance of leveling agent) to obtain glass ink, and detecting the performance of the obtained glass ink, wherein the results are shown in table 4;
TABLE 4
As can be seen from Table 4, the glass ink prepared from the colored glass powder prepared by the invention has excellent acid and alkali resistance, water resistance, strong adhesive force and difficult shedding, and can meet the wide application of the glass ink
The above description of the embodiments is only intended to facilitate the understanding of the method of the invention and its core idea. It should be noted that, for those skilled in the art, it is possible to make various improvements and modifications to the present invention without departing from the principle of the present invention, and those improvements and modifications also fall within the scope of the claims of the present invention.
Claims (6)
1. A preparation method of colored glass powder comprises the following steps:
1) 50 to 70 parts by weight of Bi2O35 to 20 parts by weight of SiO25 to 30 parts by weight of B2O35 to 10 parts by weight of ZnO and 1 to 5 parts by weight of Al2O3Mixing and heating to obtain molten glass;
2) quenching the glass liquid obtained in the step 1) to form glass particles, and performing ball milling to obtain basic glass powder;
the ball milling is to ball mill glass particles into basic glass powder of 300-500 meshes;
3) mixing 2-6 parts by weight of inorganic colorant with the base glass powder in the step 2), and sequentially carrying out mechanical alloying, molding, sintering, further alloying and ball milling by high-energy ball milling to obtain colored glass powder.
2. The method according to claim 1, wherein said step 1) is performed using Bi2O355 to 65 parts by weight of SiO210 to 15 parts by weight of B2O310 to 25 parts by weight of ZnO, 7 to 9 parts by weight of Al2O32 to 3 parts by weight.
3. The method according to claim 1, wherein the heating temperature in the step 1) is 1300 to 1400 ℃.
4. The method according to claim 1, wherein the quenching in the step 2) is performed by pouring the molten glass into deionized water to quench the molten glass to obtain glass particles.
5. The preparation method of the high-energy ball milling material as claimed in claim 1, wherein the ball-to-material ratio of the high-energy ball milling in the step 3) is (8-12): 1.
6. the method according to claim 1, wherein the sintering temperature in the step 3) is 600 to 750 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710696288.4A CN107352806B (en) | 2017-08-14 | 2017-08-14 | Colored glass powder for printing glass ink and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710696288.4A CN107352806B (en) | 2017-08-14 | 2017-08-14 | Colored glass powder for printing glass ink and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107352806A CN107352806A (en) | 2017-11-17 |
| CN107352806B true CN107352806B (en) | 2020-12-15 |
Family
ID=60287327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710696288.4A Active CN107352806B (en) | 2017-08-14 | 2017-08-14 | Colored glass powder for printing glass ink and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107352806B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105062215A (en) * | 2015-09-02 | 2015-11-18 | 江苏大学 | Bismuth-oxide-base red pigment for glass digital inkjet printing and preparation method thereof |
| CN106082682A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass air brushing bismuth silicon boron system's low-melting-point nano glass dust suspension and preparation method |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117264A (en) * | 2007-06-29 | 2008-02-06 | 上海晶采建材厂 | Process for making glass mosaic |
| KR20090025857A (en) * | 2007-09-07 | 2009-03-11 | 대주전자재료 주식회사 | Pb-free colored dielectric glass composition for pdp |
| CN101717196A (en) * | 2009-01-05 | 2010-06-02 | 四川虹欧显示器件有限公司 | Lead-free glass composition, preparation method and plasma display device using same |
| CN102044395B (en) * | 2010-12-09 | 2012-08-15 | 东南大学 | Method for directly preparing two-layer electrode by one-time silk-screen printing and used slurry thereof |
-
2017
- 2017-08-14 CN CN201710696288.4A patent/CN107352806B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105062215A (en) * | 2015-09-02 | 2015-11-18 | 江苏大学 | Bismuth-oxide-base red pigment for glass digital inkjet printing and preparation method thereof |
| CN106082682A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass air brushing bismuth silicon boron system's low-melting-point nano glass dust suspension and preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107352806A (en) | 2017-11-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105753328B (en) | A kind of windshield ink lead and cadmium free composite glass powder and preparation method thereof | |
| CN101092308B (en) | Glass frit free of alkaline, lead and cadmium and its use to produce colored enamels | |
| CN101209903B (en) | High-temperature resistant lead-less glass powder for glass fiber net printing ink, preparation and application thereof | |
| CN104046121A (en) | Tempered glass ink formula | |
| CN101244950A (en) | Method for manufacturing middle-temperature ceramics for daily use crackle glaze | |
| CN105461223A (en) | Manufacturing process for colored glass | |
| CN111302624A (en) | Black glass and preparation method thereof | |
| CN101823841B (en) | Colored decorating plate made of composite fly ash microcrystalline glass and preparation method thereof | |
| CN107352806B (en) | Colored glass powder for printing glass ink and preparation method and application thereof | |
| CN103193515A (en) | One-process fast-fired transparent microcrystalline brick and production process thereof | |
| CN107651833A (en) | Low temperature coloured glass grass green colouring agent and preparation method thereof and application method | |
| CN106565101A (en) | Vacuum glass supporting material, preparation method and vacuum glass | |
| CN110563335A (en) | lead-free transparent fritted glaze and preparation method thereof | |
| CN101717190B (en) | Moderate-borosilicate scarlet glass and preparation method | |
| CN104817271A (en) | Preparation method of enamel electrostatic glaze powder and enamel electrostatic glaze powder prepared by method | |
| CN112174533B (en) | White high-aluminum microcrystalline glass and preparation method thereof | |
| CN107021623A (en) | A kind of colored glazed glass material and preparation method | |
| CN101844868B (en) | Purplish-red glass-ceramic containing neodymium and preparation method thereof | |
| CN110713345B (en) | Enamel color material, preparation method and application in repairing enamel cultural relics painted on porcelain body | |
| CN109824265B (en) | Preparation method of environment-friendly lead-free cadmium red glass and product prepared by preparation method | |
| CN102775061B (en) | A kind of Lead-free fusible environmental protection glass and preparation method thereof | |
| CN108250801B (en) | Color material for overglaze color and preparation method thereof | |
| CN107601866A (en) | A kind of gloss coloured glaze material and preparation method thereof | |
| CN108264228A (en) | A kind of preparation method of high-strength colour glass | |
| CN112408783B (en) | Opaque peacock green high-alumina glass and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |