CN108264228A - A kind of preparation method of high-strength colour glass - Google Patents
A kind of preparation method of high-strength colour glass Download PDFInfo
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- CN108264228A CN108264228A CN201710849415.XA CN201710849415A CN108264228A CN 108264228 A CN108264228 A CN 108264228A CN 201710849415 A CN201710849415 A CN 201710849415A CN 108264228 A CN108264228 A CN 108264228A
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- glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B27/00—Tempering or quenching glass products
- C03B27/004—Tempering or quenching glass products by bringing the hot glass product in contact with a solid cooling surface, e.g. sand grains
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of preparation method of high-strength colour glass, the preparation method be by main material and auxiliary material after mixing, it is thermally treated and be cooled and shaped high-strength colour glass product is made.The high-strength colour glass being prepared using the method for the invention, intensity is big, while is also added with colorant, the performance of stained glass is not only optimized, also improves its display effect, stained glass diversification requirement can be met, its utilization ratio is high, and durability is stronger.It not only solves high strength glass in the prior art and prepares cumbersome, the problem of waste of materials, also simple with preparation process, easy to operate, prepared products application range is wide.
Description
Technical field
The present invention relates to glass making techniques field, specifically a kind of preparation side of high-strength colour glass
Method.
Background technology
Glass is a kind of transparent solid at normal temperatures, and contiguous network structure, cooling procedure medium viscosity are formed in melting
Gradually increase and harden and non crystallized silicates nonmetallic materials.Glass is by silica and the melting of other chemical substances
Formed together (main production raw material is：Soda ash, lime stone, quartz).Contiguous network structure is formed in melting, it is cooled
Journey medium viscosity gradually increases and hardens the silicates nonmetallic materials that it is caused to crystallize.The chemical composition of simple glass it is main
Ingredient is silicate double salt, is a kind of non-crystalline solids of random structure.It is widely used in building, for every wind light transmission,
Belong to mixture.Separately there are the oxide for being mixed into certain metals or salt and show the coloured glass of color and pass through object
Tempered glass etc. made from reason or the method for chemistry, sometimes some transparent plastics (such as polymethyl methacrylate) also referred to as
Make organic glass.The numerous and diverse efficiency of glass making in the prior art is low, and the glass of high intensity is even more so, not only wastes money
Source, yield rate is also low, causes price generally higher, causes its utilization ratio not high.
Invention content
The problem of the technical problem to be solved by the present invention is to be directed to background technology, provides a kind of high-strength colour glass
The preparation method of glass.
In order to solve the above technical problems, the technical solution adopted in the present invention is：A kind of preparation of high-strength colour glass
Method, the preparation method be by main material and auxiliary material after mixing, it is thermally treated and be cooled and shaped high-strength colour is made
Glass, specific preparation method include the following steps：
(1) main material is chosen, the main material is made of by weight following raw materials：90~100 parts of quartz sand, soda ash 20~25
Part, 15~20 parts of calcite, 8~12 parts of fluorite, 4~6 parts of boron oxide, 3~5 parts of sodium nitrate, 3~5 parts of nickel oxide, barium carbonate 2
0.5~1 part of~4 parts, 1~3 part of bismuth oxide, 0.5~1 part of cobalt sulfide and zirconium oxide；
(2) auxiliary material is chosen, the auxiliary material includes having toner and fluxing agent, wherein the usage amount of the colorant accounts for the main material
Expect the 0.01~0.03% of total weight, the usage amount of the fluxing agent accounts for the 0.03~0.05% of the main material total weight；
(3) material in step (1) and (2) being poured into blender and be stirred, whipping temp is controlled between 22~24 DEG C,
After stirring evenly, it is spare to obtain mixture；
(4) mixture of gained in step (3) is poured into and melt process is carried out in smelting furnace, temperature of smelting furnace is controlled 1450~1680
Between DEG C, constant temperature rises in melting process, controls 1.5~2 DEG C of temperature rise per minute, stops when being raised to maximum temperature
Heating, heat preservation continue melting 2~3 hours；
(5) solution melted in step (4) is poured into glass template, it is to be formed stands cooling etc.；
(6) glass after molding in step (5) is put into high temperature furnace and be heated to close to after softening, then put it into fluid bed
The middle aluminium oxide quenching through solia particle, cooled to room temperature is to get to high-strength colour glass product after quenching.
Further, the preparation method of a kind of high-strength colour glass, wherein the colorant by red colorant,
Green colorant and cyan coloring agent by weight ratio 1:1 mixing composition, wherein the red stain is copper oxide, the green
Toner is chromium oxide, and the blue colorant is cobalt oxide.
Further, the preparation method of a kind of high-strength colour glass, wherein the glass molds in the step (5)
Plate is made of graphite material.
Further, the preparation method of a kind of high-strength colour glass, wherein the aluminium oxide in the step (6)
Particle size is 80~120 microns.
Using a kind of preparation method of high-strength colour glass of the present invention, compared with prior art, beneficial to effect
Fruit is：By the selection to raw material, high-strength colour glass is made in thermally treated and cooling and shaping, and intensity is big, while also adds
Added with colorant, the performance of stained glass is not only optimized, also improves its display effect, can meet stained glass diversification will
It asks, utilization ratio is high, and durability is stronger.Preparation method of the present invention solve high strength glass in the prior art prepare it is numerous
It is trivial, the problem of waste of materials.Simple with preparation process, easy to operate, prepared products application range is wide.
Specific embodiment
In order to more fully explain the implementation of the present invention, further illustrated the present invention below in conjunction with specific embodiment.Institute
It gives an actual example and is served only for explaining the present invention rather than limits the scope of the present invention.
Embodiment 1
A kind of preparation method of high-strength colour glass, the preparation method be by main material and auxiliary material after mixing, through heat
High-strength colour glass is made in processing and cooling and shaping, specifically includes following steps：
(1) main material is chosen, the main material is made of by weight following raw materials：90 parts of quartz sand, 20 parts of soda ash, calcite
15 parts, 8 parts of fluorite, 4 parts of boron oxide, 3 parts of sodium nitrate, 3 parts of nickel oxide, 2 parts of barium carbonate, 1 part of bismuth oxide, 0.5 part of cobalt sulfide and
0.5 part of zirconium oxide；
(2) auxiliary material is chosen, the auxiliary material includes having a toner and fluxing agent, and it is total that the usage amount of wherein colorant accounts for the main material
The 0.01% of weight, the usage amount of the fluxing agent account for the 0.03% of the main material total weight；Wherein described colorant is by red
Colorant, green colorant and cyan coloring agent by weight ratio 1:1 mixing composition, wherein the red stain is copper oxide, institute
Green colourant is stated as chromium oxide, the blue colorant is cobalt oxide；
(3) material in step (1) and (2) being poured into blender and be stirred, whipping temp is controlled between 22~24 DEG C,
After stirring evenly, it is spare to obtain mixture；
(4) mixture of gained in step (3) is poured into and melt process is carried out in smelting furnace, temperature of smelting furnace is controlled 1450~1680
Between DEG C, constant temperature rises in melting process, controls 1.5~2 DEG C of temperature rise per minute, stops when being raised to maximum temperature
Heating, heat preservation continue melting 2 hours；
(5) solution melt in step (4) is poured into made of the graphite material in glass template, stand cool down waiting into
Type；
(6) glass after molding in step (5) is put into high temperature furnace and be heated to close to after softening, then put it into fluid bed
The middle aluminium oxide quenching through solia particle, the wherein grain size of alumina particulate are 80 microns, the cooled to room temperature after quenching,
Obtain high-strength colour glass product.
Embodiment 2
A kind of preparation method of high-strength colour glass, the preparation method be by main material and auxiliary material after mixing, through heat
High-strength colour glass is made in processing and cooling and shaping, specifically includes following steps：
(1) main material is chosen, the main material is made of by weight following raw materials：95 parts of quartz sand, 23 parts of soda ash, calcite
18 parts, 10 parts of fluorite, 5 parts of boron oxide, 4 parts of sodium nitrate, 4 parts of nickel oxide, 3 parts of barium carbonate, 2 parts of bismuth oxide, 0.8 part of cobalt sulfide and
0.8 part of zirconium oxide；
(2) auxiliary material is chosen, the auxiliary material includes having a toner and fluxing agent, and it is total that the usage amount of wherein colorant accounts for the main material
The 0.02% of weight, the usage amount of the fluxing agent account for the 0.04% of the main material total weight；Wherein described colorant is by red
Colorant, green colorant and cyan coloring agent by weight ratio 1:1 mixing composition, wherein the red stain is copper oxide, institute
Green colourant is stated as chromium oxide, the blue colorant is cobalt oxide；
(3) material in step (1) and (2) being poured into blender and be stirred, whipping temp is controlled between 22~24 DEG C,
After stirring evenly, it is spare to obtain mixture；
(4) mixture of gained in step (3) is poured into and melt process is carried out in smelting furnace, temperature of smelting furnace is controlled 1450~1680
Between DEG C, constant temperature rises in melting process, controls 1.5~2 DEG C of temperature rise per minute, stops when being raised to maximum temperature
Heating, heat preservation continue melting 2.5 hours；
(5) solution melt in step (4) is poured into made of the graphite material in glass template, stand cool down waiting into
Type；
(6) glass after molding in step (5) is put into high temperature furnace and be heated to close to after softening, then put it into fluid bed
The middle aluminium oxide quenching through solia particle, the wherein grain size of alumina particulate is 90 microns, and room is naturally cooled to after quenching
Temperature is to get to high-strength colour glass product.
Embodiment 3
A kind of preparation method of high-strength colour glass, the preparation method be by main material and auxiliary material after mixing, through heat
High-strength colour glass is made in processing and cooling and shaping, specifically includes following steps：
(1) main material is chosen, the main material is made of by weight following raw materials：100 parts of quartz sand, 25 parts of soda ash, Fang Xie
20 parts of stone, 12 parts of fluorite, 6 parts of boron oxide, 5 parts of sodium nitrate, 5 parts of nickel oxide, 4 parts of barium carbonate, 3 parts of bismuth oxide, 1 part of cobalt sulfide and
1 part of zirconium oxide；
(2) auxiliary material is chosen, the auxiliary material includes having a toner and fluxing agent, and it is total that the usage amount of wherein colorant accounts for the main material
The 0.03% of weight, the usage amount of the fluxing agent account for the 0.05% of the main material total weight；Wherein described colorant is by red
Colorant, green colorant and cyan coloring agent by weight ratio 1:1 mixing composition, wherein the red stain is copper oxide, institute
Green colourant is stated as chromium oxide, the blue colorant is cobalt oxide；
(3) material in step (1) and (2) being poured into blender and be stirred, whipping temp is controlled between 22~24 DEG C,
After stirring evenly, it is spare to obtain mixture；
(4) mixture of gained in step (3) is poured into and melt process is carried out in smelting furnace, temperature of smelting furnace is controlled 1450~1680
Between DEG C, constant temperature rises in melting process, controls 1.5~2 DEG C of temperature rise per minute, stops when being raised to maximum temperature
Heating, heat preservation continue melting 3 hours；
(5) solution melt in step (4) is poured into made of the graphite material in glass template, stand cool down waiting into
Type；
(6) glass after molding in step (5) is put into high temperature furnace and be heated to close to after softening, then put it into fluid bed
The middle aluminium oxide quenching through solia particle, the wherein grain size of alumina particulate are 120 microns, and room is naturally cooled to after quenching
Temperature is to get to high-strength colour glass product.
The above described is only a preferred embodiment of the present invention, be not intended to limit the scope of the present invention,
Therefore any subtle modifications, equivalent variations and modifications that every technical spirit according to the present invention makees above example, still
Belong in the range of technical solution of the present invention.
Claims (4)
1. a kind of preparation method of high-strength colour glass, which is characterized in that the preparation method is to mix main material and auxiliary material
After closing uniformly, high-strength colour glass is made in thermally treated and cooling and shaping, and specific preparation method includes the following steps：
(1) main material is chosen, the main material is made of by weight following raw materials：90~100 parts of quartz sand, soda ash 20~25
Part, 15~20 parts of calcite, 8~12 parts of fluorite, 4~6 parts of boron oxide, 3~5 parts of sodium nitrate, 3~5 parts of nickel oxide, barium carbonate 2
0.5~1 part of~4 parts, 1~3 part of bismuth oxide, 0.5~1 part of cobalt sulfide and zirconium oxide；
(2) auxiliary material is chosen, the auxiliary material includes having toner and fluxing agent, wherein the usage amount of the colorant accounts for the main material
Expect the 0.01~0.03% of total weight, the usage amount of the fluxing agent accounts for the 0.03~0.05% of the main material total weight；
(3) material in step (1) and (2) being poured into blender and be stirred, whipping temp is controlled between 22~24 DEG C,
After stirring evenly, it is spare to obtain mixture；
(4) mixture of gained in step (3) is poured into and melt process is carried out in smelting furnace, temperature of smelting furnace is controlled 1450~1680
Between DEG C, constant temperature rises in melting process, controls 1.5~2 DEG C of temperature rise per minute, stops when being raised to maximum temperature
Heating, heat preservation continue melting 2~3 hours；
(5) solution melted in step (4) is poured into glass template, it is to be formed stands cooling etc.；
(6) glass after molding in step (5) is put into high temperature furnace and be heated to close to after softening, then put it into fluid bed
The middle aluminium oxide quenching through solia particle, cooled to room temperature is to get to high-strength colour glass product after quenching.
2. a kind of preparation method of high-strength colour glass according to claim 1, it is characterised in that：The colorant by
Red colorant, green colorant and cyan coloring agent by weight ratio 1:1 mixing composition, wherein the red stain is copper oxide,
The green colourant is chromium oxide, and the blue colorant is cobalt oxide.
3. a kind of preparation method of high-strength colour glass according to claim 1, it is characterised in that：The step (5)
In glass template be made of graphite material.
4. a kind of preparation method of high-strength colour glass according to claim 1, it is characterised in that：The step (6)
In alumina particulate size be 80~120 microns.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710849415.XA CN108264228A (en) | 2017-09-20 | 2017-09-20 | A kind of preparation method of high-strength colour glass |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710849415.XA CN108264228A (en) | 2017-09-20 | 2017-09-20 | A kind of preparation method of high-strength colour glass |
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| CN108264228A true CN108264228A (en) | 2018-07-10 |
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| CN201710849415.XA Pending CN108264228A (en) | 2017-09-20 | 2017-09-20 | A kind of preparation method of high-strength colour glass |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109970339A (en) * | 2019-04-09 | 2019-07-05 | 张家港市国华安全玻璃有限公司 | A kind of method for glass preparation that safety coefficient is high |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775064A (en) * | 2012-02-16 | 2012-11-14 | 湖北晶彩玻璃有限公司 | Production recipe of purple true color glass bottle |
| CN104370469A (en) * | 2014-10-28 | 2015-02-25 | 蒋达光 | Colorful glass ceramic with ultralow expansion coefficient and high transparency, and parathion method thereof |
| CN105461223A (en) * | 2014-08-29 | 2016-04-06 | 天津市瀚凯玻璃科技有限公司 | Manufacturing process for colored glass |
| CN106892558A (en) * | 2017-02-24 | 2017-06-27 | 江西瑞晶家饰有限公司 | A kind of novel high-strength method for glass preparation |
-
2017
- 2017-09-20 CN CN201710849415.XA patent/CN108264228A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775064A (en) * | 2012-02-16 | 2012-11-14 | 湖北晶彩玻璃有限公司 | Production recipe of purple true color glass bottle |
| CN105461223A (en) * | 2014-08-29 | 2016-04-06 | 天津市瀚凯玻璃科技有限公司 | Manufacturing process for colored glass |
| CN104370469A (en) * | 2014-10-28 | 2015-02-25 | 蒋达光 | Colorful glass ceramic with ultralow expansion coefficient and high transparency, and parathion method thereof |
| CN106892558A (en) * | 2017-02-24 | 2017-06-27 | 江西瑞晶家饰有限公司 | A kind of novel high-strength method for glass preparation |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109970339A (en) * | 2019-04-09 | 2019-07-05 | 张家港市国华安全玻璃有限公司 | A kind of method for glass preparation that safety coefficient is high |
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Application publication date: 20180710 |