CN107347892A - A kind of bactericidal composition containing prothioconazoles Yu fluorobenzene ether amide - Google Patents
A kind of bactericidal composition containing prothioconazoles Yu fluorobenzene ether amide Download PDFInfo
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- CN107347892A CN107347892A CN201610308410.1A CN201610308410A CN107347892A CN 107347892 A CN107347892 A CN 107347892A CN 201610308410 A CN201610308410 A CN 201610308410A CN 107347892 A CN107347892 A CN 107347892A
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- prothioconazoles
- ether amide
- fluorobenzene ether
- bactericidal composition
- fluorobenzene
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- Health & Medical Sciences (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The present invention relates to a kind of bactericidal composition containing prothioconazoles Yu fluorobenzene ether amide, its active ingredient is prothioconazoles and fluorobenzene ether amide binary built.The mass ratio of wherein pyridine prothioconazoles and fluorobenzene ether amide is 1~40: 40~1, active ingredient prothioconazoles and the quality parts ratio 1%~80% of fluorobenzene ether amide in preparation, remaining is the auxiliary element for allowing to use and receiving in agricultural chemicals, the formulation of bactericidal composition of the present invention is missible oil, suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion, it is mainly used in preventing and treating wheat rust, wheat powdery mildew, wheat sharp eyespot, rice sheath blight disease, false smut, powdery mildew of cucumber, cucumber downy mildew, downy mildew of garpe, alternaria leaf spot of apple, apple mildew, sigatoka, early blight of tomato, pear scab, powdery mildew of strawberry, the multiple diseases such as rust of sunflower.
Description
Technical field
The present invention relates to technical field of pesticide combination, more particularly to a kind of sterilization containing prothioconazoles Yu fluorobenzene ether amide
Composition.
Background technology
Prothioconazoles are a kind of New-type wide-spectrum triazolinthione series bactericidal agents that Beyer Co., Ltd develops, and prothioconazoles toxicity is low, no teratogenesis,
Mutagenesis type, it is non-toxic to embryo, to human and environment safety.Prothioconazoles are mainly used in preventing and treating cereal crop such as wheat, big
Numerous diseases such as wheat, rape, peanut, rice and legume crop.Almost there is good prevention effect to all wheat class diseases, such as
The powdery mildew of wheat and barley, banded sclerotial blight, droop, leaf spot, rust, sclerotiniose, net blotch, moire disease etc..Can also
Prevent and treat the soil-borne disease of oily Lay and peanut, such as sclerotiniose, and main foliage disease, as gray mold, black spot, brown spot,
Balck shank, sclerotiniose and rust etc..
Fluorobenzene ether amide (exploitation code name：Y13149 it is) new succinate dehydrogenase inhibitors (SDHI), to rice sheath blight disease
With remarkable preventive effect, while have efficient sterilizing active to powdery mildew, the late blight of potato.Fluorobenzene ether amide has Uptake and translocation
Property, and there is resistance to rainwater shower, dosage is low, cost is low.
It is the maximally efficient means of controlling plant diseases using chemical agent.But apply single chemistry long-term continuous high dose
Bactericide, easily cause the problems such as residual of medicament, environmental pollution and resistance to resistance to the action of a drug fungi are developed.Rational chemical bactericide
Compounding or mixture, which have, expands fungicidal spectrum, improves prevention effect, extends the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce
Remain, delay the positive feature such as Antifungal resistance and drug-fast generation and development, bactericide compounded is to solve the above problems most
For one of effective method.Develop new product bactericide price is constantly soaring, and by contrast, exploitation with research efficiently, low toxicity,
The compounding of low-residual with mixture has small investment, the lead time is short and is paid attention to both at home and abroad, numerous and confused increase develops dynamics.
We screen and on the basis of field test, filter out prothioconazoles and compounded with fluorobenzene ether amide indoors, have obvious
Synergistic effect.And people there is no to report at present on the bactericidal composition and application of prothioconazoles and the compounding of fluorobenzene ether amide.
The content of the invention
Based on case above, present invention aims at provide a kind of new and effective pesticide sterilizing composite.It is mainly used in preventing
Control wheat rust, wheat powdery mildew, wheat sharp eyespot, rice sheath blight disease, false smut, powdery mildew of cucumber, cucumber downy mildew,
Downy mildew of garpe, alternaria leaf spot of apple, apple mildew, sigatoka, early blight of tomato, pear scab, strawberry are white
The multiple diseases such as powder disease, rust of sunflower.
Technical scheme of the present invention is realized by following measures：
A kind of bactericidal composition containing prothioconazoles Yu fluorobenzene ether amide, the active ingredient prothioconazoles of the bactericidal composition
Compounded with fluorobenzene ether amide two-spot, remaining is auxiliary element.Active ingredient prothioconazoles and fluorine in wherein described Pesticidal combination
The mass ratio of phenylate acid amides is 1~40: 40~1, and described bactericidal composition of the present invention is through toxicity test experimental verification, rosickyite
When bacterium azoles and the mass ratio of fluorobenzene ether amide are 1~40: 40~1, synergistic effect is preferable.
The formulations of pesticide that described bactericidal composition of the present invention can be prepared are missible oil, suspending agent, wettable powder, water-dispersible grain
Agent, aqueous emulsion, microemulsion.Wherein active ingredient prothioconazoles account for whole preparation with the gross mass of fluorobenzene ether amide in the formulation
The 1%~80% of quality, wherein when accounting for 15%-50%, toxicity and residual reach preferable balance, and cost is relatively low.
The specific embodiment for the formulations of pesticide that bactericidal composition of the present invention is configured to is as follows：
Described bactericidal composition is cream preparation, and the mass fraction of component is：1~40 part of prothioconazoles；Fluorobenzene ether amide 1~
40 parts；10~30 parts of conventional emulsifier；20~50 parts of Conventional solvents；Conventional 1~5 part of synergist.The tool of the cream preparation
Body production stage for first active ingredient prothioconazoles and fluorobenzene ether amide are added in solvent be completely dissolved after add emulsifying agent,
Synergist stir after into transparent and homogeneous oily liquids, it is filling, you can the cream preparation of the present composition is made.
Described bactericidal composition is suspending agent, and the mass fraction of component is：1~40 part of prothioconazoles；Fluorobenzene ether amide 1~
40 parts；5~20 parts of dispersant；1~5 part of antifreezing agent；0.1~2 part of thickener；0.1~0.8 part of defoamer；Penetrating agent 0~
10 parts；0.1~5 part of pH value regulator；Water, surplus.The specific production stage of the suspending agent is first to mix other auxiliary agents,
It is well mixed through high speed shear, addition active ingredient prothioconazoles and fluorobenzene ether amide, abrading-ball 2~3 hours in ball crusher,
Make a diameter in below 5mm, you can the aqueous suspension formulations of the present composition are made.
Described bactericidal composition is wettable powder, and the mass fraction of component is：1~40 part of prothioconazoles；Fluorobenzene ether acyl
1~40 part of amine；3~10 parts of dispersant；1~5 part of wetting agent；Filler, surplus.The specific production stage of the wettable powder
For：Active ingredient prothioconazoles are mixed with fluorobenzene ether amide and dispersant, wetting agent and filler by above-mentioned formula, stirred
Uniform stirring in kettle is mixed, well mixed after airslide disintegrating mill, you can the wettable powder of the present composition is made.
Described bactericidal composition is water dispersible granules, and the mass fraction of component is：1~40 part of prothioconazoles；Fluorobenzene ether amide
1~40 part；3~10 parts of dispersant；1~10 part of wetting agent；1~5 part of disintegrant；Filler, surplus.The water-dispersible grain
The specific production stage of agent is：By above-mentioned formula by active ingredient prothioconazoles and fluorobenzene ether amide and dispersant, wetting agent,
Disintegrant and filler are well mixed, and are crushed with micro jet, through mediating, are then added in fluidized-bed granulation dryer
Be granulated, dried, sieve after through sampling analysis, you can the water dispersible granules of the present composition are made.
Described bactericidal composition is aqueous emulsion, and the mass fraction of component is：1~40 part of prothioconazoles；Fluorobenzene ether amide 1~
40 parts；3~30 parts of emulsifying agent；5~15 parts of solvent；2~15 parts of stabilizer；1~5 part of antifreezing agent；Defoamer 0.1~8
Part；0.2~2 part of thickener；Water, surplus.The specific production stage of the aqueous emulsion is：First by prothioconazoles and fluorobenzene ether
Acid amides, solvent and emulsifying agent, cosolvent are added together, and make to be dissolved into uniform oil phase；By part water, antifreeze, resist micro- life
Other insecticides adjuvants such as agent mix into uniform aqueous phase；Oil phase is added into water while high-speed stirred in a kettle
Phase, slowly plus water is until reach phase inversion point, and unlatching cutter carries out high speed shear, and adds remaining water, shearing about half an hour,
Form the aqueous emulsion of oil-in-water type, you can the aqueous emulsion of the present composition is made.
Described bactericidal composition is microemulsion, and the mass fraction of component is：1~40 part of prothioconazoles, fluorobenzene ether amide 1~
40 parts, 10~30 parts of emulsifying agent, 1~8 part of antifreezing agent, 0.5~10 part of stabilizer, 20~50 parts of Conventional solvents cosolvent.
Prothioconazoles are completely dissolved with fluorobenzene ether amide with cosolvent, add the other compositions such as emulsifying agent, antifreezing agent stabilizer,
Uniformly mixing, is eventually adding water, microemulsion can be made into after being sufficiently stirred.
Wherein above-described emulsifying agent is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, APES
Sulfosuccinate, styrylphenol polyoxyethylene ether, NPE, castor oil polyoxyethylene ether, aliphatic acid
Any one of polyoxyethylene base ester, polyoxyethylene aliphatic alcohol ether or more than one any mixtures than composition.
Described solvent is dimethylbenzene or biodiesel, toluene, diesel oil, methanol, ethanol, n-butanol, isopropanol, turpentine oil,
Solvent naphtha, dimethylformamide, dimethyl sulfoxide (DMSO), the one or more in water equal solvent are arbitrarily than the mixtures of composition.
Described dispersant is selected from polycarboxylate, lignosulfonates, APES methyl ether condensate sulfate, alkane
Base sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, APES, polyoxyethylene carboxylate, fatty amine gather
One or more of oxygen vinethene, glycerine fatty acid ester APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX, moistens bleeding agent F, alkane
Base benzene sulfonate polyoxyethylene triphen phosphenylic acid salt dimly, spaonin powder, silkworm excrement, the one or more in spaonin powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, and one in sodium acid carbonate
Kind is a variety of.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate,
It is one or more in polyvinyl alcohol.
Described stabilizer is selected from sodium citrate, one kind in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, the one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C10-20Saturated fat acids compound, C8-10One kind of fatty alcohol
It is or a variety of.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, in precipitated calcium carbonate
It is one or more.
The present invention has obvious synergistic effect using prothioconazoles and composite bactericide of the fluorobenzene ether amide as active ingredient, prolongs
The slow drug-fast generation in key, and reduce into production cost and use cost, the improvement available for resistance disease.It is mainly used in preventing
Control wheat rust, wheat powdery mildew, wheat sharp eyespot, rice sheath blight disease, false smut, powdery mildew of cucumber, cucumber downy mildew,
Downy mildew of garpe, alternaria leaf spot of apple, apple mildew, sigatoka, early blight of tomato, pear scab, strawberry are white
The multiple diseases such as powder disease, rust of sunflower.
Embodiment
To make technical scheme, purpose and advantage are more clearly understood, and the present invention is said with specific examples below
It is bright, but the present invention is not limited to these examples.The side that the effect experiment of the present invention is combined using indoor biometricses and field test
Formula, unless otherwise instructed, ratio mentioned below are all quality parts ratio.
Embodiment：Prothioconazoles are tested with fluorobenzene ether amide different ratio co-toxicity.
1.1 reagent agent
96% prothioconazoles active compound, 95% fluorobenzene ether amide active compound, above-mentioned active compound are ground by extra large rel medicine company limited company
Hair portion provides.
1.2 experiment targets
From Shandong Shouguang never applied prothioconazoles and the cucumber of fluorobenzene ether amide and same type it is potted plant gather and separate,
For trying cucumber variety：Chang Chun Mi Ci.
1.3 test method
1.3.1 medicament is prepared
Acetone solution active compound is first used, two appropriate active compounds are made into by different ratio according to the result of preliminary experiment, then will be each with acetone
It is stand-by that processing is diluted to some concentration gradients respectively.
By the cultivation of susceptible cucumber variety Chang Chun Mi Ci in pot for growing seedlings, it is placed in greenhouse and cultivates, plant grows to three to after four leaf stage,
The blade of identical leaf age is gathered, culture and measure for cucumber powdery mildew's pathogen.
1.3.2 the culture of cucumber powdery mildew's pathogen and the preparation of spore suspension
Cucumber powdery mildew's pathogen is cultivated using plants method under conditions of 20 DEG C, 12h alternation of light and darkness, turns to be commissioned to train foster 1 per 30d
It is secondary.With the conidium on sterile water elution incidence of leaf during inoculation, it is l × 10 to be configured to spore concentration6Individual/mL suspension.
1.3.3 strains tested sensitivity testing
Toxicity test is carried out using leaf dish moisturizing method.The blade of collection is first prepared into a diameter of 1.5cm leaf dish, it is random to mix,
Be respectively placed in the series concentration decoction configured and soak lh, each 50 leaf dishes of concentration, test using the processing of not adding medicine as
Blank control, after immersion terminates, leaf is face-up placed on the blotting paper of identical liquor strength wetting, the medicine in leaf dish
Liquid is blotted, and the spore suspension l0L prepared is inoculated in into leaf dish center, after room temperature places 5min, is placed in 20 DEG C, 12h
Cultivated under conditions of alternation of light and darkness, the onset area in leaf dish is measured after 10d, calculates EC50。
On the basis of pilot study, toxicity test is carried out to single dose prothioconazoles and fluorobenzene ether amide respectively with above method,
The two EC50Value is respectively 4.13 ㎎/l and 3.97 ㎎/l
The percentage that leaf dish area is accounted for according to lesion area divides sick level
0 grade：It is disease-free；
1 grade：Sorus area accounts for less than the 5% of whole leaf area；
3 grades：Sorus area accounts for below the 6%-10% of whole leaf area；
5 grades：Sorus area accounts for below the 11%-20% of whole leaf area；
7 grades：Sorus area accounts for below the 21%-50% of whole leaf area；
9 grades：Sorus area accounts for more than the 50% of whole leaf area；
1.3.4 mixture toxicity test and interpretation of result
The toxicity test of mixture is carried out according to mixed ratio with single dose toxicity test method.
If compare the death rate<5%, do not correct, the control death rate is corrected between 5%-20% by formula 2, and control is dead
Rate>20%, experiment need to reform.
Using the logarithm value of drug concentration (mg/L) as independent variable x, using the niqueMin of corrected mortality as dependent variable y, build respectively
Vertical virulence regression equation, the EC of single dose and each proportioning mixture is calculated using DPS softwares50Poison altogether is calculated according to the abundant methods of Sun Yun
Coefficient (CTC).Co-toxicity coefficient CTC, calculation formula are as follows：(using prothioconazoles as standard agent, 100) its toxicity index is：
The LC of toxicity index (TI)=prothioconazoles of fluorobenzene ether amide50The LC of/fluorobenzene ether amide50×100
The LC of M true toxicity index (ATI)=prothioconazoles50/ M LC50×100
TI × P fluorobenzene ether acyls of TI × P prothioconazoles+fluorobenzene ether amide of M theoretical toxicity index (TTI)=prothioconazoles
Amine
M co-toxicity coefficient (CTC)=M ATI/M TTI × 100
In formula：
M is the mixture of prothioconazoles and fluorobenzene ether amide different ratio
P prothioconazoles are prothioconazoles ratio shared in mixture
P fluorobenzene ether amide is fluorobenzene ether amide ratio shared in mixture
2.1 toxicity test results
Toxicity test of the prothioconazoles of table 1 with fluorobenzene ether amide to powdery mildew of cucumber
As can be seen from the table, different proportion proportioning result of the test show, diluted respectively in active ingredient ratio show compared with
Strong synergistic effect, wherein with prothioconazoles：Fluorobenzene ether amide is 24:Synergistic effect is optimal when 24, and its co-toxicity coefficient is
180.39.It is recommended that to suitable proportion 24:24 or so mixture preparations carry out further field control effectiveness test, to evaluate its field reality
Application effect.
3 field tests prevent and treat powdery mildew of cucumber, the experimental result of wheat powdery mildew
3.1 field tests prevent and treat powdery mildew of cucumber
3.1.1 test method
Experiment in Shandong Pingdu City cucumber, 4 points is investigated per cell, and every is investigated 2 plants, and occurring degree is recorded with staging,
Grade scale is as follows：
0 grade：It is disease-free；
1 grade：Sorus area accounts for less than the 5% of whole leaf area；
3 grades：Sorus area accounts for below the 6%-10% of whole leaf area；
5 grades：Sorus area accounts for below the 11%-20% of whole leaf area；
7 grades：Sorus area accounts for below the 21%-50% of whole leaf area；
9 grades：Sorus area accounts for more than the 50% of whole leaf area.
3.1.2 control time and number
Experiment is investigated 4 times altogether, and radix is investigated before medicine, is investigated within 15 days 7 days after first time medicine, after second 7 days and medicine.
3.1.3 drug effect computational methods
Sick leaf rate (the %)=sick number of sheets/investigation total number of sheets × 100
Disease index=∑ (the sick numbers of sheets at different levels × relative value of series)/(investigation total number of sheets × 9) × 100
Prevention effect (%)=(1- (disease index after disease index × treatment region medicine before blank district medicine)/(blank district
Disease index before disease index × treatment region medicine after medicine)) × 100.
3.1.4 poisoning investigation method
Whether continuous 15d range estimations medicament has poisoning to crop after dispenser.
3.1.5 result of the test and analysis
The effect of each processing preventing and treating powdery mildew of cucumber.(table 2)
Table 2 respectively handles the effect of preventing and treating powdery mildew of cucumber
48% prothioconazoles and fluorobenzene ether amide are with 24 as shown in Table 2:24 ratio composite bactericides control effect for powdery mildew of cucumber
Apparently higher than prothioconazoles and fluorobenzene ether amide single dose, bactericidal effect is incremented by fruit with the increase of dosage.Estimated according to field,
In the range of test dose, plant growth is normal, and each treatment agent does not occur the poisoning phenomenon to cucumber, illustrates it to cucumber
It is safe.It is recommended that the bactericide different from the mechanism of action is used in mixed way to delay the drug-fast generation of germ.
Preventive effect of 3.2 field tests to wheat powdery mildew
3.2.1 experimental field basic condition：
Henan is experimental field located at, selecting the medium wheat paddock of occurring degree, irrigation and drainage are convenient for experimental field, soil fertility is medium.Dispenser
Same day weather is clear to cloudy, 11 DEG C of temperature on average, relative humidity 81%, 2~3 grades of southerly；It is fine day after one week, puts down
Equal 18.2 DEG C of temperature, relative humidity 60%, 2~3 grades of southerly.
3.2.2 spraying time and method
The 1st medicine is sprayed in wheat powdery mildew early stage, second of medicine is sprayed after 10d, sprays altogether 2 times.Carried on the back using 3WBS-16
Negative formula sprayer (0.2~0.3MPa of operating pressure), foliar spray is carried out according to per hectare amount of liquid medicine 750L.
3.2.3 pilot survey and data processing
State of an illness radix is investigated before medicine, experiment is investigated 3 times altogether, i.e., disease index is investigated before medicine, preventive effect investigation in 10 days after the 1st medicine,
10 days and preventive effect investigation in 20 days after 2 medicines.
3.2.4 drug effect computational methods
Sick leaf rate (the %)=sick number of sheets/investigation total number of sheets × 100
Disease index=∑ (the sick numbers of sheets at different levels × relative value of series)/(investigation total number of sheets × 9) × 100
Prevention effect (%)=(1- (disease index after disease index × treatment region medicine before blank district medicine)/(blank district
Disease index before disease index × treatment region medicine after medicine)) × 100.
3.2.5 poisoning investigation method
Whether continuous 7d range estimations medicament has poisoning to crop after dispenser.
3.2.6 experimental result and analysis
The test effect of each group test medicine of table 3 processing preventing and treating wheat powdery mildew
Interpretation of result：
As shown in Table 3,48% prothioconazoles and fluorobenzene ether amide are with 24:The effect of 24 ratio compositional bactericidal agent for preventing and treating wheat powdery mildews
Fruit is than more significant, and the significant effect of complex preparation is better than two kinds of single doses, is estimated according to field, in the range of test dose, makees
Thing growth is normal, and each treatment agent does not occur the poisoning phenomenon to wheat, not only significantly improves the effect for wheat powdery mildew
Fruit, and further extend its lasting period.
In summary, the bactericidal composition of the invention containing prothioconazoles Yu fluorobenzene ether amide, to powdery mildew of cucumber and white wheat
Powder disease has good prevention effect, and it is safe to Target crops.Complex preparation not only increases preventive effect, and expands and kill
Bacterium is composed, so this compounded combination has being of great significance in production practices.
Claims (4)
- A kind of 1. bactericidal composition containing prothioconazoles Yu fluorobenzene ether amide, it is characterised in that：The active ingredient of the bactericidal composition For prothioconazoles and fluorobenzene ether amide binary built, remaining is auxiliary element, wherein active ingredient prothioconazoles and fluorobenzene ether acyl The mass ratio of amine is 1~40: 40~1.
- 2. bactericidal composition according to claim 1, it is characterised in that：Prothioconazoles and fluorobenzene ether amide are in the formulation Gross weight accounts for the 1%~80% of the whole quality of the pharmaceutical preparations.
- 3. bactericidal composition according to claim 2, it is characterised in that：Prothioconazoles and fluorobenzene ether amide are in the formulation Gross weight accounts for the 15%~50% of the whole quality of the pharmaceutical preparations.
- 4. according to the bactericidal composition described in claim 1 or 2 or 3, it is characterised in that：The formulation of the bactericidal composition be missible oil, Suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610308410.1A CN107347892A (en) | 2016-05-10 | 2016-05-10 | A kind of bactericidal composition containing prothioconazoles Yu fluorobenzene ether amide |
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| CN201610308410.1A CN107347892A (en) | 2016-05-10 | 2016-05-10 | A kind of bactericidal composition containing prothioconazoles Yu fluorobenzene ether amide |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113180037A (en) * | 2020-01-14 | 2021-07-30 | 东莞市东阳光菌阳氢专利农药有限公司 | Environment-friendly type fluophenyl ether amide missible oil preparation and preparation method and application thereof |
-
2016
- 2016-05-10 CN CN201610308410.1A patent/CN107347892A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113180037A (en) * | 2020-01-14 | 2021-07-30 | 东莞市东阳光菌阳氢专利农药有限公司 | Environment-friendly type fluophenyl ether amide missible oil preparation and preparation method and application thereof |
| CN113180037B (en) * | 2020-01-14 | 2024-02-02 | 东莞市东阳光菌阳氢专利农药有限公司 | Environment-friendly fluorophenylether amide emulsifiable concentrate preparation as well as preparation method and application thereof |
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Application publication date: 20171117 |
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| WW01 | Invention patent application withdrawn after publication |