CN107345110A - A kind of epoxy zinc rich primer for improving antiseptic property and preparation method thereof - Google Patents

A kind of epoxy zinc rich primer for improving antiseptic property and preparation method thereof Download PDF

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Publication number
CN107345110A
CN107345110A CN201710689038.8A CN201710689038A CN107345110A CN 107345110 A CN107345110 A CN 107345110A CN 201710689038 A CN201710689038 A CN 201710689038A CN 107345110 A CN107345110 A CN 107345110A
Authority
CN
China
Prior art keywords
rich primer
zinc rich
antiseptic property
epoxy zinc
epoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710689038.8A
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Chinese (zh)
Inventor
王占庭
赵云鹏
王辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
Original Assignee
Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
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Filing date
Publication date
Application filed by Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd filed Critical Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
Priority to CN201710689038.8A priority Critical patent/CN107345110A/en
Publication of CN107345110A publication Critical patent/CN107345110A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/106Anti-corrosive paints containing metal dust containing Zn
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of epoxy zinc rich primer for improving antiseptic property and preparation method thereof.Its main constituents and weight proportion are:Epoxy resin 10% 20%, compound thixotropic agent 1% 5%, functional aid 0.1% 0.5%, filler 30% 50%, spherical zinc powder 20% 30%, graphene 0.5% 2%, mixed solvent:10%‑20%.Beneficial effects of the present invention are:Composite primer breaches the conventional epoxy zinc rich primer salt spray resistance limit, and salt-fog resistant time reaches thousands of individual hours, and several times are improved than conventional epoxy zinc rich primer.The antiseptic property of epoxy zinc rich primer is greatly improved, and stores stable be not likely to produce and sinks to the bottom phenomenon.

Description

A kind of epoxy zinc rich primer for improving antiseptic property and preparation method thereof
Technical field
The present invention relates to technical field of coatings, specially a kind of epoxy zinc rich primer for improving antiseptic property and its making side Method.
Background technology
Paint is that a kind of body surface that can firmly be covered in plays protection, decoration, the product of mark, epoxy zinc rich primer conduct Wherein common a paint, it is typically not less than dry film quality using universal, traditional its zinc content of epoxy zinc rich primer 80%, serious deposited phenomenon is easily produced in storage process, is unfavorable for preserving, and in some relatively harsh corrosion ring Applied in border, the anti-corrosion protection phase is limited.
The content of the invention
It is an object of the invention to provide a kind of epoxy zinc rich primer for improving antiseptic property and preparation method thereof.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of epoxy zinc rich primer for improving antiseptic property, its main constituents and weight proportion are:Epoxy resin 10%- 20%, compound thixotropic agent 1%-5%, functional aid 0.1%-0.5%, filler 30%-50%, spherical zinc powder 20%-30%, graphene 0.5%-2%, mixed solvent:10%-20%.
Preferably, the main constituents of the compound thixotropic agent are:, castor oil modified derivative, organically-modified swelling Soil and polyamide shine wax liquor.
Preferably, the main constituents of the double solvents are:Aromatic hydrocarbon solvent, alcohols solvent are and ketones solvent Mixed solvent.
A kind of preparation method for the epoxy zinc rich primer for improving antiseptic property, it is mainly included the following steps that:
(1)Stock:Epoxy resin, compound thixotropic agent, functional aid, filler, spherical zinc powder, graphene and mixed solvent are pressed Stock of weighing is carried out according to above-mentioned weight proportion;
(2)Batch mixing material:Mixed solvent is added in container, is slow added into functional aid, filler, spherical zinc powder, graphite Alkene, stir in a reservoir, mixing time is not less than 1 hour, is slow added into epoxy resin, compound thixotropic agent, during stirring Between be not less than 30 minutes, final mixture is ground to the paint of specified fineness requirement;
(3)Performance test:From the cold-reduced sheet that specification is 15mm × 7.5mm × 3mm, sprayed according to GB/T8923.1-2011 Sand processing, surface state to sa2.5 levels, paint film coating thickness are(19±10)Um, meeting bar as defined in GB/T9278-2008 Salt-fog resistant test is carried out after part maintenance 10d, test result is:Unilateral corrosion≤2.0mm at cut, non-scored area bubble-free, Phenomena such as getting rusty, ftracture, peeling off;
(4)Finished product packing:Step will be passed through(3)The coating of performance test carries out finished product packing.
The beneficial effects of the invention are as follows:Composite primer breaches the conventional epoxy zinc rich primer salt spray resistance limit, during salt spray resistance Between reach thousands of individual hours, than conventional epoxy zinc rich primer improve several times.The antiseptic property of epoxy zinc rich primer is greatly improved, And stable be not likely to produce of storage sinks to the bottom phenomenon.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects Enclose.
A kind of epoxy zinc rich primer for improving antiseptic property, its main constituents and weight proportion are:Epoxy resin 10%-20%, compound thixotropic agent 1%-5%, functional aid 0.1%-0.5%, filler 30%-50%, spherical zinc powder 20%-30%, graphite Alkene 0.5%-2%, mixed solvent:10%-20%.
For further optimisation technique scheme, the main constituents of the compound thixotropic agent are:, castor oil modified derivative Thing, organic modified bentonite and polyamide shine wax liquor.
For further optimisation technique scheme, the main constituents of the double solvents are:Aromatic hydrocarbon solvent, alcohols are molten Agent is the mixed solvent with ketones solvent.
A kind of preparation method for the epoxy zinc rich primer for improving antiseptic property, it is mainly included the following steps that:
(1)Stock:Epoxy resin, compound thixotropic agent, functional aid, filler, spherical zinc powder, graphene and mixed solvent are pressed Stock of weighing is carried out according to above-mentioned weight proportion;
(2)Batch mixing material:Mixed solvent is added in container, is slow added into functional aid, filler, spherical zinc powder, graphite Alkene, stir in a reservoir, mixing time is not less than 1 hour, is slow added into epoxy resin, compound thixotropic agent, during stirring Between be not less than 30 minutes, final mixture is ground to the paint of specified fineness requirement;
(3)Performance test:From the cold-reduced sheet that specification is 15mm × 7.5mm × 3mm, sprayed according to GB/T8923.1-2011 Sand processing, surface state to sa2.5 levels, paint film coating thickness are(19±10)Um, meeting bar as defined in GB/T9278-2008 Salt-fog resistant test is carried out after part maintenance 10d, test result is:Unilateral corrosion≤2.0mm at cut, non-scored area bubble-free, Phenomena such as getting rusty, ftracture, peeling off;
(4)Finished product packing:Step will be passed through(3)The coating of performance test carries out finished product packing.
Embodiment 1:
A kind of epoxy zinc rich primer for improving antiseptic property, its main constituents and weight proportion are:Epoxy resin 20%, it is multiple Close thixotropic agent 5%, functional aid 0.3%, filler 40%, spherical zinc powder 23%, graphene 0.7%, mixed solvent:11%.
Embodiment 2:
A kind of epoxy zinc rich primer for improving antiseptic property, its main constituents and weight proportion are:Epoxy resin 18%, it is multiple Close thixotropic agent 4%, functional aid 0.4%, filler 35%, spherical zinc powder 26%, graphene 0.6%, mixed solvent:18%.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still may be used To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic, Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in the present invention's Within protection domain.

Claims (4)

  1. A kind of 1. epoxy zinc rich primer for improving antiseptic property, it is characterised in that:Its main constituents and weight proportion are:Ring Oxygen tree fat 10%-20%, compound thixotropic agent 1%-5%, functional aid 0.1%-0.5%, filler 30%-50%, spherical zinc powder 20%- 30%, graphene 0.5%-2%, mixed solvent:10%-20%.
  2. 2. a kind of epoxy zinc rich primer for improving antiseptic property according to claim 1, it is characterised in that described compound tactile Become agent main constituents into:, castor oil modified derivative, organic modified bentonite and polyamide shine wax liquor.
  3. 3. a kind of epoxy zinc rich primer for improving antiseptic property according to claim 1, main group of the double solvents It is into composition:Aromatic hydrocarbon solvent, alcohols solvent are and the mixed solvent of ketones solvent.
  4. 4. a kind of preparation method for the epoxy zinc rich primer for improving antiseptic property, it is characterised in that it is mainly included the following steps that:
    (1)Stock:Epoxy resin, compound thixotropic agent, functional aid, filler, spherical zinc powder, graphene and mixed solvent are pressed Stock of weighing is carried out according to above-mentioned weight proportion;
    (2)Batch mixing material:Mixed solvent is added in container, is slow added into functional aid, filler, spherical zinc powder, graphite Alkene, stir in a reservoir, mixing time is not less than 1 hour, is slow added into epoxy resin, compound thixotropic agent, during stirring Between be not less than 30 minutes, final mixture is ground to the paint of specified fineness requirement;
    (3)Performance test:From the cold-reduced sheet that specification is 15mm × 7.5mm × 3mm, sprayed according to GB/T8923.1-2011 Sand processing, surface state to sa2.5 levels, paint film coating thickness are(19±10)Um, meeting bar as defined in GB/T9278-2008 Salt-fog resistant test is carried out after part maintenance 10d, test result is:Unilateral corrosion≤2.0mm at cut, non-scored area bubble-free, Phenomena such as getting rusty, ftracture, peeling off;
    (4)Finished product packing:Step will be passed through(3)The coating of performance test carries out finished product packing.
CN201710689038.8A 2017-08-13 2017-08-13 A kind of epoxy zinc rich primer for improving antiseptic property and preparation method thereof Pending CN107345110A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710689038.8A CN107345110A (en) 2017-08-13 2017-08-13 A kind of epoxy zinc rich primer for improving antiseptic property and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710689038.8A CN107345110A (en) 2017-08-13 2017-08-13 A kind of epoxy zinc rich primer for improving antiseptic property and preparation method thereof

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CN107345110A true CN107345110A (en) 2017-11-14

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108070310A (en) * 2017-12-10 2018-05-25 中海油常州涂料化工研究院有限公司 A kind of graphene is modified zinc powder anti-corrosion primer and preparation method thereof
CN109971230A (en) * 2017-12-27 2019-07-05 江南石墨烯研究院 A kind of the highway facilities low zinc anticorrosive paint of environment-friendly type graphene and preparation method
CN112194959A (en) * 2020-09-30 2021-01-08 浙江中泓新材料科技有限公司 Epoxy anticorrosive primer and production process thereof
CN115707745A (en) * 2021-08-18 2023-02-21 中山市珉和化工科技有限公司 Low-odor aerosol paint and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103173095A (en) * 2013-03-06 2013-06-26 常州第六元素材料科技股份有限公司 Zinc-rich epoxy anticorrosion paint and preparation method thereof
CN105400374A (en) * 2015-12-21 2016-03-16 深圳市嘉达高科产业发展有限公司 Anticorrosive coating and preparation method thereof
CN105505110A (en) * 2015-12-15 2016-04-20 深圳市嘉达高科产业发展有限公司 Graphene-coated galvanized anticorrosive paint and preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103173095A (en) * 2013-03-06 2013-06-26 常州第六元素材料科技股份有限公司 Zinc-rich epoxy anticorrosion paint and preparation method thereof
CN105086758A (en) * 2013-03-06 2015-11-25 常州第六元素材料科技股份有限公司 Preparation method of graphene anticorrosive paint
CN105505110A (en) * 2015-12-15 2016-04-20 深圳市嘉达高科产业发展有限公司 Graphene-coated galvanized anticorrosive paint and preparation method
CN105400374A (en) * 2015-12-21 2016-03-16 深圳市嘉达高科产业发展有限公司 Anticorrosive coating and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108070310A (en) * 2017-12-10 2018-05-25 中海油常州涂料化工研究院有限公司 A kind of graphene is modified zinc powder anti-corrosion primer and preparation method thereof
CN109971230A (en) * 2017-12-27 2019-07-05 江南石墨烯研究院 A kind of the highway facilities low zinc anticorrosive paint of environment-friendly type graphene and preparation method
CN112194959A (en) * 2020-09-30 2021-01-08 浙江中泓新材料科技有限公司 Epoxy anticorrosive primer and production process thereof
CN115707745A (en) * 2021-08-18 2023-02-21 中山市珉和化工科技有限公司 Low-odor aerosol paint and preparation method thereof

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