CN107345109A - A kind of novel anticorrosion environmental protection priming paint - Google Patents

A kind of novel anticorrosion environmental protection priming paint Download PDF

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Publication number
CN107345109A
CN107345109A CN201710689033.5A CN201710689033A CN107345109A CN 107345109 A CN107345109 A CN 107345109A CN 201710689033 A CN201710689033 A CN 201710689033A CN 107345109 A CN107345109 A CN 107345109A
Authority
CN
China
Prior art keywords
parts
polyamide
powder
environmental protection
priming paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710689033.5A
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Chinese (zh)
Inventor
唐品章
孙庆兵
姜阀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
Original Assignee
Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd filed Critical Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
Priority to CN201710689033.5A priority Critical patent/CN107345109A/en
Publication of CN107345109A publication Critical patent/CN107345109A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/106Anti-corrosive paints containing metal dust containing Zn
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of novel anticorrosion environmental protection priming paint.Its main constituents and weight proportion are:0.3 0.5 parts of 10.5 12 parts of epoxy resin, electroneutral polyamide and polyester mixture, 58 parts of talcum powder, 12 15 parts of blanc fixe, 25 30 parts of ferrophosphorus powder, 20 25 parts of spherical zinc powder, 0.5 1 parts of graphene, castor oil modified 0.1 0.2 parts of derivative, 1.5 2 parts of organic modified bentonite, polyamide shine 12 parts of wax liquor, polyamide-based 20 22 parts of curing agent, 58 parts of aromatic hydrocarbon solvent, 3 4.5 parts of alcohols solvent.Beneficial effects of the present invention are:Composite primer breaches the conventional epoxy zinc rich primer salt spray resistance limit, and salt-fog resistant time reaches thousands of individual hours, and several times are improved than conventional epoxy zinc rich primer.The antiseptic property of epoxy zinc rich primer is greatly improved, and stores stable be not likely to produce and sinks to the bottom phenomenon.

Description

A kind of novel anticorrosion environmental protection priming paint
Technical field
The present invention relates to technical field of coatings, specially a kind of novel anticorrosion environmental protection priming paint.
Background technology
Paint is that a kind of body surface that can firmly be covered in plays protection, decoration, the product of mark, epoxy zinc rich primer conduct Wherein common a paint, it is typically not less than dry film quality using universal, traditional its zinc content of epoxy zinc rich primer 80%, serious deposited phenomenon is easily produced in storage process, is unfavorable for preserving, and in some relatively harsh corrosion ring Applied in border, the anti-corrosion protection phase is limited.
The content of the invention
It is an object of the invention to provide a kind of novel anticorrosion environmental protection priming paint, for solving the above problems.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of novel anticorrosion environmental protection priming paint, its main constituents and weight proportion are:Epoxy resin 10.5-12 parts, electroneutral Polyamide and polyester mixture 0.3-0.5 parts, talcum powder 5-8 parts, blanc fixe 12-15 parts, ferrophosphorus powder 25-30 parts are spherical Zinc powder 20-25 parts, graphene 0.5-1 parts, castor oil modified derivative 0.1-0.2 parts, organic modified bentonite 1.5-2 parts, gather Acid amides shines wax liquor 1-2 parts, polyamide-based curing agent 20-22 parts, aromatic hydrocarbon solvent 5-8 parts, alcohols solvent 3-4.5 parts.
A kind of preparation method of novel anticorrosion environmental protection priming paint, it is mainly included the following steps that:
(1)Stock:The main constituents of novel anticorrosion environmental protection priming paint are subjected to stock of weighing according to above-mentioned weight proportion;
(2)Batch mixing material:Aromatic hydrocarbon solvent is sequentially added in container, alcohols solvent is and ketones solvent is mixed, then delay Slow addition electroneutral polyamide and polyester mixture, talcum powder, blanc fixe, ferrophosphorus powder, spherical zinc powder, graphene are holding Stirred in device, mixing time is not less than 1 hour, is slow added into epoxy resin, castor oil modified derivative, organically-modified Bentonite and polyamide shine wax liquor, and mixing time is not less than 30 minutes, final mixture is ground to specified fineness requirement Paint;
(3)Performance test:From the cold-reduced sheet that specification is 15mm × 7.5mm × 3mm, sprayed according to GB/T8923.1-2011 Sand processing, surface state to sa2.5 levels, paint film coating thickness are(19±10)Um, meeting bar as defined in GB/T9278-2008 Salt-fog resistant test is carried out after part maintenance 10d, test result is:Unilateral corrosion≤2.0mm at cut, non-scored area bubble-free, Phenomena such as getting rusty, ftracture, peeling off;
(4)Finished product packing:Step will be passed through(3)The coating of performance test carries out finished product packing.
The beneficial effects of the invention are as follows:Composite primer breaches the conventional epoxy zinc rich primer salt spray resistance limit, during salt spray resistance Between reach thousands of individual hours, than conventional epoxy zinc rich primer improve several times.The antiseptic property of epoxy zinc rich primer is greatly improved, And stable be not likely to produce of storage sinks to the bottom phenomenon.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects Enclose.
A kind of novel anticorrosion environmental protection priming paint, epoxy resin 10.5-12 parts, electroneutral polyamide and polyester mixture 0.3- 0.5 part, talcum powder 5-8 parts, blanc fixe 12-15 parts, ferrophosphorus powder 25-30 parts, spherical zinc powder 20-25 parts, graphene 0.5-1 Part, castor oil modified derivative 0.1-0.2 parts, organic modified bentonite 1.5-2 parts, polyamide solarization wax liquor 1-2 parts, polyamide Class curing agent 20-22 parts, aromatic hydrocarbon solvent 5-8 parts, alcohols solvent 3-4.5 parts.
A kind of preparation method of novel anticorrosion environmental protection priming paint, it is mainly included the following steps that:
(1)Stock:The main constituents of novel anticorrosion environmental protection priming paint are subjected to stock of weighing according to above-mentioned weight proportion;
(2)Batch mixing material:Aromatic hydrocarbon solvent is sequentially added in container, alcohols solvent is and ketones solvent is mixed, then delay Slow addition electroneutral polyamide and polyester mixture, talcum powder, blanc fixe, ferrophosphorus powder, spherical zinc powder, graphene are holding Stirred in device, mixing time is not less than 1 hour, is slow added into epoxy resin, castor oil modified derivative, organically-modified Bentonite and polyamide shine wax liquor, and mixing time is not less than 30 minutes, final mixture is ground to specified fineness requirement Paint;
(3)Performance test:From the cold-reduced sheet that specification is 15mm × 7.5mm × 3mm, sprayed according to GB/T8923.1-2011 Sand processing, surface state to sa2.5 levels, paint film coating thickness are(19±10)Um, meeting bar as defined in GB/T9278-2008 Salt-fog resistant test is carried out after part maintenance 10d, test result is:Unilateral corrosion≤2.0mm at cut, non-scored area bubble-free, Phenomena such as getting rusty, ftracture, peeling off;
(4)Finished product packing:Step will be passed through(3)The coating of performance test carries out finished product packing.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still may be used To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic, Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in the present invention's Within protection domain.

Claims (2)

1. a kind of novel anticorrosion environmental protection priming paint, it is characterised in that its main constituents and weight proportion are:Epoxy resin 10.5-12 parts, electroneutral polyamide and polyester mixture 0.3-0.5 parts, talcum powder 5-8 parts, blanc fixe 12-15 parts, phosphorus Iron powder 25-30 parts, spherical zinc powder 20-25 parts, graphene 0.5-1 parts, castor oil modified derivative 0.1-0.2 parts are organically-modified Bentonite 1.5-2 parts, polyamide solarization wax liquor 1-2 parts, polyamide-based curing agent 20-22 parts, aromatic hydrocarbon solvent 5-8 parts, alcohols are molten Agent 3-4.5 parts.
2. a kind of preparation method of novel anticorrosion environmental protection priming paint, it is characterised in that it is mainly included the following steps that:
(1)Stock:The main constituents of novel anticorrosion environmental protection priming paint are subjected to stock of weighing according to above-mentioned weight proportion;
(2)Batch mixing material:Aromatic hydrocarbon solvent is sequentially added in container, alcohols solvent is and ketones solvent is mixed, then delay Slow addition electroneutral polyamide and polyester mixture, talcum powder, blanc fixe, ferrophosphorus powder, spherical zinc powder, graphene are holding Stirred in device, mixing time is not less than 1 hour, is slow added into epoxy resin, castor oil modified derivative, organically-modified Bentonite and polyamide shine wax liquor, and mixing time is not less than 30 minutes, final mixture is ground to specified fineness requirement Paint;
(3)Performance test:From the cold-reduced sheet that specification is 15mm × 7.5mm × 3mm, sprayed according to GB/T8923.1-2011 Sand processing, surface state to sa2.5 levels, paint film coating thickness are(19±10)Um, meeting bar as defined in GB/T9278-2008 Salt-fog resistant test is carried out after part maintenance 10d, test result is:Unilateral corrosion≤2.0mm at cut, non-scored area bubble-free, Phenomena such as getting rusty, ftracture, peeling off;
(4)Finished product packing:Step will be passed through(3)The coating of performance test carries out finished product packing.
CN201710689033.5A 2017-08-13 2017-08-13 A kind of novel anticorrosion environmental protection priming paint Pending CN107345109A (en)

Priority Applications (1)

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CN201710689033.5A CN107345109A (en) 2017-08-13 2017-08-13 A kind of novel anticorrosion environmental protection priming paint

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Application Number Priority Date Filing Date Title
CN201710689033.5A CN107345109A (en) 2017-08-13 2017-08-13 A kind of novel anticorrosion environmental protection priming paint

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CN107345109A true CN107345109A (en) 2017-11-14

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109971230A (en) * 2017-12-27 2019-07-05 江南石墨烯研究院 A kind of the highway facilities low zinc anticorrosive paint of environment-friendly type graphene and preparation method
CN110878184A (en) * 2019-10-15 2020-03-13 浙江衢州贝利德涂料有限公司 Graphene modified epoxy zinc-rich primer and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105623473A (en) * 2016-03-25 2016-06-01 信和新材料股份有限公司 Zinc-containing graphene anti-corrosive primer based on graphene dispersoid

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105623473A (en) * 2016-03-25 2016-06-01 信和新材料股份有限公司 Zinc-containing graphene anti-corrosive primer based on graphene dispersoid

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109971230A (en) * 2017-12-27 2019-07-05 江南石墨烯研究院 A kind of the highway facilities low zinc anticorrosive paint of environment-friendly type graphene and preparation method
CN110878184A (en) * 2019-10-15 2020-03-13 浙江衢州贝利德涂料有限公司 Graphene modified epoxy zinc-rich primer and preparation method thereof

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Application publication date: 20171114

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