CN107345082A - It is a kind of that there is the reactive dye compound for washing function of missing old times or old friends - Google Patents
It is a kind of that there is the reactive dye compound for washing function of missing old times or old friends Download PDFInfo
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- CN107345082A CN107345082A CN201610298241.8A CN201610298241A CN107345082A CN 107345082 A CN107345082 A CN 107345082A CN 201610298241 A CN201610298241 A CN 201610298241A CN 107345082 A CN107345082 A CN 107345082A
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- Prior art keywords
- formula
- old
- reactive dye
- dye compound
- missing
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/004—Mixtures of two or more reactive dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
- C09B67/0052—Mixtures of two or more reactive monoazo dyes
- C09B67/0054—Mixtures of two or more reactive monoazo dyes all the reactive groups not being directly attached to a heterocyclic system
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of reactive dye compound for having and washing function of missing old times or old friends, the mixing face and auxiliary agent that the reactive dye compound is made up of a variety of pigment components form, from glauber salt and nonionic surfactant as auxiliary agent, after physical mixed processing being carried out using mixer or dyestuff special equipment, it is high with a kind of washing fastness is made after mixer or professional equipment combination drying, it is small using difficulty, the environment-friendly active dyestuff of the high function of missing old times or old friends with washing of dyeing one-time success rate, solve the problems, such as that current active black can not make ready-made clothes nostalgic effect, solves tradition directly, the problem of insurmountable environmental issue of sulfur dye and poor color fastness.
Description
Technical field
It is more particularly to a kind of that there is the reactive dye compound for washing function of missing old times or old friends the present invention relates to dye field.
Background technology
More focus on quality in Aesthetical Viewpoint on Modern Fashion Design with fashion, nature with the unification of ecology with merging.The restructuring of traditional classical element
Or the sincerity of missing old times or old friends that reconstruction embodies is favored by more and more people.Nostalgic effect no longer stays in the stimulation of vision, but
More focus on the experience of comfort, emphasize fuzzy and dim effect, the colour fading sense after washing slightly thoroughly goes out a kind of soft matter
The implicit noble sense of Piao.
Present jeans, garment dyeing, the oxidation using potassium permanganate and acid, and oxygen are needed after piece dyeing
Reduction neutralization after change so that clothing color turn white and reach the effect missed old times or old friends i.e. by be commonly called as frying snowflake, hydro-peening,
The methods of doing cat's whisker is to make the effect missed old times or old friends.Prior art is carried out dyeing and is reached water using sulfur dye or direct dyes more
Wash nostalgic effect, Publication No.CN101481880Chinese invention patent disclose it is a kind of using a kind of bosom of sulfur dyeing production
The method of old ecological cotton, fiber crops and its blended yarn weaved fabric.Publication No.CN103510409AChinese invention patent application disclose one kind
The method that direct dyeing produces woollen sweater of missing old times or old friends.
Although direct dyes and sulfur dyeing can reach washing nostalgic effect, because direct dyes and sulfur dye are
Organic dyestuff, substantial amounts of organic volatile being had in dyeing course and is come out, dyeing product also can be for some time organic waves
Stimulating food distributes, and has not met the green theme in the world today；Direct dyes and sulfur dye are turned into using alkali soluble solution
Water miscible ionic condition and be colored main body absorption, rather than actively infiltration is dyed, so it has washing fastness
Difference, the problem of stain utilization rate is low.
There is a kind of reactive black dye on the market at present, it can reach requirement, but nothing at washing fastness, green aspect
Needs fry snowflake, hydro-peening, do cat's whisker etc. to make the requirement of the whiteness for the effect missed old times or old friends after method meets garment dyeing.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of high, green, function of missing old times or old friends with washing the activity of washing fastness
Dye composite.
In order to solve the above-mentioned technical problem, the technical scheme is that：It is a kind of that there is the reactive dye combination for washing function of missing old times or old friends
Thing.As the pigment component shown in formula (1), and two kinds of 3 kinds of pigment components shown in formula (2), formula (3), formula (4)
Or hybrid pigment and the auxiliary agent composition of a variety of compositions.
Preferably, four kinds of pigment component parts by weight are as follows：
Formula (1) represent pigment component be：5-40 parts；
Formula (2) represent pigment component be：10-40 parts
Formula (3) represent pigment component be：10-45 parts
Formula (4) represent pigment component be：5-35 parts.
Preferably, auxiliary agent is glauber salt (anhydrous sodium sulfate) and nonionic surfactant.
Preferably, the ratio that auxiliary agent accounts for reactive dye compound is 50%-75%.
Preferably, the preparation method for washing the reactive dye compound for function of missing old times or old friends is that each component reactive dye are normal using this area
Processing method, mixed by certain weight, glauber salt and nonionic surfactant are taken as auxiliary agent, with stirring
Machine or dyestuff special equipment carry out physical mixed processing, with obtain powdered after mixer or professional equipment combination drying,
Graininess black mixture, a kind of reactive dye compound for having and washing function of missing old times or old friends is made.
Compared with prior art, it is using the advantages of above-mentioned technical proposal：1st, it is green, meet OEKO-TEX100 environmental protection
It is required that；2nd, can fry it is white, fry snowflake, monkey wash and do various cowboys, garment dye water washing technology；3rd, there is excellent Exposure to Sunlight
Fastness and washing fastness, solve well existing using fastness difference existing for direct dyes, sulfur dye, pigment dyeing
Problem；4th, solve the problems, such as that existing active black can not do water washing technology.
Embodiment
The embodiment of the present invention is described further below.Herein it should be noted that for these embodiments
Illustrate to be used to help understand the present invention, but do not form limitation of the invention.In addition, each reality of invention described below
It is mutually combined as long as applying technical characteristic involved in mode and not forming conflict can each other.
Embodiment one：
It is a kind of that there is the reactive dye compound for washing function of missing old times or old friends.As 3 kinds of pigment shown in formula (1), formula (2), formula (3)
The hybrid pigment and auxiliary agent composition of component synthesis.
Three kinds of pigment component parts by weight are as follows：
Formula (1) represent pigment component be：35 parts
Formula (2) represent pigment component be：30 parts
Formula (3) represent pigment component be：45 parts
Wherein, auxiliary agent is glauber salt (anhydrous sodium sulfate) and nonionic surfactant.Auxiliary agent accounts for the ratio of reactive dye compound
Example is 50%.
The pigment component that formula (1), formula (2), formula (3) represent is used into processing method commonly used in the art, by certain weight
Mixed, take glauber salt and non-surface-active agent to be carried out as auxiliary agent with mixer or dyestuff special equipment at physical mixed
Reason processing, with obtain powdered after mixer or professional equipment combination drying, graininess black mixture, obtained one kind has
Wash the reactive dye for function of missing old times or old friends.
Embodiment two：
It is a kind of that there is the reactive dye compound for washing function of missing old times or old friends.As shown in formula (1), formula (2), formula (3), formula (4)
The hybrid pigment and auxiliary agent composition of 4 kinds of pigment component synthesis.
Four kinds of pigment component parts by weight are as follows：
Formula (1) represent pigment component be：30 parts
Formula (2) represent pigment component be：20 parts
Formula (3) represent pigment component be：50 parts
Formula (4) represent pigment component be：20 parts
Wherein, auxiliary agent is glauber salt (anhydrous sodium sulfate) and nonionic surfactant.Auxiliary agent accounts for the ratio of reactive dye compound
Example is 60%.
The pigment component that formula (1), formula (2), formula (3), formula (4) represent is used into processing method commonly used in the art, by certain
Weight mixed, take glauber salt and non-surface-active agent to carry out physics with mixer or dyestuff special equipment as auxiliary agent
Mixed processing process, with obtain powdered after mixer or professional equipment combination drying, graininess black mixture, be made one
Kind is with the reactive dye for washing function of missing old times or old friends.
Embodiment three：
It is a kind of that there is the reactive dye compound for washing function of missing old times or old friends.As shown in formula (1), formula (2), formula (3), formula (4)
The hybrid pigment and auxiliary agent composition of 4 kinds of pigment component synthesis.
Four kinds of pigment component parts by weight are as follows：
Formula (1) represent pigment component be：35 parts
Formula (2) represent pigment component be：30 parts
Formula (3) represent pigment component be：30 parts
Formula (4) represent pigment component be：0 part
Wherein, auxiliary agent is glauber salt (anhydrous sodium sulfate) and nonionic surfactant.Auxiliary agent accounts for the ratio of reactive dye compound
Example is 75%.
The pigment component that formula (1), formula (2), formula (3), formula (4) represent will be used processing method commonly used in the art, by one
Fixed weight is mixed, and takes glauber salt and non-surface-active agent to carry out thing with mixer or dyestuff special equipment as auxiliary agent
Manage mixed processing processing, with obtain powdered after mixer or professional equipment combination drying, graininess black mixture, be made
It is a kind of that there are the reactive dye for washing function of missing old times or old friends.
Embodiments of the present invention are explained in detail above, but the invention is not restricted to described embodiment.For ability
For the technical staff in domain, do not depart from the principle of the invention and spirit in the case of, to these embodiments carry out it is a variety of change,
Modification, replacement and modification, still fall within protection scope of the present invention.
Claims (5)
1. a kind of have the reactive dye compound for washing function of missing old times or old friends, it is characterised in that：As the pigment component shown in formula (1),
And the mixed dye and auxiliary agent composition of two or more compositions of 3 kinds of pigment components shown in formula (2), formula (3), formula (4).
2. a kind of according to claim 1 have the reactive dye compound for washing function of missing old times or old friends, it is characterised in that：Four kinds of face
Expect that ingredients weight parts are as follows：
Formula (1) represent pigment component be：5-40 parts；
Formula (2) represent pigment component be：10-40 parts
Formula (3) represent pigment component be：10-45 parts
Formula (4) represent pigment component be：5-35 parts.
3. a kind of according to claim 1 have the reactive dye compound for washing function of missing old times or old friends, it is characterised in that：It is used to help
Agent is anhydrous sodium sulfate and nonionic surfactant.
4. a kind of according to claim 1 have the reactive dye compound for washing function of missing old times or old friends, it is characterised in that：It is used to help
The ratio that agent accounts for reactive dye compound is 50%-75%.
5. a kind of according to claim 1 have the reactive dye compound for washing function of missing old times or old friends, it is characterised in that：Preparation side
Method is to use processing method commonly used in the art, physical mixed processing is carried out with mixer or dyestuff special equipment, with stirring
Machine or professional equipment carry out combination drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610298241.8A CN107345082A (en) | 2016-05-05 | 2016-05-05 | It is a kind of that there is the reactive dye compound for washing function of missing old times or old friends |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610298241.8A CN107345082A (en) | 2016-05-05 | 2016-05-05 | It is a kind of that there is the reactive dye compound for washing function of missing old times or old friends |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107345082A true CN107345082A (en) | 2017-11-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610298241.8A Pending CN107345082A (en) | 2016-05-05 | 2016-05-05 | It is a kind of that there is the reactive dye compound for washing function of missing old times or old friends |
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| Country | Link |
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| CN (1) | CN107345082A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01315469A (en) * | 1988-03-24 | 1989-12-20 | Mitsubishi Kasei Corp | Mixture of reactive black dyestuff |
| US5071442A (en) * | 1990-01-09 | 1991-12-10 | Ciba-Geigy Corporation | Process for dyeing or printing cellulosic textile fibre material by the trichromatic technique: reactive dyes |
| JPH07196940A (en) * | 1994-01-06 | 1995-08-01 | Mitsubishi Kasei Hoechst Kk | Reactive dye composition and dyeing method |
| JPH07278461A (en) * | 1994-04-13 | 1995-10-24 | Mitsubishi Kasei Hoechst Kk | Reactive dye composition |
| CN1478133A (en) * | 2000-12-22 | 2004-02-25 | 德意志戴斯达纺织品及染料两合公司 | Black dye mixtures of fibre-reactive azo dyes and use thereof for dyeing fibre material containing hydroxy and/or carbonamide groups |
| JP2006045448A (en) * | 2004-08-09 | 2006-02-16 | Sumitomo Chemical Co Ltd | Reactive dye composition, and method for dyeing or printing with the composition |
| CN102115612A (en) * | 2009-12-30 | 2011-07-06 | 上海雅运纺织化工有限公司 | Dark blue active dye composition and application thereof in dyeing fibers |
-
2016
- 2016-05-05 CN CN201610298241.8A patent/CN107345082A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01315469A (en) * | 1988-03-24 | 1989-12-20 | Mitsubishi Kasei Corp | Mixture of reactive black dyestuff |
| US5071442A (en) * | 1990-01-09 | 1991-12-10 | Ciba-Geigy Corporation | Process for dyeing or printing cellulosic textile fibre material by the trichromatic technique: reactive dyes |
| JPH07196940A (en) * | 1994-01-06 | 1995-08-01 | Mitsubishi Kasei Hoechst Kk | Reactive dye composition and dyeing method |
| JPH07278461A (en) * | 1994-04-13 | 1995-10-24 | Mitsubishi Kasei Hoechst Kk | Reactive dye composition |
| CN1478133A (en) * | 2000-12-22 | 2004-02-25 | 德意志戴斯达纺织品及染料两合公司 | Black dye mixtures of fibre-reactive azo dyes and use thereof for dyeing fibre material containing hydroxy and/or carbonamide groups |
| JP2006045448A (en) * | 2004-08-09 | 2006-02-16 | Sumitomo Chemical Co Ltd | Reactive dye composition, and method for dyeing or printing with the composition |
| CN102115612A (en) * | 2009-12-30 | 2011-07-06 | 上海雅运纺织化工有限公司 | Dark blue active dye composition and application thereof in dyeing fibers |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20171114 |