CN107337444A - Beautiful energy porcelain - Google Patents

Beautiful energy porcelain Download PDF

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Publication number
CN107337444A
CN107337444A CN201710492000.1A CN201710492000A CN107337444A CN 107337444 A CN107337444 A CN 107337444A CN 201710492000 A CN201710492000 A CN 201710492000A CN 107337444 A CN107337444 A CN 107337444A
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beautiful
composition
jade
energy porcelain
mud
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李贺文
邱成春
李佳儒
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Tangshan Li Xiongfeng Converges Material Science And Technology Ltd
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Tangshan Li Xiongfeng Converges Material Science And Technology Ltd
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Priority to CN201710492000.1A priority Critical patent/CN107337444A/en
Publication of CN107337444A publication Critical patent/CN107337444A/en
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

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  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
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  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

Beautiful energy porcelain of the invention, is related to ceramic fabrication technique field, more particularly to a kind of close former beautiful ceramic of physical and chemical composition.It is characterized in that mainly by Xiuyan Jade 7 9%, dushan diopside 6 8%, wood grain jade 8 10%, tourmaline 11 14%, obsidian 5 7%, Huanglong's jade 5 7%, feldspar 11 13%, rectorite 8 10%, 4 6% etc. form in temple Figure 10 12%, Longyan clay 9 11%, zeolite 5 7%, medical stone 9 10%, crystal quartz.The present invention has permanent radiation negative oxygen ion and far infrared, breaks the present situation that existing domestic ceramics is inorganic ceramic, is 0 to leaching ability of heavy metal amounts such as human body beneficial mineral matter composition, lead, cadmiums rich in calcium, magnesium, potassium, sodium, iron etc..

Description

Beautiful energy porcelain
Technical field
Beautiful energy porcelain of the invention, is related to ceramic fabrication technique field, pure more particularly to one kind based on beautiful matter mineral material Supplemented by natural function mineral, using its natural energy, science mixture, is allowed to performance superposition and producing one kind can discharge for a long time The ceramic ware for daily use of negative oxygen ion and far infrared.
Technical background：
The domestic porcelain product that domestic ceramics in the market is circulated at present such as clay ceramics, shellfish porcelain, magnesium paper porcelain, Bone China etc. Traditional ceramics material is limited only to the making of silicate mineral, all practical ceramics, and does not possess any additional work( Energy.
The content of the invention：
Beautiful energy porcelain purpose of the invention is change domestic ceramics unicity, and which employs brand-new ceramic formula, adds five Kind above prepared from natural jade mineral fine powder, using its superimposion principle with traditional ceramics materials, allocated in accurate ratio, make production Product possess the distinct energy of natural jade and ultimate attainment performance, while natural nano-mineral material is additionally added in this formula and is had natural The multiple aperture raw mineral materials of the title of molecular sieve, organically combined with natural minerals composition, realize brand-new natural material formula group Close, thoroughly overturned traditional ceramics concept, do not add any industrial chemicals, and processed by fine technique, create one The new porcelain kind that can radiate negative oxygen ion and far infrared for a long time of natural health.
The realization of beautiful energy porcelain of the invention, by the repetition test to compositing formula, is obtaining outside beautiful mass-energy amount, is having radiation Negative oxygen ion and the beautiful of far infrared function can porcelain.Specifically, the beautiful energy porcelain of the present invention, it is characterised in that mainly by Xiuyan Jade 7- 9%th, dushan diopside 6-8%, wood grain jade 8-10%, tourmaline 11-14%, obsidian 5-7%, Huanglong jade 5-7%, feldspar 11- 13%th, rectorite 8-10%, in temple Figure 10-12%, Longyan clay 9-11%, zeolite 5-7%, medical stone 9-10%, crystal quartz 4-6% etc. is formed.
In the present invention：
Xiuyan Jade：Quality is solid gentle, and exquisiteness circle melts, and more than 30 kinds of selenium, zinc, cobalt, manganese, magnesium, calcium containing needed by human body etc. is to people The beneficial trace element of body, spectral measurement analysis shows, its special molecular structure transmitting absorbent far infrared electromagnetism of human body Ripple, wavelength 8-10um, crest is at 9.9um.
Dushan diopside：Beautiful matter is tough and tensile micro- close, fine and smooth soft and moist, chemical composition category calc-aluminosilicate rock class, Sio2Content 45-52% is rich Tio2, also containing micro copper, nickel, manganese etc..
Wood grain jade：1173/scm of raw ore generating negative ions amount3, far infrared wavelength 8-15um, the noble metal containing a large amount The biological electricity of germanium and needed by human body, the element rich in nutrition such as calcium, magnesium, sodium, potassium, iron, selenium, zinc.
Tourmaline：It is the uniquely crystal with permanent electrode on the earth be present in mineral, caused anion, micro-current and remote red Outside line is to improving health and environment to be present highly beneficial.
Obsidian：It is mainly silica, after 1000 DEG C of temperatures above heating, because internal moisture is scattered and disappeared, becomes matter Ground is loose porous.It is the most strong a kind of crystal of the property received in crystal.
Huanglong is beautiful：Main component has silica, muscovite etc., and rich in having, the metallic elements such as iron, aluminium, manganese and 40 lot of trace are first Element.
Feldspar：It is the aluminum silicate rock-forming mineral of a kind of common calcic, sodium and potassium, is ceramic raw material.Hardness fluctuations are in 6- 6.5, proportion is fluctuated in 2-2.5, and property is crisp, there is higher compression strength, has stronger chemical stability to acid.
Rectorite：With high-temperature stability, refractoriness is up to 1650 DEG C, and holding structure can stablize under 500 DEG C of states.Also have There are polymolecularity and high-ductility, plasticity index may be up to 50, easily be bonded to shape, and drying or sintering do not crack.In the present invention In increase base substrate plasticity when being mainly used in formed product, reduce base substrate refractoriness.
Bentonite：Be the nonmetallic minerals using montmorillonite as main mineral constituent, there is very strong hygroscopicity and dilatancy, have compared with Strong cation exchange capacity (CEC), there is certain adsorption capacity to various gases, liquid, organic substance, coloured ion can be adsorbed.
Longyan clay：, can be significantly during production with physical properties such as superior plasticity, dry tenacity and viscosity Reduce the deformation of semi-finished product and ceramic product and crush.
Zeolite：With adsorptivity, ion exchangeable, catalysis and acidproof, heat resistance, thus be widely used in sorbing material materials, Ion-exchanger, gas dry decontamination etc..It is mainly used in realizing molecular sieve function in the present invention.
Medical stone：Also known as long-lived stone, health-care stone, be a kind of natural medicine ore, containing potassium necessary to human body, sodium, calcium, 18 kinds of trace elements such as magnesium, phosphorus macroelement and zinc, iron, selenium, copper, strontium, iodine, fluorine, metasilicic acid.Contain a large amount of zirconiums in medical stone Stone, can discharge the far infrared beneficial to human body, far-infrared radiation rate ＞ 0.88~0.92 under normal temperature, bacteriostasis rate under normal temperature (Escherichia coli, staphylococcus aureus) ＞ 90%.Radiation far infrared function is mainly realized in the present invention.
Crystal quartz：Wuli-Shili-Renli system approach with uniqueness, particularly have in it in molecular chain structure character changing rule High temperature resistant, thermal coefficient of expansion are small, high-insulation, corrosion resistance, piezo-electric effect, resonance effect etc..
The production technology of beautiful energy porcelain of the invention, it is substantially similar with ceramic product, which is mainly characterized in that composition of raw materials, mainly By Xiuyan Jade 7-9%, dushan diopside 6-8%, wood grain jade 8-10%, tourmaline 11-14%, obsidian 5-7%, Huanglong jade 5-7%, Feldspar 11-13%, rectorite 8-10%, in temple Figure 10-12%, Longyan clay 9-11%, zeolite 5-7%, medical stone 9-10%, water Spar English 4-6% etc. is formed.Selected material is fitted into progress 26-28 hour lappingout fine grindings, shape in ball mill by accurate proportioning Into particle in below 0.18g fineness mud, mud sieves by 400 mesh vibratory sieves, then mud cake is made with mud press drainage, is passing through Stirring extrusion mud bar under negative pressure of vacuum 9.5-10MP, mud bar is by technological requirement plastotype into base, and molding blank is through 1180 (± 3) DEG C Oxidizing flame kiln is fired.Because the pug expression activitiy is strong, need to fire using interim heating mode in sintering procedure, base substrate Enter kiln first through 0~500 DEG C of hydrofuge, then persistently overheating to 800 DEG C, temperature control is surely risen in 800~1080 DEG C of sections on 8 hours left sides Right completion, control was at 19 hours or so between 1080~1180 DEG C, so as to reduce Product Variant, discoloration, while keep it is beautiful can ceramics Product special performance, about 29-31 hours overall firing time.Through choosing, polishing after kiln discharge, as finished product.
Beautiful energy porcelain of the invention, as a result of above-mentioned formula, the beautiful energy porcelain finally obtained, by the physics and chemistry for detecting beautiful energy porcelain Composition is：SiO2Measure 50-60%, Al2O3Composition 10-13%, CaO composition 3-6%, Fe2O3Composition 0.8-1.7%, MgO composition 3- 7%, K2O compositions 1-2.7%, Na2O composition 1.83-1.9%, it is basic that beautiful energy porcelain physical and chemical composition is obtained from physical and chemical index numerical value Kindly helped secure the success of point close to original.
Beautiful energy porcelain of the invention breaks the present situation that existing domestic ceramics is inorganic ceramic, rich in calcium, magnesium, potassium, sodium, iron etc. to people The leaching ability of heavy metal amounts such as body beneficial mineral matter composition, lead, cadmium are 0.
Beautiful energy porcelain of the invention, as a result of above-mentioned formula, has ion translation function, negative oxygen ion exit dose is 800- 1500/s.cm3, while emitting far-infrared, wavelength 5-14um, emissivity 0.90.
The big water clusters of water in product, positive potential etc. can be converted into small by beautiful energy porcelain of the invention by being contacted with water Water clusters, negative potential, oxygen-enriched property, while itself leachable trace element to beneficial to human body.
Specific embodiment
Embodiment 1：By Xiuyan Jade 7-9%, dushan diopside 6-8%, wood grain jade 8-10%, tourmaline 11-14%, obsidian 5- 7%th, Huanglong's jade 5-7%, feldspar 11-13%, rectorite 8-10%, in temple Figure 10-12%, Longyan clay 9-11%, zeolite 5- 7%th, medical stone 9-10%, crystal quartz 4-6% mixtures, selected material is fitted into ball mill by accurate proportioning and carries out 26- Lappingout fine grinding in 28 hours, particle is formed in below 0.18g fineness mud, mud is by the screening of 400 mesh vibratory sieves, then uses mud press Mud cake is made in drainage, and the stirring extrusion mud bar under through negative pressure of vacuum 9.5-10MP, mud bar presses technological requirement plastotype into base, into parison Oxidizing flame kiln of the body through 1180 (± 3) DEG C is fired.Because the pug expression activitiy is strong, needed in sintering procedure using stage Heating mode is fired, and base substrate enters kiln first through 0~500 DEG C of hydrofuge, then persistently overheating to 800 DEG C, surely risen in 800~1080 DEG C of sections Temperature control was controlled between 8 hours or so, 1080~1180 DEG C at 19 hours or so, about 29-31 hours overall firing time. After kiln discharge finished product is finished to through selection.Physical and chemical composition detection is beautiful close to original.Function detection, negative oxygen ion emission measure 800-1500 Individual/s.cm3, far infrared wavelength 5-14um, emissivity 0.90.

Claims (6)

1. beautiful energy porcelain of the invention, it is characterised in that composition of raw materials is mainly by Xiuyan Jade 7-9%, dushan diopside 6-8%, wood grain jade 8- 10%th, tourmaline 11-14%, obsidian 5-7%, Huanglong jade 5-7%, feldspar 11-13%, rectorite 8-10%, in temple Figure 10- 12%th, Longyan clay 9-11%, zeolite 5-7%, medical stone 9-10%, crystal quartz 4-6% etc. are formed.
2. according to the beautiful energy porcelain described in from claim 1, it is characterised in that selected material is loaded into ball mill by accurate proportioning Middle progress 26-28 hour lappingout fine grindings, form particle and sieved in below 0.18g fineness mud, mud by 400 mesh vibratory sieves, Mud cake is made with mud press drainage again, stirring extrusion mud bar, mud bar press technological requirement plastotype under through negative pressure of vacuum 9.5-10MP Into base, oxidizing flame kiln of the molding blank through 1180 (± 3) DEG C is fired.Because pug expression activitiy is strong, needed in sintering procedure Fired using interim heating mode, base substrate enters kiln first through 0~500 DEG C of hydrofuge, then persistently overheating to 800 DEG C, 800~1080 DEG C section surely rises temperature control and controlled between 8 hours or so, 1080~1180 DEG C at 19 hours or so, becomes so as to reduce product Type, discoloration, while kept for beautiful energy porcelain special performance, about 29-31 hours overall firing time.Through choosing, polishing after kiln discharge, i.e., For finished product.
3. the beautiful energy porcelain according to claim 1,2, it is characterised in that be by the physical and chemical composition for detecting beautiful energy porcelain：SiO2Amount 50-60%, Al2O3Composition 10-13%, CaO composition 3-6%, Fe2O3Composition 0.8-1.7%, MgO composition 3-7%, K2O compositions 1- 2.7%, Na2O composition 1.83-1.9%, obtained from physical and chemical index numerical value it is beautiful can ceramic ware for daily use physical and chemical composition substantially close to Original is kindly helped secure the success of point.
4. according to claim 1,2, the 3 beautiful energy porcelain, it is characterised in that break the present situation that existing domestic ceramics is inorganic ceramic, It is 0 to leaching ability of heavy metal amounts such as human body beneficial mineral matter composition, lead, cadmiums rich in calcium, magnesium, potassium, sodium, iron etc..
5. according to claim 1,2,3, the 4 beautiful energy porcelain, it is characterised in that employ above-mentioned special formulation, there is ion conversion Function, negative oxygen ion exit dose are 800-1500/s.cm3, while emitting far-infrared, wavelength 5-14um, emissivity 0.90.
6. according to claim 1,2,3,4, the 5 beautiful energy porcelain, it is characterised in that can be by being contacted with water, by the water in product Big water clusters, positive potential etc. are converted into small water molecule group, negative potential, oxygen-enriched property, while itself is leachable to beneficial to human body Trace element.
CN201710492000.1A 2017-06-19 2017-06-19 Beautiful energy porcelain Pending CN107337444A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109809796A (en) * 2019-04-10 2019-05-28 河南御龙缘实业有限公司 A kind of your porcelain of multipurpose and preparation method thereof
CN109998380A (en) * 2019-04-03 2019-07-12 唐山立雄峰汇材料科技有限公司 Beautiful material electric cooker inner container

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101928132A (en) * 2010-06-23 2010-12-29 平定莹玉陶瓷有限公司 Ordinary fine procelain
CN104529420A (en) * 2015-01-13 2015-04-22 唐山立雄峰汇材料科技有限公司 Functional ceramic tea set
CN105174903A (en) * 2015-07-27 2015-12-23 陈广平 Resonant biological energy ceramic and preparation method therefor
CN105924129A (en) * 2016-04-08 2016-09-07 唐山立雄峰汇材料科技有限公司 Domestic energy fruit washing basin
CN106278212A (en) * 2016-07-01 2017-01-04 唐山立雄峰汇材料科技有限公司 Egg thick soup tank

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101928132A (en) * 2010-06-23 2010-12-29 平定莹玉陶瓷有限公司 Ordinary fine procelain
CN104529420A (en) * 2015-01-13 2015-04-22 唐山立雄峰汇材料科技有限公司 Functional ceramic tea set
CN105174903A (en) * 2015-07-27 2015-12-23 陈广平 Resonant biological energy ceramic and preparation method therefor
CN105924129A (en) * 2016-04-08 2016-09-07 唐山立雄峰汇材料科技有限公司 Domestic energy fruit washing basin
CN106278212A (en) * 2016-07-01 2017-01-04 唐山立雄峰汇材料科技有限公司 Egg thick soup tank

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109998380A (en) * 2019-04-03 2019-07-12 唐山立雄峰汇材料科技有限公司 Beautiful material electric cooker inner container
CN109809796A (en) * 2019-04-10 2019-05-28 河南御龙缘实业有限公司 A kind of your porcelain of multipurpose and preparation method thereof

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Application publication date: 20171110