CN107331432A - A kind of nano silver wire transparent conductive film and preparation method thereof - Google Patents
A kind of nano silver wire transparent conductive film and preparation method thereof Download PDFInfo
- Publication number
- CN107331432A CN107331432A CN201710500222.3A CN201710500222A CN107331432A CN 107331432 A CN107331432 A CN 107331432A CN 201710500222 A CN201710500222 A CN 201710500222A CN 107331432 A CN107331432 A CN 107331432A
- Authority
- CN
- China
- Prior art keywords
- nano silver
- silver wire
- conductive film
- transparent conductive
- nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/14—Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
Abstract
The present invention is applied to transparent conductive film field there is provided a kind of nano silver wire transparent conductive film, and the nano silver wire transparent conductive film includes flexible substrate and the nano silver wire being covered in the flexible substrate, and the nano silver wire is connected in flattening；The flattening is connected as nano-silver thread generation plastic deformation and network is connected with each other as formed by cylindrical shape is changed into strip.The nano silver wire transparent conductive film that the present invention is provided, nano silver wire is inlayed on flexible substrates in netted in the transparent conductive film, connected between the nano silver wire in flattening, contact is close, contact area is big and need not add any binding agent, the transparent conductive film light transmittance of acquisition is up to 85%~90%, sheet resistance is reduced to 30~50 Ω/square, mist degree 3 15.
Description
Technical field
The invention belongs to transparent conductive film field, more particularly to a kind of nano silver wire transparent conductive film and its preparation side
Method.
Background technology
The transparent conductive film having been widely used at present is all prepared on the hard backing materials such as ceramics, glass, but
Due to these materials exist matter it is crisp it is frangible, the defect such as be unlikely to deform, therefore largely limit transparent conductive film should
With.Compared with hard backing material, the transparent conductive film prepared on organic flexible backing material not only possesses identical light
Electrical characteristics, but also there are many distinctive advantages, such as：Can bending deformation, it is frivolous it is portable, non-breakable, can using volume pair
The continuous mode of production of volume industrialization is conducive to improving efficiency, is readily transported.
The characteristics of nano silver wire transparent conductive film has low sheet resistance and high transmittance, high conductivity, is to make electricity
One of optimal selection of sub- optical component, compared with tin indium oxide (ITO) conductive film, with more preferable electric conductivity, and
And property is more soft.
However, the preparation of traditional nano silver wire transparent conductive film needs to add resinae bonding agent, to increase silver nanoparticle
Contact between line and substrate and nano wire, the addition of bonding agent can influence the transmitance of transparent conductive film, increase its sheet resistance,
Reduce electric conductivity.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of nano silver wire transparent conductive film and preparation method thereof,
While being meant to ensure that holding is in close contact between nano silver wire and substrate and nano silver wire, the printing opacity of transparent conductive film is improved
Rate, electric conductivity, and reduce its mist degree.
The present invention is achieved in that a kind of nano silver wire transparent conductive film, the nano silver wire transparent conductive film
Including flexible substrate and the nano silver wire being covered in the flexible substrate, the nano silver wire is connected in flattening；It is described flat
Graduation is connected as nano-silver thread generation plastic deformation and network is connected with each other as formed by cylindrical shape is changed into strip.
Further, the flexible substrate includes PET, makrolon, polyimides, polypropylene
At least one of own diester and polypropylene.
Further, a diameter of 40~70nm of the nano silver wire, length is 5~20 μm.
Present invention also offers the preparation method of nano silver wire transparent conductive film described above, comprise the following steps：
The ultrasonic cleaning processing carried out to flexible substrate；
By the scattered formation nano silver wire dispersion liquid in a solvent of nano silver wire, the nano silver wire homogeneous dispersion is coated with
To flexible substrate, dry, obtain nano silver wire conductive layer；
Hot-pressing processing is carried out to the nano silver wire conductive layer of acquisition so that nano-silver thread occurs to be plastically deformed and weld, and obtains
Obtain the nano silver wire transparent conductive film of flattening connection.
Further, the process of the hydrophily processing includes：
The flexible substrate is respectively placed in cleaning agent after ultrasonically treated 10-30min and dried, the cleaning agent is second
At least one of alcohol, acetone, deionized water.
Further, the solvent is at least one of methanol, ethanol, isopropanol and deionized water.
Further, the concentration of the silver nanoparticle dispersion liquid is 0.5-2.0g/L.
Further, described hot-pressing processing is to applying one while the nano silver wire of flexible substrate is heated after coating
Constant-pressure, heating-up temperature is 100~150 DEG C, and application pressure is 1~5bar, and the dwell time is 1~30s.
Compared with prior art, beneficial effect is the present invention：Nano silver wire electrically conducting transparent provided in an embodiment of the present invention
Nano silver wire is inlayed on flexible substrates in netted in film, the transparent conductive film, in flat between the nano silver wire
Change connection and form the network being connected with each other, contact is close, contact area is big and need not add any binding agent, acquisition it is saturating
Bright conductive film light transmittance is up to 85%~90%, and sheet resistance is reduced to 30~50 Ω/square, and mist degree declines than before processing
50%.
Brief description of the drawings
Fig. 1 is the process schematic of nano silver wire transparent conductive film hot-pressing processing provided in an embodiment of the present invention；
Fig. 2 is the scanning electron microscope diagram of nano silver wire provided in an embodiment of the present invention, and wherein Fig. 2 a are hot-pressing processing
Preceding nano silver wire, Fig. 2 b be hot-pressing processing after nano silver wire, Fig. 2 c be hot-pressing processing after nano silver wire sectional view.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples
The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and
It is not used in the restriction present invention.
The embodiments of the invention provide a kind of nano silver wire transparent conductive film, the nano silver wire transparent conductive film bag
Flexible substrate and the nano silver wire being covered in the flexible substrate are included, the nano silver wire is connected in flattening；It is described flat
Change is connected as nano-silver thread generation plastic deformation and network is connected with each other as formed by cylindrical shape is changed into strip.
Nano silver wire is in net in nano silver wire transparent conductive film provided in an embodiment of the present invention, the transparent conductive film
Shape is embedded between flexible substrate surface, the nano silver wire to be connected in flattening, and contact is close, contact area is big and need not
Add any binding agent, the transparent conductive film light transmittance of acquisition up to 85%~90%, sheet resistance be reduced to 30~50 Ω/
square。
Specifically, the flexible substrate include PET, makrolon, polyimides, polypropylene oneself
At least one of diester and polypropylene.
Specifically, a diameter of 40~70nm of the nano silver wire, length is 5~20 μm.
The embodiment of the present invention additionally provides the preparation method of nano silver wire transparent conductive film described above, including following
Step：
The ultrasonic cleaning processing carried out to flexible substrate；
By the scattered formation nano silver wire dispersion liquid in a solvent of nano silver wire, the nano silver wire homogeneous dispersion is coated with
To flexible substrate, dry, obtain nano silver wire conductive layer；
Hot-pressing processing is carried out to the nano silver wire conductive layer of acquisition so that nano-silver thread occurs to be plastically deformed and weld, and obtains
Obtain the nano silver wire transparent conductive film of flattening connection.
The preparation method of nano silver wire transparent conductive film provided in an embodiment of the present invention, is made by the method for hot-pressing processing
Nano silver wire conductive layer is mechanically embedded on flexible substrate surface, and it is in flattening to make the nano silver wire in nano silver wire conductive layer
It is connected with each other, without adding any bonding agent.
Specifically, the process of the hydrophily processing includes：
The flexible substrate is respectively placed in cleaning agent after ultrasonically treated 10-30min and dried, the cleaning agent is second
At least one of alcohol, acetone, deionized water.
Specifically, the solvent is at least one of methanol, ethanol, isopropanol and deionized water.The silver nanoparticle point
The concentration of dispersion liquid is 0.5-2.0g/L.
Specifically, the process of the coating includes：
By sol evenning machine by nano silver wire solution coating in the flexible substrate, the rotating speed of the sol evenning machine for 3000~
5000r/min, the time is 10~30s.
Specifically, described hot-pressing processing is to applying certain while the nano silver wire of flexible substrate is heated after coating
Pressure, heating-up temperature is 100~150 DEG C, and application pressure is 1~5bar, and the dwell time is 1~30s.
Fig. 1 is the process schematic of nano silver wire transparent conductive film hot-pressing processing provided in an embodiment of the present invention.Referring to
Fig. 1, wherein F are that pressure applies direction, and 1 is nano silver wire conductive layer, and 2 be flexible substrate, and 3 be heating plate.The hot-pressing processing
Heating-up temperature be 100~150 DEG C, pressure size be 1~5bar (bar), the dwell time be 1~30s.
Fig. 2 is the scanning electron microscope diagram of nano silver wire provided in an embodiment of the present invention, and wherein Fig. 2 a are pressure treatment
Preceding nano silver wire, Fig. 2 b be pressure treatment after nano silver wire, Fig. 2 c be pressure treatment after nano silver wire sectional view.From
As can be seen that nano silver wire is distributed in flexible substrate surface before pressure treatment in overlap joint state up and down, through excess pressure in Fig. 2 a
After processing, it can be seen that nano silver wire is become for flat by original cylindrical shape from Fig. 2 b, Fig. 2 c, interconnection is formd
Network, and realize and be connected with each other and embedded flexible substrate surface between nano wire.
Technical scheme is described further below in conjunction with specific embodiment.
Embodiment 1
PET is chosen as flexible substrate, it is carried out to dry after hydrophily processing；By silver nanoparticle
Line is dispersed in ethanol solution, and configuration obtains the nano silver wire solution that concentration is 0.5g/L；By silver by the way of spin coating
On flexible substrates, spin speed 3500r/min, time 30s is dried nanowire solution even spread, obtains nano silver wire conductive
Layer；Flexible substrate after spin coating is placed in heating plate and carries out hot-pressing processing, 100 DEG C of temperature of heating plate, applying pressure is
1.5bar, time 10s.The light transmittance of silver-colored transparent conductive film after hot-pressing processing be 86.5%, sheet resistance be 47.6 Ω/
Square, mist degree is 7.2.
Embodiment 2
PET is chosen as flexible substrate, it is carried out to dry after hydrophily processing；By silver nanoparticle
Line is dispersed in ethanol solution, and configuration obtains the nano silver wire solution that concentration is 1.0g/L；By silver by the way of spin coating
On flexible substrates, spin speed 3500r/min, time 30s is dried nanowire solution even spread, obtains nano silver wire conductive
Layer；Flexible substrate after spin coating is placed in heating plate and carries out hot-pressing processing, 120 DEG C of temperature of heating plate, applying pressure is
2.0bar, time 10s.The light transmittance of silver-colored transparent conductive film after hot-pressing processing be 85.7%, sheet resistance be 41.8 Ω/
Square, mist degree is 10.3.
Embodiment 3
PET is chosen as flexible substrate, it is carried out to dry after hydrophily processing；By silver nanoparticle
Line is dispersed in ethanol solution, and configuration obtains the nano silver wire solution that concentration is 1.5g/L；By silver by the way of spin coating
On flexible substrates, spin speed 3500r/min, time 30s is dried nanowire solution even spread, obtains nano silver wire conductive
Layer；Flexible substrate after spin coating is placed in heating plate and carries out hot-pressing processing, 150 DEG C of temperature of heating plate, applying pressure is
2.5bar, time 10s.The light transmittance of silver-colored transparent conductive film after hot-pressing processing be 84.5%, sheet resistance be 37.5 Ω/
Square, mist degree is 5.1.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modifications, equivalent substitutions and improvements made within refreshing and principle etc., should be included in the scope of the protection.
Claims (8)
1. a kind of nano silver wire transparent conductive film, it is characterised in that the nano silver wire transparent conductive film includes flexible liner
Bottom and the nano silver wire being covered in the flexible substrate, the nano silver wire are connected in flattening；The flattening is connected as
Nano-silver thread occurs plastic deformation and network is connected with each other as formed by cylindrical shape is changed into strip.
2. nano silver wire transparent conductive film as claimed in claim 1, it is characterised in that the flexible substrate includes poly- to benzene
At least one of dioctyl phthalate second diester, makrolon, polyimides, the own diester of polypropylene and polypropylene.
3. nano silver wire transparent conductive film as claimed in claim 1, it is characterised in that the nano silver wire a diameter of 40~
70nm, length is 5~20 μm.
4. the preparation method of the nano silver wire transparent conductive film as described in claims 1 to 3 any one, it is characterised in that
Comprise the following steps：
The ultrasonic cleaning processing carried out to flexible substrate；
By the scattered formation nano silver wire dispersion liquid in a solvent of nano silver wire, the nano silver wire homogeneous dispersion is applied to soft
Property substrate on, dry, obtain nano silver wire conductive layer；
Hot-pressing processing is carried out to the nano silver wire conductive layer of acquisition so that nano-silver thread occurs to be plastically deformed and weld, and obtains flat
The nano silver wire transparent conductive film of graduation connection.
5. the preparation method of nano silver wire transparent conductive film as claimed in claim 4, it is characterised in that at the hydrophily
The process of reason includes：
The flexible substrate is respectively placed in cleaning agent after ultrasonically treated 10-30min and dried, the cleaning agent is ethanol, third
At least one of ketone, deionized water.
6. the preparation method of nano silver wire transparent conductive film as claimed in claim 4, it is characterised in that the solvent is first
At least one of alcohol, ethanol, isopropanol and deionized water.
7. the preparation method of nano silver wire transparent conductive film as claimed in claim 4, it is characterised in that the silver nanoparticle point
The concentration of dispersion liquid is 0.5-2.0g/L.
8. the preparation method of the nano silver wire transparent conductive film as described in claim 4 to 7 any one, it is characterised in that
Described hot-pressing processing is that heating-up temperature is to applying certain pressure while the nano silver wire of flexible substrate is heated after coating
100~150 DEG C, application pressure is 1~5bar, and the dwell time is 1~30s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710500222.3A CN107331432A (en) | 2017-06-27 | 2017-06-27 | A kind of nano silver wire transparent conductive film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710500222.3A CN107331432A (en) | 2017-06-27 | 2017-06-27 | A kind of nano silver wire transparent conductive film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107331432A true CN107331432A (en) | 2017-11-07 |
Family
ID=60197093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710500222.3A Pending CN107331432A (en) | 2017-06-27 | 2017-06-27 | A kind of nano silver wire transparent conductive film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107331432A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108184310A (en) * | 2017-12-28 | 2018-06-19 | 深圳大学 | The production method of transparent flexible multi-layer PCB |
| CN108519703A (en) * | 2018-04-17 | 2018-09-11 | 苏州顾氏新材料有限公司 | A kind of flexible single substrate nano silver wire electrode liquid crystal light modulation film and preparation method thereof |
| CN108995103A (en) * | 2018-08-20 | 2018-12-14 | 中国科学院工程热物理研究所 | Low radiation film and preparation method thereof |
| CN109036619A (en) * | 2018-08-31 | 2018-12-18 | 深圳大学 | A kind of silver nanoparticle band transparent conductive film and preparation method |
| CN110600199A (en) * | 2019-09-25 | 2019-12-20 | 天津大学 | AgNWs flexible transparent conductive film and preparation method thereof |
| CN110634621A (en) * | 2019-09-25 | 2019-12-31 | 天津大学 | Flexible transparent touch screen based on AgNWs and preparation method thereof |
| CN110797140A (en) * | 2019-11-13 | 2020-02-14 | 东南大学 | Silver nanowire and graphene composite flexible transparent conductive film and preparation method thereof |
| WO2020042141A1 (en) * | 2018-08-31 | 2020-03-05 | 深圳大学 | Silver nanoribbon transparent conductive film, and preparation method therefor |
| CN110875098A (en) * | 2018-08-29 | 2020-03-10 | 天津大学 | Nano silver wire conductive ink sintered film based on hot-pressing sintering and preparation method and application thereof |
| CN110957059A (en) * | 2019-12-26 | 2020-04-03 | 海泰纳鑫科技(成都)有限公司 | Silver nanowire transparent conductive film and preparation method and application thereof |
| CN110993147A (en) * | 2019-12-09 | 2020-04-10 | 重庆文理学院 | Preparation method of silver nanowire transparent conductive film |
| CN112687429A (en) * | 2020-12-10 | 2021-04-20 | 宁波敏实汽车零部件技术研发有限公司 | Advancing type hot-pressing wire embedding device |
| CN113512222A (en) * | 2021-03-30 | 2021-10-19 | 浙江中科玖源新材料有限公司 | Transparent polyimide conductive film |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102270524A (en) * | 2010-05-21 | 2011-12-07 | 中国科学院福建物质结构研究所 | Silver nano-wire transparent conducting film based on thermoplastic transparent polymer and preparation method thereof |
| CN102993995A (en) * | 2012-12-17 | 2013-03-27 | 常州大学 | Preparation method of transparent conductive film |
| CN104952551A (en) * | 2015-06-16 | 2015-09-30 | 北京石油化工学院 | Method and equipment for preparing flexible substrate silver nanowire transparent conducting thin film |
-
2017
- 2017-06-27 CN CN201710500222.3A patent/CN107331432A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102270524A (en) * | 2010-05-21 | 2011-12-07 | 中国科学院福建物质结构研究所 | Silver nano-wire transparent conducting film based on thermoplastic transparent polymer and preparation method thereof |
| CN102993995A (en) * | 2012-12-17 | 2013-03-27 | 常州大学 | Preparation method of transparent conductive film |
| CN104952551A (en) * | 2015-06-16 | 2015-09-30 | 北京石油化工学院 | Method and equipment for preparing flexible substrate silver nanowire transparent conducting thin film |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108184310A (en) * | 2017-12-28 | 2018-06-19 | 深圳大学 | The production method of transparent flexible multi-layer PCB |
| CN108519703A (en) * | 2018-04-17 | 2018-09-11 | 苏州顾氏新材料有限公司 | A kind of flexible single substrate nano silver wire electrode liquid crystal light modulation film and preparation method thereof |
| CN108995103A (en) * | 2018-08-20 | 2018-12-14 | 中国科学院工程热物理研究所 | Low radiation film and preparation method thereof |
| CN110875098A (en) * | 2018-08-29 | 2020-03-10 | 天津大学 | Nano silver wire conductive ink sintered film based on hot-pressing sintering and preparation method and application thereof |
| CN109036619B (en) * | 2018-08-31 | 2020-10-09 | 深圳大学 | Silver nanobelt transparent conductive film and preparation method thereof |
| CN109036619A (en) * | 2018-08-31 | 2018-12-18 | 深圳大学 | A kind of silver nanoparticle band transparent conductive film and preparation method |
| WO2020042141A1 (en) * | 2018-08-31 | 2020-03-05 | 深圳大学 | Silver nanoribbon transparent conductive film, and preparation method therefor |
| CN110600199A (en) * | 2019-09-25 | 2019-12-20 | 天津大学 | AgNWs flexible transparent conductive film and preparation method thereof |
| CN110634621A (en) * | 2019-09-25 | 2019-12-31 | 天津大学 | Flexible transparent touch screen based on AgNWs and preparation method thereof |
| CN110797140A (en) * | 2019-11-13 | 2020-02-14 | 东南大学 | Silver nanowire and graphene composite flexible transparent conductive film and preparation method thereof |
| CN110993147A (en) * | 2019-12-09 | 2020-04-10 | 重庆文理学院 | Preparation method of silver nanowire transparent conductive film |
| CN110957059A (en) * | 2019-12-26 | 2020-04-03 | 海泰纳鑫科技(成都)有限公司 | Silver nanowire transparent conductive film and preparation method and application thereof |
| CN112687429A (en) * | 2020-12-10 | 2021-04-20 | 宁波敏实汽车零部件技术研发有限公司 | Advancing type hot-pressing wire embedding device |
| CN113512222A (en) * | 2021-03-30 | 2021-10-19 | 浙江中科玖源新材料有限公司 | Transparent polyimide conductive film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107331432A (en) | A kind of nano silver wire transparent conductive film and preparation method thereof | |
| Jiang et al. | Highly transparent, conductive, flexible resin films embedded with silver nanowires | |
| KR101908825B1 (en) | Transparent conductive electrodes comprising merged metal nanowires, their structure design, and method of making such structures | |
| JPWO2016140196A1 (en) | Conductive paste, electric module, and method of manufacturing electric module | |
| Wang et al. | A facile method for preparing transparent, conductive, and paper-like silver nanowire films | |
| He et al. | Ionic gel paper with long-term bendable electrical robustness for use in flexible electroluminescent devices | |
| CN104952551A (en) | Method and equipment for preparing flexible substrate silver nanowire transparent conducting thin film | |
| CN103700430B (en) | A kind of conductive film being distributed in order and its manufacture method | |
| JP2011090879A (en) | Method of manufacturing transparent conductor | |
| CN106548828B (en) | A kind of method for improving nano silver wire electrically conducting transparent film conductivity and transmitance | |
| Yu et al. | Binding conductive ink initiatively and strongly: transparent and thermally stable cellulose nanopaper as a promising substrate for flexible electronics | |
| CN107342117B (en) | Anisotropic conductive film and preparation method thereof | |
| Chung et al. | The surface plasmonic welding of silver nanowires via intense pulsed light irradiation combined with NIR for flexible transparent conductive films | |
| Yu et al. | Enhanced adhesion of Ag nanowire based transparent conducting electrodes for application in flexible electrochromic devices | |
| CN107705884A (en) | A kind of electrically conducting transparent paper based on nano silver wire and preparation method thereof | |
| CN104821192B (en) | High-haze flexible transparent conductive film and method thereof | |
| CN107910128B (en) | Method for improving mechanical property of flexible device by graphene oxide self-assembled composite silver nanowire | |
| KR101484771B1 (en) | Electrode element using silver nano-wire and its manufacturing method | |
| CN108984027A (en) | Conductive laminate structure and preparation method thereof, display device | |
| CN108962434A (en) | A kind of nano-silver thread conductive film and preparation method thereof | |
| Tang et al. | Chemical resistant silver nanowire/cellulose nanofibril flexible transparent conductive coatings | |
| CN108475583A (en) | The manufacturing method of electrical component and electrical component | |
| Chen et al. | Flexible, Transparent and Conductive Metal Mesh Films with Ultra-High FoM for Stretchable Heating and Electromagnetic Interference Shielding | |
| CN205334442U (en) | Flexible transparent conductive electrode structure of compound nanometer silver line | |
| CN108074660A (en) | A kind of composite and flexible transparent conductive film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171107 |