CN107325695A - A kind of corrosion-resistant water-fast water paint - Google Patents
A kind of corrosion-resistant water-fast water paint Download PDFInfo
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- CN107325695A CN107325695A CN201710522356.5A CN201710522356A CN107325695A CN 107325695 A CN107325695 A CN 107325695A CN 201710522356 A CN201710522356 A CN 201710522356A CN 107325695 A CN107325695 A CN 107325695A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses the corrosion-resistant water-fast water paint of one kind, its raw material includes by weight：20 30 parts of epoxy resin, 60 80 parts of saturated linear polyester resin, 12 parts of pine tar, 15 25 parts of Tissuemat E, 1.2 2 parts of neopelex, 10 15 parts of ethylene glycol, 0.8 1.4 parts of calcium sorbate, 12 parts of rosin resin, 24 parts of thickener, 24 parts of crosslinking agent, 24 parts of pigment, 70 80 parts of inserts, 40 60 parts of water.Wood fibre compound is prepared using following technique：Added water to bean powder, the processing of glue mill adds Tissuemat E, heating stirring, add and heated up under wood fibre, tong ma anhydride methyl esters, dimethylformamide mixing, stirring, continue to stir, be down to room temperature, filtering, solids is washed with acetone, dry, pulverize and obtain wood fibre compound.
Description
Technical field
The present invention relates to technical field of aqueous paint, more particularly to a kind of corrosion-resistant water-fast water paint.
Background technology
With the lifting of mankind's environmental consciousness, building coating just from the past by protect wall, decoration for the purpose of performance to
Multi-functional, greenization direction to develop.Thermal insulation coatings combine the dual characteristicses of coating and insulation material, and it is formed with after drying
The heat-insulation layer of some strength and elasticity, so as to play insulation effect.At present, though the thermal insulation coatings of market sale are with certain guarantor
Warm nature energy, but its corrosion-resistant, water resistance, adhesion strength are poor, can not meet demand, it would be highly desirable to solve.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of corrosion-resistant water-fast water paint, not only has
There are preferable heat-insulating property, and its alkali resistance, a water resistance, the performance such as adhesion strength is good, while smelly eliminating, anti-microbial property, organic
The decomposability of dirt is excellent.
The corrosion-resistant water-fast water paint of one kind proposed by the present invention, its raw material includes by weight：Epoxy resin 20-30
Part, 60-80 parts of saturated linear polyester resin, 1-2 parts of pine tar, 15-25 parts of Tissuemat E, neopelex 1.2-2
Part, 10-15 parts of ethylene glycol, 0.8-1.4 parts of calcium sorbate, 1-2 parts of rosin resin, 2-4 parts of thickener, 2-4 parts of crosslinking agent, pigment
2-4 parts, 70-80 parts of inserts, 40-60 parts of water.
Preferably, crosslinking agent is cyclohexanone peroxide.
Preferably, inserts includes by weight：10-16 parts of nano silicon, 8-15 parts of nano imvite, Nanowire
Plain 4-8 parts of the whisker of dimension, is calcined 5-7 parts of clay, 8-12 parts of wood fibre compound, poly- 2-6 parts of boric acid ester fiber.
Preferably, wood fibre compound is prepared using following technique：Added water to bean powder, the processing of glue mill adds polyethylene
Wax, heating stirring is added and heated up under wood fibre, tong ma anhydride methyl esters, dimethylformamide mixing, stirring, continues to stir
Mix, be down to room temperature, filter, solids is washed with acetone, dry, pulverize and obtain wood fibre compound.
Preferably, wood fibre compound is prepared using following technique：Added water by weight to 16-20 parts of bean powderes, glue mill
Processing, adds 25-35 parts of Tissuemat Es, and heating stirring adds 10-20 parts of wood fibres, 4-8 parts of tong ma anhydride methyl esters, 25-45
Heated up under part dimethylformamide mixing, stirring, continue to stir, be down to room temperature, filtering, solids is washed with acetone, do
Dry, crushing obtains wood fibre compound.
Preferably, wood fibre compound is prepared using following technique：Added water to by weight to 16-20 parts of bean powderes aqueous
Measure as 40-48wt%, glue mill processing adds 25-35 part Tissuemat Es to 250-350 mesh, is warming up to 65-75 DEG C and stirs 2-4h,
Add and heated up under 10-20 parts of wood fibres, 4-8 parts of tong ma anhydride methyl esters, 25-45 parts of dimethylformamide mixing, stirring
To 80-90 DEG C, continue to stir 4-8h, be down to room temperature, filter, solids is washed with acetone, 110-120 DEG C of dry 6-9h, crush
Obtain wood fibre compound.
The present invention makes the present invention not only have preferable heat insulating ability after construction by raw material and the consumption of reasonably arranging in pairs or groups
Can, and its alkali resistance, water resistance, the performance such as adhesion strength are good, and film elasticity is non-aging, and flintiness is good, effectively protects wall
The intensity of flour brush bottom, metope is not likely to produce cracking, come off, and keeps influence building attractive in appearance, will not produce metope leak and show
As while the decomposability of smelly eliminating, anti-microbial property, organic dirt is excellent.
In wood fibre compound, bean powder is ground structural connectivity key and phase between polypeptide chain in soybean protein by glue
Interaction is broken, and is sufficiently spread out protein molecule, and coordinating with Tissuemat E can be in wood fibre, dimethylformamide, paulownia horse
Disperse in acid anhydrides methyl esters and stretch, in the case where ensureing enough bonding strengths, good fluidity, and the work in tong ma anhydride methyl esters molecule
The hydroxyl reaction of property anhydride group and wood fibre surface, wooden fibre is grafted to by the tong ma anhydride methyl esters containing ester group and long alkyl chain
The surface of dimension, can effectively reduce the surface polarity of wood fibre, surface hydrophobic be improved, so as to strengthen wood fibre and saturated line
Property polyester resin, the interface compatibility of epoxy resin-base, make the present invention it is fabulous to substrate adhesion and film compactness and resistance to
Hot, resistance to extensive chemical corrosive nature is excellent；Coordinate neopelex, Tissuemat E effect again, the present invention is not only had
Strong affinity, and degree of scatter is high in material, with nano silicon, nano imvite, nano-cellulose whisker, calcination
Clay, poly- borate fiber dispersion are good, and adhesive force is further enhanced after coating film forming, and resistance to extensive chemical corrosive nature is excellent, and
And can wet-heat resisting, temperature variation resistant, even if under the adverse circumstances of pole, wall will not also produce spot, obscission.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
The corrosion-resistant water-fast water paint of one kind proposed by the present invention, its raw material includes by weight：20 parts of epoxy resin, satisfies
With 80 parts of linear polyester resin, 1 part of pine tar, 25 parts of Tissuemat E, 1.2 parts of neopelex, 15 parts of ethylene glycol, mountain
Pears 0.8 part of calcium of acid, 2 parts of rosin resin, 2 parts of thickener, 4 parts of crosslinking agent, 2 parts of pigment, 80 parts of inserts, 40 parts of water.
Embodiment 2
The corrosion-resistant water-fast water paint of one kind proposed by the present invention, its raw material includes by weight：30 parts of epoxy resin, satisfies
With 60 parts of linear polyester resin, 2 parts of pine tar, 15 parts of Tissuemat E, 2 parts of neopelex, 10 parts of ethylene glycol, sorb
Sour 1.4 parts of calcium, 1 part of rosin resin, 4 parts of thickener, 2 parts of cyclohexanone peroxide, 4 parts of pigment, 70 parts of inserts, 60 parts of water.
Inserts includes by weight：10 parts of nano silicon, 15 parts of nano imvite, 4 parts of nano-cellulose whisker,
It is calcined 7 parts of clay, 8 parts of wood fibre compound, poly- 6 parts of boric acid ester fiber.
Wood fibre compound is prepared using following technique：Added water to bean powder, the processing of glue mill adds Tissuemat E, heating
Stirring, adds and is heated up under wood fibre, tong ma anhydride methyl esters, dimethylformamide mixing, stirring, continue to stir, be down to
Room temperature, filtering, solids is washed with acetone, dry, pulverize and obtain wood fibre compound.
Embodiment 3
The corrosion-resistant water-fast water paint of one kind proposed by the present invention, its raw material includes by weight：22 parts of epoxy resin, satisfies
With 75 parts of linear polyester resin, 1.2 parts of pine tar, 22 parts of Tissuemat E, 1.4 parts of neopelex, 14 parts of ethylene glycol,
1 part of calcium sorbate, 1.8 parts of rosin resin, 2.5 parts of thickener, 3.5 parts of cyclohexanone peroxide, 2.5 parts of pigment, 78 parts of inserts,
45 parts of water.
Inserts includes by weight：16 parts of nano silicon, 8 parts of nano imvite, 8 parts of nano-cellulose whisker,
It is calcined 5 parts of clay, 12 parts of wood fibre compound, poly- 2 parts of boric acid ester fiber.
Wood fibre compound is prepared using following technique：Added water by weight to 18 parts of bean powderes, the processing of glue mill adds 30
Part Tissuemat E, heating stirring adds 15 parts of wood fibres, 6 parts of tong ma anhydride methyl esters, 35 parts of dimethylformamides mixing, stirred
Mix and heated up under state, continue to stir, be down to room temperature, filter, solids washs with acetone, dry, pulverize and obtain wood fibre and answer
Compound.
Embodiment 4
The corrosion-resistant water-fast water paint of one kind proposed by the present invention, its raw material includes by weight：28 parts of epoxy resin, satisfies
With 65 parts of linear polyester resin, 1.8 parts of pine tar, 18 parts of Tissuemat E, 1.8 parts of neopelex, 12 parts of ethylene glycol,
1.2 parts of calcium sorbate, 1.2 parts of rosin resin, 3.5 parts of thickener, 2.5 parts of cyclohexanone peroxide, 3.5 parts of pigment, inserts 72
Part, 55 parts of water.
Inserts includes by weight：12 parts of nano silicon, 14 parts of nano imvite, 5 parts of nano-cellulose whisker,
It is calcined 6.5 parts of clay, 10 parts of wood fibre compound, poly- 5 parts of boric acid ester fiber.
Wood fibre compound is prepared using following technique：Adding water to water content to 16 parts of bean powderes by weight is
48wt%, glue mill processing adds 35 parts of Tissuemat Es to 250 mesh, is warming up to 65 DEG C of stirring 4h, add 10 parts of wood fibres, 8 parts
90 DEG C are warming up under tong ma anhydride methyl esters, 25 parts of dimethylformamide mixing, stirring, continues to stir 4h, is down to room temperature, mistake
Filter, solids is washed with acetone, 120 DEG C of dry 6h, and crushing obtains wood fibre compound.
Embodiment 5
The corrosion-resistant water-fast water paint of one kind proposed by the present invention, its raw material includes by weight：24 parts of epoxy resin, satisfies
With 67 parts of linear polyester resin, 1.4 parts of pine tar, 19 parts of Tissuemat E, 1.6 parts of neopelex, 13 parts of ethylene glycol,
1.1 parts of calcium sorbate, 1.4 parts of rosin resin, 2.9 parts of thickener, 2.6 parts of cyclohexanone peroxide, 2.8 parts of pigment, inserts 76
Part, 47 parts of water.
Inserts includes by weight：14 parts of nano silicon, 10 parts of nano imvite, 7 parts of nano-cellulose whisker,
It is calcined 5.5 parts of clay, wood fibre compound 11 part, poly- 4 parts of boric acid ester fiber.
Wood fibre compound is prepared using following technique：Adding water to water content to 20 parts of bean powderes by weight is
40wt%, glue mill processing adds 25 parts of Tissuemat Es to 350 mesh, is warming up to 75 DEG C of stirring 2h, add 20 parts of wood fibres, 4 parts
80 DEG C are warming up under tong ma anhydride methyl esters, 45 parts of dimethylformamide mixing, stirring, continues to stir 8h, is down to room temperature, mistake
Filter, solids is washed with acetone, 110 DEG C of dry 9h, and crushing obtains wood fibre compound.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (6)
1. a kind of corrosion-resistant water-fast water paint, it is characterised in that its raw material includes by weight：20-30 parts of epoxy resin, satisfies
With 60-80 parts of linear polyester resin, 1-2 parts of pine tar, 15-25 parts of Tissuemat E, 1.2-2 parts of neopelex, second
10-15 parts of glycol, 0.8-1.4 parts of calcium sorbate, 1-2 parts of rosin resin, 2-4 parts of thickener, 2-4 parts of crosslinking agent, pigment 2-4
Part, 70-80 parts of inserts, 40-60 parts of water.
2. corrosion-resistant water-fast water paint according to claim 1, it is characterised in that crosslinking agent is cyclohexanone peroxide.
3. corrosion-resistant water-fast water paint according to claim 1 or claim 2, it is characterised in that inserts includes by weight：Receive
0-16 parts of silica 1 of rice, 8-15 parts of nano imvite, 4-8 parts of nano-cellulose whisker is calcined 5-7 parts of clay, wood fibre
8-12 parts of compound, poly- 2-6 parts of boric acid ester fiber.
4. corrosion-resistant water-fast water paint according to claim 3, it is characterised in that wood fibre compound uses following work
It is prepared by skill：Added water to bean powder, the processing of glue mill adds Tissuemat E, and heating stirring adds wood fibre, tong ma anhydride methyl esters, two
NMF is mixed, and is heated up under stirring, is continued to stir, is down to room temperature, filter, solids is washed with acetone, dries, powder
It is broken to obtain wood fibre compound.
5. the corrosion-resistant water-fast water paint according to claim 3 or 4, it is characterised in that wood fibre compound is using such as
It is prepared by lower technique：Added water by weight to 16-20 parts of bean powderes, the processing of glue mill adds 25-35 parts of Tissuemat Es, and heating is stirred, plus
Enter and heated up under 10-20 parts of wood fibres, 4-8 parts of tong ma anhydride methyl esters, 25-45 parts of dimethylformamide mixing, stirring, after
Continuous stirring, is down to room temperature, filters, and solids is washed with acetone, dry, pulverize and obtain wood fibre compound.
6. according to any one of the claim 3-5 corrosion-resistant water-fast water paints, it is characterised in that wood fibre compound is adopted
Prepared with following technique：Water content is added water to for 40-48wt% to 16-20 parts of bean powderes by weight, glue mill processing to 250-350
Mesh, adds 25-35 parts of Tissuemat Es, is warming up to 65-75 DEG C of stirring 2-4h, adds 10-20 parts of wood fibres, 4-8 parts of paulownia horse acid
80-90 DEG C is warming up under acid anhydride methyl esters, 25-45 parts of dimethylformamide mixing, stirring, continues to stir 4-8h, is down to room temperature,
Filtering, solids is washed with acetone, 110-120 DEG C of dry 6-9h, and crushing obtains wood fibre compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522356.5A CN107325695A (en) | 2017-06-30 | 2017-06-30 | A kind of corrosion-resistant water-fast water paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522356.5A CN107325695A (en) | 2017-06-30 | 2017-06-30 | A kind of corrosion-resistant water-fast water paint |
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| CN107325695A true CN107325695A (en) | 2017-11-07 |
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| CN201710522356.5A Withdrawn CN107325695A (en) | 2017-06-30 | 2017-06-30 | A kind of corrosion-resistant water-fast water paint |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112175491A (en) * | 2020-10-22 | 2021-01-05 | 湖南墙上飞涂料有限公司 | Novel water-based paint for protecting indoor wall |
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| CN101475767A (en) * | 2006-03-31 | 2009-07-08 | 中国科学院过程工程研究所 | Coating for collecting formaldehyde |
| CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
| CN101993644A (en) * | 2009-08-05 | 2011-03-30 | 关西涂料株式会社 | Anticorrosive paint composition |
| CN102206917A (en) * | 2011-03-29 | 2011-10-05 | 中国林业科学研究院林产化学工业研究所 | Method for manufacturing methyl malei-eleostearate anhydride modified wood fiber |
| CN104059598A (en) * | 2014-06-19 | 2014-09-24 | 东营人造板厂 | Method for manufacturing soybean protein modified adhesive formaldehyde-free medium-density fiberboard |
| CN105385295A (en) * | 2015-11-14 | 2016-03-09 | 合肥标兵凯基新型材料有限公司 | Modified waterborne epoxy resin paint specially used for pop can |
-
2017
- 2017-06-30 CN CN201710522356.5A patent/CN107325695A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475767A (en) * | 2006-03-31 | 2009-07-08 | 中国科学院过程工程研究所 | Coating for collecting formaldehyde |
| CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
| CN101993644A (en) * | 2009-08-05 | 2011-03-30 | 关西涂料株式会社 | Anticorrosive paint composition |
| CN102206917A (en) * | 2011-03-29 | 2011-10-05 | 中国林业科学研究院林产化学工业研究所 | Method for manufacturing methyl malei-eleostearate anhydride modified wood fiber |
| CN104059598A (en) * | 2014-06-19 | 2014-09-24 | 东营人造板厂 | Method for manufacturing soybean protein modified adhesive formaldehyde-free medium-density fiberboard |
| CN105385295A (en) * | 2015-11-14 | 2016-03-09 | 合肥标兵凯基新型材料有限公司 | Modified waterborne epoxy resin paint specially used for pop can |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112175491A (en) * | 2020-10-22 | 2021-01-05 | 湖南墙上飞涂料有限公司 | Novel water-based paint for protecting indoor wall |
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Application publication date: 20171107 |
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