CN106674670A - High temperature-resisting anti-corrosion cable for ship - Google Patents

High temperature-resisting anti-corrosion cable for ship Download PDF

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Publication number
CN106674670A
CN106674670A CN201611131684.4A CN201611131684A CN106674670A CN 106674670 A CN106674670 A CN 106674670A CN 201611131684 A CN201611131684 A CN 201611131684A CN 106674670 A CN106674670 A CN 106674670A
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parts
asbestos fiber
corrosion
restrictive coating
weight
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毛文秀
杨小康
李贻斌
周承兰
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Electric Group PLC Of Jin Yuan
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Electric Group PLC Of Jin Yuan
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00Compositions of rubber derivatives
    • C08L15/02Rubber derivatives containing halogen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a high temperature-resisting anti-corrosion cable for a ship. The high temperature-resisting anti-corrosion cable comprises a conductor and a jacket layer sleeved on the outer side of the conductor, wherein the jacket layer comprises the following raw materials in parts by weight: 25-35 parts of fluorinated silicone rubber, 70-90 parts of chlorinated rubber, 1.4-2 parts of 202 resin, 1.4-2.2 parts of di-tert-butyl peroxide, 25-35 parts of shell powder, 25-45 parts of modified asbestos fiber, 1.5-2.5 parts of polyphenylene sulfide, 4-6 parts of phenyl triethoxy silane, 0.6-1 part of coal tar, 0.4-0.8 part of epoxidized soybean oil, 0.4-0.8 part of epoxy rice bran butyl oleate, 1-2 parts of disproportionated rosin, 4-10 parts of saw dust, 1.5-2.5 parts of gamma-(ethylenediamine) propyl methyl dimethoxy silane, 1-1.6 parts of butyl titanate and 1.5-3.5 parts of maleic anhydride. The high temperature-resisting anti-corrosion cable for the ship, provided by the invention, has excellent corrosion resistance and is easy to degrade after being abandoned.

Description

A kind of ship corrosion-and high-temp-resistant cable
Technical field
The present invention relates to field of cable technology, more particularly to a kind of ship corrosion-and high-temp-resistant cable.
Background technology
With the development of science and technology, cable has become article indispensable in people's life, in mine, marine boat Cable must be all used in row and factory, but is all different, traditional electricity in requirement of the varying environment to cable Cable functions only as holding current-carrying effect, and itself does not have the abilities such as protection against the tide, waterproof, so people must just solve these asking Inscribe to adapt to various environment.At present marine ships cable requires very high, existing many cables to decay resistance Use sheath inferior, life-time service not only will cause damage to copper wire, and had a strong impact on the safe handling of cable, how to have pressed down The generation of this phenomenon is made, at sea normally travel is particularly important for ship.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of ship corrosion-and high-temp-resistant cable, resists Corrosivity are fabulous, while degradable after discarded.
A kind of ship corrosion-and high-temp-resistant cable proposed by the present invention, including conductor and the sheath being coated on the outside of conductor Layer;The raw material of restrictive coating includes by weight:Fluorosioloxane rubber 25-35 parts, chlorinated rubber 70-90 parts, 202 resin 1.4-2 parts, mistake Oxidation di-t-butyl 1.4-2.2 parts, conch meal 25-35 parts, modified asbestos fiber 25-45 parts, polyphenylene sulfide 1.5-2.5 parts, benzene Ethyl triethoxy silicane alkane 4-6 parts, coal tar 0.6-1 parts, epoxy soybean oil 0.4-0.8 parts, epoxyfuoic-oleic 0.4-0.8 Part, disproportionated rosin 1-2 parts, wood flour 4-10 parts, γ-(ethylenediamine base) hydroxypropyl methyl dimethoxysilane 1.5-2.5 parts, metatitanic acid fourth Ester 1-1.6 parts, maleic anhydride 1.5-3.5 parts.
Preferably, in the raw material of restrictive coating, fluorosioloxane rubber, chlorinated rubber, 202 resins, di-t-butyl peroxide, modified stone The weight ratio of cotton fiber is 28-32:75-85:1.6-1.8:1.6-2:30-40.
Preferably, in the raw material of restrictive coating, conch meal, modified asbestos fiber, polyphenylene sulfide, phenyl triethoxysilane, Coal tar, epoxy soybean oil, epoxyfuoic-oleic, the weight ratio of disproportionated rosin are 28-32:30-40:1.7-2.3:4.5- 5.5:0.7-0.9:0.5-0.7:0.5-0.7:1.5-1.7.
Preferably, the raw material of restrictive coating includes by weight:Fluorosioloxane rubber 28-32 parts, chlorinated rubber 75-85 parts, 202 trees Fat 1.6-1.8 parts, di-t-butyl peroxide 1.6-2 parts, conch meal 28-32 parts, modified asbestos fiber 30-40 parts, polyphenylene sulfide 1.7-2.3 parts, phenyl triethoxysilane 4.5-5.5 parts, coal tar 0.7-0.9 parts, epoxy soybean oil 0.5-0.7 parts, epoxy Rice oil acid butyl ester 0.5-0.7 parts, disproportionated rosin 1.5-1.7 parts, wood flour 6-8 parts, γ-(ethylenediamine base) hydroxypropyl methyl dimethoxy Silane 1.8-2.2 parts, butyl titanate 1.2-1.4 parts, maleic anhydride 2-3 parts.
Preferably, the modified asbestos fiber in restrictive coating raw material is prepared using following technique:Nitrogen protection is lower will double-N, N- (hydroxypropyl sulfobetaines base propyl group) secondary amine, chloroform mixing and stirring, add in lauric acid/dodecanoic acid acyl chlorides, cooling under stirring Stirring, sends into recrystallization in DMF, removes solvent, is dried to obtain prefabricated material;By Asbestos Fibre Bundles, condensation silicon Sour sodium, water are mixed, and add graphite powder, Disodium sulfosuccinate to mix, and add enuatrol intensification stirring, are added prefabricated Material, aluminum sulfate mix homogeneously, dry, pulverize and obtain modified asbestos fiber.
Preferably, the modified asbestos fiber in restrictive coating raw material is prepared using following technique:Under nitrogen protection by weight By the double-N of 1-2 parts, N- (hydroxypropyl sulfobetaines base propyl group) secondary amine, 25-35 part chloroform mixing and stirrings, under stirring In adding 1.5-2.5 part lauric acid/dodecanoic acid acyl chlorides, recrystallization in DMF is sent in cooling stirring, removes solvent, is dried Obtain prefabricated material;15-23 part Asbestos Fibre Bundles, 2-4 part condensation of sodium silicate, 100-130 parts water are mixed by weight, plus Enter 2-4 part graphite powders, 1-2 parts Disodium sulfosuccinate to mix, add 2-5 parts enuatrol to heat up and stir, add 2-6 parts pre- System material, 1-2 part aluminum sulfate mix homogeneously, dry, pulverize and obtain modified asbestos fiber.
Preferably, the modified asbestos fiber in restrictive coating raw material is prepared using following technique:Under nitrogen protection by weight By the double-N of 1-2 parts, N- (hydroxypropyl sulfobetaines base propyl group) secondary amine, 25-35 part chloroform mixing and stirrings, under stirring In adding 1.5-2.5 part lauric acid/dodecanoic acid acyl chlorides, 2-6 DEG C of stirring 2-4h is cooled to, sends into recrystallization in DMF, gone Except solvent, prefabricated material is dried to obtain;By weight by 15-23 part Asbestos Fibre Bundles, 2-4 part condensation of sodium silicate, 100-130 part water 2-6h is mixed, adds 2-4 part graphite powders, 1-2 parts Disodium sulfosuccinate to mix 80-120min, add 2-5 parts oil Sour sodium is warming up to 60-70 DEG C of stirring 80-120min, adds the prefabricated material of 2-6 parts, 1-2 part aluminum sulfate mix homogeneously, dry, pulverize Obtain modified asbestos fiber.
The present invention is obtained using conventional fabrication process.
In the prefabricated material of the modified asbestos fiber of the present invention, make prefabricated material that there is good life by introducing amide functional group Thing degradability, mildness and chemical stability, and containing abundant parents' base can make prefabricated material have good solubilizing effect, stone Cotton fiber beam is acted on condensation of sodium silicate, and its internal structure can be effectively loose, is further made with the graphite powder for adding With in Disodium sulfosuccinate effect, not only mutual good penetrability, and graphite powder is formed with asbestos fibre and interlinked, pre- System material, the lower solidification of aluminum sulfate effect, high temperature resistant, excellent corrosion resistance after drying and crushing, and good stability;The present invention is adopted Modified asbestos fiber, conch meal and maleic anhydride, γ-(ethylenediamine base) hydroxypropyl methyl dimethoxysilane, butyl titanate effect, And coordinate after sulfuration with chlorinated rubber, fluorosioloxane rubber, high temperature resistant chemical bond can be not only formed, corrosion resistance is fabulous, while It is degradable after discarded.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of ship corrosion-and high-temp-resistant cable proposed by the present invention, including conductor and the sheath being coated on the outside of conductor Layer;The raw material of restrictive coating includes by weight:25 parts of fluorosioloxane rubber, 90 parts of chlorinated rubber, 202 1.4 parts of resins, the uncle of peroxidating two 2.2 parts of butyl, 25 parts of conch meal, 45 parts of modified asbestos fiber, 1.5 parts of polyphenylene sulfide, 6 parts of phenyl triethoxysilane, coal tar 0.6 part of oil, 0.8 part of epoxy soybean oil, 0.4 part of epoxyfuoic-oleic, 2 parts of disproportionated rosin, 4 parts of wood flour, γ-(ethylenediamine base) 2.5 parts of hydroxypropyl methyl dimethoxysilane, 1 part of butyl titanate, 3.5 parts of maleic anhydride.
Embodiment 2
A kind of ship corrosion-and high-temp-resistant cable proposed by the present invention, including conductor and the sheath being coated on the outside of conductor Layer;The raw material of restrictive coating includes by weight:35 parts of fluorosioloxane rubber, 70 parts of chlorinated rubber, 202 2 parts of resins, the tertiary fourth of peroxidating two 1.4 parts of base, 35 parts of conch meal, 25 parts of modified asbestos fiber, 2.5 parts of polyphenylene sulfide, 4 parts of phenyl triethoxysilane, coal tar 1 Part, 0.4 part of epoxy soybean oil, 0.8 part of epoxyfuoic-oleic, 1 part of disproportionated rosin, 10 parts of wood flour, γ-(ethylenediamine base) propyl group 1.5 parts of methyl dimethoxysilane, 1.6 parts of butyl titanate, 1.5 parts of maleic anhydride.
Modified asbestos fiber in restrictive coating raw material is prepared using following technique:Nitrogen protection is lower by double-N, N- (hydroxypropyls Sulfobetaines base propyl group) secondary amine, chloroform mixing and stirring, under stirring add lauric acid/dodecanoic acid acyl chlorides in, cooling stirring, send Enter recrystallization in DMF, remove solvent, be dried to obtain prefabricated material;By Asbestos Fibre Bundles, condensation of sodium silicate, water Mix, add graphite powder, Disodium sulfosuccinate to mix, add enuatrol intensification stirring, add prefabricated material, sulphuric acid Aluminum mix homogeneously, dry, pulverize and obtain modified asbestos fiber.
Embodiment 3
A kind of ship corrosion-and high-temp-resistant cable proposed by the present invention, including conductor and the sheath being coated on the outside of conductor Layer;The raw material of restrictive coating includes by weight:28 parts of fluorosioloxane rubber, 85 parts of chlorinated rubber, 202 1.6 parts of resins, the uncle of peroxidating two 2 parts of butyl, 28 parts of conch meal, 40 parts of modified asbestos fiber, 1.7 parts of polyphenylene sulfide, 5.5 parts of phenyl triethoxysilane, coal tar 0.7 part of oil, 0.7 part of epoxy soybean oil, 0.5 part of epoxyfuoic-oleic, 1.7 parts of disproportionated rosin, 6 parts of wood flour, γ-(ethylenediamine Base) 2.2 parts of hydroxypropyl methyl dimethoxysilane, 1.2 parts of butyl titanate, 3 parts of maleic anhydride.
Modified asbestos fiber in restrictive coating raw material is prepared using following technique:Under nitrogen protection by weight by 1 part it is double- N, N- (hydroxypropyl sulfobetaines base propyl group) secondary amine, 35 parts of chloroform mixing and stirrings, add 1.5 part 12 under stirring In isoxazolecarboxylic acid, 6 DEG C of stirring 2h are cooled to, send into recrystallization in DMF, remove solvent, be dried to obtain prefabricated Material;By weight 23 parts of Asbestos Fibre Bundles, 2 parts of condensation of sodium silicate, 130 parts of water are mixed into 2h, add 4 parts of graphite powders, 1 part Disodium sulfosuccinate mixes 120min, adds 2 parts of enuatrols to be warming up to 70 DEG C of stirring 80min, add 6 parts of prefabricated material, 1 Part aluminum sulfate mix homogeneously, dry, pulverize and obtain modified asbestos fiber.
Embodiment 4
A kind of ship corrosion-and high-temp-resistant cable proposed by the present invention, including conductor and the sheath being coated on the outside of conductor Layer;The raw material of restrictive coating includes by weight:32 parts of fluorosioloxane rubber, 75 parts of chlorinated rubber, 202 1.8 parts of resins, the uncle of peroxidating two 1.6 parts of butyl, 32 parts of conch meal, 30 parts of modified asbestos fiber, 2.3 parts of polyphenylene sulfide, 4.5 parts of phenyl triethoxysilane, coal 0.9 part of tar, 0.5 part of epoxy soybean oil, 0.7 part of epoxyfuoic-oleic, 1.5 parts of disproportionated rosin, 8 parts of wood flour, γ-(second two Amido) 1.8 parts of hydroxypropyl methyl dimethoxysilane, 1.4 parts of butyl titanate, 2 parts of maleic anhydride.
Modified asbestos fiber in restrictive coating raw material is prepared using following technique:Under nitrogen protection by weight by 2 parts it is double- N, N- (hydroxypropyl sulfobetaines base propyl group) secondary amine, 25 parts of chloroform mixing and stirrings, add 2.5 part 12 under stirring In isoxazolecarboxylic acid, 2 DEG C of stirring 4h are cooled to, send into recrystallization in DMF, remove solvent, be dried to obtain prefabricated Material;By weight 15 parts of Asbestos Fibre Bundles, 4 parts of condensation of sodium silicate, 100 parts of water are mixed into 6h, add 2 parts of graphite powders, 2 parts Disodium sulfosuccinate mixes 80min, adds 5 parts of enuatrols to be warming up to 60 DEG C of stirring 120min, add 2 parts of prefabricated material, 2 Part aluminum sulfate mix homogeneously, dry, pulverize and obtain modified asbestos fiber.
Embodiment 5
A kind of ship corrosion-and high-temp-resistant cable proposed by the present invention, including conductor and the sheath being coated on the outside of conductor Layer;The raw material of restrictive coating includes by weight:30 parts of fluorosioloxane rubber, 80 parts of chlorinated rubber, 202 1.7 parts of resins, the uncle of peroxidating two 1.8 parts of butyl, 30 parts of conch meal, 35 parts of modified asbestos fiber, 2 parts of polyphenylene sulfide, 5 parts of phenyl triethoxysilane, coal tar 0.8 part, 0.6 part of epoxy soybean oil, 0.6 part of epoxyfuoic-oleic, 1.6 parts of disproportionated rosin, 7 parts of wood flour, γ-(ethylenediamine base) 2 parts of hydroxypropyl methyl dimethoxysilane, 1.3 parts of butyl titanate, 2.5 parts of maleic anhydride.
Modified asbestos fiber in restrictive coating raw material is prepared using following technique:By weight by 1.5 parts under nitrogen protection Double-N, N- (hydroxypropyl sulfobetaines base propyl group) secondary amine, 30 parts of chloroform mixing and stirrings, add 2 part ten under stirring In diacid chloride, recrystallization in DMF is sent in cooling stirring, removes solvent, is dried to obtain prefabricated material;By weight Amount part mixes in 20 parts of Asbestos Fibre Bundles, 3 parts of condensation of sodium silicate, 120 parts of water, adds 3 parts of graphite powders, 1.5 parts of succinic acid Ester sodium sulfonate is mixed, and is added 3.5 parts of enuatrols to heat up and is stirred, and adds 4 parts of prefabricated material, 1.5 parts of aluminum sulfate mix homogeneously, is done Dry, crushing obtains modified asbestos fiber.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.

Claims (7)

1. a kind of ship corrosion-and high-temp-resistant cable, it is characterised in that including conductor and the restrictive coating being coated on the outside of conductor; The raw material of restrictive coating includes by weight:Fluorosioloxane rubber 25-35 parts, chlorinated rubber 70-90 parts, 202 resin 1.4-2 parts, peroxide Change di-t-butyl 1.4-2.2 parts, conch meal 25-35 parts, modified asbestos fiber 25-45 parts, polyphenylene sulfide 1.5-2.5 parts, phenyl Triethoxysilane 4-6 parts, coal tar 0.6-1 parts, epoxy soybean oil 0.4-0.8 parts, epoxyfuoic-oleic 0.4-0.8 parts, Disproportionated rosin 1-2 parts, wood flour 4-10 parts, γ-(ethylenediamine base) hydroxypropyl methyl dimethoxysilane 1.5-2.5 parts, butyl titanate 1-1.6 parts, maleic anhydride 1.5-3.5 parts.
2. ship corrosion-and high-temp-resistant cable according to claim 1, it is characterised in that in the raw material of restrictive coating, fluorine silicon Rubber, chlorinated rubber, 202 resins, di-t-butyl peroxide, the weight ratio of modified asbestos fiber are 28-32:75-85:1.6- 1.8:1.6-2:30-40.
3. ship according to claim 1 or claim 2 corrosion-and high-temp-resistant cable, it is characterised in that in the raw material of restrictive coating, shellfish Shell powder, modified asbestos fiber, polyphenylene sulfide, phenyl triethoxysilane, coal tar, epoxy soybean oil, epoxyfuoic-oleic, The weight ratio of disproportionated rosin is 28-32:30-40:1.7-2.3:4.5-5.5:0.7-0.9:0.5-0.7:0.5-0.7:1.5- 1.7。
4. the corrosion-and high-temp-resistant cable of the ship according to any one of claim 1-3, it is characterised in that the raw material of restrictive coating Include by weight:Fluorosioloxane rubber 28-32 parts, chlorinated rubber 75-85 parts, 202 resin 1.6-1.8 parts, di-t-butyl peroxide 1.6-2 parts, conch meal 28-32 parts, modified asbestos fiber 30-40 parts, polyphenylene sulfide 1.7-2.3 parts, phenyl triethoxysilane 4.5-5.5 parts, coal tar 0.7-0.9 parts, epoxy soybean oil 0.5-0.7 parts, epoxyfuoic-oleic 0.5-0.7 parts, disproportionation pine Fragrant 1.5-1.7 parts, wood flour 6-8 parts, γ-(ethylenediamine base) hydroxypropyl methyl dimethoxysilane 1.8-2.2 parts, butyl titanate 1.2- 1.4 parts, maleic anhydride 2-3 parts.
5. the corrosion-and high-temp-resistant cable of the ship according to any one of claim 1-4, it is characterised in that in restrictive coating raw material Modified asbestos fiber using following technique prepare:Nitrogen protection is lower by double-N, and N- (hydroxypropyl sulfobetaines base propyl group) is secondary Amine, chloroform mixing and stirring, add in lauric acid/dodecanoic acid acyl chlorides under stirring, and DMF is sent in cooling stirring Middle recrystallization, removes solvent, is dried to obtain prefabricated material;Asbestos Fibre Bundles, condensation of sodium silicate, water are mixed, graphite is added Powder, Disodium sulfosuccinate are mixed, and are added enuatrol to heat up and are stirred, and add prefabricated material, aluminum sulfate mix homogeneously, are dried, Crushing obtains modified asbestos fiber.
6. the corrosion-and high-temp-resistant cable of the ship according to any one of claim 1-5, it is characterised in that in restrictive coating raw material Modified asbestos fiber using following technique prepare:By weight by the double-N of 1-2 parts under nitrogen protection, (hydroxypropyl sulfo group is sweet for N- Dish base propyl group) secondary amine, 25-35 part chloroform mixing and stirrings, under stirring add 1.5-2.5 part lauric acid/dodecanoic acid acyl chlorides in, Cooling stirring, sends into recrystallization in DMF, removes solvent, is dried to obtain prefabricated material;By weight by 15-23 Part Asbestos Fibre Bundles, 2-4 part condensation of sodium silicate, 100-130 parts water are mixed, and add 2-4 part graphite powders, 1-2 part succinic acid Ester sodium sulfonate is mixed, and is added 2-5 parts enuatrol to heat up and is stirred, and adds the prefabricated material of 2-6 parts, 1-2 part aluminum sulfate mix homogeneously, Dry, pulverize and obtain modified asbestos fiber.
7. the corrosion-and high-temp-resistant cable of the ship according to any one of claim 1-6, it is characterised in that in restrictive coating raw material Modified asbestos fiber using following technique prepare:By weight by the double-N of 1-2 parts under nitrogen protection, (hydroxypropyl sulfo group is sweet for N- Dish base propyl group) secondary amine, 25-35 part chloroform mixing and stirrings, under stirring add 1.5-2.5 part lauric acid/dodecanoic acid acyl chlorides in, 2-6 DEG C of stirring 2-4h is cooled to, recrystallization in DMF is sent into, solvent is removed, prefabricated material is dried to obtain;By weight 15-23 part Asbestos Fibre Bundles, 2-4 part condensation of sodium silicate, 100-130 parts water are mixed 2-6h by amount part, add 2-4 part graphite Powder, 1-2 parts Disodium sulfosuccinate mix 80-120min, add 2-5 part enuatrols to be warming up to 60-70 DEG C of stirring 80- 120min, adds the prefabricated material of 2-6 parts, 1-2 part aluminum sulfate mix homogeneously, dry, pulverize and obtains modified asbestos fiber.
CN201611131684.4A 2016-12-09 2016-12-09 High temperature-resisting anti-corrosion cable for ship Withdrawn CN106674670A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107216654A (en) * 2017-05-31 2017-09-29 晋源电气集团股份有限公司 A kind of diglyhus isaea
CN107353651A (en) * 2017-05-31 2017-11-17 晋源电气集团股份有限公司 A kind of oil resistant Acidproof cable oversheath
CN110343387A (en) * 2019-07-09 2019-10-18 苏州经贸职业技术学院 Preparation method based on electronic welding real training high temperature protection material
CN117238564A (en) * 2023-09-19 2023-12-15 安徽省康利亚股份有限公司 Cable for railway vehicle

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CN104437238A (en) * 2014-12-11 2015-03-25 江南大学 Amide-type bis-hydroxypropyl sulphobetaine surfactant as well as preparation method and application thereof
CN105504379A (en) * 2015-12-31 2016-04-20 天长市富信电子有限公司 Rubber sheath material for motor power line and preparation method thereof
CN105647037A (en) * 2016-03-01 2016-06-08 苏州科茂电子材料科技有限公司 Cable sheath material resistant to acid and base corrosion and preparation method of cable sheath material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1058793A (en) * 1991-08-22 1992-02-19 青岛石棉制品总厂 The preparation method of graphite modified asbestos seal filler
CN104437238A (en) * 2014-12-11 2015-03-25 江南大学 Amide-type bis-hydroxypropyl sulphobetaine surfactant as well as preparation method and application thereof
CN105504379A (en) * 2015-12-31 2016-04-20 天长市富信电子有限公司 Rubber sheath material for motor power line and preparation method thereof
CN105647037A (en) * 2016-03-01 2016-06-08 苏州科茂电子材料科技有限公司 Cable sheath material resistant to acid and base corrosion and preparation method of cable sheath material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107216654A (en) * 2017-05-31 2017-09-29 晋源电气集团股份有限公司 A kind of diglyhus isaea
CN107353651A (en) * 2017-05-31 2017-11-17 晋源电气集团股份有限公司 A kind of oil resistant Acidproof cable oversheath
CN110343387A (en) * 2019-07-09 2019-10-18 苏州经贸职业技术学院 Preparation method based on electronic welding real training high temperature protection material
CN117238564A (en) * 2023-09-19 2023-12-15 安徽省康利亚股份有限公司 Cable for railway vehicle
CN117238564B (en) * 2023-09-19 2024-05-07 安徽省康利亚股份有限公司 Cable for railway vehicle

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Application publication date: 20170517