CN105647037A - Cable sheath material resistant to acid and base corrosion and preparation method of cable sheath material - Google Patents

Cable sheath material resistant to acid and base corrosion and preparation method of cable sheath material Download PDF

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Publication number
CN105647037A
CN105647037A CN201610113928.XA CN201610113928A CN105647037A CN 105647037 A CN105647037 A CN 105647037A CN 201610113928 A CN201610113928 A CN 201610113928A CN 105647037 A CN105647037 A CN 105647037A
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parts
acid
cable sheath
sheath material
methyl
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CN201610113928.XA
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邹黎清
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SUZHOU KEMAO ELECTRONIC MATERIAL TECHNOLOGY Co Ltd
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SUZHOU KEMAO ELECTRONIC MATERIAL TECHNOLOGY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/2806Protection against damage caused by corrosion
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing Of Electric Cables (AREA)
  • Insulated Conductors (AREA)

Abstract

The invention discloses a cable sheath material resistant to acid and base corrosion. The cable sheath material comprises components in parts by weight as follows: 40-50 parts of chlorinated butyl rubber, 30-40 parts of fluorosilicone rubber, 20-30 parts of polyvinyl chloride, 12-18 parts of polyphenylene sulfide, 3-8 parts of silicon carbide, 15-20 parts of 4-(carboxymethyl)phenylboronic acid pinacol ester, 8-15 parts of a molecular sieve, 8-16 parts of 2-isopropyl-5-methylhexyl acetate, 6-12 parts of cedryl formate, 7-11 parts of ethylene glycol, 3-8 parts of di-cyclopentyl dimethoxy silane, 2-9 parts of methyl-tri(butanone-oxime)silane and 2-6 parts of 2-ethyl-4-methylimidazole. The cable sheath material has good acid and base resistance and can meet the operation requirement of cables in acid and base working environments.

Description

A kind of acid-alkali-corrosive-resisting cable sheath material and preparation method thereof
Technical field
The invention belongs to cable sheath material field, be specifically related to a kind of acid-alkali-corrosive-resisting cable sheath material and preparation method thereof.
Background technology
Along with developing rapidly of electric wire, the use scope of cable and environment are increasingly wider, and at the working environment that some are comparatively severe, in working environment acid, alkaline, cable tends to be corroded by materials such as soda acids. Often there is the situation such as dropout, poor TV signal Chu in transmitting procedure in the cable being corroded, has a strong impact on the transmitting procedure of cable, affects stability and the reliability of its work. Therefore, the cable cover(ing) how being developed to better conform to soda acid adverse circumstances seems extremely important.
Summary of the invention
For the above technical problem existed in prior art, the present invention provides a kind of acid-alkali-corrosive-resisting cable sheath material and preparation method thereof, and this cable sheath material can meet the job requirements of cable under soda acid working environment.
Technical scheme: a kind of acid-alkali-corrosive-resisting cable sheath material, including the composition of following parts by weight: chlorinated scoline 40-50 part, fluorosioloxane rubber 30-40 part, polrvinyl chloride 20-30 part, polyphenylene sulfide 12-18 part, carborundum 3-8 part, 4-(carboxymethyl) phenylboric acid pinacol ester 15-20 part, molecular sieve 8-15 part, 2-isopropyl-5-methyl own ester acetic acid 8-16 part, cedryl formate 6-12 part, ethylene glycol oleate 7-11 part, dicyclopentyl dimethoxyl silane 3-8 part, methyl tributanoximo silane 2-9 part, 2-ethyl-4-methylimidazole 2-6 part.
Preferably, described chlorinated scoline 42-48 part, fluorosioloxane rubber 35-40 part, polrvinyl chloride 22-28 part, polyphenylene sulfide 14-17 part, carborundum 4-7 part, 4-(carboxymethyl) phenylboric acid pinacol ester 16-19 part, molecular sieve 10-13 part, 2-isopropyl-5-methyl own ester acetic acid 10-14 part, cedryl formate 8-11 part, ethylene glycol oleate 9-11 part, dicyclopentyl dimethoxyl silane 5-7 part, methyl tributanoximo silane 3-8 part, 2-ethyl-4-methylimidazole 4-6 part.
Preferably, described chlorinated scoline 46 parts, fluorosioloxane rubber 38 parts, polrvinyl chloride 25 parts, polyphenylene sulfide 16 parts, carborundum 5 parts, 4-(carboxymethyl) phenylboric acid pinacol ester 18 parts, 12 parts of molecular sieve, the own ester acetic acid of 2-isopropyl-5-methyl 13 parts, cedryl formate 10 parts, ethylene glycol oleate 10 parts, dicyclopentyl dimethoxyl silane 6 parts, methyl tributanoximo silane 6 parts, 2-ethyl-4-methylimidazole 5 parts.
The preparation method of a kind of acid-alkali-corrosive-resisting cable sheath material, comprises the steps:
(1) chlorinated scoline 40-50 part, carborundum 3-8 part, 4-(carboxymethyl) phenylboric acid pinacol ester 15-20 part and polyphenylene sulfide 12-18 part are added in reactor, at temperature 35-45 DEG C, stir 20-30min;
(2) in step (1), add molecular sieve 8-15 part, 2-isopropyl-5-methyl own ester acetic acid 8-16 part, ethylene glycol oleate 7-11 part and dicyclopentyl dimethoxyl silane 3-8 part, raise temperature and stir 30-40min to 60-70 DEG C with 250-300r/min speed;
(3) in step (2), add fluorosioloxane rubber 30-40 part and polrvinyl chloride 20-30 part, continue to raise temperature to 80-95 DEG C, after reaction 10-15min;
(4) reacted product, cedryl formate 6-12 part, methyl tributanoximo silane 2-9 part in step (3) are added in banbury together with 2-ethyl-4-methylimidazole 2-6 part, mixing 3-5min at temperature 90-100 DEG C, extruded machine extrusion can obtain described cable sheath material subsequently.
Preferably, temperature described in step (1) is 42 DEG C, stirs 25min.
Preferably, temperature described in step (2) is 65 DEG C, and speed is 280r/min.
Preferably, temperature described in step (3) is 92 DEG C, reacts 12min.
Preferably, temperature described in step (4) is 95 DEG C, mixing 4min.
Beneficial effect:The preparation method of a kind of acid-alkali-corrosive-resisting cable sheath material of the present invention, prepares cable sheath material by 4-(carboxymethyl) phenylboric acid pinacol ester, molecular sieve, the own ester acetic acid of 2-isopropyl-5-methyl, cedryl formate, ethylene glycol oleate, dicyclopentyl dimethoxyl silane, methyl tributanoximo silane and 2-ethyl-4-methylimidazole through techniques such as heating, stirring, banburying, extrusions; When this cable sheath material can carry out operation in acid-base environment, it is to avoid be subject to the corrosion of acid and alkali substance, it is ensured that the stable transmission signal of cable, improve the service life of cable.
Detailed description of the invention
Embodiment 1
(1) in chlorinated scoline 40 parts, carborundum 3 parts, 4-(carboxymethyl) phenylboric acid pinacol ester 15 parts and 12 parts of addition reactors of polyphenylene sulfide, 20min will be stirred at temperature 35 DEG C;
(2) in step (1), add 8 parts of molecular sieve, the own ester acetic acid of 2-isopropyl-5-methyl 8 parts, ethylene glycol oleate 7 parts and dicyclopentyl dimethoxyl silane 3 parts, raise temperature and stir 30min to 60 DEG C with 250r/min speed;
(3) in step (2), add fluorosioloxane rubber 30 parts and polrvinyl chloride 20 parts, continue to raise temperature to 80 DEG C, after reaction 10min;
(4) reacted product, cedryl formate 6 parts, methyl tributanoximo silane 2 parts in step (3) are added in banbury together with 2-ethyl-4-methylimidazole 2 parts, mixing 3min at temperature 90 DEG C, extruded machine extrusion can obtain described cable sheath material subsequently.
Comparative example 1
(1) in chlorinated scoline 40 parts, carborundum 3 parts and 12 parts of addition reactors of polyphenylene sulfide, 20min will be stirred at temperature 35 DEG C;
(2) in step (1), add fluorosioloxane rubber 30 parts and polrvinyl chloride 20 parts, continue to raise temperature to 80 DEG C, after reaction 10min;
(3) adding in banbury by reacted product in step (2), mixing 3min at temperature 90 DEG C, extruded machine extrusion can obtain cable sheath material subsequently.
Embodiment 2
(1) in chlorinated scoline 50 parts, carborundum 8 parts, 4-(carboxymethyl) phenylboric acid pinacol ester 20 parts and 18 parts of addition reactors of polyphenylene sulfide, 30min will be stirred under temperature 45 C;
(2) in step (1), add 15 parts of molecular sieve, the own ester acetic acid of 2-isopropyl-5-methyl 16 parts, ethylene glycol oleate 11 parts and dicyclopentyl dimethoxyl silane 8 parts, raise temperature and stir 40min to 70 DEG C with 300r/min speed;
(3) in step (2), add fluorosioloxane rubber 40 parts and polrvinyl chloride 30 parts, continue to raise temperature to 95 DEG C, after reaction 15min;
(4) reacted product, cedryl formate 12 parts, methyl tributanoximo silane 9 parts in step (3) are added in banbury together with 2-ethyl-4-methylimidazole 6 parts, mixing 5min at temperature 100 DEG C, extruded machine extrusion can obtain described cable sheath material subsequently.
Comparative example 2
(1) in chlorinated scoline 50 parts, carborundum 8 parts and 18 parts of addition reactors of polyphenylene sulfide, 30min will be stirred under temperature 45 C;
(2) in step (1), add fluorosioloxane rubber 40 parts and polrvinyl chloride 30 parts, continue to raise temperature to 95 DEG C, after reaction 15min;
(3) adding in banbury by reacted product in step (2), mixing 5min at temperature 100 DEG C, extruded machine extrusion can obtain described cable sheath material subsequently.
Embodiment 3
(1) in chlorinated scoline 42 parts, carborundum 4 parts, 4-(carboxymethyl) phenylboric acid pinacol ester 16 parts and 14 parts of addition reactors of polyphenylene sulfide, 20min will be stirred at temperature 35 DEG C;
(2) in step (1), add 10 parts of molecular sieve, the own ester acetic acid of 2-isopropyl-5-methyl 10 parts, ethylene glycol oleate 9 parts and dicyclopentyl dimethoxyl silane 5 parts, raise temperature and stir 30min to 60 DEG C with 250r/min speed;
(3) in step (2), add fluorosioloxane rubber 35 parts and polrvinyl chloride 22 parts, continue to raise temperature to 80 DEG C, after reaction 10min;
(4) reacted product, cedryl formate 8 parts, methyl tributanoximo silane 3 parts in step (3) are added in banbury together with 2-ethyl-4-methylimidazole 4 parts, mixing 3min at temperature 90 DEG C, extruded machine extrusion can obtain described cable sheath material subsequently.
Embodiment 4
(1) in chlorinated scoline 48 parts, carborundum 7 parts, 4-(carboxymethyl) phenylboric acid pinacol ester 19 parts and 17 parts of addition reactors of polyphenylene sulfide, 30min will be stirred under temperature 45 C;
(2) in step (1), add 13 parts of molecular sieve, the own ester acetic acid of 2-isopropyl-5-methyl 14 parts, ethylene glycol oleate 11 parts and dicyclopentyl dimethoxyl silane 7 parts, raise temperature and stir 40min to 70 DEG C with 300r/min speed;
(3) in step (2), add fluorosioloxane rubber 40 parts and polrvinyl chloride 28 parts, continue to raise temperature to 95 DEG C, after reaction 15min;
(4) reacted product, cedryl formate 11 parts, methyl tributanoximo silane 8 parts in step (3) are added in banbury together with 2-ethyl-4-methylimidazole 6 parts, mixing 5min at temperature 100 DEG C, extruded machine extrusion can obtain described cable sheath material subsequently.
Embodiment 5
(1) in chlorinated scoline 46 parts, carborundum 5 parts, 4-(carboxymethyl) phenylboric acid pinacol ester 18 parts and 16 parts of addition reactors of polyphenylene sulfide, 25min will be stirred at temperature 42 DEG C;
(2) in step (1), add 12 parts of molecular sieve, the own ester acetic acid of 2-isopropyl-5-methyl 13 parts, ethylene glycol oleate 10 parts and dicyclopentyl dimethoxyl silane 6 parts, raise temperature and stir 35min to 65 DEG C with 280r/min speed;
(3) in step (2), add fluorosioloxane rubber 38 parts and polrvinyl chloride 25 parts, continue to raise temperature to 92 DEG C, after reaction 12min;
(4) reacted product, cedryl formate 10 parts, methyl tributanoximo silane 6 parts in step (3) are added in banbury together with 2-ethyl-4-methylimidazole 5 parts, mixing 4min at temperature 95 DEG C, extruded machine extrusion can obtain described cable sheath material subsequently.
Each embodiment and comparative example being placed in 40% sodium hydroxide solution 48h, and is placed in 20% hydrochloric acid solution 48h, investigate its alkaline-resisting acidproof effect, result is as follows:
Table 1 alkaline resistance properties result
Experiment Hot strength rate of change (%) Elongation at break rate of change (%)
Embodiment 1 10.5 12.5
Comparative example 1 50.4 54.1
Embodiment 2 9.5 10.5
Comparative example 2 51.6 52.7
Embodiment 3 8.4 8.7
Embodiment 4 7.5 7.4
Embodiment 5 6.0 6.5
Table 2 acid resistance result
Experiment Hot strength rate of change (%) Elongation at break rate of change (%)
Embodiment 1 12.7 10.7
Comparative example 1 48.6 50.8
Embodiment 2 11.5 9.5
Comparative example 2 50.7 51.7
Embodiment 3 10.8 8.5
Embodiment 4 9.5 8.0
Embodiment 5 7.8 7.0

Claims (8)

1. an acid-alkali-corrosive-resisting cable sheath material, it is characterized in that, including the composition of following parts by weight: chlorinated scoline 40-50 part, fluorosioloxane rubber 30-40 part, polrvinyl chloride 20-30 part, polyphenylene sulfide 12-18 part, carborundum 3-8 part, 4-(carboxymethyl) phenylboric acid pinacol ester 15-20 part, molecular sieve 8-15 part, 2-isopropyl-5-methyl own ester acetic acid 8-16 part, cedryl formate 6-12 part, ethylene glycol oleate 7-11 part, dicyclopentyl dimethoxyl silane 3-8 part, methyl tributanoximo silane 2-9 part, 2-ethyl-4-methylimidazole 2-6 part.
2. a kind of acid-alkali-corrosive-resisting cable sheath material according to claim 1, it is characterized in that, described chlorinated scoline 42-48 part, fluorosioloxane rubber 35-40 part, polrvinyl chloride 22-28 part, polyphenylene sulfide 14-17 part, carborundum 4-7 part, 4-(carboxymethyl) phenylboric acid pinacol ester 16-19 part, molecular sieve 10-13 part, 2-isopropyl-5-methyl own ester acetic acid 10-14 part, cedryl formate 8-11 part, ethylene glycol oleate 9-11 part, dicyclopentyl dimethoxyl silane 5-7 part, methyl tributanoximo silane 3-8 part, 2-ethyl-4-methylimidazole 4-6 part.
3. a kind of acid-alkali-corrosive-resisting cable sheath material according to claim 2, it is characterized in that, described chlorinated scoline 46 parts, fluorosioloxane rubber 38 parts, polrvinyl chloride 25 parts, polyphenylene sulfide 16 parts, carborundum 5 parts, 4-(carboxymethyl) phenylboric acid pinacol ester 18 parts, 12 parts of molecular sieve, the own ester acetic acid of 2-isopropyl-5-methyl 13 parts, cedryl formate 10 parts, ethylene glycol oleate 10 parts, dicyclopentyl dimethoxyl silane 6 parts, methyl tributanoximo silane 6 parts, 2-ethyl-4-methylimidazole 5 parts.
4. the preparation method of an acid-alkali-corrosive-resisting cable sheath material, it is characterised in that comprise the steps:
(1) chlorinated scoline 40-50 part, carborundum 3-8 part, 4-(carboxymethyl) phenylboric acid pinacol ester 15-20 part and polyphenylene sulfide 12-18 part are added in reactor, at temperature 35-45 DEG C, stir 20-30min;
(2) in step (1), add molecular sieve 8-15 part, 2-isopropyl-5-methyl own ester acetic acid 8-16 part, ethylene glycol oleate 7-11 part and dicyclopentyl dimethoxyl silane 3-8 part, raise temperature and stir 30-40min to 60-70 DEG C with 250-300r/min speed;
(3) in step (2), add fluorosioloxane rubber 30-40 part and polrvinyl chloride 20-30 part, continue to raise temperature to 80-95 DEG C, after reaction 10-15min;
(4) reacted product, cedryl formate 6-12 part, methyl tributanoximo silane 2-9 part in step (3) are added in banbury together with 2-ethyl-4-methylimidazole 2-6 part, mixing 3-5min at temperature 90-100 DEG C, extruded machine extrusion can obtain described cable sheath material subsequently.
5. the preparation method of a kind of acid-alkali-corrosive-resisting cable sheath material according to claim 4, it is characterised in that temperature described in step (1) is 42 DEG C, stirs 25min.
6. the preparation method of a kind of acid-alkali-corrosive-resisting cable sheath material according to claim 4, it is characterised in that temperature described in step (2) is 65 DEG C, and speed is 280r/min.
7. the preparation method of a kind of acid-alkali-corrosive-resisting cable sheath material according to claim 4, it is characterised in that temperature described in step (3) is 92 DEG C, reacts 12min.
8. the preparation method of a kind of acid-alkali-corrosive-resisting cable sheath material according to claim 4, it is characterised in that temperature described in step (4) is 95 DEG C, mixing 4min.
CN201610113928.XA 2016-03-01 2016-03-01 Cable sheath material resistant to acid and base corrosion and preparation method of cable sheath material Withdrawn CN105647037A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106317905A (en) * 2016-08-30 2017-01-11 安徽蓝德集团股份有限公司 Coal mine cable sheath material with excellent heat stability
CN106674670A (en) * 2016-12-09 2017-05-17 晋源电气集团股份有限公司 High temperature-resisting anti-corrosion cable for ship
CN108148223A (en) * 2017-12-14 2018-06-12 孝感市锐思新材科技有限公司 A kind of flame-retarding new material for Corvic
CN110240805A (en) * 2019-06-17 2019-09-17 新奥(内蒙古)石墨烯材料有限公司 Graphene modified polyphenyl thioether material and preparation method thereof, heat-conduction plastic pipe
CN114181471A (en) * 2020-09-15 2022-03-15 中国石油化工股份有限公司 Acid-resistant rubber composition based on brominated butyl rubber and application thereof, vulcanized rubber and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103374158A (en) * 2013-06-21 2013-10-30 安徽荣玖光纤通信科技有限公司 Anticorrosion cable sheath material and preparation method thereof
CN103509351A (en) * 2013-09-05 2014-01-15 安徽省科林电子有限公司 Aging-resistant insulating sheath material for transformer and preparation method thereof
CN103509260A (en) * 2013-09-05 2014-01-15 安徽省科林电子有限公司 Acid-base-resistant insulating sheath material for transformer and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103374158A (en) * 2013-06-21 2013-10-30 安徽荣玖光纤通信科技有限公司 Anticorrosion cable sheath material and preparation method thereof
CN103509351A (en) * 2013-09-05 2014-01-15 安徽省科林电子有限公司 Aging-resistant insulating sheath material for transformer and preparation method thereof
CN103509260A (en) * 2013-09-05 2014-01-15 安徽省科林电子有限公司 Acid-base-resistant insulating sheath material for transformer and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106317905A (en) * 2016-08-30 2017-01-11 安徽蓝德集团股份有限公司 Coal mine cable sheath material with excellent heat stability
CN106674670A (en) * 2016-12-09 2017-05-17 晋源电气集团股份有限公司 High temperature-resisting anti-corrosion cable for ship
CN108148223A (en) * 2017-12-14 2018-06-12 孝感市锐思新材科技有限公司 A kind of flame-retarding new material for Corvic
CN110240805A (en) * 2019-06-17 2019-09-17 新奥(内蒙古)石墨烯材料有限公司 Graphene modified polyphenyl thioether material and preparation method thereof, heat-conduction plastic pipe
CN110240805B (en) * 2019-06-17 2021-11-19 新奥(内蒙古)石墨烯材料有限公司 Graphene modified polyphenylene sulfide material, preparation method thereof and heat-conducting plastic pipe
CN114181471A (en) * 2020-09-15 2022-03-15 中国石油化工股份有限公司 Acid-resistant rubber composition based on brominated butyl rubber and application thereof, vulcanized rubber and preparation method and application thereof
CN114181471B (en) * 2020-09-15 2023-02-28 中国石油化工股份有限公司 Acid-resistant rubber composition based on brominated butyl rubber and application thereof, vulcanized rubber and preparation method and application thereof

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