CN102965036A - Nano-wollastonite modified adhesive for packaging - Google Patents

Nano-wollastonite modified adhesive for packaging Download PDF

Info

Publication number
CN102965036A
CN102965036A CN2012104326059A CN201210432605A CN102965036A CN 102965036 A CN102965036 A CN 102965036A CN 2012104326059 A CN2012104326059 A CN 2012104326059A CN 201210432605 A CN201210432605 A CN 201210432605A CN 102965036 A CN102965036 A CN 102965036A
Authority
CN
China
Prior art keywords
parts
adhesive
packaging
rubber
nanometer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2012104326059A
Other languages
Chinese (zh)
Other versions
CN102965036B (en
Inventor
何益庆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongling Xiangyun Fire Fighting Technology Co Ltd
Original Assignee
Tongling Xiangyun Fire Fighting Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongling Xiangyun Fire Fighting Technology Co Ltd filed Critical Tongling Xiangyun Fire Fighting Technology Co Ltd
Priority to CN201210432605.9A priority Critical patent/CN102965036B/en
Publication of CN102965036A publication Critical patent/CN102965036A/en
Application granted granted Critical
Publication of CN102965036B publication Critical patent/CN102965036B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a nano-wollastonite modified adhesive for packaging. The adhesive is prepared from the following raw materials in parts by weight: The adhesive is prepared from the following raw materials in parts by weight: 100-120 parts of styrene, 100-150 parts of ethyl acetate, 20-25 parts of duprene rubber CR121, 15-20 parts of xylene, 1-2 parts of 4,4'-diphenyl methane diisocyanate, 8-12 parts of polyisobutylene, 2-3 parts of (3-aminopropyl)trimethoxysilane, 2-3 parts of polytetramethylene ether glycol, 3-5 parts of SG-2 PVC (polyvinyl chloride) resin, 1-2 parts of ferrocene, 10-15 parts of 704 silicon rubber, 8-12 parts of butyl rubber CBK139, 3-5 parts of epoxidized soybean oil, and the like. The adhesive is excellent in heat resistance heat resistance and cold resistance, high in cohesive strength, water-resistant, moisture-proof, good in storage stability, good in environment friendliness, good in using effect and convenient.

Description

The adhesive for packaging that a kind of nanometer is Wollastonite modified
Technical field
The present invention relates to a kind of sizing agent, be specifically related to the Wollastonite modified adhesive for packaging of a kind of nanometer.
Background technology
Adhesive for packaging is in the generation of the basis of packaging industry fast development and develops, the performance of adhesive for packaging, quality have directly affected packing effect and quality, present wrapping sizing agent ubiquity thermotolerance is relatively poor, and winter hardiness is not good, and package stability is poor.Relatively poor in order to overcome traditional sizing agent thermotolerance, the shortcoming such as winter hardiness is not good, and package stability is poor by improving prescription, thereby is produced a kind of novel package sizing agent.
Summary of the invention
The purpose of this invention is to provide that a kind of thermal insulation is good, water-tolerant, cohesive strength are high, the Wollastonite modified adhesive for packaging of nanometer of excellent storage stability.
The technical solution used in the present invention is as follows:
The adhesive for packaging that a kind of nanometer is Wollastonite modified, raw material by following weight part is made: vinylbenzene 100-120, ethyl acetate 100-150, chloroprene rubber CR121 20-25, dimethylbenzene 15-20,4,4 '-diphenylmethanediisocyanate 1-2, polyisobutene 8-12,3-aminopropyl trimethoxysilane 2-3, PTMG 2-3, SG-2 type polyvinyl chloride resin 3-5, ferrocene 1-2,704 silicon rubber 10-15, isoprene-isobutylene rubber CBK139 8-12, epoxy soybean oil 3-5, phthalic acid dibutyl ester 3-5, clorafin 1-2, sulphur 0.5-1, zinc oxide 3-5, Imarcaptoacetate dioctyltin 1-2, nano-silicon lime stone 10-15, nanometer Feldspar Powder 5-10, titanium dioxide 5-10, titanate coupling agent TMC-TTS 1-2, oxidation inhibitor 1035 1-2, antioxidant MB 2-3, anti-scorching agent CTP 1-2, Vulcanization accelerator TMTD 1-2, altax 1-2, accelerant N a-22 1-2, modification trees ashes 1-2.
Described modification trees ashes are made by following steps: use first 10-15% salt acid soak trees ashes 3-4h, deionized water wash is clean, soak 3-4h with the 10-12% sodium hydroxide solution again, extremely neutral with deionized water wash again, oven dry adds and is equivalent to the sodium lignosulfonate of trees ashes weight 2-3%, the paregal O of 1-2%, the phthalic ester of 2-3%, the talcum powder of 3-5%, and high speed 1200-1500r/min stirs 1-2h, oven dry, pulverizing grinds to form ultrafine powder and gets final product.
The preparation method of the adhesive for packaging that nanometer is Wollastonite modified may further comprise the steps:
(1) with vinylbenzene, ethyl acetate, chloroprene rubber CR121, dimethylbenzene, 4,4 '-diphenylmethanediisocyanate, polyisobutene, 3-aminopropyl trimethoxysilane, PTMG, SG-2 type polyvinyl chloride resin, ferrocene, 704 silicon rubber, isoprene-isobutylene rubber CBK139 mix, at 100-120 ℃ of lower reaction 1-2h;
(2) other material is mixed with reactant, stir 30-40min, obtain finished product, packing gets final product.
Beneficial effect of the present invention:
The present invention has improved it at the dispersing uniformity in the sizing agent component by the trees ashes are carried out modification, thereby can obviously improve bonding strength and the water tolerance of sizing agent, and it is low to have a cost, the characteristics that effect is good.The present invention adds the nano-silicon lime stone sizing agent is carried out modification by to formula adjustment, can obviously improve the performance such as heat-resisting, water-fast, wear-resisting of sizing agent.Chloroprene rubber sizing agent of the present invention has good thermotolerance, winter hardiness, and cohesive strength is high, water-fast protection against the tide, and excellent storage stability, the feature of environmental protection is good, and result of use is good and convenient.
Embodiment
The present invention is further illustrated below in conjunction with specific embodiment.
Embodiment
The adhesive for packaging that a kind of nanometer is Wollastonite modified, raw material by following weight part is made: 120 parts of vinylbenzene, 120 parts of ethyl acetate, 22 parts of chloroprene rubber CR121,18 parts of dimethylbenzene, 4,1.6 parts of 4 '-diphenylmethanediisocyanates, 10 parts of polyisobutene, 2 parts of 3-aminopropyl trimethoxysilane, 3 parts of PTMG, 5 parts of SG-2 type polyvinyl chloride resins, 2 parts of ferrocene, 12 parts in 704 silicon rubber, 8 parts of isoprene-isobutylene rubber CBK139,5 parts of epoxy soybean oils, 4 parts of phthalic acid dibutyl esters, 2 parts of clorafins, 1 part in sulphur, 4 parts in zinc oxide, 2 parts of Imarcaptoacetate dioctyltins, 15 parts of nano-silicon lime stones, 8 parts of nanometer Feldspar Powders, 8 parts of titanium dioxides, 1.5 parts of titanate coupling agent TMC-TTS, 1,035 1.8 parts in oxidation inhibitor, 2 parts of antioxidant MBs, 1.6 parts of anti-scorching agent CTPs, 1 part of Vulcanization accelerator TMTD, 1 part of altax, 2 parts of accelerant N a-22,2 parts in modification trees ashes.
Wherein, described modification trees ashes are made by following steps: use first 12% salt acid soak trees ashes 4h, deionized water wash is clean, soak 4h with 10% sodium hydroxide solution again, extremely neutral with deionized water wash again, oven dry, add and be equivalent to the sodium lignosulfonate of trees ashes weight 2%, 2% paregal O, 3% phthalic ester, 5% talcum powder, high speed 1500r/min stirs 2h, oven dry, and pulverizing grinds to form ultrafine powder and gets final product.
The preparation method of the adhesive for packaging that nanometer is Wollastonite modified may further comprise the steps:
(1) with vinylbenzene, ethyl acetate, chloroprene rubber CR121, dimethylbenzene, 4,4 '-diphenylmethanediisocyanate, polyisobutene, 3-aminopropyl trimethoxysilane, PTMG, SG-2 type polyvinyl chloride resin, ferrocene, 704 silicon rubber, isoprene-isobutylene rubber CBK139 mix, at 108 ℃ of lower reaction 2h;
(2) other material is mixed with reactant, stir 40min, obtain finished product, packing gets final product.
The salient features of the sizing agent that present embodiment makes such as following table 1.
Table 1
Performance project Test result
Shearing resistance (MPa) 27
Tensile strength (MPa) 38
Stripping strength (N/cm) 75

Claims (3)

1. adhesive for packaging that nanometer is Wollastonite modified, it is characterized in that, raw material by following weight part is made: vinylbenzene 100-120, ethyl acetate 100-150, chloroprene rubber CR121 20-25, dimethylbenzene 15-20,4,4 '-diphenylmethanediisocyanate 1-2, polyisobutene 8-12,3-aminopropyl trimethoxysilane 2-3, PTMG 2-3, SG-2 type polyvinyl chloride resin 3-5, ferrocene 1-2,704 silicon rubber 10-15, isoprene-isobutylene rubber CBK139 8-12, epoxy soybean oil 3-5, phthalic acid dibutyl ester 3-5, clorafin 1-2, sulphur 0.5-1, zinc oxide 3-5, Imarcaptoacetate dioctyltin 1-2, nano-silicon lime stone 10-15, nanometer Feldspar Powder 5-10, titanium dioxide 5-10, titanate coupling agent TMC-TTS 1-2, oxidation inhibitor 1035 1-2, antioxidant MB 2-3, anti-scorching agent CTP 1-2, Vulcanization accelerator TMTD 1-2, altax 1-2, accelerant N a-22 1-2, modification trees ashes 1-2.
2. the Wollastonite modified adhesive for packaging of nanometer according to claim 1, it is characterized in that, described modification trees ashes are made by following steps: use first 10-15% salt acid soak trees ashes 3-4h, deionized water wash is clean, soak 3-4h with the 10-12% sodium hydroxide solution again, extremely neutral with deionized water wash again, oven dry, add the sodium lignosulfonate that is equivalent to trees ashes weight 2-3%, the paregal O of 1-2%, the phthalic ester of 2-3%, the talcum powder of 3-5%, high speed 1200-1500r/min stirs 1-2h, oven dry, pulverizing grinds to form ultrafine powder and gets final product.
3. the preparation method of the Wollastonite modified adhesive for packaging of a nanometer as claimed in claim 1 is characterized in that may further comprise the steps:
(1) with vinylbenzene, ethyl acetate, chloroprene rubber CR121, dimethylbenzene, 4,4 '-diphenylmethanediisocyanate, polyisobutene, 3-aminopropyl trimethoxysilane, PTMG, SG-2 type polyvinyl chloride resin, ferrocene, 704 silicon rubber, isoprene-isobutylene rubber CBK139 mix, at 100-120 ℃ of lower reaction 1-2h;
(2) other material is mixed with reactant, stir 30-40min, obtain finished product, packing gets final product.
CN201210432605.9A 2012-11-02 2012-11-02 Nano-wollastonite modified adhesive for packaging Expired - Fee Related CN102965036B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210432605.9A CN102965036B (en) 2012-11-02 2012-11-02 Nano-wollastonite modified adhesive for packaging

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210432605.9A CN102965036B (en) 2012-11-02 2012-11-02 Nano-wollastonite modified adhesive for packaging

Publications (2)

Publication Number Publication Date
CN102965036A true CN102965036A (en) 2013-03-13
CN102965036B CN102965036B (en) 2014-07-16

Family

ID=47795478

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201210432605.9A Expired - Fee Related CN102965036B (en) 2012-11-02 2012-11-02 Nano-wollastonite modified adhesive for packaging

Country Status (1)

Country Link
CN (1) CN102965036B (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103232821A (en) * 2013-04-07 2013-08-07 青阳县华鼎包装有限公司 Package-use adhesive comprising nano-grade calcite, and preparation method thereof
CN103232823A (en) * 2013-04-07 2013-08-07 青阳县华鼎包装有限公司 Package-use adhesive comprising nano-grade sepiolite, and preparation method thereof
CN103232822A (en) * 2013-04-07 2013-08-07 青阳县华鼎包装有限公司 Package-use adhesive comprising organic bentonite, and preparation method thereof
CN103265914A (en) * 2013-04-07 2013-08-28 青阳县华鼎包装有限公司 Packaging adhesive containing white fused alumina powder and a preparation method thereof
CN103265911A (en) * 2013-04-07 2013-08-28 青阳县华鼎包装有限公司 Adhesive containing ultra-fine aluminum silicate for packaging and preparation method thereof
CN103265915A (en) * 2013-04-07 2013-08-28 青阳县华鼎包装有限公司 Packaging adhesive containing graphite powder and preparation method thereof
CN103265917A (en) * 2013-04-07 2013-08-28 青阳县华鼎包装有限公司 Adhesive containing nano attapulgite for packaging and preparation method thereof
CN103773303A (en) * 2014-02-20 2014-05-07 铜陵祥云消防科技有限责任公司 Nano blue asbestos modified adhesive for packaging
CN103773307A (en) * 2014-02-20 2014-05-07 铜陵祥云消防科技有限责任公司 Nano asbestos powder modified water-resistant adhesive
CN103805123A (en) * 2014-02-20 2014-05-21 铜陵祥云消防科技有限责任公司 Adhesive containing modified silica powder
CN103805074A (en) * 2014-02-20 2014-05-21 铜陵祥云消防科技有限责任公司 Nano palygorskite-modified flame-retardant adhesive
CN104327753A (en) * 2014-11-05 2015-02-04 吴俊荣 Water-based adhesive
CN106433494A (en) * 2016-10-11 2017-02-22 安徽卡塔门窗有限公司 Waterproof glue for wood doors and windows and preparation method thereof
CN108977156A (en) * 2018-06-29 2018-12-11 佛山市高明区爪和新材料科技有限公司 A kind of high-temp resisting high-humidity resisting is packed for the preparation method of binder

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3746606A (en) * 1971-06-17 1973-07-17 Ncr Off-line process for laminating magnetic tape to tab stock
US20060020067A1 (en) * 2004-04-15 2006-01-26 Patrick Brant Syndiotactic rich polyolefins
CN101921551A (en) * 2009-09-08 2010-12-22 上海科建化工有限公司 High temperature resistant vacuum bag sealing adhesive tape
CN102190994A (en) * 2010-03-15 2011-09-21 张耀华 Production method for chloroprene rubber adhesive

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3746606A (en) * 1971-06-17 1973-07-17 Ncr Off-line process for laminating magnetic tape to tab stock
US20060020067A1 (en) * 2004-04-15 2006-01-26 Patrick Brant Syndiotactic rich polyolefins
CN101921551A (en) * 2009-09-08 2010-12-22 上海科建化工有限公司 High temperature resistant vacuum bag sealing adhesive tape
CN102190994A (en) * 2010-03-15 2011-09-21 张耀华 Production method for chloroprene rubber adhesive

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103232822B (en) * 2013-04-07 2016-02-10 青阳县华鼎包装有限公司 A kind of containing bentonite adhesives in Packaging and preparation method thereof
CN103232822A (en) * 2013-04-07 2013-08-07 青阳县华鼎包装有限公司 Package-use adhesive comprising organic bentonite, and preparation method thereof
CN103265917B (en) * 2013-04-07 2016-02-10 青阳县华鼎包装有限公司 A kind of adhesives in Packaging containing nano-attapulgite and preparation method thereof
CN103265914A (en) * 2013-04-07 2013-08-28 青阳县华鼎包装有限公司 Packaging adhesive containing white fused alumina powder and a preparation method thereof
CN103265911A (en) * 2013-04-07 2013-08-28 青阳县华鼎包装有限公司 Adhesive containing ultra-fine aluminum silicate for packaging and preparation method thereof
CN103265915A (en) * 2013-04-07 2013-08-28 青阳县华鼎包装有限公司 Packaging adhesive containing graphite powder and preparation method thereof
CN103265917A (en) * 2013-04-07 2013-08-28 青阳县华鼎包装有限公司 Adhesive containing nano attapulgite for packaging and preparation method thereof
CN103232823B (en) * 2013-04-07 2016-02-10 青阳县华鼎包装有限公司 A kind of adhesives in Packaging containing nanometer sepiolite and preparation method thereof
CN103265911B (en) * 2013-04-07 2016-02-10 青阳县华鼎包装有限公司 A kind of adhesives in Packaging containing superfine alumina silicate and preparation method thereof
CN103232821A (en) * 2013-04-07 2013-08-07 青阳县华鼎包装有限公司 Package-use adhesive comprising nano-grade calcite, and preparation method thereof
CN103232823A (en) * 2013-04-07 2013-08-07 青阳县华鼎包装有限公司 Package-use adhesive comprising nano-grade sepiolite, and preparation method thereof
CN103773307A (en) * 2014-02-20 2014-05-07 铜陵祥云消防科技有限责任公司 Nano asbestos powder modified water-resistant adhesive
CN103805074B (en) * 2014-02-20 2015-06-10 铜陵祥云消防科技有限责任公司 Nano palygorskite-modified flame-retardant adhesive
CN103805123B (en) * 2014-02-20 2015-07-01 铜陵祥云消防科技有限责任公司 Adhesive containing modified silica powder
CN103805123A (en) * 2014-02-20 2014-05-21 铜陵祥云消防科技有限责任公司 Adhesive containing modified silica powder
CN103773303B (en) * 2014-02-20 2015-05-13 铜陵祥云消防科技有限责任公司 Nano blue asbestos modified adhesive for packaging
CN103773303A (en) * 2014-02-20 2014-05-07 铜陵祥云消防科技有限责任公司 Nano blue asbestos modified adhesive for packaging
CN103805074A (en) * 2014-02-20 2014-05-21 铜陵祥云消防科技有限责任公司 Nano palygorskite-modified flame-retardant adhesive
CN104327753A (en) * 2014-11-05 2015-02-04 吴俊荣 Water-based adhesive
CN104327753B (en) * 2014-11-05 2016-04-20 吴俊荣 Water-based adhesive
CN106433494A (en) * 2016-10-11 2017-02-22 安徽卡塔门窗有限公司 Waterproof glue for wood doors and windows and preparation method thereof
CN108977156A (en) * 2018-06-29 2018-12-11 佛山市高明区爪和新材料科技有限公司 A kind of high-temp resisting high-humidity resisting is packed for the preparation method of binder

Also Published As

Publication number Publication date
CN102965036B (en) 2014-07-16

Similar Documents

Publication Publication Date Title
CN102965036B (en) Nano-wollastonite modified adhesive for packaging
CN102965033B (en) Nano-mica powder modified compound adhesive for packaging
CN104559203A (en) High-power high-stability cable material and preparation method thereof
CN103013133B (en) A kind of automobile V-shaped circle sizing material and preparation method thereof
CN102965050A (en) Nano-kieselguhr modified adhesive for packaging
CN102851998A (en) Environmental protection type PVC synthetic leather and preparation method thereof
CN103173140B (en) Neoprene adhesive for woodworking
CN103351495A (en) Mixed solvent resistant chloroprene rubber sealing pad and preparation method thereof
CN103045106B (en) Adhesive containing modified PVC (polyvinyl chloride) resin for packaging materials
CN102977767A (en) Metal antirust paint containing modified nano-TiO2, and its preparation method
CN103013356B (en) Low-temperature-resistant binding agent for packaging material
CN103173134B (en) Solvent-based neoprene adhesive
CN103059750A (en) Epoxy resin and nitrile rubber adhesive and preparing method thereof
CN102965035B (en) Calcium sulfate crystal whisker modified adhesive for packaging
JP2007031587A (en) Rubber composition for tire
CN103045104A (en) Phenolic resin-chloroprene rubber adhesive and preparation method thereof
CN103013361B (en) Medium-resistant binding agent for packaging material
CN104650415A (en) High-temperature resisting nitrile rubber material
CN103031067A (en) Fast-curing chloroprene rubber adhesive and preparation method thereof
CN107163320A (en) A kind of nitrile rubber flexible pipe glue and preparation method thereof
CN102965034B (en) Nano-barite powder modified compound adhesive for packaging
CN102952378B (en) Modified nano-clay dinner plate material and processing method thereof
CN103173131B (en) Nanometer dolomite powder modified chloroprene rubber adhesive
CN105924708A (en) Environment-friendly silica gel material
CN103045124B (en) A kind of two component wrapping material binding agent

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140716

Termination date: 20151102

EXPY Termination of patent right or utility model