CN107315424A - For sewage disposal solar energy tracking displacement platform, manufacture method and its application - Google Patents
For sewage disposal solar energy tracking displacement platform, manufacture method and its application Download PDFInfo
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- CN107315424A CN107315424A CN201710401229.XA CN201710401229A CN107315424A CN 107315424 A CN107315424 A CN 107315424A CN 201710401229 A CN201710401229 A CN 201710401229A CN 107315424 A CN107315424 A CN 107315424A
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- displacement platform
- methyl
- condenser
- naphthalenecarboxamides
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- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D3/00—Control of position or direction
- G05D3/12—Control of position or direction using feedback
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01C—MEASURING DISTANCES, LEVELS OR BEARINGS; SURVEYING; NAVIGATION; GYROSCOPIC INSTRUMENTS; PHOTOGRAMMETRY OR VIDEOGRAMMETRY
- G01C1/00—Measuring angles
Abstract
One kind is used for sewage disposal solar energy tracking displacement platform, manufacture method and its application, and the constituent of displacement platform is as follows:3 methoxyl group dopamine hydrochlorides, [(oxopropoxy of the 3 sulfydryl 1) methyl] 1 of 3 mercaptopropionic acid, 2 ethyl 2, 3 propylene diesters, N (the methoxybenzene methylene of 4 hydroxyl 3) para-totuidine, 3 hydroxyl N (4 methoxyphenyl) 4 (phenylazo) 2 naphthalenecarboxamide, the naphthalenecarboxamide of 3 hydroxyl 4 [(nitrobenzophenone of 2 methoxyl group 4) azo] 1 naphthyls of N 2, 2, 2 dimethyl 3 (2, 2 dichloroethylenes) 3 phenoxy benzyl ester of cyclopropane-carboxylic acid alpha cyano group, 3 amino Ns, the methoxybenzenesulphoismide of N diethyl 4;Preparation method:By a variety of macromolecular material heating stirrings, ray radiation, it is passed through radon gas, adds that crosslinking agent is mixed, stood, pressing mold is made after polymerisation;Using:It is used as a kind of building block for sewage disposal solar energy tracking equipment.The platform structure is stable, non-aging, and control performance is stable;The preparation method technique is simple;The application can improve generating efficiency.
Description
Technical field
The present invention relates to sewage disposal new energy apparatus field, and in particular to one kind is used for sewage disposal solar energy tracking position
Move platform, manufacture method and its application.
Background technology
Displacement platform is the key equipment in solar energy tracking device, and displacement platform is generally in outdoor longtime running, and it resists
The indexs such as Compressive Strength, unit mass, coefficient of friction, rate of depreciation are significant to the performance of solar power plant, existing
Some displacement platforms are long-term by the irradiation of sunlight and corroding for rainwater, the index such as its compression strength, coefficient of friction, rate of depreciation
It can change, and then aging easily occurs for its structure, is so unfavorable for the stabilization of solar energy tracking device performance, so as to need to determine
Phase is changed, and not only maintenance period is shortened, and maintenance cost is also higher, while can also influence utilizing for solar energy to imitate
Rate.The unit mass of other displacement platform is lighter, is more conducive to the accurate control by motor
The content of the invention
In view of the above-mentioned problems of the prior art, the present invention provides a kind of flat for the displacement of sewage disposal solar energy tracking
Platform, manufacture method and its application, the displacement platform Stability Analysis of Structures, its compression strength, unit mass, coefficient of friction, rate of depreciation
It is excellent etc. index, it is non-aging, be conducive to the stable operation of solar energy tracking device, be conducive to the extension of maintenance period, also can
Reduce maintenance cost;The preparation method technique is simple, be difficult to produce pollution to environment;The application can significantly improve the profit of solar energy
With efficiency, the maintenance efficiency of solar power plant can be substantially reduced.
It is used for sewage disposal solar energy tracking displacement platform the invention provides one kind, institute's translation stage is by a variety of high scores
Sub- material pressing mold shaping is made, and its component is counted as follows by weight:
77~140 parts of 3- methoxyl groups dopamine hydrochloride, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- the third oxygen of oxo
Base) methyl] 138~242 parts of -1,3- propylene diesters, N- (4- hydroxy 3-methoxybenzenes methylene)-para-totuidine 162~293
Part, 3- hydroxy-ns -119~246 parts of (4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -4- [(2- first
Epoxide -4- nitrobenzophenones) azo] 91~128 parts of-N-1- naphthyl -2- naphthalenecarboxamides, 2,2- dimethyl -3- (2,2- dichloroethylene
Base) -40~173 parts of cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester, concentration is 68ppm~94ppm 1- amino
Formic acid 3- (2- methoxycarbonyl phenoxies) -88~167 parts of 1,2-PD ester, 3- amino-N, N- diethyl -4- methoxybenzenesulphoismides
143~198 parts, 2,2- double [[(caprylyl) oxygen] methyl] 55~125 parts of two ubidecarenones of 1,3-PD, crosslinking agent 155~282
Part, N- (2,3- dihydro-2-oxo -1H- benzimidazole -5- bases) -3- hydroxyls -4- [[2- methoxyl groups -5- [(phenyl amino) first
Acyl] phenyl] azo] 67~99 parts of -2- naphthalenecarboxamides, 3- (N, N- dihydroxy ethyl) amino-4-methoxyacetanilide 49~132
Part, 181~213 parts of 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid cyano group (3- Phenoxyphenyls) methyl esters;
The crosslinking agent is N- (3- hydroxyl -2- naphthoyls) parachloroanilinum, 5- benzyloxy -3- indolecarboxaldehydes, 2,2- bis-
Any one in methyl cyclopropane Ethyl formate.
Wherein N- (4- hydroxy 3-methoxybenzenes methylene)-para-totuidine, 2,2- dimethyl -3- (2,2- dichloroethylene
Base)-cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester, [(2- methoxyl group -4- nitrobenzophenones) is even by 3- hydroxyls -4-
Nitrogen]-N-1- naphthyl -2- naphthalenecarboxamides, risen to improving the compression strength of material, unit mass, coefficient of friction, rate of depreciation index
Decisive role.The displacement platform Stability Analysis of Structures, the index such as its compression strength, unit mass, coefficient of friction, rate of depreciation is excellent
It is good, it is non-aging, be conducive to the stable operation of solar energy tracking device, be conducive to the extension of maintenance period, can also reduce maintenance
Cost.
Further, in order to improve the stability and ageing-resistant performance of displacement platform structure, institute's translation stage component is by weight
Measure number meter as follows:78~139 parts of 3- methoxyl groups dopamine hydrochloride, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- oxygen
For propoxyl group) methyl] 139~240 parts of -1,3- propylene diesters, N- (4- hydroxy 3-methoxybenzenes methylene)-para-totuidine 163
~290 parts, 3- hydroxy-ns -120~240 parts of (4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -4-
[(2- methoxyl group -4- nitrobenzophenones) azo] 92~127 parts of-N-1- naphthyl -2- naphthalenecarboxamides, 2,2- dimethyl -3- (2,2- bis-
Chlorovinyl) -41~170 parts of cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester, concentration is 69ppm~90ppm's
1- carbamic acids 3- (2- methoxycarbonyl phenoxies) -89~160 parts of 1,2-PD ester, 3- amino-N, N- diethyl -4- methoxybenzene sulphurs
144~190 parts of acid amides, 2,2- double [[(caprylyl) oxygen] methyl] 56~120 parts of two ubidecarenones of 1,3-PD, crosslinking agent 156
~280 parts, N- (2,3- dihydro-2-oxo -1H- benzimidazole -5- bases) -3- hydroxyls -4- [[2- methoxyl group -5- [(phenylaminos
Base) formyl] phenyl] azo] 68~90 parts of -2- naphthalenecarboxamides, 3- (N, N- dihydroxy ethyl) amino-4-methoxyacetanilide 50
~130 parts, 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid cyano group (3- Phenoxyphenyls) methyl esters 182~
210 parts;
The crosslinking agent is N- (3- hydroxyl -2- naphthoyls) parachloroanilinum, 5- benzyloxy -3- indolecarboxaldehydes, 2,2- bis-
Any one in methyl cyclopropane Ethyl formate.
The present invention also provides a kind of preparation method for sewage disposal solar energy tracking displacement platform, including following step
Suddenly:
Step one:The ultra-pure water 2460~3670 that electrical conductivity is the μ S/cm of 4.86 μ S/cm~7.12 is added in a kettle.
Part, start agitator in reactor, rotating speed is 117rpm~183rpm, starts heat pump, reactor temperature is risen to 122
DEG C~185 DEG C;Sequentially add 3- methoxyl groups dopamine hydrochloride, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- oxos third
Epoxide) methyl] -1,3- propylene diesters, N- (4- hydroxy 3-methoxybenzenes methylene)-para-totuidine, stirring to being completely dissolved,
It is 4.55~9.64 to adjust pH value, and agitator speed is adjusted into 185rpm~224rpm, and temperature is 181 DEG C~242 DEG C, and esterification is anti-
Answer 25~36 hours;
Step 2:Take 3- hydroxy-ns-(4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -4-
[(2- methoxyl group -4- nitrobenzophenones) azo]-N-1- naphthyl -2- naphthalenecarboxamides are crushed, and powder diameter is 1000~1500
Mesh;2,2- dimethyl -3- (2,2- dichloroethylenes)-cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester is added to mix
Close uniform, be laid in pallet, tiling thickness is 24mm~42mm, use the dosage to be for 5.25kGy~8.81kGy, energy
5.27MeV~9.47MeV alpha ray is irradiated 130~270 minutes, and Isodose β x ray irradiation xs 130~270 minutes;
Step 3:The mixed-powder handled through step 2 is dissolved in 1- carbamic acids 3- (2- methoxycarbonyl phenoxies) -1,2- propane diols
In ester, reactor is added, agitator speed is 164rpm~213rpm, and temperature is 194 DEG C~261 DEG C, and starting vavuum pump makes instead
Answer the vacuum of kettle to reach -0.67MPa~2.29MPa, keep this state response 20~32 hours;Pressure release is simultaneously passed through radon gas, makes
Reacting kettle inner pressure is 0.90MPa~1.48MPa, and insulation stands 8~18 hours;Agitator speed be promoted to 227rpm~
311rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 3- amino-N, N- diethyl -4- methoxybenzenesulphoismides, 2,2- double
After the ubidecarenone of [[(caprylyl) oxygen] methyl] 1,3-PD two is completely dissolved, crosslinking agent stirring mixing is added so that reactor
The hydrophilic lipophilic balance of solution is 4.53~6.34, and insulation stands 13~24 hours;
Step 4:When agitator speed is 239rpm~375rpm, N- (2,3- dihydro-2-oxo -1H- are sequentially added
Benzimidazole -5- bases) -3- hydroxyls -4- [[2- methoxyl groups -5- [(phenyl amino) formyl] phenyl] azo] -2- naphthalenecarboxamides, 3-
(N, N- dihydroxy ethyl) amino-4-methoxyacetanilide and 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane carboxylic acid
Sour cyano group (3- Phenoxyphenyls) methyl esters, lifts reactor pressure, reaches 2.49MPa~3.26MPa, and temperature is 247 DEG C
~328 DEG C, polymerisation 15~25 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 24 DEG C~28 DEG C are cooled to,
Discharging, enters molding press and can be prepared by displacement platform.
This preparation method technique is simple, be difficult to produce pollution, its high yield rate to environment.
The present invention also provides a kind of application for sewage disposal solar energy tracking displacement platform, as sewage disposal
Solar panel automatic tracking device building block, the solar panel for sewage disposal sets from motion tracking
It is standby, including horizontally disposed displacement platform, be arranged at the fixed support of displacement platform bottom, be fixedly installed on inside fixed support
Rotary electric machine, the battery and controller that are arranged at displacement platform top solar panels and are arranged inside fixed support,
Institute's translation stage upper left-hand is fixedly installed what pushing motor and two extended along displacement platform length direction
Two support columns are symmetrically fixedly installed before and after slide bar, its upper right, two slide bars are symmetrically disposed in pushing motor
Front and rear sides, the two ends of each slide bar are supported by two fixed stations being fixedly installed on displacement platform respectively;It is one of sliding
The two ends of bar are each provided with a position sensor;
Rotatably arranged with there is vertical rotary shaft in the middle part of the support bracket fastened bottom plate, the upper end of rotary shaft is extended to admittedly
The outside of fixed rack is simultaneously fixedly connected with institute translation stage;Driven gear is set with the middle part of the rotary shaft;
The drive gear being meshed with the driven gear is set with the output shaft of the rotary electric machine;And rotary electric machine
Output shaft on be also equipped with rotary angle transmitter;
The solar panels include push rod, two support bars, solar module, two sliding blocks and four and are arranged on too
Sunray angle sensor at positive energy battery module upper surface corner;The upper end of two support bars respectively with solar cell
The front and rear sides of module one end are hinged, and its lower end is hinged with being sleeved on the upper end of two sliding blocks on two slide bars respectively;Solar energy
It is divided to both sides column articulated with two supports respectively before the other end of battery module;Connecting rod is disposed between described two sliding blocks, it is described
The right-hand member of push rod in the middle part of the connecting rod with being fixedly connected, and its left end is fixedly connected with the output end of pushing motor;
The battery, sunray angle sensor, rotary angle transmitter, rotary electric machine and position sensor respectively with control
Device control processed is connected.
This application can significantly improve the utilization ratio of solar energy, can substantially reduce the maintenance effect of solar power plant
Rate.
Further, in order to adapt to the work under a variety of natural conditions, the sunray angle sensor includes distortion
Condenser, pedestal, light sensation instrument and chassis cover;There is the cylindrical cavity of up/down perforation, outside it inside the distortion condenser
Structure is drawn in the distortion of many dentation corrugateds for cross section, and graphite material is coated with its outer surface;The pedestal is fixed
The lower end of distortion condenser is connected to, and it has the receiving space for connecting the cylindrical cavity;The light sensation instrument includes glass
The direct projection of glass tubulose enter polished rod, scattering optical fiber, by photosensitive material be made can double-sided light sensitive translucent photo resistance, multiple
Condenser, optical fibre ring and the reflective gratings being made up of lucite material;The direct projection is entered polished rod, scattering optical fiber and is arranged at
The central area of the cylindrical cavity of distortion condenser, the photo resistance, condenser, optical fibre ring and reflective gratings are arrived from above
It is fixedly installed at intervals in the receiving space of pedestal successively lowerly;The direct projection enters polished rod and is fixedly installed on distortion condenser
Axial line on, its top and the top flush of distortion condenser, the distance of its bottom to photo resistance is 10mm~20mm,
Its outer surface is coated with equadag coating;The scattering optical fiber is enters the sped structure that polished rod is axis of rotation around direct projection, under it
End is fixedly connected on the upper surface of photo resistance;Left between the outer edge surface of the photo resistance and the madial wall of pedestal for passing through
The annular space that the light of distortion condenser madial wall refraction passes through;The upper and lower surface of photo resistance connects with controller respectively
Connect;Multiple condensers are equally spacedly arranged on the optical fibre ring top, cone structure of the condenser for cone bottom surface upward, and
Its surface is coated with silver-colored light coating, and the lower end of condenser is fixedly connected with one end of optical fibre ring, the other end of optical fibre ring with
The optical port connection of controller;The lattice that the reflective gratings are made up of a plurality of stainless steel mirror material in right-angled intersection meshy arrangement
Grid are constituted;The inside of the chassis cover has cylindrical cavity, and its upper end open is simultaneously embedded with cloche at opening, is by saturating
The cylindrical structural that bright material is made, it is located at the outside of distortion condenser and pedestal, and its lower end is fixedly connected on solar energy
The top of battery module.
Brief description of the drawings
Fig. 1 is that displacement platform fatigue strength changes over time figure in the present invention;
Fig. 2 is the structural representation of the application of the present invention;
Fig. 3 is heretofore described solar panels structural representation;
Fig. 4 is heretofore described displacement platform structural representation;
Fig. 5 is heretofore described sunray angle sensor schematic diagram;
Fig. 6 is heretofore described light sensation instrument schematic diagram.
Embodiment
The invention will be further described below in conjunction with the accompanying drawings.
The present invention provides a kind of for sewage disposal solar energy tracking displacement platform, and institute's translation stage is by a variety of macromolecules
The shaping of material pressing mold is made, and its component is counted as follows by weight:
77~140 parts of 3- methoxyl groups dopamine hydrochloride, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- the third oxygen of oxo
Base) methyl] 138~242 parts of -1,3- propylene diesters, N- (4- hydroxy 3-methoxybenzenes methylene)-para-totuidine 162~293
Part, 3- hydroxy-ns -119~246 parts of (4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -4- [(2- first
Epoxide -4- nitrobenzophenones) azo] 91~128 parts of-N-1- naphthyl -2- naphthalenecarboxamides, 2,2- dimethyl -3- (2,2- dichloroethylene
Base) -40~173 parts of cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester, concentration is 68ppm~94ppm 1- amino
Formic acid 3- (2- methoxycarbonyl phenoxies) -88~167 parts of 1,2-PD ester, 3- amino-N, N- diethyl -4- methoxybenzenesulphoismides
143~198 parts, 2,2- double [[(caprylyl) oxygen] methyl] 55~125 parts of two ubidecarenones of 1,3-PD, crosslinking agent 155~282
Part, N- (2,3- dihydro-2-oxo -1H- benzimidazole -5- bases) -3- hydroxyls -4- [[2- methoxyl groups -5- [(phenyl amino) first
Acyl] phenyl] azo] 67~99 parts of -2- naphthalenecarboxamides, 3- (N, N- dihydroxy ethyl) amino-4-methoxyacetanilide 49~132
Part, 181~213 parts of 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid cyano group (3- Phenoxyphenyls) methyl esters;
The crosslinking agent is N- (3- hydroxyl -2- naphthoyls) parachloroanilinum, 5- benzyloxy -3- indolecarboxaldehydes, 2,2- bis-
Any one in methyl cyclopropane Ethyl formate.
The displacement platform Stability Analysis of Structures, it is non-aging, be conducive to the stable operation of solar energy tracking device, be conducive to safeguarding
The extension in cycle, can also reduce maintenance cost.
Further, in order to improve the stability and ageing-resistant performance of displacement platform structure, institute's translation stage component is by weight
Measure number meter as follows:78~139 parts of 3- methoxyl groups dopamine hydrochloride, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- oxygen
For propoxyl group) methyl] 139~240 parts of -1,3- propylene diesters, N- (4- hydroxy 3-methoxybenzenes methylene)-para-totuidine 163
~290 parts, 3- hydroxy-ns -120~240 parts of (4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -4-
[(2- methoxyl group -4- nitrobenzophenones) azo] 92~127 parts of-N-1- naphthyl -2- naphthalenecarboxamides, 2,2- dimethyl -3- (2,2- bis-
Chlorovinyl) -41~170 parts of cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester, concentration is 69ppm~90ppm's
1- carbamic acids 3- (2- methoxycarbonyl phenoxies) -89~160 parts of 1,2-PD ester, 3- amino-N, N- diethyl -4- methoxybenzene sulphurs
144~190 parts of acid amides, 2,2- double [[(caprylyl) oxygen] methyl] 56~120 parts of two ubidecarenones of 1,3-PD, crosslinking agent 156
~280 parts, N- (2,3- dihydro-2-oxo -1H- benzimidazole -5- bases) -3- hydroxyls -4- [[2- methoxyl group -5- [(phenylaminos
Base) formyl] phenyl] azo] 68~90 parts of -2- naphthalenecarboxamides, 3- (N, N- dihydroxy ethyl) amino-4-methoxyacetanilide 50
~130 parts, 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid cyano group (3- Phenoxyphenyls) methyl esters 182~
210 parts;
The crosslinking agent is N- (3- hydroxyl -2- naphthoyls) parachloroanilinum, 5- benzyloxy -3- indolecarboxaldehydes, 2,2- bis-
Any one in methyl cyclopropane Ethyl formate.
The present invention also provides a kind of preparation method for sewage disposal solar energy tracking displacement platform, including following step
Suddenly:
Step one:The ultra-pure water 2460~3670 that electrical conductivity is the μ S/cm of 4.86 μ S/cm~7.12 is added in a kettle.
Part, start agitator in reactor, rotating speed is 117rpm~183rpm, starts heat pump, reactor temperature is risen to 122
DEG C~185 DEG C;Sequentially add 3- methoxyl groups dopamine hydrochloride, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- oxos third
Epoxide) methyl] -1,3- propylene diesters, N- (4- hydroxy 3-methoxybenzenes methylene)-para-totuidine, stirring to being completely dissolved,
It is 4.55~9.64 to adjust pH value, and agitator speed is adjusted into 185rpm~224rpm, and temperature is 181 DEG C~242 DEG C, and esterification is anti-
Answer 25~36 hours;
Step 2:Take 3- hydroxy-ns-(4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -4-
[(2- methoxyl group -4- nitrobenzophenones) azo]-N-1- naphthyl -2- naphthalenecarboxamides are crushed, and powder diameter is 1000~1500
Mesh;2,2- dimethyl -3- (2,2- dichloroethylenes)-cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester is added to mix
Close uniform, be laid in pallet, tiling thickness is 24mm~42mm, use the dosage to be for 5.25kGy~8.81kGy, energy
5.27MeV~9.47MeV alpha ray is irradiated 130~270 minutes, and Isodose β x ray irradiation xs 130~270 minutes;
Step 3:The mixed-powder handled through step 2 is dissolved in 1- carbamic acids 3- (2- methoxycarbonyl phenoxies) -1,2- propane diols
In ester, reactor is added, agitator speed is 164rpm~213rpm, and temperature is 194 DEG C~261 DEG C, and starting vavuum pump makes instead
Answer the vacuum of kettle to reach -0.67MPa~2.29MPa, keep this state response 20~32 hours;Pressure release is simultaneously passed through radon gas, makes
Reacting kettle inner pressure is 0.90MPa~1.48MPa, and insulation stands 8~18 hours;Agitator speed be promoted to 227rpm~
311rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 3- amino-N, N- diethyl -4- methoxybenzenesulphoismides, 2,2- double
After the ubidecarenone of [[(caprylyl) oxygen] methyl] 1,3-PD two is completely dissolved, crosslinking agent stirring mixing is added so that reactor
The hydrophilic lipophilic balance of solution is 4.53~6.34, and insulation stands 13~24 hours;
Step 4:When agitator speed is 239rpm~375rpm, N- (2,3- dihydro-2-oxo -1H- are sequentially added
Benzimidazole -5- bases) -3- hydroxyls -4- [[2- methoxyl groups -5- [(phenyl amino) formyl] phenyl] azo] -2- naphthalenecarboxamides, 3-
(N, N- dihydroxy ethyl) amino-4-methoxyacetanilide and 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane carboxylic acid
Sour cyano group (3- Phenoxyphenyls) methyl esters, lifts reactor pressure, reaches 2.49MPa~3.26MPa, and temperature is 247 DEG C
~328 DEG C, polymerisation 15~25 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 24 DEG C~28 DEG C are cooled to,
Discharging, enters molding press and can be prepared by displacement platform.
This preparation method technique is simple, be difficult to produce pollution, its high yield rate to environment.
The following is the embodiment of displacement platform manufacture method of the present invention, embodiment is to further illustrate the present invention
Content, but should not be construed as limiting the invention.Without departing from the spirit and substance of the case in the present invention, to present invention side
Modification and replacement that method, step or condition are made, belong to the scope of the present invention.Unless otherwise specified, used in embodiment
The conventional meanses that technological means is well known to those skilled in the art.
Embodiment 1
A kind of heretofore described displacement platform is prepared according to following steps, and is counted by weight:
1st step:2460 parts of the ultra-pure water that electrical conductivity is 4.86 μ S/cm is added in a kettle., is started in reactor and is stirred
Device, rotating speed is 117rpm, starts heat pump, reactor temperature is risen to 122 DEG C;Sequentially add 3- methoxyl group DOPA amine salt
77 parts of hydrochlorate, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- oxopropoxies) methyl] 138 parts of -1,3- propylene diesters, N-
(4- hydroxy 3-methoxybenzenes methylene) 162 parts of-para-totuidine, stirring is to being completely dissolved, and regulation pH value is 4.55, will be stirred
Mix device rotating speed and be adjusted to 185rpm, temperature is 181 DEG C, esterification 25 hours;
2nd step:Take 3- hydroxy-ns -119 parts of (4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -
4- [(2- methoxyl group -4- nitrobenzophenones) azo] 91 parts of-N-1- naphthyl -2- naphthalenecarboxamides are crushed, and powder diameter is 1000
Mesh;Add 2,2- dimethyl -3- (2,2- dichloroethylenes)-cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester 40
Part is well mixed, is laid in pallet, and tiling thickness is 24mm, uses the alpha ray that dosage is 5.27MeV for 5.25kGy, energy
Irradiation 130 minutes, and Isodose β x ray irradiation xs 130 minutes;
3rd step:Through the 2nd step handle mixed-powder be dissolved in concentration be 68ppm 1- carbamic acids 3- (2- methoxycarbonyl phenoxies)-
In 88 parts of 1,2-PD ester, reactor is added, agitator speed is 164rpm, and temperature is 194 DEG C, and starting vavuum pump makes reaction
The vacuum of kettle reaches -0.67MPa, keeps this state response 20 hours;Pressure release is simultaneously passed through radon gas, makes the reacting kettle inner pressure be
0.90MPa, insulation stands 8 hours;Agitator speed is promoted to 227rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 3-
Double [[(caprylyl) oxygen] methyl] the 1,3- propane diols didecyls of 143 parts of amino-N, N- diethyl -4- methoxybenzenesulphoismides, 2,2-
After 55 parts of alkene ester is completely dissolved, the stirring mixing of 155 parts of crosslinking agent is added so that the hydrophilic lipophilic balance of reactor solution is
4.53, insulation stands 13 hours;
4th step:Agitator speed be 239rpm when, sequentially add N- (2,3- dihydro-2-oxo -1H- benzimidazoles -
5- yls) -3- hydroxyls -4- [[2- methoxyl groups -5- [(phenyl amino) formyl] phenyl] azo] 67 parts of -2- naphthalenecarboxamides, 3- (N, N-
Dihydroxy ethyl) 49 parts of amino-4-methoxyacetanilide and 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid
181 parts of cyano group (3- Phenoxyphenyls) methyl esters, lifts reactor pressure, reaches 2.49MPa, and temperature is 247 DEG C, and polymerization is anti-
Answer 15 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 24 DEG C are cooled to, discharging enters molding press and can be prepared by position
Move platform.
The crosslinking agent is N- (3- hydroxyl -2- naphthoyls) parachloroanilinum.
Embodiment 2
Displacement platform of the present invention is manufactured according to following steps, and is counted by weight:
1st step:3065 parts of the ultra-pure water that electrical conductivity is 5.99 μ S/cm is added in a kettle., is started in reactor and is stirred
Device, rotating speed is 150rpm, starts heat pump, reactor temperature is risen to 153 DEG C;Sequentially add 3- methoxyl group DOPA amine salt
112 parts of hydrochlorate, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- oxopropoxies) methyl] 190 parts of -1,3- propylene diesters, N-
(4- hydroxy 3-methoxybenzenes methylene) 227 parts of-para-totuidine, stirring is to being completely dissolved, and regulation pH value is 7.09, will be stirred
Mix device rotating speed and be adjusted to 206rpm, temperature is 211 DEG C, esterification 30 hours;
2nd step:Take 3- hydroxy-ns -182 parts of (4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -
4- [(2- methoxyl group -4- nitrobenzophenones) azo] 110 parts of-N-1- naphthyl -2- naphthalenecarboxamides are crushed, and powder diameter is 1250
Mesh;Add 2,2- dimethyl -3- (2,2- dichloroethylenes)-cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester 106
Part is well mixed, is laid in pallet, and tiling thickness is 33mm, uses the alpha ray that dosage is 7.38MeV for 7.03kGy, energy
Irradiation 200 minutes, and Isodose β x ray irradiation xs 200 minutes;
3rd step:Through the 2nd step handle mixed-powder be dissolved in concentration be 81ppm 1- carbamic acids 3- (2- methoxycarbonyl phenoxies)-
In 127 parts of 1,2-PD ester, reactor is added, agitator speed is 188rpm, and temperature is 227 DEG C, and starting vavuum pump makes instead
Answer the vacuum of kettle to reach 0.81MPa, keep this state response 26 hours;Pressure release is simultaneously passed through radon gas, makes the reacting kettle inner pressure be
1.19MPa, insulation stands 13 hours;Agitator speed is promoted to 269rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 3-
Double [[(caprylyl) oxygen] methyl] the 1,3- propane diols didecyls of 170 parts of amino-N, N- diethyl -4- methoxybenzenesulphoismides, 2,2-
After 90 parts of alkene ester is completely dissolved, the stirring mixing of 218 parts of crosslinking agent is added so that the hydrophilic lipophilic balance of reactor solution is
5.43, insulation stands 18 hours;
4th step:Agitator speed be 307rpm when, sequentially add N- (2,3- dihydro-2-oxo -1H- benzimidazoles -
5- yls) -3- hydroxyls -4- [[2- methoxyl groups -5- [(phenyl amino) formyl] phenyl] azo] 83 parts of -2- naphthalenecarboxamides, 3- (N, N-
Dihydroxy ethyl) 90 parts of amino-4-methoxyacetanilide and 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid
197 parts of cyano group (3- Phenoxyphenyls) methyl esters, lifts reactor pressure, reaches 2.87MPa, and temperature is 287 DEG C, and polymerization is anti-
Answer 20 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 26 DEG C are cooled to, discharging enters molding press and can be prepared by position
Move platform.
The crosslinking agent is 5- benzyloxy -3- indolecarboxaldehydes.
Embodiment 3
Displacement platform of the present invention is manufactured according to following steps, and is counted by weight:
1st step:3670 parts of the ultra-pure water that electrical conductivity is 7.12 μ S/cm is added in a kettle., is started in reactor and is stirred
Device, rotating speed is 183rpm, starts heat pump, reactor temperature is risen to 185 DEG C;Sequentially add 3- methoxyl group DOPA amine salt
140 parts of hydrochlorate, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- oxopropoxies) methyl] 242 parts of -1,3- propylene diesters, N-
(4- hydroxy 3-methoxybenzenes methylene) 293 parts of-para-totuidine, stirring is to being completely dissolved, and regulation pH value is 9.64, will be stirred
Mix device rotating speed and be adjusted to 224rpm, temperature is 242 DEG C, esterification 36 hours;
2nd step:Take 3- hydroxy-ns -246 parts of (4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -
4- [(2- methoxyl group -4- nitrobenzophenones) azo] 128 parts of-N-1- naphthyl -2- naphthalenecarboxamides are crushed, and powder diameter is 1500
Mesh;Add 2,2- dimethyl -3- (2,2- dichloroethylenes)-cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester 173
Part is well mixed, is laid in pallet, and tiling thickness is 42mm, uses the alpha ray that dosage is 9.47MeV for 8.81kGy, energy
Irradiation 270 minutes, and Isodose β x ray irradiation xs 270 minutes;
3rd step:Through the 2nd step handle mixed-powder be dissolved in concentration be 94ppm 1- carbamic acids 3- (2- methoxycarbonyl phenoxies)-
In 167 parts of 1,2-PD ester, reactor is added, agitator speed is 213rpm, and temperature is 261 DEG C, and starting vavuum pump makes instead
Answer the vacuum of kettle to reach 2.29MPa, keep this state response 32 hours;Pressure release is simultaneously passed through radon gas, makes the reacting kettle inner pressure be
1.48MPa, insulation stands 18 hours;Agitator speed is promoted to 311rpm, simultaneous reactions kettle pressure release to 0MPa;Sequentially add 3-
Double [[(caprylyl) oxygen] methyl] the 1,3- propane diols didecyls of 198 parts of amino-N, N- diethyl -4- methoxybenzenesulphoismides, 2,2-
After 125 parts of alkene ester is completely dissolved, the stirring mixing of 282 parts of crosslinking agent is added so that the hydrophilic lipophilic balance of reactor solution is
6.34, insulation stands 24 hours;
4th step:Agitator speed be 375rpm when, sequentially add N- (2,3- dihydro-2-oxo -1H- benzimidazoles -
5- yls) -3- hydroxyls -4- [[2- methoxyl groups -5- [(phenyl amino) formyl] phenyl] azo] 99 parts of -2- naphthalenecarboxamides, 3- (N, N-
Dihydroxy ethyl) 132 parts of amino-4-methoxyacetanilide and 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane carboxylic acid
Sour 213 parts of cyano group (3- Phenoxyphenyls) methyl esters, lifts reactor pressure, reaches 3.26MPa, and temperature is 328 DEG C, polymerization
Reaction 25 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 28 DEG C are cooled to, discharging enters molding press and can be prepared by
Displacement platform.
The crosslinking agent is 2,2- dinethyl cyclopropane carboxylic acid ethyl esters.
Reference examples
Reference examples are the displacement platform of certain commercially available brand.
Displacement platform described in the displacement platform and reference examples that embodiment 1~3 is prepared carries out using effect contrast.
The two compression strength, unit mass, coefficient of friction, rate of depreciation are counted, as a result as shown in table 1.
As seen from Table 1, displacement platform of the present invention, its compression strength, unit mass, coefficient of friction, rate of depreciation
Etc. the product that index is superior to prior art production.
In addition, as shown in figure 1, being the system that the fatigue of materials intensity of displacement platform 2 of the present invention changes with use time
Meter.Find out in figure, displacement platform used in embodiment 1~3, its fatigue of materials intensity is with use time intensity of variation significantly better than existing
There is product.
As shown in Figures 2 to 6, the present invention also provides a kind of application for sewage disposal solar energy tracking displacement platform,
It is used as the building block of the solar panel automatic tracking device for sewage disposal, the solar energy for sewage disposal
Power generation plate automatic tracking device includes horizontally disposed displacement platform 2, the fixed support 4 for being arranged at the bottom of displacement platform 2, fixed
The rotary electric machine 7 inside fixed support 4 is arranged on, the top solar panels 3 of displacement platform 2 is arranged at and is arranged at fixed support
Battery 1 and controller 8 inside 4, the upper left-hand of institute's translation stage 2 are fixedly installed pushing motor 2-1 and two along position
Move before and after the slide bar 2-2 of platform 2 length direction extension, its upper right and be symmetrically fixedly installed two support column 2-4, two
Slide bar 2-2 is symmetrically disposed in pushing motor 2-1 front and rear sides, and each slide bar 2-2 two ends are fixedly installed by two respectively
Fixed station 2-3 supports on displacement platform 2;One of slide bar 2-2 two ends are each provided with a position sensor 2-5;
Rotatably arranged with there is vertical rotary shaft 5 in the middle part of the bottom plate of the fixed support 4, the upper end of rotary shaft 5 extends to fixed branch
The outside of frame 4 is simultaneously fixedly connected with institute translation stage 2;The middle part of the rotary shaft 5 is set with driven gear;It is described to rotate electricity
The drive gear being meshed with the driven gear is set with the output shaft of machine 7;And also installed on the output shaft of rotary electric machine 7
There is rotary angle transmitter 6;The solar panels 3 include push rod 3-1, two support bar 3-2, solar module 3-3, two cunnings
The sunray angle sensor 3-4 that block 3-5 and four are arranged at the corner of solar module 3-3 upper surfaces;Two branch
Front and rear sides of the strut 3-2 upper end respectively with solar module 3-3 one end are hinged, and its lower end is respectively with being sleeved on two
The upper two sliding block 3-5 of slide bar 2-2 upper end is hinged;Be divided to before the solar module 3-3 other end both sides respectively with two branch
Dagger 2-4 is hinged;Connecting rod is disposed between described two sliding block 3-5, the right-hand member of the push rod 3-1 is consolidated with the middle part of the connecting rod
Fixed connection, its left end is fixedly connected with pushing motor 2-1 output end;The battery 1, sunray angle sensor 3-4,
Rotary angle transmitter 6, the position sensor 2-5 of rotary electric machine 7 are connected with the control of controller 8 respectively.Controller 8 can use X2N-
128MR-001 type Mitsubishi PLC programmable multifunctional controllers.
The setting of regulation motor and rotary shaft can easily realize the regulation of displacement platform in the horizontal direction, so that convenient
Ground finds the incident orientation of optimal sunshine, then can be easy to by two cunnings being set in outside slide bar by the setting of push rod
Block is moved left and right, and to adjust optimal incident angle, the device structure is simple, maintenance process is convenient, and following range is wide, and can be with
Conveniently and efficiently realize the adjustment at the solar module elevation angle.
This application can significantly improve the utilization ratio of solar energy, can substantially reduce the maintenance effect of solar power plant
Rate.
Further, in order to adapt to the work under a variety of natural conditions, the sunray angle sensor 3-4 includes turning round
Become condenser 3-4-2, pedestal 3-4-3, light sensation instrument 3-4-4 and chassis cover 3-4-1;Have inside the distortion condenser 3-4-2
The cylindrical cavity of up/down perforation, its outside distortion drawing structure for being in many dentation corrugateds for cross section, and in its outer surface
Graphite material is coated with, to prevent light from being injected from its lateral wall, and can guarantee that its madial wall has preferable refractive index, distortion gathers
Light microscopic 3-4-2 can be distorted by cylinder and is made around vertical shaft direction;The pedestal 3-4-3 is fixedly connected on distortion condenser
3-4-2 lower end, and it has the receiving space for connecting the cylindrical cavity;The light sensation instrument 3-4-4 includes glass tubular
Direct projection enter polished rod 3-4-4-2, scattering optical fiber 3-4-4-1, by photosensitive material be made can double-sided light sensitive it is translucent photosensitive
Resistance 3-4-4-3, multiple condenser 3-4-4-4 being made up of lucite material, optical fibre ring 3-4-4-5 and reflective gratings 3-
4-4-6;The direct projection enters polished rod 3-4-4-2, scattering optical fiber 3-4-4-1 and is arranged at distortion condenser 3-4-2 cylindrical empty
The central area of chamber, the photo resistance 3-4-4-3, condenser 3-4-4-4, optical fibre ring 3-4-4-5 and reflective gratings 3-4-
4-6 is fixedly installed in pedestal 3-4-3 receiving space at intervals successively from top to bottom;Photo resistance 3-4-4-3 can be with
Be fixedly connected by the pillar extended laterally with pedestal 3-4-3 madial wall, certainly with can by the pillar that extends downwardly with
Pedestal 3-4-3 bottom wall is fixedly connected;Optical fibre ring 3-4-4-5 can by the pillar that extends laterally with pedestal 3-4-3
Side wall is fixedly connected, certainly with that can be fixedly connected by the pillar extended downwardly with pedestal 3-4-3 bottom wall;Reflective gratings 3-
4-4-6 can be fixedly connected by the pillar extended laterally with pedestal 3-4-3 madial wall, certainly with can be by extending downwardly
Pillar be fixedly connected with pedestal 3-4-3 bottom wall, can also directly be fixedly installed on pedestal 3-4-3 bottom wall.
The direct projection is entered polished rod 3-4-4-2 and is fixedly installed on distortion condenser 3-4-2 axial line, and polished rod 3- is entered in direct projection
4-4-2 lower sides can be fixedly connected by the pillar extended laterally with pedestal 3-4-3 madial wall, certainly with that can lead to
Cross the pillar for extending laterally and bending downwards to be fixedly connected with photo resistance 3-4-4-3 top, certainly, polished rod 3-4- is entered in direct projection
4-2 upper end can also with scattering optical fiber 3-4-4-1 be fixedly connected, direct projection enter polished rod 3-4-4-2 lower ends can also and scattered light
Fine 3-4-4-1 is fixedly connected;Its top and distortion condenser 3-4-2 top flush, its bottom to photo resistance 3-4-4-3
Distance be 10mm~20mm, its outer surface is coated with equadag coating;The scattering optical fiber 3-4-4-1 is to enter polished rod 3- around direct projection
4-4-2 is the sped structure of axis of rotation, and its lower end is fixedly connected on photo resistance 3-4-4-3 upper surface, scatters optical fiber
3-4-4-1 is used to receive scattering light source;Stayed between the outer edge surface of the photo resistance 3-4-4-3 and pedestal 3-4-3 madial wall
There is the annular space passed through for the light by the refraction of distortion condenser 3-4-2 madial walls;Photo resistance 3-4-4-3 can be piece
Shape, photo resistance 3-4-4-3 receives the direct light source for entering polished rod 3-4-4-2 irradiations by direct projection, and in this, as adjustment direction angle
The parameter of degree, while photo resistance 3-4-4-3 receives the scattering light source of scattering optical fiber 3-4-4-1 irradiations, and is differentiated round the clock with this,
Photo resistance 3-4-4-3 upper and lower surface is connected with controller 8 respectively;Photo resistance 3-4-4-3 upper surface is main
Control refraction light, is easy to for each parameter of analytical refraction light, photo resistance 3-4-4-3 lower surface receives scattered light, works as wet weather
My god, the seizure realized to the aerial highlights domain in day is acted on by light filling.Multiple condenser 3-4-4-4 are in the optical fibre ring 3-4-
4-5 tops are equally spacedly arranged, cone structures of the condenser 3-4-4-4 for cone bottom surface upward, and are coated with silver-colored light on its surface
Coating, can so receive faint light, and the effect of light filling can also be carried out when the light such as cloudy day are weaker, with when light is bad
Realize effective seizure to light;Condenser 3-4-4-4 lower end is fixedly connected with optical fibre ring 3-4-4-5 one end, ring light
The fine 3-4-4-5 other end is connected with the optical port of controller 8;The reflective gratings 3-4-4-6 is by a plurality of netted in right-angled intersection
The grid composition that the stainless steel mirror material of arrangement is made, reflective gratings 3-4-4-6 is used to scattered light reflexing to photo resistance
3-4-4-3 lower surfaces;The inside of the chassis cover 3-4-1 has cylindrical cavity, and its upper end open is simultaneously embedded with opening
Cloche, for the cylindrical structural being made of clear material, it is located at distortion condenser 3-4-2 and pedestal 3-4-3 outside,
Its lower end is fixedly connected on solar module 3-3 top.
In order to improve reflecting effect, the chassis cover 3-4-1 is made of stainless steel mirror material.
In order to improve the effect of filtering lateral wall incident light, while the refraction effect of internal refraction light can be also improved, it is described
Distortion condenser 3-4-2 is made of glass material, and distortion condenser 3-4-2 top cross-sections are turned round relative to the level of bottom section
Curvature is 15~35 degree.
In order to improve light filling effect, the screw diameter of the scattering optical fiber 3-4-4-1 is 50mm~90mm, its spiral spacing
For 5mm~10mm.
In order to improve light filling effect, polished rod 3-4-4-2 a diameter of 10mm~20mm is entered in the direct projection.
In order to improve reflecting effect, the institute condenser 3-4-4-4 is made of stainless steel, and its quantity is 6.
As a preferred embodiment, the chassis cover 3-4-1 is highly 20mm~60mm, a diameter of 10mm~20mm.
In order to improve reflecting effect, the grid spacing is 10mm~20mm;The pedestal 3-4-3 is cylinder, and its
Inside has waterproof construction.
For the application method of the solar panel automatic tracking device of sewage disposal, comprise the following steps:
Step one:Controlled by controller 8 to connect supply access, sunray angle sensor 3-4 starts working, its
The angle of sunray and solar module 3-3 is monitored in real time;When sunray angle sensor 3-4 is monitored
When sunray and solar module 3-3 azimuth and the angle of pitch be not in its range of set value, sunray is inclined
Angle transducer 3-4 produces an electric signal A and transmitted to controller 8;
Step 2:Controller 8 is received after electric signal A, controls rotary electric machine 7 to drive displacement platform 2 in one direction first
Rotated, when the sunray angle sensor 3-4 azimuths for monitoring sunray and solar module 3-3 are set at it
When in limits, sunray angle sensor 3-4 produces an electric signal B and transmitted to controller 8;In rotary electric machine 7
In the course of work, the rotational angle of rotary angle transmitter 6 in the rotary shaft of rotary electric machine 7 monitoring rotary electric machine 7 in real time, when turning
When dynamic motor 7 turns to the limiting value of the setting of rotary angle transmitter 6, rotary angle transmitter 6 gives a warning electric signal to controller 8, controls
The rotary electric machine 7 of device 8 processed is rotated backward, until reaching required position.
Step 3:Controller 8 is received after electric signal B, and control rotary electric machine 7 is stopped, and controls pushing motor 2-1 works
Make, to carry out the regulation of the angle of pitch to solar module 3-3;When sunray angle sensor 3-4 monitors sunray
During with the solar module 3-3 angle of pitch in its range of set value, sunray angle sensor 3-4 produces an electricity
Signal C is transmitted to controller 8, and controller 8 is received controls pushing motor 2-1 to be stopped after electric signal C;In pushing motor 2-1
In the course of work, the position sensor 2-5 positioned at slide bar 2-2 two ends monitors sliding block 3-5 relative position in real time, as sliding block 3-5
When will move to the extreme position at slide bar 2-2 two ends, now position sensor 2-5 gives a warning electric signal to controller 8, controls
The control of device 8 pushing motor 2-1 processed is rotated backward, until reaching required position.
This method can rapidly adjust angle of the solar-electricity source module relative to sunshine, can rapidly track optimal
Sunshine incoming position, so as to improve tracking efficiency.
Claims (5)
1. one kind is used for sewage disposal solar energy tracking displacement platform, it is characterised in that institute's translation stage is by a variety of macromolecules
The shaping of material pressing mold is made, and its component is counted as follows by weight:
77~140 parts of 3- methoxyl groups dopamine hydrochloride, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- oxopropoxies)
Methyl] 138~242 parts of -1,3- propylene diesters, N- (4- hydroxy 3-methoxybenzenes methylene) 162~293 parts of-para-totuidine,
3- hydroxy-ns -119~246 parts of (4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -4- [(2- methoxies
Base -4- nitrobenzophenones) azo] 91~128 parts of-N-1- naphthyl -2- naphthalenecarboxamides, 2,2- dimethyl -3- (2,2- dichloroethylene
Base) -40~173 parts of cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester, concentration is 68ppm~94ppm 1- amino
Formic acid 3- (2- methoxycarbonyl phenoxies) -88~167 parts of 1,2-PD ester, 3- amino-N, N- diethyl -4- methoxybenzenesulphoismides
143~198 parts, 2,2- double [[(caprylyl) oxygen] methyl] 55~125 parts of two ubidecarenones of 1,3-PD, crosslinking agent 155~282
Part, N- (2,3- dihydro-2-oxo -1H- benzimidazole -5- bases) -3- hydroxyls -4- [[2- methoxyl groups -5- [(phenyl amino) first
Acyl] phenyl] azo] 67~99 parts of -2- naphthalenecarboxamides, 3- (N, N- dihydroxy ethyl) amino-4-methoxyacetanilide 49~132
Part, 181~213 parts of 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid cyano group (3- Phenoxyphenyls) methyl esters;
The crosslinking agent is N- (3- hydroxyl -2- naphthoyls) parachloroanilinum, 5- benzyloxy -3- indolecarboxaldehydes, 2,2- dimethyl
Any one in cyclopropane-carboxylic acid ethyl ester.
2. it is according to claim 1 a kind of for sewage disposal solar energy tracking displacement platform, it is characterised in that institute's rheme
Move platform component and count as follows by weight:78~139 parts of 3- methoxyl groups dopamine hydrochloride, 3- mercaptopropionic acid -2- ethyls -2-
[(3- sulfydryl -1- oxopropoxies) methyl] 139~240 parts of -1,3- propylene diesters, N- (4- hydroxy 3-methoxybenzene base methylenes
Base) 163~290 parts of-para-totuidine, 3- hydroxy-ns-(4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides 120~
240 parts, 3- hydroxyls -4- [(2- methoxyl group -4- nitrobenzophenones) azo] 92~127 parts of-N-1- naphthyl -2- naphthalenecarboxamides, 2,2-
Dimethyl -3- (2,2- dichloroethylene) -41~170 parts of cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester, concentration
For 69ppm~90ppm 1- carbamic acids 3- (2- methoxycarbonyl phenoxies) -89~160 parts of 1,2-PD ester, 3- amino-N, N- bis-
144~190 parts of ethyl -4- methoxybenzenesulphoismides, 2,2- double ubidecarenones 56 of [[(caprylyl) oxygen] methyl] 1,3-PD two
~120 parts, 156~280 parts of crosslinking agent, N- (2,3- dihydro-2-oxo -1H- benzimidazole -5- bases) -3- hydroxyls -4- [[2- first
Epoxide -5- [(phenyl amino) formyl] phenyl] azo] 68~90 parts of -2- naphthalenecarboxamides, 3- (N, N- dihydroxy ethyl) amino -4-
50~130 parts of p-methoxyacetanilide, 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid cyano group (3- benzene oxygen
Base phenyl) 182~210 parts of methyl esters;
The crosslinking agent is N- (3- hydroxyl -2- naphthoyls) parachloroanilinum, 5- benzyloxy -3- indolecarboxaldehydes, 2,2- dimethyl
Any one in cyclopropane-carboxylic acid ethyl ester.
3. a kind of preparation method for sewage disposal solar energy tracking displacement platform, it is characterised in that comprise the following steps:
Step one:2460~3670 parts of the ultra-pure water that electrical conductivity is the μ S/cm of 4.86 μ S/cm~7.12 is added in a kettle., is opened
Agitator in dynamic reactor, rotating speed is 117rpm~183rpm, starts heat pump, make reactor temperature rise to 122 DEG C~
185℃;Sequentially add 3- methoxyl groups dopamine hydrochloride, 3- mercaptopropionic acid -2- ethyls -2- [(3- sulfydryl -1- oxopropoxies)
Methyl] -1,3- propylene diesters, N- (4- hydroxy 3-methoxybenzenes methylene)-para-totuidine, stirring adjusts pH to being completely dissolved
It is worth for 4.55~9.64, agitator speed is adjusted to 185rpm~224rpm, temperature is 181 DEG C~242 DEG C, esterification 25~
36 hours;
Step 2:Take 3- hydroxy-ns-(4- methoxyphenyls) -4- (phenylazo) -2- naphthalenecarboxamides, 3- hydroxyls -4- [(2- first
Epoxide -4- nitrobenzophenones) azo]-N-1- naphthyl -2- naphthalenecarboxamides are crushed, and powder diameter is 1000~1500 mesh;Add
2,2- dimethyl -3- (2,2- dichloroethylene)-cyclopropane-carboxylic acid-alpha- cyano group -3- phenoxy-benzyls ester is well mixed,
Be laid in pallet, tiling thickness be 24mm~42mm, use dosage for 5.25kGy~8.81kGy, energy be 5.27MeV~
9.47MeV alpha ray is irradiated 130~270 minutes, and Isodose β x ray irradiation xs 130~270 minutes;
Step 3:The mixed-powder handled through step 2 is dissolved in 1- carbamic acids 3- (2- methoxycarbonyl phenoxies) -1,2-PD ester,
Reactor is added, agitator speed is 164rpm~213rpm, and temperature is 194 DEG C~261 DEG C, and starting vavuum pump makes reactor
Vacuum reaches -0.67MPa~2.29MPa, keeps this state response 20~32 hours;Pressure release is simultaneously passed through radon gas, makes reactor
Interior pressure is 0.90MPa~1.48MPa, and insulation stands 8~18 hours;Agitator speed is promoted to 227rpm~311rpm, together
When reactor pressure release to 0MPa;Sequentially add the double [[(decoyls of 3- amino-N, N- diethyl -4- methoxybenzenesulphoismides, 2,2-
Base) oxygen] methyl] and 1,3-PD two ubidecarenone be completely dissolved after, add crosslinking agent stirring mixing so that the parent of reactor solution
Hydrophile-lipophile balance value is 4.53~6.34, and insulation stands 13~24 hours;
Step 4:When agitator speed is 239rpm~375rpm, N- (2,3- dihydro-2-oxo -1H- benzos are sequentially added
Imidazoles -5- bases) -3- hydroxyls -4- [[2- methoxyl groups -5- [(phenyl amino) formyl] phenyl] azo] -2- naphthalenecarboxamides, 3- (N,
N- dihydroxy ethyls) amino-4-methoxyacetanilide and 2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid cyanogen
Base (3- Phenoxyphenyls) methyl esters, lifts reactor pressure, reaches 2.49MPa~3.26MPa, and temperature is 247 DEG C~328
DEG C, polymerisation 15~25 hours;Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 24 DEG C~28 DEG C are cooled to, discharged,
Enter molding press and can be prepared by displacement platform.
4. a kind of a kind of application for sewage disposal solar energy tracking displacement platform as claimed in claim 1 or 2, its feature
It is, as the building block of the solar panel automatic tracking device for sewage disposal,
The solar panel automatic tracking device for sewage disposal, including horizontally disposed displacement platform (2), setting
Fixed support (4) in displacement platform (2) bottom, it is fixedly installed on the internal rotary electric machine (7) of fixed support (4), is arranged at
Displacement platform (2) top solar panels (3) and the battery (1) and controller (8) for being arranged at fixed support (4) inside, its
It is characterised by,
Institute translation stage (2) upper left-hand is fixedly installed pushing motor (2-1) and two along displacement platform (2) length direction
Two support columns (2-4) are symmetrically fixedly installed before and after the slide bar (2-2) of extension, its upper right, two slide bars (2-2) are right
It is arranged on pushing motor (2-1) front and rear sides with claiming, the two ends of each slide bar (2-2) are fixedly installed on displacement by two respectively
Fixed station (2-3) support on platform (2);The two ends of one of slide bar (2-2) are each provided with a position sensor (2-
5);
Rotatably arranged with there is vertical rotary shaft (5) in the middle part of the bottom plate of the fixed support (4), the upper end of rotary shaft (5) is prolonged
Reach the outside of fixed support (4) and be fixedly connected with institute's translation stage (2);Be set with the middle part of the rotary shaft (5) from
Moving gear;
The drive gear being meshed with the driven gear is set with the output shaft of the rotary electric machine (7);And rotary electric machine
(7) rotary angle transmitter (6) is also equipped with output shaft;
The solar panels (3) include push rod (3-1), two support bars (3-2), solar module (3-3), two sliding blocks
(3-5) and four sunray angle sensors (3-4) being arranged at solar module (3-3) upper surface corner;Two
Front and rear sides of the upper end of individual support bar (3-2) respectively with solar module (3-3) one end are hinged, its lower end respectively with set
Upper end mounted in upper two sliding blocks (3-5) of two slide bars (2-2) is hinged;It is divided to two before the other end of solar module (3-3)
Side is hinged with two support columns (2-4) respectively;Connecting rod, the right side of the push rod (3-1) are disposed between described two sliding blocks (3-5)
End in the middle part of the connecting rod with being fixedly connected, and its left end is fixedly connected with the output end of pushing motor (2-1);
The battery (1), sunray angle sensor (3-4), rotary angle transmitter (6), rotary electric machine (7) and position sensing
Device (2-5) is connected with controller (8) control respectively.
5. a kind of application for sewage disposal solar energy tracking displacement platform according to claim 4, it is characterised in that
The sunray angle sensor (3-4) include distortion condenser (3-4-2), pedestal (3-4-3), light sensation instrument (3-4-4) and
Chassis cover (3-4-1);
There is the cylindrical cavity of up/down perforation, it is that cross section is in many dentations that it is outside inside the distortion condenser (3-4-2)
The distortion of corrugated draws structure, and is coated with graphite material in its outer surface;
The pedestal (3-4-3) is fixedly connected on distortion condenser (3-4-2) lower end, and it has the connection cylindrical empty
The receiving space of chamber;
The direct projection that the light sensation instrument (3-4-4) includes glass tubular enters polished rod (3-4-4-2), scattering optical fiber (3-4-4-1), by feeling
Luminescent material be made can double-sided light sensitive translucent photo resistance (3-4-4-3), it is multiple by lucite material be made it is poly-
Light microscopic (3-4-4-4), optical fibre ring (3-4-4-5) and reflective gratings (3-4-4-6);
The direct projection enters polished rod (3-4-4-2), scattering optical fiber (3-4-4-1) and is arranged at distortion condenser (3-4-2) cylinder
The central area of shape cavity, the photo resistance (3-4-4-3), condenser (3-4-4-4), optical fibre ring (3-4-4-5) and anti-
Grid (3-4-4-6) is penetrated to be fixedly installed at intervals in pedestal (3-4-3) receiving space successively from top to bottom;
The direct projection is entered polished rod (3-4-4-2) and is fixedly installed on distortion condenser (3-4-2) axial line, its top and distortion
The top flush of condenser (3-4-2), the distance of its bottom to photo resistance (3-4-4-3) is 10mm~20mm, its appearance
Face is coated with equadag coating;The scattering optical fiber (3-4-4-1) is to enter the spiral that polished rod (3-4-4-2) is axis of rotation around direct projection
Formula structure, its lower end is fixedly connected on photo resistance (3-4-4-3) upper surface;The outer rim of the photo resistance (3-4-4-3)
The ring passed through for the light reflected by distortion condenser (3-4-2) madial wall is left between the madial wall of face and pedestal (3-4-3)
Shape space;The upper and lower surface of photo resistance (3-4-4-3) is connected with controller (8) respectively;Multiple condenser (3-4-4-
4) equally spacedly arranged on the optical fibre ring (3-4-4-5) top, cone knot of the condenser (3-4-4-4) for cone bottom surface upward
Structure, and silver-colored light coating is coated with its surface, the lower end of condenser (3-4-4-4) is consolidated with one end of optical fibre ring (3-4-4-5)
Fixed connection, the other end of optical fibre ring (3-4-4-5) is connected with the optical port of controller (8);
The grid group that the reflective gratings (3-4-4-6) are made up of a plurality of stainless steel mirror material in right-angled intersection meshy arrangement
Into;
The inside of the chassis cover (3-4-1) has cylindrical cavity, and its upper end open is simultaneously embedded with cloche at opening, is
The cylindrical structural being made of clear material, it is located at the outside of distortion condenser (3-4-2) and pedestal (3-4-3), under it
End is fixedly connected on solar module (3-3) top.
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Cited By (1)
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CN108545502A (en) * | 2018-03-19 | 2018-09-18 | 徐州工程学院 | A kind of manganese slag thermal insulation material combined type paves mechanism |
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