CN107312410A - A kind of aqueous, environmental protective insect paint - Google Patents
A kind of aqueous, environmental protective insect paint Download PDFInfo
- Publication number
- CN107312410A CN107312410A CN201710584665.5A CN201710584665A CN107312410A CN 107312410 A CN107312410 A CN 107312410A CN 201710584665 A CN201710584665 A CN 201710584665A CN 107312410 A CN107312410 A CN 107312410A
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- aqueous
- water
- environmental protective
- rotenone
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
Abstract
The present invention relates to a kind of aqueous, environmental protective insect paint, include the raw material of following parts by weight：Annona lactone：1 10 parts, nicotine：1 10 parts, rotenone：15 parts, water-based acrylic resin：10 25 parts, color stuffing：10 30 parts, levelling agent：13 parts, dispersant：13 parts, defoamer：13 parts, rheological agent：13 parts, water：50 80 parts.The aqueous, environmental protective insect paint of the present invention has the good feature of environmental protection, using natural insect prevention composition：Annona lactone, nicotine and rotenone, effective insect prevention, expelling parasite and desinsection can be played a part of, purify air, safe without toxic side effect, be conducive to health and ecological environment, and the present invention uses Multiple components science compounding use, and composition is reasonable, obtained coating has excellent tack, mechanical property, filming performance, insect prevention, is a kind of coating of excellent quality.
Description
Technical field
The present invention relates to paint field, a kind of aqueous, environmental protective insect paint is specifically related to.
Background technology
The insects such as mosquito, fly can propagate a variety of diseases, and they generally build up indoors, harm human health, therefore with
Effect of the conventional various coating in interior to complete Vermins-expelling vermins-proof is ideal.But having for being supplied in the market is driven
The coating majority of worm insect prevention function is insecticide of the addition containing the material such as benzene dichloride or aromatics, and such material is poisonous to endanger
Evil human health, pollutes environment.With the continuous improvement of living standards of the people and continuing to develop for coating technology, indoor environment pair
People's is healthy particularly important, and the environment of especially public place enjoys people to pay close attention to, as hospital, school, hotel et al.
Mouth flowing and intensive place carry out disinfection it is necessary to regular many interiors, bacteria breed are reduced, so that ensureing the air of people is
Health is pure and fresh.
Chinese Patent Application No. discloses a kind of insect paint for 201210469114.1 patent, and it coats insecticide
Composition is cyclodextrin, the chrysanthemum of trichlorine cyanogen penta, calgon, and the chrysanthemum of trichlorine cyanogen penta has higher toxicity, remaining cyclodextrin and six inclined
The vermins-proof effect that the combination of sodium phosphate is played is also very limited.
The content of the invention
The present invention according to the deficiencies in the prior art there is provided a kind of safe without toxic side effect, beneficial to health and ecological environment
The aqueous, environmental protective insect paint with insect prevention function.
To achieve the above object, the present invention is adopted the following technical scheme that：
The present invention provides a kind of aqueous, environmental protective insect paint, includes the raw material of following parts by weight：
Annona lactone：1-10 parts；
Nicotine：1-10 parts；
Rotenone：1-5 parts.
Further, the aqueous, environmental protective insect paint, includes the raw material of following parts by weight：Water soluble acrylic acid tree
Fat：10-25 parts；
Color stuffing：10-30 parts；
Levelling agent：1-3 parts；
Dispersant：1-3 parts；
Defoamer：1-3 parts；
Rheological agent：1-3 parts；
Water：50-80 parts.
Further, the aqueous, environmental protective insect paint, includes the raw material of following parts by weight：
Annona lactone：3-8 parts；
Nicotine：3-8 parts；
Rotenone：2-4 parts；
Water-based acrylic resin：15-20 parts；
Color stuffing：15-25 parts；
Levelling agent：1.5-2.5 part；
Dispersant：1.5-2.5 part；
Defoamer：1.5-2.5 part；
Rheological agent：1.5-2.5 part；
Water：60-70 parts.
Further, the color stuffing is at least one of activated Calcium carbonate, zinc oxide, white carbon, talcum powder.
Further, the aqueous, environmental protective insect paint, is made up of the raw material of following parts by weight：
Annona lactone：5 parts；
Nicotine：5 parts；
Rotenone：3 parts；
Water-based acrylic resin：17 parts；
Activated Calcium carbonate：20 parts；
Levelling agent：2 parts；
Dispersant：2 parts；
Defoamer：2 parts；
Rheological agent：2 parts；
Water：65 parts.
Further, the present invention also provides a kind of preparation method of aqueous, environmental protective insect paint：First by water soluble acrylic acid tree
Fat is added to the water, and is stirring evenly and then adding into after color stuffing, 20-40min and sequentially adds dispersant, defoamer, levelling agent, stirs 5-
10min, mixing speed is 3000-4000r/min, is subsequently added into Annona lactone, nicotine, rotenone, stirs 5-10min, stirs
Speed is mixed for 3000-4000r/min, rheological agent is eventually adding, obtains aqueous, environmental protective insect paint.
Annona lactone is one of main active insecticidal components of Annonaceae plant.By prolonged research, at present oneself
Isolated nearly 400 annonaceous acetogenins from the nearly 150 kinds of plants of category more than 40.Annona lactone is preventing from posting
There is significant bioactivity in terms of life, weeding, mite killing, desinsection.Research shows, Annona lactone by strong stomach toxicity and
Antifeedant Effects embody its insecticidal activity.
The traditional main active insecticidal components of pesticide plant tobacco of Solanaceae are nicotine, have stomach toxicity to insect, tag, fumigate
And ovicidal action.
Main active rotenone in legume trifoliate jewelvine root skin to black cutworm, cigarette aphid, onion thrips, cigarette fleahopper,
There is strength action of contace poison etc. various pests.The ethanol extract of false indigo has toxic action, research knot to scarab beetle, cabbage caterpillar etc.
Fruit shows that its active ingredient is rotenone and rotenoid.
Compared with prior art, beneficial effects of the present invention are：With the good feature of environmental protection, using natural insect prevention into
Point：Annona lactone, nicotine and rotenone, safe without toxic side effect, beneficial to health and ecological environment, are easily divided in nature
Solution, do not result in problem of environmental pollution as other types insecticide, effective insect prevention, expelling parasite and desinsection can be played
Effect, purify air, and the present invention uses Multiple components science compounding use, composition is reasonable, and obtained coating has excellent
Different tack, mechanical property, filming performance, insect prevention, are a kind of coating of excellent quality.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of aqueous, environmental protective insect paint, is made up of the raw material of following parts by weight：
Annona lactone：5 parts；
Nicotine：5 parts；
Rotenone：3 parts；
Water-based acrylic resin：17 parts；
Activated Calcium carbonate：20 parts；
Levelling agent：2 parts；
Dispersant：2 parts；
Defoamer：2 parts；
Rheological agent：2 parts；
Water：65 parts.
The preparation method of above-mentioned aqueous, environmental protective insect paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after activated Calcium carbonate, 20min and sequentially adds point
Powder, defoamer, levelling agent, stir 5min, mixing speed is 3000r/min, is subsequently added into Annona lactone, nicotine, trifoliate jewelvine
Ketone, stirs 5min, mixing speed is 3000r/min, is eventually adding rheological agent, obtains aqueous, environmental protective insect paint.
Embodiment 2
A kind of aqueous, environmental protective insect paint, is made up of the raw material of following parts by weight：
Annona lactone：3 parts；
Nicotine：3 parts；
Rotenone：2 parts；
Water-based acrylic resin：15 parts；
Zinc oxide：10 parts；
White carbon：5 parts；
Levelling agent：1.5 part；
Dispersant：1.5 part；
Defoamer：1.5 part；
Rheological agent：1.5 part；
Water：60 parts.
The preparation method of above-mentioned aqueous, environmental protective insect paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after zinc oxide, white carbon, 30min and adds successively
Enter dispersant, defoamer, levelling agent, stir 6min, mixing speed is 3500r/min, be subsequently added into Annona lactone, nicotine,
Rotenone, stirs 6min, mixing speed is 3500r/min, is eventually adding rheological agent, obtains aqueous, environmental protective insect paint.
Embodiment 3
A kind of aqueous, environmental protective insect paint, is made up of the raw material of following parts by weight：
Annona lactone：8 parts；
Nicotine：8 parts；
Rotenone：4 parts；
Water-based acrylic resin：20 parts；
Zinc oxide：15 parts；
Talcum powder：10 parts；
Levelling agent：2.5 part；
Dispersant：2.5 part；
Defoamer：2.5 part；
Rheological agent：2.5 part；
Water：70 parts.
The preparation method of above-mentioned aqueous, environmental protective insect paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after zinc oxide, talcum powder, 40min and adds successively
Enter dispersant, defoamer, levelling agent, stir 7min, mixing speed is 4000r/min, be subsequently added into Annona lactone, nicotine,
Rotenone, stirs 7min, mixing speed is 4000r/min, is eventually adding rheological agent, obtains aqueous, environmental protective insect paint.
Embodiment 4
A kind of aqueous, environmental protective insect paint, is made up of the raw material of following parts by weight：
Annona lactone：1 part；
Nicotine：1 part；
Rotenone：1 part.
Water-based acrylic resin：10 parts；
Activated Calcium carbonate：10 parts；
Levelling agent：1 part；
Dispersant：1 part；
Defoamer：1 part；
Rheological agent：1 part；
Water：50 parts.
The preparation method of above-mentioned aqueous, environmental protective insect paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after activated Calcium carbonate, 25min and sequentially adds point
Powder, defoamer, levelling agent, stir 9min, mixing speed is 3500r/min, is subsequently added into Annona lactone, nicotine, trifoliate jewelvine
Ketone, stirs 9min, mixing speed is 3500r/min, is eventually adding rheological agent, obtains aqueous, environmental protective insect paint.
Embodiment 5
A kind of aqueous, environmental protective insect paint, is made up of the raw material of following parts by weight：
Annona lactone：10 parts；
Nicotine：10 parts；
Rotenone：5 parts.
Water-based acrylic resin：25 parts；
Zinc oxide：20 parts；
White carbon：10 parts；
Levelling agent：3 parts；
Dispersant：3 parts；
Defoamer：3 parts；
Rheological agent：3 parts；
Water：80 parts.
The preparation method of above-mentioned aqueous, environmental protective insect paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after zinc oxide, white carbon, 35min and adds successively
Enter dispersant, defoamer, levelling agent, stir 10min, mixing speed is 4000r/min, be subsequently added into Annona lactone, nicotine,
Rotenone, stirs 10min, mixing speed is 4000r/min, is eventually adding rheological agent, obtains aqueous, environmental protective insect paint.
Comparative example 1
In addition to Annona lactone is not added with component, other components and preparation method are same as Example 1.
Comparative example 2
In addition to nicotine is not added with component, other components and preparation method are same as Example 1.
Comparative example 3
In addition to rotenone is not added with component, other components and preparation method are same as Example 1.
Comparative example 4
In addition to Annona lactone, nicotine, rotenone are not added with component, other components and preparation method and the phase of embodiment 1
Together.
Film performance is tested
Preferably to prove that a kind of aqueous, environmental protective insect paint provided by the present invention has excellent effect, choose and implement
Example 1,2,3,4,5 distinguishes roller coat in applying body surface with comparative example 1,2,3,4, and gained film carries out performance described in following table and surveyed
Examination.
Table 1, table 2 are test index and result.
Table 1
Table 2
As a result show：
From table 1,2, embodiment 1-5 and comparative example 1-4 prepare the equal flat smooth of film, no demoulding cracking phenomena, tool
There are excellent tack, mechanical property, filming performance.
Insect prevention performance test
According to GB13917.1-92《Biological efficacy test》It is monitored insect killing effect.Selection activity is quick, vitality is prosperous
The insect of the certain amount (this experiment is 9) of Sheng selects nine pieces of 8*15cm asbestos board, is respectively respectively as object is killed
Coat to coat on the coating for coating embodiment 2 on the coating of embodiment 1, No. 2 plates, No. 3 plates on-No. 9 plates of No. 1 plate, No. 1 plate and implement
Coated on the coating of example 3, No. 4 plates and coat comparative example on the coating that embodiment 5 is coated on the coating of embodiment 4, No. 5 plates, No. 6 plates
Coated on 1 coating, No. 7 plates and coat comparative example 4 on the coating that comparative example 3 is coated on the coating of comparative example 2, No. 8 plates, No. 9 plates
Coating, respectively cover with paint, lacquer, colour wash, etc. twice, each interval time is 12h, after after dried coating film, five insects respectively placed on 9 blocks of asbestos boards,
And covered with the special small beaker that ambient atmosphere circulates, make the scope of activities of insect between asbestos board and beaker
In one small space, its insect killing effect is observed, is averaged, testing result is shown in Table 3.
Table 3
* knockdown time refer to insect go down can not free movable time, the * * death times refer to that insect is condensed to one
The thorough dead time.
It will be evident that the 1-5 plates of coating embodiment 1-5 coating are obvious to the insect killing effect of insect from table 3, coating
No. 1 plate of embodiment 1 is best to the insect killing effect of insect, and is superior to coat the 6-9 plates of comparative example 1-4 coating, and applies
No. 9 plates for covering comparative example 4 do not have the property killed to insect, and comparative example 4 is to be not added with the painting of Annona lactone, nicotine, rotenone
Material, with showing that Annona lactone, nicotine, rotenone are insect prevention, expelling parasite, gone out to the contrast of the obvious embodiment of insect insect killing effect 1
The effective active matter of worm, and it has excellent insect prevention performance.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can be readily occurred in,
It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection of claims
Scope is defined.
Claims (6)
1. a kind of aqueous, environmental protective insect paint, it is characterised in that include the raw material of following parts by weight：Annona lactone：1-10
Part, nicotine：1-10 parts, rotenone：1-5 parts.
2. aqueous, environmental protective insect paint according to claim 1, it is characterised in that also include the original of following parts by weight
Material：Water-based acrylic resin：10-25 parts, color stuffing：10-30 parts, levelling agent：1-3 parts, dispersant：1-3 parts, defoamer：1-3
Part, rheological agent：1-3 parts, water：50-80 parts.
3. aqueous, environmental protective insect paint according to claim 2, it is characterised in that include the raw material of following parts by weight：
Annona lactone：3-8 parts, nicotine：3-8 parts, rotenone：2-4 parts, water-based acrylic resin：15-20 parts, color stuffing：15-25
Part, levelling agent：1.5-2.5 part, dispersant：1.5-2.5 part, defoamer：1.5-2.5 part, rheological agent：1.5-2.5 part, water：60-
70 parts.
4. the aqueous, environmental protective insect paint according to Claims 2 or 3, it is characterised in that the color stuffing is active carbonic acid
At least one of calcium, zinc oxide, white carbon, talcum powder.
5. aqueous, environmental protective insect paint according to claim 4, it is characterised in that by the raw material system of following parts by weight
Into：Annona lactone：5 parts, nicotine：5 parts, rotenone：3 parts, water-based acrylic resin：17 parts, activated Calcium carbonate：20 parts, stream
Flat agent：2 parts, dispersant：2 parts, defoamer：2 parts, rheological agent：2 parts, water：65 parts.
6. the preparation method of the aqueous, environmental protective insect paint according to claim any one of 2-5, it is characterised in that including such as
Lower step：First water-based acrylic resin is added to the water, be stirring evenly and then adding into after color stuffing, 20-40min sequentially add it is scattered
Agent, defoamer, levelling agent, stir 5-10min, mixing speed is 3000-4000r/min, is subsequently added into Annona lactone, cigarette
Alkali, rotenone, stir 5-10min, mixing speed is 3000-4000r/min, is eventually adding rheological agent, obtains aqueous, environmental protective insect prevention
Coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710584665.5A CN107312410A (en) | 2017-07-15 | 2017-07-15 | A kind of aqueous, environmental protective insect paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710584665.5A CN107312410A (en) | 2017-07-15 | 2017-07-15 | A kind of aqueous, environmental protective insect paint |
Publications (1)
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| CN107312410A true CN107312410A (en) | 2017-11-03 |
Family
ID=60178847
Family Applications (1)
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| CN201710584665.5A Pending CN107312410A (en) | 2017-07-15 | 2017-07-15 | A kind of aqueous, environmental protective insect paint |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760138A (en) * | 2017-11-24 | 2018-03-06 | 广东华兹卜新材料科技有限公司 | A kind of water-based acrylic resin coating of resisting corrosion of chlorine ion and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1552775A (en) * | 2003-06-06 | 2004-12-08 | 舟山格兰特种涂料有限公司 | Preparing method for insect preventing and parasite expelling paint |
| CN101680160A (en) * | 2007-06-12 | 2010-03-24 | 巴斯夫欧洲公司 | Aqueous formulation and process for the impregnation of non-living-materials imparting a protective activity against pests |
| CN105199462A (en) * | 2015-10-28 | 2015-12-30 | 漳州三德利油漆涂料有限公司 | Plant sterilizing insect-repelling functional type inner wall emulsion paint and preparation method thereof |
| CN106752474A (en) * | 2016-12-12 | 2017-05-31 | 墨宝股份有限公司 | A kind of environment-friendly materials and its manufacture method and application with expelling parasite purification function |
-
2017
- 2017-07-15 CN CN201710584665.5A patent/CN107312410A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1552775A (en) * | 2003-06-06 | 2004-12-08 | 舟山格兰特种涂料有限公司 | Preparing method for insect preventing and parasite expelling paint |
| CN101680160A (en) * | 2007-06-12 | 2010-03-24 | 巴斯夫欧洲公司 | Aqueous formulation and process for the impregnation of non-living-materials imparting a protective activity against pests |
| CN105199462A (en) * | 2015-10-28 | 2015-12-30 | 漳州三德利油漆涂料有限公司 | Plant sterilizing insect-repelling functional type inner wall emulsion paint and preparation method thereof |
| CN106752474A (en) * | 2016-12-12 | 2017-05-31 | 墨宝股份有限公司 | A kind of environment-friendly materials and its manufacture method and application with expelling parasite purification function |
Non-Patent Citations (1)
| Title |
|---|
| 罗都强 张兴: "植物源杀虫剂研究进展", 《西北农林科技大学学报（自然科学版）》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760138A (en) * | 2017-11-24 | 2018-03-06 | 广东华兹卜新材料科技有限公司 | A kind of water-based acrylic resin coating of resisting corrosion of chlorine ion and preparation method thereof |
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