CN107306693A - A kind of heat-insulated antifogging type greenhouse material - Google Patents
A kind of heat-insulated antifogging type greenhouse material Download PDFInfo
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- CN107306693A CN107306693A CN201710514810.2A CN201710514810A CN107306693A CN 107306693 A CN107306693 A CN 107306693A CN 201710514810 A CN201710514810 A CN 201710514810A CN 107306693 A CN107306693 A CN 107306693A
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
- A01G9/14—Greenhouses
- A01G9/1438—Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
Abstract
The invention discloses a kind of heat-insulated antifogging type greenhouse material, the greenhouse material is glass material, four walls for heliogreenhouse, the roof of the heliogreenhouse is formed by connecting by the bar shaped cover plate of multiple inverted V-shaped shapes, it is additionally provided between the bar shaped cover plate of multiple inverted V-shaped shapes on rainwater-collecting pipeline, the roof and is also covered with one layer of external sunshade net；Four walls of the heliogreenhouse are glass material, and the outer application of the glass material, which has, is coated with one layer of antifogging coating on the inside of one layer of heat insulating coat, the film.The outer layer of garden glass material of the present invention is coated with heat insulating coat, the excessive radiation of ultraviolet and sunlight can be prevented, so that the temperature in summer greenhouse will not be too high, in addition, the internal layer of garden glass material is also coated with antifogging coating, it can prevent from hazing on the inside of cold snap greenhouse so that sunlight can fully irradiate.
Description
Technical field
The present invention relates to agricultural plantation technology field, and in particular to a kind of heat-insulated antifogging type greenhouse material.
Background technology
In vegetable melon and fruit field of planting, in order that obtaining many season high-yield plantings of crops energy, the use of glasshouse is increasingly
Extensively.But there are some shortcomings in existing glasshouse：One is that roof rain water can not be discharged, and roof causes ponding；Two be temperature
Room glass light blocking effect of heat insulation is too poor, and the temperature in hot summer greenhouse is too high, is not suitable for crop growth, and can not prevent
The injury that ultraviolet and excessive illumination are caused to crops；Three be that garden glass can not be antifog, in cold winter, garden glass
Internal layer easily haze, thus irradiation of the outdoor solar light to crops can be reduced, be unfavorable for growth of the crops in winter.
The content of the invention
In view of the above-mentioned problems, the present invention provides a kind of heat-insulated antifogging type garden glass material, the outer layer coating of garden glass
There is heat insulating coat, the excessive radiation of ultraviolet and sunlight can be prevented so that the temperature in summer greenhouse will not be too high, in addition,
The internal layer of garden glass is also coated with antifogging coating, can prevent from hazing on the inside of cold snap greenhouse so that sunlight can be abundant
Irradiation.
The present invention is specially a kind of heat-insulated antifogging type greenhouse material, and the greenhouse material is glass material, for sunlight
Four walls of room, the heliogreenhouse includes above wall, below left side wall, wall and right side wall, before, the left side, below,
Right side wall surrounds four walls of heliogreenhouse jointly, and the above wall is provided with gate, and the heliogreenhouse also includes covering
Roof on Yu Sibi, the roof is formed by connecting by the bar shaped cover plate of multiple inverted V-shaped shapes, the bar shaped lid of multiple inverted V-shaped shapes
It is additionally provided between plate on rainwater-collecting pipeline, the roof and is also covered with one layer of external sunshade net.
The outer application of the glass material have be coated with the inside of one layer of heat insulating coat, the glass material one layer it is antifog
Coating, the heat insulating coat is specially In2O3-SnO2Heat insulating coat, the antifogging coating is specially that fluorocarbon resin reflective insulation is prevented
Mist coating.
The In2O3-SnO2The preparation method of heat insulating coat specifically includes following steps：Step (11), by the inorganic salts of indium
With the inorganic salt blend of tin, and precipitating reagent, dispersant are added, control pH value and reaction temperature are obtained before hydroxide after reaction
Drive body；Step (12), the hydroxide precursor obtains In after carrying out low-temperature hydrothermal reaction and high-temperature heat treatment2O3-SnO2Receive
Ground rice body；Step (13), the In2O3-SnO2Dispersant is added in nano-powder, is obtained using after the dispersing mode of ultrasonic ball milling
To In2O3-SnO2Ethanol slurry；Step (14), the In2O3-SnO2Ethanol slurry is mixed by blending method with acrylic resin
Obtain In2O3-SnO2Insulating moulding coating；Step (15), the In2O3-SnO2Insulating moulding coating acts on film by the way of lifting
On matrix, In is finally obtained2O3-SnO2Heat insulating coat.
The preparation method of fluorocarbon resin reflective insulation anti-fog coating specifically includes following steps：Step (21), by fluorine carbon tree
Fat, reflective insulation color stuffing, auxiliary agent and solvent mixing；Step (22), 10 points are stirred by mixture in high speed dispersor high speed
Clock；Step (23), adds hollow glass bead；Step (24), continues stirring at low speed 30 minutes, obtains fluorocarbon resin reflective insulation and prevents
Mist coating.
Further, In described in step (12)2O3-SnO2The preparation method of nano-powder is specially by InCl3Solution and
SnCl4■5H2After O crystallized mixeds, add dispersant, and be added dropwise ammoniacal liquor heating be hydrolyzed, control pH value be 7, it is still aging after
The sediment of gained is washed with distilled water and ethanol, and grinding obtains precursor powder, the forerunner after oven drying
Body powder obtains In in 700 DEG C of temperature lower calcinations and after cooling down2O3-SnO2Nano-powder.
Further, In described in step (13)2O3-SnO2The preparation method of ethanol slurry is specially the In2O3-SnO2
Nano-powder is carried out adding dispersant after magnetic force is mixed with absolute ethyl alcohol, and In is obtained after disperseing by ultrasonic disperse and ball milling2O3-
SnO2Ethanol slurry.
Further, In described in step (14)2O3-SnO2The preparation method of insulating moulding coating is specially the In2O3-SnO2
Ethanol slurry carries out magnetic agitation after being mixed with acrylic resin, and by ultrasonic disperse and ball milling it is scattered after obtain In2O3-
SnO2Insulating moulding coating.
Further, In described in step (15)2O3-SnO2The preparation method of heat insulating coat is specially by the In2O3-
SnO2Insulating moulding coating is coated on film matrix by the way of lifting plated film, and wet film is dried through room temperature, after isothermal curing
Complete In2O3-SnO2The preparation of heat insulating coat.
Further, hollow glass bead described in step (23) is specially the cenosphere of titanium dioxide cladding.
Further, the preparation method of the cenosphere of the titanium dioxide cladding is specially by hollow glass bead and distilled water
By 1:After 10 mixing, 1% neopelex solution ＆ stir is added dropwise 5 minutes, hollow glass bead is disperseed in water
Uniformly, heating and controlling reaction temperature, are slowly dropped into sustained response 6 hours after titanium sulfate solution, washing and mistake after reaction terminates
Dry, the finally calcining at 600 DEG C is filtered dry, the cenosphere of titanium dioxide cladding is made.
The present invention by being improved to garden glass, be respectively coated in the outside and inner side of glass one layer of heat insulating coat and
One layer of antifogging coating so that garden glass is provided simultaneously with heat-insulated and anti-fog function, it is ensured that the environment in greenhouse is adapted to crops life
It is long.
Brief description of the drawings
Fig. 1 is the structural representation of the heat-insulated antifog heliogreenhouse of the present invention.
Embodiment
The embodiment to heat-insulated antifogging type greenhouse material of the invention is elaborated below in conjunction with the accompanying drawings.
As shown in figure 1, heat-insulated antifogging type greenhouse material of the invention is glass material, it is described for four walls of heliogreenhouse
Heliogreenhouse includes above wall (1), below left side wall (2), wall (3) and right side wall (4), before, the left side, below,
Right side wall surrounds four walls of heliogreenhouse jointly, and the above wall is provided with gate (5), and the heliogreenhouse also includes covering
The roof (6) on four walls is placed on, the roof (6) is formed by connecting by the bar shaped cover plate of multiple inverted V-shaped shapes, multiple inverted V-shaped shapes
Bar shaped cover plate between be additionally provided with rainwater-collecting pipeline, the roof (6) and be also covered with one layer of external sunshade net.
The outer application of the glass material have be coated with the inside of one layer of heat insulating coat, the glass material one layer it is antifog
Coating, the heat insulating coat is specially In2O3-SnO2Heat insulating coat, the antifogging coating is specially that fluorocarbon resin reflective insulation is prevented
Mist coating.
The In2O3-SnO2The preparation method of heat insulating coat specifically includes following steps：Step (11), by the inorganic salts of indium
With the inorganic salt blend of tin, and precipitating reagent, dispersant are added, control pH value and reaction temperature are obtained before hydroxide after reaction
Drive body；Step (12), the hydroxide precursor obtains In after carrying out low-temperature hydrothermal reaction and high-temperature heat treatment2O3-SnO2Receive
Ground rice body；Step (13), the In2O3-SnO2Dispersant is added in nano-powder, is obtained using after the dispersing mode of ultrasonic ball milling
To In2O3-SnO2Ethanol slurry；Step (14), the In2O3-SnO2Ethanol slurry is mixed by blending method with acrylic resin
Obtain In2O3-SnO2Insulating moulding coating；Step (15), the In2O3-SnO2Insulating moulding coating acts on film by the way of lifting
On matrix, In is finally obtained2O3-SnO2Heat insulating coat.
The preparation method of fluorocarbon resin reflective insulation anti-fog coating specifically includes following steps：Step (21), by fluorine carbon tree
Fat, reflective insulation color stuffing, auxiliary agent and solvent mixing；Step (22), 10 points are stirred by mixture in high speed dispersor high speed
Clock；Step (23), adds hollow glass bead；Step (24), continues stirring at low speed 30 minutes, obtains fluorocarbon resin reflective insulation and prevents
Mist coating.
In described in step (12)2O3-SnO2The preparation method of nano-powder is specially by InCl3Solution and SnCl4·
5H2After O crystallized mixeds, add dispersant, and be added dropwise ammoniacal liquor heating be hydrolyzed, control pH value be 7, it is still aging after obtained by
Sediment is washed with distilled water and ethanol, and grinding obtains precursor powder, the precursor powder after oven drying
In is obtained in 700 DEG C of temperature lower calcinations and after cooling down2O3-SnO2Nano-powder.
In described in step (13)2O3-SnO2The preparation method of ethanol slurry is specially the In2O3-SnO2Nano-powder
Carry out adding dispersant after magnetic force is mixed with absolute ethyl alcohol, In is obtained after disperseing by ultrasonic disperse and ball milling2O3-SnO2Ethanol
Slurry.
In described in step (14)2O3-SnO2The preparation method of insulating moulding coating is specially the In2O3-SnO2Ethanol slurry
Carry out magnetic agitation after being mixed with acrylic resin, and by ultrasonic disperse and ball milling it is scattered after obtain In2O3-SnO2It is heat-insulated to apply
Material.
In described in step (15)2O3-SnO2The preparation method of heat insulating coat is specially by the In2O3-SnO2It is heat-insulated to apply
Material is coated on film matrix by the way of plated film using lifting, and wet film is dried through room temperature, In is completed after isothermal curing2O3-
SnO2The preparation of heat insulating coat.
Hollow glass bead described in step (23) is specially the cenosphere of titanium dioxide cladding.
The preparation method of the cenosphere of the titanium dioxide cladding is specially that hollow glass bead and distilled water are pressed into 1:10 mix
After conjunction, 1% neopelex solution ＆ stir is added dropwise 5 minutes, hollow glass bead is uniformly dispersed in water, heat
And controlling reaction temperature, sustained response 6 hours after titanium sulfate solution are slowly dropped into, reaction is washed and filtration drying after terminating, most
Calcined afterwards at 600 DEG C, the cenosphere of titanium dioxide cladding is made.
Finally it should be noted that only illustrating technical scheme rather than its limitations with reference to above-described embodiment.Institute
The those of ordinary skill in category field is it is to be understood that those skilled in the art can repair to the embodiment of the present invention
Change or equivalent substitution, but these modifications or change are among pending claims are applied for.
Claims (7)
1. a kind of heat-insulated antifogging type greenhouse material, it is characterised in that the greenhouse material is glass material, for heliogreenhouse
Four walls, the heliogreenhouse includes above wall, below left side wall, wall and right side wall, before, the left side, below, the right side
Wall surrounds four walls of heliogreenhouse jointly, and the above wall is provided with gate, and the heliogreenhouse also includes being covered in four
Roof on wall, the roof is formed by connecting by the bar shaped cover plate of multiple inverted V-shaped shapes, the bar shaped cover plates of multiple inverted V-shaped shapes it
Between be additionally provided with rainwater-collecting pipeline, the roof and be also covered with one layer of external sunshade net；
The outer application of the glass material, which has, is coated with one layer of antifog painting on the inside of one layer of heat insulating coat, the glass material
Layer, the heat insulating coat is specially In2O3-SnO2Heat insulating coat, the antifogging coating is specially that fluorocarbon resin reflective insulation is antifog
Coating；
The In2O3-SnO2The preparation method of heat insulating coat specifically includes following steps：Step (11), by the inorganic salts and tin of indium
Inorganic salt blend, and add precipitating reagent, dispersant, control pH value and reaction temperature obtain hydroxide precursor after reaction；
Step (12), the hydroxide precursor obtains In after carrying out low-temperature hydrothermal reaction and high-temperature heat treatment2O3-SnO2Nano powder
Body；Step (13), the In2O3-SnO2Dispersant is added in nano-powder, is obtained after the dispersing mode using ultrasonic ball milling
In2O3-SnO2Ethanol slurry；Step (14), the In2O3-SnO2Ethanol slurry is mixed by blending method with acrylic resin to be obtained
Obtain In2O3-SnO2Insulating moulding coating；Step (15), the In2O3-SnO2Insulating moulding coating acts on film base by the way of lifting
On body, In is finally obtained2O3-SnO2Heat insulating coat；
The preparation method of fluorocarbon resin reflective insulation anti-fog coating specifically includes following steps：Step (21), by fluorocarbon resin, instead
Penetrate heat-insulated color stuffing, auxiliary agent and solvent mixing；Step (22), mixture is stirred 10 minutes in high speed dispersor high speed；Step
Suddenly (23), hollow glass bead is added；Step (24), continues stirring at low speed 30 minutes, obtains the antifog painting of fluorocarbon resin reflective insulation
Material.
2. a kind of heat-insulated antifogging type greenhouse material according to claim 1, it is characterised in that described in step (12)
In2O3-SnO2The preparation method of nano-powder is specially by InCl3Solution and SnCl4·5H2After O crystallized mixeds, add scattered
Agent, and be added dropwise ammoniacal liquor heating be hydrolyzed, control pH value be 7, it is still aging after obtained by sediment distilled water and ethanol enter
Row washing, grinding obtains precursor powder after oven drying, and the precursor powder is in 700 DEG C of temperature lower calcinations and cools down
After obtain In2O3-SnO2Nano-powder.
3. a kind of heat-insulated antifogging type greenhouse material according to claim 2, it is characterised in that described in step (13)
In2O3-SnO2The preparation method of ethanol slurry is specially the In2O3-SnO2Nano-powder carries out magnetic force with absolute ethyl alcohol and mixed
After add dispersant, by ultrasonic disperse and ball milling it is scattered after obtain In2O3-SnO2Ethanol slurry.
4. a kind of heat-insulated antifogging type greenhouse material according to claim 3, it is characterised in that described in step (14)
In2O3-SnO2The preparation method of insulating moulding coating is specially the In2O3-SnO2Ethanol slurry is carried out after being mixed with acrylic resin
Magnetic agitation, and by ultrasonic disperse and ball milling it is scattered after obtain In2O3-SnO2Insulating moulding coating.
5. a kind of heat-insulated antifogging type greenhouse material according to claim 4, it is characterised in that described in step (15)
In2O3-SnO2The preparation method of heat insulating coat is specially by the In2O3-SnO2Insulating moulding coating is applied by the way of lifting plated film
It is overlying on film matrix, and wet film is dried through room temperature, In is completed after isothermal curing2O3-SnO2The preparation of heat insulating coat.
6. a kind of heat-insulated antifogging type greenhouse material according to claim 5, it is characterised in that hollow described in step (23)
Bead is specially the cenosphere of titanium dioxide cladding.
7. a kind of heat-insulated antifogging type greenhouse material according to claim 6, it is characterised in that the sky of the titanium dioxide cladding
The preparation method of heart microballon is specially that hollow glass bead and distilled water are pressed into 1:After 10 mixing, 1% detergent alkylate sulphur is added dropwise
Acid sodium solution is simultaneously stirred 5 minutes, hollow glass bead is uniformly dispersed in water, is heated and controlling reaction temperature, be slowly dropped into sulphur
Sustained response 6 hours after sour titanium solution, washing and filtration drying after reaction terminates, are finally calcined at 600 DEG C, and titanium dioxide is made
The cenosphere of cladding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710514810.2A CN107306693A (en) | 2017-06-29 | 2017-06-29 | A kind of heat-insulated antifogging type greenhouse material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710514810.2A CN107306693A (en) | 2017-06-29 | 2017-06-29 | A kind of heat-insulated antifogging type greenhouse material |
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| CN107306693A true CN107306693A (en) | 2017-11-03 |
Family
ID=60180977
Family Applications (1)
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|---|---|---|---|
| CN201710514810.2A Pending CN107306693A (en) | 2017-06-29 | 2017-06-29 | A kind of heat-insulated antifogging type greenhouse material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111045142A (en) * | 2019-12-26 | 2020-04-21 | 重庆大学 | Light guide system suitable for biological cultivation of extraterrestrial space |
| CN115135140A (en) * | 2020-03-11 | 2022-09-30 | 日本板硝子株式会社 | Greenhouse and glass plate with coating film |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111045142A (en) * | 2019-12-26 | 2020-04-21 | 重庆大学 | Light guide system suitable for biological cultivation of extraterrestrial space |
| CN115135140A (en) * | 2020-03-11 | 2022-09-30 | 日本板硝子株式会社 | Greenhouse and glass plate with coating film |
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Application publication date: 20171103 |