CN107223489A - A kind of heat-insulated antifogging type greenhouse film - Google Patents

A kind of heat-insulated antifogging type greenhouse film Download PDF

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Publication number
CN107223489A
CN107223489A CN201710514783.9A CN201710514783A CN107223489A CN 107223489 A CN107223489 A CN 107223489A CN 201710514783 A CN201710514783 A CN 201710514783A CN 107223489 A CN107223489 A CN 107223489A
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CN
China
Prior art keywords
greenhouse
sno
film
heat
insulated
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Pending
Application number
CN201710514783.9A
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Chinese (zh)
Inventor
徐磊
蒋希芝
柳军
皮杰
孟力力
夏礼如
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Jiangsu Academy of Agricultural Sciences
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Jiangsu Academy of Agricultural Sciences
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Priority to CN201710514783.9A priority Critical patent/CN107223489A/en
Publication of CN107223489A publication Critical patent/CN107223489A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/14Greenhouses
    • A01G9/1438Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/14Greenhouses
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/28Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/10Encapsulated ingredients
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/25Greenhouse technology, e.g. cooling systems therefor

Abstract

The invention discloses a kind of heat-insulated antifogging type greenhouse film, for beam-connected greenhouse, the beam-connected greenhouse includes multiple greenhouse units, the multiple greenhouse unit is closely connected in multiple rows of multiple row, each greenhouse unit includes telescopic pole, arc ceiling, greenhouse side skirt, gate and skylight, and each greenhouse unit is all covered with being also covered with one layer of external sunshade net outside thin film, the film, the outer application of the film, which has, is coated with one layer of antifogging coating on the inside of one layer of heat insulating coat, the film.The present invention realizes that crops large area is planted by way of greenhouse company, and the outer layer of greenhouse film is coated with heat insulating coat, the excessive radiation of ultraviolet and sunlight can be prevented, so that the temperature in summer greenhouse will not be too high, in addition, the internal layer of greenhouse film is also coated with antifogging coating, can prevent from hazing on the inside of cold snap greenhouse so that sunlight can fully irradiate.

Description

A kind of heat-insulated antifogging type greenhouse film
Technical field
The present invention relates to agricultural plantation technology field, and in particular to a kind of heat-insulated antifogging type greenhouse film.
Background technology
In vegetable melon and fruit field of planting, in order that obtaining many season high-yield plantings of crops energy, the use of greenhouse is more and more extensive. But there are some shortcomings in existing greenhouse:One is greenhouse limited area, it is impossible to realize that Large Area of Crops is planted;Two be greenhouse Film light blocking effect of heat insulation is too poor, and the temperature in hot summer greenhouse is too high, is not suitable for crop growth, and can not prevent purple The injury that outside line and excessive illumination are caused to crops;Three be that greenhouse film can not be antifog, in cold winter, greenhouse film Internal layer easily hazes, thus can reduce irradiation of the outdoor solar light to crops, is unfavorable for growth of the crops in winter.
The content of the invention
In view of the above-mentioned problems, the present invention provides a kind of heat-insulated antifogging type film for beam-connected greenhouse, pass through greenhouse company Mode realize that crops large area is planted, and the outer layer of greenhouse film is coated with heat insulating coat, can prevent ultraviolet and The excessive radiation of sunlight so that the temperature in summer greenhouse will not be too high, in addition, the internal layer of greenhouse film is also coated with antifog painting Layer, can prevent from hazing on the inside of cold snap greenhouse so that sunlight can fully irradiate.
The present invention is specially a kind of heat-insulated antifogging type greenhouse film, and the film is used for beam-connected greenhouse, and beam-connected greenhouse includes Multiple greenhouse units, the multiple greenhouse unit is closely connected in multiple rows of multiple row, and each greenhouse unit includes telescopic pole, arc Shape ceiling, greenhouse side skirt, gate and skylight, skylight are located on arc ceiling, between adjacent greenhouse unit share two it is scalable Vertical rod and one side of arc ceiling, the film are used to cover the arc ceiling of each greenhouse unit, greenhouse side in beam-connected greenhouse One layer of external sunshade net is also covered with outside skirt, gate and skylight, the film.
In addition, the outer application of the film, which has, is coated with one layer of antifog painting on the inside of one layer of heat insulating coat, the film Layer, the heat insulating coat is specially In2O3-SnO2Heat insulating coat, the antifogging coating is specially that fluorocarbon resin reflective insulation is antifog Coating.
The In2O3-SnO2The preparation method of heat insulating coat specifically includes following steps:Step (11), by the inorganic salts of indium With the inorganic salt blend of tin, and precipitating reagent, dispersant are added, control pH value and reaction temperature are obtained before hydroxide after reaction Drive body;Step (12), the hydroxide precursor obtains In after carrying out low-temperature hydrothermal reaction and high-temperature heat treatment2O3-SnO2Receive Ground rice body;Step (13), the In2O3-SnO2Dispersant is added in nano-powder, is obtained using after the dispersing mode of ultrasonic ball milling To In2O3-SnO2Ethanol slurry;Step (14), the In2O3-SnO2Ethanol slurry is mixed by blending method with acrylic resin Obtain In2O3-SnO2Insulating moulding coating;Step (15), the In2O3-SnO2Insulating moulding coating acts on film by the way of lifting On matrix, In is finally obtained2O3-SnO2Heat insulating coat.
The preparation method of fluorocarbon resin reflective insulation anti-fog coating specifically includes following steps:Step (21), by fluorine carbon tree Fat, reflective insulation color stuffing, auxiliary agent and solvent mixing;Step (22), 10 points are stirred by mixture in high speed dispersor high speed Clock;Step (23), adds hollow glass bead;Step (24), continues stirring at low speed 30 minutes, obtains fluorocarbon resin reflective insulation and prevents Mist coating.
Further, In described in step (12)2O3-SnO2The preparation method of nano-powder is specially by InCl3Solution and SnCl4·5H2After O crystallized mixeds, add dispersant, and be added dropwise ammoniacal liquor heating be hydrolyzed, control pH value be 7, it is still aging after The sediment of gained is washed with distilled water and ethanol, and grinding obtains precursor powder, the forerunner after oven drying Body powder obtains In in 700 DEG C of temperature lower calcinations and after cooling down2O3-SnO2Nano-powder.
Further, In described in step (13)2O3-SnO2The preparation method of ethanol slurry is specially the In2O3-SnO2 Nano-powder is carried out adding dispersant after magnetic force is mixed with absolute ethyl alcohol, and In is obtained after disperseing by ultrasonic disperse and ball milling2O3- SnO2Ethanol slurry.
Further, In described in step (14)2O3-SnO2The preparation method of insulating moulding coating is specially the In2O3-SnO2 Ethanol slurry carries out magnetic agitation after being mixed with acrylic resin, and by ultrasonic disperse and ball milling it is scattered after obtain In2O3- SnO2Insulating moulding coating.
Further, In described in step (15)2O3-SnO2The preparation method of heat insulating coat is specially by the In2O3- SnO2Insulating moulding coating is coated on film matrix by the way of lifting plated film, and wet film is dried through room temperature, after isothermal curing Complete In2O3-SnO2The preparation of heat insulating coat.
Further, hollow glass bead described in step (23) is specially the cenosphere of titanium dioxide cladding.
Further, the preparation method of the cenosphere of the titanium dioxide cladding is specially by hollow glass bead and distilled water By 1:After 10 mixing, 1% neopelex solution & stir is added dropwise 5 minutes, hollow glass bead is disperseed in water Uniformly, heating and controlling reaction temperature, are slowly dropped into sustained response 6 hours after titanium sulfate solution, washing and mistake after reaction terminates Dry, the finally calcining at 600 DEG C is filtered dry, the cenosphere of titanium dioxide cladding is made.
The present invention by being improved to greenhouse film, be respectively coated in the outside and inner side of film one layer of heat insulating coat and One layer of antifogging coating so that greenhouse film is provided simultaneously with heat-insulated and anti-fog function, such film is used for beam-connected greenhouse, can be true Protect crops and realize large area high-yield planting.
Brief description of the drawings
Fig. 1 is beam-connected greenhouse composition schematic diagram of the present invention;
Fig. 2 is greenhouse cellular construction schematic diagram of the present invention.
Embodiment
The embodiment to heat-insulated antifogging type greenhouse film of the invention is elaborated below in conjunction with the accompanying drawings.
As shown in figure 1, the heat-insulated antifog beam-connected greenhouse of the present invention includes multiple greenhouse units (1), the multiple greenhouse list First (1) is closely connected in multiple rows of multiple row.As shown in Fig. 2 each greenhouse unit (1) includes telescopic pole (2), arc ceiling (3), greenhouse side skirt (4), gate (5) and skylight (6), gate (5) are located at the front of greenhouse, and skylight (6) is located at arc ceiling (3) On, one side of two telescopic poles (2) and arc ceiling (3) is shared between adjacent greenhouse unit (1);In the beam-connected greenhouse Thin film each is all covered with the arc ceiling (3) of greenhouse unit (1), greenhouse side skirt (4), gate (5) and skylight (6), One layer of external sunshade net is also covered with outside the film;The outer application of the film has one layer of heat insulating coat, the film Inner side is coated with one layer of antifogging coating.
The heat insulating coat is specially In2O3-SnO2Heat insulating coat, the antifogging coating be specially fluorocarbon resin reflection every Hot antifogging coating.
The In2O3-SnO2The preparation method of heat insulating coat specifically includes following steps:Step (11), by the inorganic salts of indium With the inorganic salt blend of tin, and precipitating reagent, dispersant are added, control pH value and reaction temperature are obtained before hydroxide after reaction Drive body;Step (12), the hydroxide precursor obtains In after carrying out low-temperature hydrothermal reaction and high-temperature heat treatment2O3-SnO2Receive Ground rice body;Step (13), the In2O3-SnO2Dispersant is added in nano-powder, is obtained using after the dispersing mode of ultrasonic ball milling To In2O3-SnO2Ethanol slurry;Step (14), the In2O3-SnO2Ethanol slurry is mixed by blending method with acrylic resin Obtain In2O3-SnO2Insulating moulding coating;Step (15), the In2O3-SnO2Insulating moulding coating acts on film by the way of lifting On matrix, In is finally obtained2O3-SnO2Heat insulating coat.
The preparation method of fluorocarbon resin reflective insulation anti-fog coating specifically includes following steps:Step (21), by fluorine carbon tree Fat, reflective insulation color stuffing, auxiliary agent and solvent mixing;Step (22), 10 points are stirred by mixture in high speed dispersor high speed Clock;Step (23), adds hollow glass bead;Step (24), continues stirring at low speed 30 minutes, obtains fluorocarbon resin reflective insulation and prevents Mist coating.
In described in step (12)2O3-SnO2The preparation method of nano-powder is specially by InCl3Solution and SnCl4· 5H2After O crystallized mixeds, add dispersant, and be added dropwise ammoniacal liquor heating be hydrolyzed, control pH value be 7, it is still aging after obtained by Sediment is washed with distilled water and ethanol, and grinding obtains precursor powder, the precursor powder after oven drying In is obtained in 700 DEG C of temperature lower calcinations and after cooling down2O3-SnO2Nano-powder.
In described in step (13)2O3-SnO2The preparation method of ethanol slurry is specially the In2O3-SnO2Nano-powder Carry out adding dispersant after magnetic force is mixed with absolute ethyl alcohol, In is obtained after disperseing by ultrasonic disperse and ball milling2O3-SnO2Ethanol Slurry.
In described in step (14)2O3-SnO2The preparation method of insulating moulding coating is specially the In2O3-SnO2Ethanol slurry Carry out magnetic agitation after being mixed with acrylic resin, and by ultrasonic disperse and ball milling it is scattered after obtain In2O3-SnO2It is heat-insulated to apply Material.
In described in step (15)2O3-SnO2The preparation method of heat insulating coat is specially by the In2O3-SnO2It is heat-insulated to apply Material is coated on film matrix by the way of plated film using lifting, and wet film is dried through room temperature, In is completed after isothermal curing2O3- SnO2The preparation of heat insulating coat.
Hollow glass bead described in step (23) is specially the cenosphere of titanium dioxide cladding.
The preparation method of the cenosphere of the titanium dioxide cladding is specially that hollow glass bead and distilled water are pressed into 1:10 mix After conjunction, 1% neopelex solution & stir is added dropwise 5 minutes, hollow glass bead is uniformly dispersed in water, heat And controlling reaction temperature, sustained response 6 hours after titanium sulfate solution are slowly dropped into, reaction is washed and filtration drying after terminating, most Calcined afterwards at 600 DEG C, the cenosphere of titanium dioxide cladding is made.
Finally it should be noted that only illustrating technical scheme rather than its limitations with reference to above-described embodiment.Institute The those of ordinary skill in category field is it is to be understood that those skilled in the art can repair to the embodiment of the present invention Change or equivalent substitution, but these modifications or change are among pending claims are applied for.

Claims (7)

1. a kind of heat-insulated antifogging type greenhouse film, it is characterised in that the film is used for beam-connected greenhouse, beam-connected greenhouse includes multiple Greenhouse unit, the multiple greenhouse unit is closely connected in multiple rows of multiple row, and each greenhouse unit includes telescopic pole, arched top Canopy, greenhouse side skirt, gate and skylight, skylight are located on arc ceiling, and two telescopic poles are shared between adjacent greenhouse unit With one side of arc ceiling, the film be used for cover the arc ceiling of each greenhouse unit in beam-connected greenhouse, greenhouse side skirt, greatly One layer of external sunshade net is also covered with outside door and skylight, the film;
In addition, the outer application of the film, which has, is coated with one layer of antifogging coating, institute on the inside of one layer of heat insulating coat, the film State heat insulating coat specially In2O3-SnO2Heat insulating coat, the antifogging coating is specially fluorocarbon resin reflective insulation antifogging coating;
The In2O3-SnO2The preparation method of heat insulating coat specifically includes following steps:Step (11), by the inorganic salts and tin of indium Inorganic salt blend, and add precipitating reagent, dispersant, control pH value and reaction temperature obtain hydroxide precursor after reaction; Step (12), the hydroxide precursor obtains In after carrying out low-temperature hydrothermal reaction and high-temperature heat treatment2O3-SnO2Nano powder Body;Step (13), the In2O3-SnO2Dispersant is added in nano-powder, is obtained after the dispersing mode using ultrasonic ball milling In2O3-SnO2Ethanol slurry;Step (14), the In2O3-SnO2Ethanol slurry is mixed by blending method with acrylic resin to be obtained Obtain In2O3-SnO2Insulating moulding coating;Step (15), the In2O3-SnO2Insulating moulding coating acts on film base by the way of lifting On body, In is finally obtained2O3-SnO2Heat insulating coat;
The preparation method of fluorocarbon resin reflective insulation anti-fog coating specifically includes following steps:Step (21), by fluorocarbon resin, instead Penetrate heat-insulated color stuffing, auxiliary agent and solvent mixing;Step (22), mixture is stirred 10 minutes in high speed dispersor high speed;Step Suddenly (23), hollow glass bead is added;Step (24), continues stirring at low speed 30 minutes, obtains the antifog painting of fluorocarbon resin reflective insulation Material.
2. a kind of heat-insulated antifogging type greenhouse film according to claim 1, it is characterised in that described in step (12) In2O3-SnO2The preparation method of nano-powder is specially by InCl3Solution and SnCl4·5H2After O crystallized mixeds, add scattered Agent, and be added dropwise ammoniacal liquor heating be hydrolyzed, control pH value be 7, it is still aging after obtained by sediment distilled water and ethanol enter Row washing, grinding obtains precursor powder after oven drying, and the precursor powder is in 700 DEG C of temperature lower calcinations and cools down After obtain In2O3-SnO2Nano-powder.
3. a kind of heat-insulated antifogging type greenhouse film according to claim 2, it is characterised in that described in step (13) In2O3-SnO2The preparation method of ethanol slurry is specially the In2O3-SnO2Nano-powder carries out magnetic force with absolute ethyl alcohol and mixed After add dispersant, by ultrasonic disperse and ball milling it is scattered after obtain In2O3-SnO2Ethanol slurry.
4. a kind of heat-insulated antifogging type greenhouse film according to claim 3, it is characterised in that described in step (14) In2O3-SnO2The preparation method of insulating moulding coating is specially the In2O3-SnO2Ethanol slurry is carried out after being mixed with acrylic resin Magnetic agitation, and by ultrasonic disperse and ball milling it is scattered after obtain In2O3-SnO2Insulating moulding coating.
5. a kind of heat-insulated antifogging type greenhouse film according to claim 4, it is characterised in that described in step (15) In2O3-SnO2The preparation method of heat insulating coat is specially by the In2O3-SnO2Insulating moulding coating is applied by the way of lifting plated film It is overlying on film matrix, and wet film is dried through room temperature, In is completed after isothermal curing2O3-SnO2The preparation of heat insulating coat.
6. a kind of heat-insulated antifogging type greenhouse film according to claim 5, it is characterised in that hollow described in step (23) Bead is specially the cenosphere of titanium dioxide cladding.
7. a kind of heat-insulated antifogging type greenhouse film according to claim 6, it is characterised in that the sky of the titanium dioxide cladding The preparation method of heart microballon is specially that hollow glass bead and distilled water are pressed into 1:After 10 mixing, 1% detergent alkylate sulphur is added dropwise Acid sodium solution is simultaneously stirred 5 minutes, hollow glass bead is uniformly dispersed in water, is heated and controlling reaction temperature, be slowly dropped into sulphur Sustained response 6 hours after sour titanium solution, washing and filtration drying after reaction terminates, are finally calcined at 600 DEG C, and titanium dioxide is made The cenosphere of cladding.
CN201710514783.9A 2017-06-29 2017-06-29 A kind of heat-insulated antifogging type greenhouse film Pending CN107223489A (en)

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Publication number Priority date Publication date Assignee Title
CN108017959A (en) * 2017-11-09 2018-05-11 江苏省农业科学院 A kind of greenhouse film water-based hydrophobic coating and its preparation method and application
CN108034311A (en) * 2017-10-31 2018-05-15 江苏省农业科学院 A kind of hydrophobic dirt resistance coatings of greenhouse film and its preparation method and application
CN111045142A (en) * 2019-12-26 2020-04-21 重庆大学 Light guide system suitable for biological cultivation of extraterrestrial space

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CN202759895U (en) * 2012-08-02 2013-03-06 安徽春生农业科技有限公司 Health vegetable sunshade greenhouse capable of being rolled up
CN204653181U (en) * 2015-05-19 2015-09-23 苏州市种子管理站 A kind of interior canopy motion of double-deck multispan greenhouse
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CN201781823U (en) * 2010-07-26 2011-04-06 公安县银欣棉贸站 Extensible plastic glasshouse shed
CN202759895U (en) * 2012-08-02 2013-03-06 安徽春生农业科技有限公司 Health vegetable sunshade greenhouse capable of being rolled up
CN204653181U (en) * 2015-05-19 2015-09-23 苏州市种子管理站 A kind of interior canopy motion of double-deck multispan greenhouse
CN205727300U (en) * 2016-05-06 2016-11-30 黄志亮 An a kind of even planting greenhouse

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108034311A (en) * 2017-10-31 2018-05-15 江苏省农业科学院 A kind of hydrophobic dirt resistance coatings of greenhouse film and its preparation method and application
CN108017959A (en) * 2017-11-09 2018-05-11 江苏省农业科学院 A kind of greenhouse film water-based hydrophobic coating and its preparation method and application
CN111045142A (en) * 2019-12-26 2020-04-21 重庆大学 Light guide system suitable for biological cultivation of extraterrestrial space

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