CN107299119A - A kind of utilization rice husk produces the preparation method of biomass fuel - Google Patents

A kind of utilization rice husk produces the preparation method of biomass fuel Download PDF

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Publication number
CN107299119A
CN107299119A CN201710731676.1A CN201710731676A CN107299119A CN 107299119 A CN107299119 A CN 107299119A CN 201710731676 A CN201710731676 A CN 201710731676A CN 107299119 A CN107299119 A CN 107299119A
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China
Prior art keywords
parts
powder
rice husk
fermentation
preparation
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Pending
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CN201710731676.1A
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Chinese (zh)
Inventor
江五
江五一
徐康海
王松让
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Anhui Xiang Yang New Energy Technology Development Co Ltd
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Anhui Xiang Yang New Energy Technology Development Co Ltd
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Priority to CN201710731676.1A priority Critical patent/CN107299119A/en
Publication of CN107299119A publication Critical patent/CN107299119A/en
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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00Preparation of oxygen-containing organic compounds
    • C12P7/02Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06Ethanol, i.e. non-beverage
    • C12P7/08Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate
    • C12P7/10Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate substrate containing cellulosic material
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00Preparation of compounds containing saccharide radicals
    • C12P19/14Preparation of compounds containing saccharide radicals produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase, e.g. by cellulase, hemicellulase
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses the preparation method that a kind of utilization rice husk produces biomass fuel, belong to the technical field of the preparation method of the wood chip biomass fuel of cleaning.Include the material of following parts by weight:10 15 parts of carbon dust, 20 25 parts of white poplar powder, 10 15 parts of rubber tree powder, 100 200 parts of rice husk, 20 50 parts of maize straw, 100 120 parts of straw powder, 5 10 parts of cotton, 59 parts of cow dung, 13 parts of bagasse, 10 15 parts of kaolin, 5 10 parts of aluminum oxide, 59 parts of eucalyptus powder, the biomass material that 28 parts of Chinese medicine dreg, the biomass clean fuel of the present invention is reasonable with sufficient raw, matching using agricultural wastes as primary raw material, light weight, cost is low, and combustion value is high.

Description

A kind of utilization rice husk produces the preparation method of biomass fuel
Technical field
The present invention relates to environmental protection and energy technology field, it is related to the preparation side that a kind of utilization rice husk produces biomass fuel Method.
Background technology
Constantly expand with industrial production, the technology constantly progressive, increasingly depleted of fossil energy resource and to the energy and ring The enhancing of consciousness is protected, the mankind need find new, cleaning, sustainable alternative fuel.
Agriculture and forestry organic waste material is the main Types of reproducible biomass material, has huge dive to solving energy problem Power.Agriculture and forestry organic waste material is that farm-forestry crop harvests and produces substantial amounts of discarded object in process, for example, being remained during crop harvesting Remaining rice husk, chaff skin, the branch remained during production of forestry, leaf, wood in stalk in farmland, agricultural production process Leftover pieces that bits and timber are processed etc., and the residue that food-processing industry is discharged.China produces about 1,400,000,000 tons of agricultural crop straw per year, If rational exploitation and utilization, the fuel of about 700,000,000 tons of standard coals can be obtained, yule logs and forestry industrial wood waste annual production are roughly equal to 300,000,000 Ton standard coal, ought to turn into the emphasis of biomass utilization, but this part resource is fully utilized far away, and utilization rate is not enough 20%.
At present, agriculture and forestry organic waste material is loosely dispersed in wide area, except least a portion of agricultural crop straw is used for domestic animal Feed, cook and warm oneself it is outer, it is most of by as discarded object abandon in field.The traditional treatment method of agriculture and forestry organic waste material is landfill And burning, environmental pollution can be caused and cause disaster hidden-trouble;Other utilization ways newly developed, although energy utilization rate and economy Benefit is all very high, but consumption is few, require high to agriculture and forestry organic waste material, it is impossible to fundamentally solve the processing of agriculture and forestry organic waste material resource And Utilizing question.
The content of the invention
It is an object of the invention to provide the preparation method that a kind of utilization rice husk produces biomass fuel.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of utilization rice husk produces the preparation method of biomass fuel, and the preparation method comprises the following steps:
1) the formula mixing of material, removes the material of row parts by weight:10-15 parts of carbon dust, 20-25 parts of white poplar powder, rubber Set 10-15 parts of powder, 100-200 parts of rice husk, 20-50 parts of maize straw, 100-120 parts of straw powder, 5-10 parts of cotton, cow dung 5- 9 parts, 1-3 parts of bagasse, 10-15 parts of kaolin, 5-10 parts of aluminum oxide, 5-9 parts of eucalyptus powder, 2-8 parts of Chinese medicine dreg crushes mixed It is even;
2) ferment, cellulase is added in 40~60 DEG C of 12~36h of enzymolysis by 10~200U/g mixed materials;Gained is digested Liquid glucose is added by 2~3kg/ tons of ethanol carries out alcohol fermentation after dry ferments, fermentation temperature control is at 30~40 DEG C, and fermentation period is 48~96h;The ripe wine with dregs fermented directly band slag is distilled in destilling tower, and vapo(u)rizing temperature is maintained at 85~95 DEG C, tower top The coarse ethanol of extraction delivers to rectifying column and carries out rectifying and dewatering rectifying in atmospheric conditions in 70~85 DEG C of progress, can obtain after rectifying The alcohol product of purity 95%, fermentation residue is standby;
3) residue drying storage extruding clamp dog, carries out magnetic sorting, the metal cleared out of is sent to by the residue that step 2 is fermented Regenerate unit and carry out regeneration, the residue of fermentation is further dried, it is ensured that moisture content is made within 15%, and with this product The heat drying provided for fuel, natural air drying can be used in dry area, by above-mentioned well mixed and dried thing Material, is dried to curable type cleaning generative fuel of different shapes, geomery can be by institute using single lead screw ex truding briquetting machine extruding as needed The pore size of template of design reaches.
Beneficial effects of the present invention:The present invention produces new, high heating value biomass molding fuel skill using agriculture and forestry organic waste material Art not only solves biomass molding fuel low heat value (general 3500-4000kcal/kg), high energy consumption, cost some row such as big Biomass molding fuel industry problem, and bring great number profit return to enterprise.
Embodiment
The present invention is described in further detail with reference to specific embodiment.
A kind of utilization rice husk produces the preparation method of biomass fuel, and the preparation method comprises the following steps:
1) the formula mixing of material, removes the material of row parts by weight:10-15 parts of carbon dust, 20-25 parts of white poplar powder, rubber Set 10-15 parts of powder, 100-200 parts of rice husk, 20-50 parts of maize straw, 100-120 parts of straw powder, 5-10 parts of cotton, cow dung 5- 9 parts, 1-3 parts of bagasse, 10-15 parts of kaolin, 5-10 parts of aluminum oxide, 5-9 parts of eucalyptus powder, 2-8 parts of Chinese medicine dreg crushes mixed It is even;
2) ferment, cellulase is added in 40~60 DEG C of 12~36h of enzymolysis by 10~200U/g mixed materials;Gained is digested Liquid glucose is added by 2~3kg/ tons of ethanol carries out alcohol fermentation after dry ferments, fermentation temperature control is at 30~40 DEG C, and fermentation period is 48~96h;The ripe wine with dregs fermented directly band slag is distilled in destilling tower, and vapo(u)rizing temperature is maintained at 85~95 DEG C, tower top The coarse ethanol of extraction delivers to rectifying column and carries out rectifying and dewatering rectifying in atmospheric conditions in 70~85 DEG C of progress, can obtain after rectifying The alcohol product of purity 95%, fermentation residue is standby;
3) residue drying storage extruding clamp dog, carries out magnetic sorting, the metal cleared out of is sent to by the residue that step 2 is fermented Regenerate unit and carry out regeneration, the residue of fermentation is further dried, it is ensured that moisture content is made within 15%, and with this product The heat drying provided for fuel, natural air drying can be used in dry area, by above-mentioned well mixed and dried thing Material, is dried to curable type cleaning generative fuel of different shapes, geomery can be by institute using single lead screw ex truding briquetting machine extruding as needed The pore size of template of design reaches.
Embodiment 1
1) implementation condition
Solid renewable clean fuel, it is made up of following components:Carbon dust 15kg, white poplar powder 25kg, rubber tree powder 10kg, Rice husk 150kg, maize straw 30kg, straw powder 100kg, cotton 8kg, cow dung 6kg, bagasse 2kg, kaolin 12kg, oxygen Change aluminium 8kg, eucalyptus powder 9kg, Chinese medicine dreg 2kg, crush mixing pretreated.Above-mentioned material is conveyed into mixer to carry out Spice, cellulase is added in 50 DEG C of enzymolysis 36h by 10~200U/g mixed materials;Gained enzymolysis liquid glucose is added by 3kg/ tons of ethanol Enter and alcohol fermentation is carried out after dry ferment, fermentation temperature is controlled at 40 DEG C, and fermentation period is 96h;The direct band of ripe wine with dregs fermented Slag is distilled in destilling tower, and vapo(u)rizing temperature is maintained at 90 DEG C, and the coarse ethanol of overhead extraction is delivered to rectifying column progress rectifying and taken off Crystal evaporate can obtain the alcohol product of purity 95%, fermentation residue material is through drying in atmospheric conditions in 85 DEG C of progress after rectifying Moisture content is 13% after dry, is then squeezed into the bar-shaped solid renewable clean fuel of densification, finished product grain size Φ 12mm, length 50mm Left and right.
2) result of implementation
The proportion of this solid renewable clean fuel is 1.65g/cm3, ignition point is 346 DEG C, caloric value QNet, adFor 19.04MJ/kg, burn-off rate is up to 93%, and thermal expansion is smaller in combustion process, smokelessly, dust emission concentration < 0.85mgm-3, nitrogen Emissions of oxides concentration < 100mgm-3, HCl contents 0mol/kg.
Above content is only to structure example of the present invention and explanation, affiliated those skilled in the art couple Described specific embodiment is made various modifications or supplement or substituted using similar mode, without departing from invention Structure surmounts scope defined in the claims, all should belong to protection scope of the present invention.

Claims (1)

1. a kind of utilization rice husk produces the preparation method of biomass fuel, it is characterised in that the preparation method includes following step Suddenly:
1) the formula mixing of material, removes the material of row parts by weight:10-15 parts of carbon dust, 20-25 parts of white poplar powder, rubber tree powder 10-15 parts, 100-200 parts of rice husk, 20-50 parts of maize straw, 100-120 parts of straw powder, 5-10 parts of cotton, 5-9 parts of cow dung, 1-3 parts of bagasse, 10-15 parts of kaolin, 5-10 parts of aluminum oxide, 5-9 parts of eucalyptus powder, 2-8 parts of Chinese medicine dreg is crushed and mixed;
2) ferment, cellulase is added in 40~60 DEG C of 12~36h of enzymolysis by 10~200U/g mixed materials;Gained digests liquid glucose Added by 2~3kg/ tons of ethanol and alcohol fermentation carried out after dry ferments, fermentation temperature control at 30~40 DEG C, fermentation period is 48~ 96h;The ripe wine with dregs fermented directly band slag is distilled in destilling tower, and vapo(u)rizing temperature is maintained at 85~95 DEG C, overhead extraction Coarse ethanol deliver to rectifying column and carry out rectifying and dewatering rectifying in atmospheric conditions in 70~85 DEG C of progress, can obtain purity after rectifying 95% alcohol product, fermentation residue is standby;
3) residue drying storage extruding clamp dog, carries out magnetic sorting, the metal cleared out of is sent to regeneration by the residue that step 2 is fermented Unit carries out regeneration, the residue of fermentation is further dried, it is ensured that moisture content is used as combustion within 15%, and with this product The heat drying that material is provided, natural air drying can be used in dry area, by above-mentioned well mixed and dried material, root Curable type cleaning generative fuel of different shapes is dried to according to needing to extrude using single lead screw ex truding briquetting machine, geomery can be by designed Pore size of template reaches.
CN201710731676.1A 2017-08-23 2017-08-23 A kind of utilization rice husk produces the preparation method of biomass fuel Pending CN107299119A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109810741A (en) * 2019-03-25 2019-05-28 厦门理工学院 A kind of compound biomass granular fuel and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105861567A (en) * 2016-04-27 2016-08-17 安徽香杨林业有限公司 Method for producing high-heating-value biomass fuel from agricultural and forestry wastes
CN106635232A (en) * 2017-01-05 2017-05-10 安徽润发生物能源科技有限公司 Preparation method of clean wood chip biomass fuel
CN106675692A (en) * 2017-01-05 2017-05-17 安徽润发生物能源科技有限公司 Composite biomass fuel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105861567A (en) * 2016-04-27 2016-08-17 安徽香杨林业有限公司 Method for producing high-heating-value biomass fuel from agricultural and forestry wastes
CN106635232A (en) * 2017-01-05 2017-05-10 安徽润发生物能源科技有限公司 Preparation method of clean wood chip biomass fuel
CN106675692A (en) * 2017-01-05 2017-05-17 安徽润发生物能源科技有限公司 Composite biomass fuel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109810741A (en) * 2019-03-25 2019-05-28 厦门理工学院 A kind of compound biomass granular fuel and preparation method thereof

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Application publication date: 20171027

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