CN107299119A - A kind of utilization rice husk produces the preparation method of biomass fuel - Google Patents
A kind of utilization rice husk produces the preparation method of biomass fuel Download PDFInfo
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- CN107299119A CN107299119A CN201710731676.1A CN201710731676A CN107299119A CN 107299119 A CN107299119 A CN 107299119A CN 201710731676 A CN201710731676 A CN 201710731676A CN 107299119 A CN107299119 A CN 107299119A
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
- C12P7/06—Ethanol, i.e. non-beverage
- C12P7/08—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate
- C12P7/10—Ethanol, i.e. non-beverage produced as by-product or from waste or cellulosic material substrate substrate containing cellulosic material
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P19/00—Preparation of compounds containing saccharide radicals
- C12P19/14—Preparation of compounds containing saccharide radicals produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase, e.g. by cellulase, hemicellulase
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Biotechnology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses the preparation method that a kind of utilization rice husk produces biomass fuel, belong to the technical field of the preparation method of the wood chip biomass fuel of cleaning.Include the material of following parts by weight:10 15 parts of carbon dust, 20 25 parts of white poplar powder, 10 15 parts of rubber tree powder, 100 200 parts of rice husk, 20 50 parts of maize straw, 100 120 parts of straw powder, 5 10 parts of cotton, 59 parts of cow dung, 13 parts of bagasse, 10 15 parts of kaolin, 5 10 parts of aluminum oxide, 59 parts of eucalyptus powder, the biomass material that 28 parts of Chinese medicine dreg, the biomass clean fuel of the present invention is reasonable with sufficient raw, matching using agricultural wastes as primary raw material, light weight, cost is low, and combustion value is high.
Description
Technical field
The present invention relates to environmental protection and energy technology field, it is related to the preparation side that a kind of utilization rice husk produces biomass fuel
Method.
Background technology
Constantly expand with industrial production, the technology constantly progressive, increasingly depleted of fossil energy resource and to the energy and ring
The enhancing of consciousness is protected, the mankind need find new, cleaning, sustainable alternative fuel.
Agriculture and forestry organic waste material is the main Types of reproducible biomass material, has huge dive to solving energy problem
Power.Agriculture and forestry organic waste material is that farm-forestry crop harvests and produces substantial amounts of discarded object in process, for example, being remained during crop harvesting
Remaining rice husk, chaff skin, the branch remained during production of forestry, leaf, wood in stalk in farmland, agricultural production process
Leftover pieces that bits and timber are processed etc., and the residue that food-processing industry is discharged.China produces about 1,400,000,000 tons of agricultural crop straw per year,
If rational exploitation and utilization, the fuel of about 700,000,000 tons of standard coals can be obtained, yule logs and forestry industrial wood waste annual production are roughly equal to 300,000,000
Ton standard coal, ought to turn into the emphasis of biomass utilization, but this part resource is fully utilized far away, and utilization rate is not enough
20%.
At present, agriculture and forestry organic waste material is loosely dispersed in wide area, except least a portion of agricultural crop straw is used for domestic animal
Feed, cook and warm oneself it is outer, it is most of by as discarded object abandon in field.The traditional treatment method of agriculture and forestry organic waste material is landfill
And burning, environmental pollution can be caused and cause disaster hidden-trouble;Other utilization ways newly developed, although energy utilization rate and economy
Benefit is all very high, but consumption is few, require high to agriculture and forestry organic waste material, it is impossible to fundamentally solve the processing of agriculture and forestry organic waste material resource
And Utilizing question.
The content of the invention
It is an object of the invention to provide the preparation method that a kind of utilization rice husk produces biomass fuel.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of utilization rice husk produces the preparation method of biomass fuel, and the preparation method comprises the following steps:
1) the formula mixing of material, removes the material of row parts by weight:10-15 parts of carbon dust, 20-25 parts of white poplar powder, rubber
Set 10-15 parts of powder, 100-200 parts of rice husk, 20-50 parts of maize straw, 100-120 parts of straw powder, 5-10 parts of cotton, cow dung 5-
9 parts, 1-3 parts of bagasse, 10-15 parts of kaolin, 5-10 parts of aluminum oxide, 5-9 parts of eucalyptus powder, 2-8 parts of Chinese medicine dreg crushes mixed
It is even;
2) ferment, cellulase is added in 40~60 DEG C of 12~36h of enzymolysis by 10~200U/g mixed materials;Gained is digested
Liquid glucose is added by 2~3kg/ tons of ethanol carries out alcohol fermentation after dry ferments, fermentation temperature control is at 30~40 DEG C, and fermentation period is
48~96h;The ripe wine with dregs fermented directly band slag is distilled in destilling tower, and vapo(u)rizing temperature is maintained at 85~95 DEG C, tower top
The coarse ethanol of extraction delivers to rectifying column and carries out rectifying and dewatering rectifying in atmospheric conditions in 70~85 DEG C of progress, can obtain after rectifying
The alcohol product of purity 95%, fermentation residue is standby;
3) residue drying storage extruding clamp dog, carries out magnetic sorting, the metal cleared out of is sent to by the residue that step 2 is fermented
Regenerate unit and carry out regeneration, the residue of fermentation is further dried, it is ensured that moisture content is made within 15%, and with this product
The heat drying provided for fuel, natural air drying can be used in dry area, by above-mentioned well mixed and dried thing
Material, is dried to curable type cleaning generative fuel of different shapes, geomery can be by institute using single lead screw ex truding briquetting machine extruding as needed
The pore size of template of design reaches.
Beneficial effects of the present invention:The present invention produces new, high heating value biomass molding fuel skill using agriculture and forestry organic waste material
Art not only solves biomass molding fuel low heat value (general 3500-4000kcal/kg), high energy consumption, cost some row such as big
Biomass molding fuel industry problem, and bring great number profit return to enterprise.
Embodiment
The present invention is described in further detail with reference to specific embodiment.
A kind of utilization rice husk produces the preparation method of biomass fuel, and the preparation method comprises the following steps:
1) the formula mixing of material, removes the material of row parts by weight:10-15 parts of carbon dust, 20-25 parts of white poplar powder, rubber
Set 10-15 parts of powder, 100-200 parts of rice husk, 20-50 parts of maize straw, 100-120 parts of straw powder, 5-10 parts of cotton, cow dung 5-
9 parts, 1-3 parts of bagasse, 10-15 parts of kaolin, 5-10 parts of aluminum oxide, 5-9 parts of eucalyptus powder, 2-8 parts of Chinese medicine dreg crushes mixed
It is even;
2) ferment, cellulase is added in 40~60 DEG C of 12~36h of enzymolysis by 10~200U/g mixed materials;Gained is digested
Liquid glucose is added by 2~3kg/ tons of ethanol carries out alcohol fermentation after dry ferments, fermentation temperature control is at 30~40 DEG C, and fermentation period is
48~96h;The ripe wine with dregs fermented directly band slag is distilled in destilling tower, and vapo(u)rizing temperature is maintained at 85~95 DEG C, tower top
The coarse ethanol of extraction delivers to rectifying column and carries out rectifying and dewatering rectifying in atmospheric conditions in 70~85 DEG C of progress, can obtain after rectifying
The alcohol product of purity 95%, fermentation residue is standby;
3) residue drying storage extruding clamp dog, carries out magnetic sorting, the metal cleared out of is sent to by the residue that step 2 is fermented
Regenerate unit and carry out regeneration, the residue of fermentation is further dried, it is ensured that moisture content is made within 15%, and with this product
The heat drying provided for fuel, natural air drying can be used in dry area, by above-mentioned well mixed and dried thing
Material, is dried to curable type cleaning generative fuel of different shapes, geomery can be by institute using single lead screw ex truding briquetting machine extruding as needed
The pore size of template of design reaches.
Embodiment 1
1) implementation condition
Solid renewable clean fuel, it is made up of following components:Carbon dust 15kg, white poplar powder 25kg, rubber tree powder 10kg,
Rice husk 150kg, maize straw 30kg, straw powder 100kg, cotton 8kg, cow dung 6kg, bagasse 2kg, kaolin 12kg, oxygen
Change aluminium 8kg, eucalyptus powder 9kg, Chinese medicine dreg 2kg, crush mixing pretreated.Above-mentioned material is conveyed into mixer to carry out
Spice, cellulase is added in 50 DEG C of enzymolysis 36h by 10~200U/g mixed materials;Gained enzymolysis liquid glucose is added by 3kg/ tons of ethanol
Enter and alcohol fermentation is carried out after dry ferment, fermentation temperature is controlled at 40 DEG C, and fermentation period is 96h;The direct band of ripe wine with dregs fermented
Slag is distilled in destilling tower, and vapo(u)rizing temperature is maintained at 90 DEG C, and the coarse ethanol of overhead extraction is delivered to rectifying column progress rectifying and taken off
Crystal evaporate can obtain the alcohol product of purity 95%, fermentation residue material is through drying in atmospheric conditions in 85 DEG C of progress after rectifying
Moisture content is 13% after dry, is then squeezed into the bar-shaped solid renewable clean fuel of densification, finished product grain size Φ 12mm, length 50mm
Left and right.
2) result of implementation
The proportion of this solid renewable clean fuel is 1.65g/cm3, ignition point is 346 DEG C, caloric value QNet, adFor
19.04MJ/kg, burn-off rate is up to 93%, and thermal expansion is smaller in combustion process, smokelessly, dust emission concentration < 0.85mgm-3, nitrogen
Emissions of oxides concentration < 100mgm-3, HCl contents 0mol/kg.
Above content is only to structure example of the present invention and explanation, affiliated those skilled in the art couple
Described specific embodiment is made various modifications or supplement or substituted using similar mode, without departing from invention
Structure surmounts scope defined in the claims, all should belong to protection scope of the present invention.
Claims (1)
1. a kind of utilization rice husk produces the preparation method of biomass fuel, it is characterised in that the preparation method includes following step
Suddenly:
1) the formula mixing of material, removes the material of row parts by weight:10-15 parts of carbon dust, 20-25 parts of white poplar powder, rubber tree powder
10-15 parts, 100-200 parts of rice husk, 20-50 parts of maize straw, 100-120 parts of straw powder, 5-10 parts of cotton, 5-9 parts of cow dung,
1-3 parts of bagasse, 10-15 parts of kaolin, 5-10 parts of aluminum oxide, 5-9 parts of eucalyptus powder, 2-8 parts of Chinese medicine dreg is crushed and mixed;
2) ferment, cellulase is added in 40~60 DEG C of 12~36h of enzymolysis by 10~200U/g mixed materials;Gained digests liquid glucose
Added by 2~3kg/ tons of ethanol and alcohol fermentation carried out after dry ferments, fermentation temperature control at 30~40 DEG C, fermentation period is 48~
96h;The ripe wine with dregs fermented directly band slag is distilled in destilling tower, and vapo(u)rizing temperature is maintained at 85~95 DEG C, overhead extraction
Coarse ethanol deliver to rectifying column and carry out rectifying and dewatering rectifying in atmospheric conditions in 70~85 DEG C of progress, can obtain purity after rectifying
95% alcohol product, fermentation residue is standby;
3) residue drying storage extruding clamp dog, carries out magnetic sorting, the metal cleared out of is sent to regeneration by the residue that step 2 is fermented
Unit carries out regeneration, the residue of fermentation is further dried, it is ensured that moisture content is used as combustion within 15%, and with this product
The heat drying that material is provided, natural air drying can be used in dry area, by above-mentioned well mixed and dried material, root
Curable type cleaning generative fuel of different shapes is dried to according to needing to extrude using single lead screw ex truding briquetting machine, geomery can be by designed
Pore size of template reaches.
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CN201710731676.1A CN107299119A (en) | 2017-08-23 | 2017-08-23 | A kind of utilization rice husk produces the preparation method of biomass fuel |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109810741A (en) * | 2019-03-25 | 2019-05-28 | 厦门理工学院 | A kind of compound biomass granular fuel and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105861567A (en) * | 2016-04-27 | 2016-08-17 | 安徽香杨林业有限公司 | Method for producing high-heating-value biomass fuel from agricultural and forestry wastes |
CN106635232A (en) * | 2017-01-05 | 2017-05-10 | 安徽润发生物能源科技有限公司 | Preparation method of clean wood chip biomass fuel |
CN106675692A (en) * | 2017-01-05 | 2017-05-17 | 安徽润发生物能源科技有限公司 | Composite biomass fuel |
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2017
- 2017-08-23 CN CN201710731676.1A patent/CN107299119A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105861567A (en) * | 2016-04-27 | 2016-08-17 | 安徽香杨林业有限公司 | Method for producing high-heating-value biomass fuel from agricultural and forestry wastes |
CN106635232A (en) * | 2017-01-05 | 2017-05-10 | 安徽润发生物能源科技有限公司 | Preparation method of clean wood chip biomass fuel |
CN106675692A (en) * | 2017-01-05 | 2017-05-17 | 安徽润发生物能源科技有限公司 | Composite biomass fuel |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109810741A (en) * | 2019-03-25 | 2019-05-28 | 厦门理工学院 | A kind of compound biomass granular fuel and preparation method thereof |
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