CN107298944A - Soluble asphalt anticorrosive paint - Google Patents
Soluble asphalt anticorrosive paint Download PDFInfo
- Publication number
- CN107298944A CN107298944A CN201710609382.1A CN201710609382A CN107298944A CN 107298944 A CN107298944 A CN 107298944A CN 201710609382 A CN201710609382 A CN 201710609382A CN 107298944 A CN107298944 A CN 107298944A
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- Prior art keywords
- parts
- anticorrosive paint
- agent
- soluble
- asphalt
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
- C09D195/005—Aqueous compositions, e.g. emulsions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of soluble asphalt anticorrosive paint, mainly it is made up of each raw material of following parts by weight:65 90 parts of anti-corrosion emulsified asphalt;5 12 parts of acrylic emulsion;5 12 parts of styrene-butadiene latex;0.1 0.5 parts of defoamer;13 parts of coalescents;0.5 1 parts of levelling agent;Anti- 0.1 0.2 parts of flash rusting agent;0.3 1 parts of thickener;The present invention possesses good stability, water resistance and weatherability, and with rate of drying it is fast, environmentally friendly, it is efficient the characteristics of.
Description
Technical field
The present invention relates to a kind of soluble asphalt anticorrosive paint.
Background technology
Asphalt has good cohesiveness, ageing resistance and antiseptic power, is used as anti-corrosion material for a long time.With
In antiseptic project have the advantages that raw material be easy to get, it is cheap, be one of most widely used material in domestic and international antiseptic project.Gold
Loss is extremely serious caused by category corrosion, and it is to prevent one of main method of metal erosion to coat anticorrosive paint.
Most of anticorrosive paint is all that based on solvent based coating, it contains substantial amounts of organic volatile both at home and abroad at present
Thing, most of these organic volatiles are inflammable and explosive noxious material, not only pollute environment, waste the energy, and seriously endanger
Evil workmen's is healthy, and multiple harm is brought to the mankind and environment.
As people's environmental consciousness is gradually stepped up, environmental regulation is increasingly perfect, and the product structure of anticorrosive paint there occurs very
It is big to change:Traditional solvent based coating is just progressively substituted using water-based anticorrosive paint as the high-performance of representative, low contamination coating.Therefore
Energy-saving and environmental protection, efficient water-based anticorrosive paint have good development prospect.
Water-based metal anticorrosive coating experienced very long course to practical application from research and development, in development early stage, list
Component water-based metal anticorrosive coating can only be applied to the comparatively gentle field of environmental condition, such as replace solvent-borne alkyd resins
Make general purpose priming paint and finish paint.With the progress of coating technology, water-based metal anticorrosive coating has been gradually available for environment
The more severe place of condition, such as harsh industry and marine environment, especially bi-component aqueous epoxy resin, polyurethane coating
Appearance, water paint performance is reached the requirement of anticorrosive coating under severe rugged environment.Develop in succession both at home and abroad at present
The water-based metal anticorrosive coating series of products of the systems such as aqueous epoxy, aqueous polyurethane, water-based fluororesin.
Waterborne epoxy coatings existence and stability is poor, is unfavorable for storing and constructs, but also there is cost height, weatherability
The shortcomings of difference, slow drying speed, two-component complicated construction technique, it is subject to certain restrictions market.
Aqueous polyurethane coating most study is polyurethane/polyacrylate composite diffusion liquid system, but water resistance,
In place of construction still has some deficits with the performance in terms of application.
Water-based fluororesin coating, price is higher, is currently limited to use natural conditions are severe, decorative effect and uses the longevity
Life requires high, is difficult in the building of maintenance.
The content of the invention
The technical problems to be solved by the invention are the shortcomings for overcoming above prior art:Offer is a kind of to possess good
Stability, water resistance and weatherability, rate of drying is fast, environmentally friendly, efficient soluble asphalt anticorrosive paint.
The technical solution of the present invention is as follows:A kind of soluble asphalt anticorrosive paint, mainly by each of following parts by weight
Raw material is made:
65-90 parts of anti-corrosion emulsified asphalt;
5-12 parts of acrylic emulsion;
5-12 parts of styrene-butadiene latex;
0.1-0.5 parts of defoamer;
1-3 parts of coalescents;
0.5-1 parts of levelling agent;
Anti- 0.1-0.2 parts of flash rusting agent;
0.3-1 parts of thickener.
The preparation method of the soluble asphalt anticorrosive paint is as follows:First by acrylic emulsion, styrene-butadiene latex and anti-fermented bean curd
Change and be well mixed in pitch addition paint mixing tank, then add defoamer, coalescents, levelling agent, anti-flash rusting agent and thickener and stir
Mix 10-20 minutes and be well mixed, you can soluble asphalt anticorrosive paint is made;
Preferably, the coalescents are one or both of alcohol ester 12, propylene glycol.
Preferably, the levelling agent is organosilicon levelling agent or polyurethane levelling agent.
Preferably, the anti-flash rusting agent is the aqueous anti-flash rusting agent Raybo 60 of the auspicious precious production in the U.S..
The anti-corrosion emulsified asphalt is prepared from the following raw materials in parts by weight:
50-60 parts of 70# pitches;
0.5-1.5 parts of rosin soap;
0.5-1.5 parts of emulsifying agent;
0.1-0.5 parts of sodium hydroxide;
0.2-1 parts of defoamer;
0.2-0.8 parts of thickener;
40-50 parts of water.
The preparation method of the anti-corrosion emulsified asphalt is as follows:By rosin soap, emulsifying agent, sodium hydroxide, defoamer, thickener
Add in reactor A, stir with water, be heated to 50-70 DEG C it is standby;Meanwhile, 70# pitches are added in reactor B
Be heated to 100-120 DEG C it is standby;Finally the raw material in reactor A, B is mixed and passes through colloid mill high speed shear;
Preferably, described emulsifying agent be carboxylic acid type emulsifying agent, sulfonate type emulsifying agent, sodium sulfovinate emulsifier, it is non-from
One or more in subtype emulsifying agent.
Preferably, the defoamer is one or both of organic silicon defoamer, mineral oil antifoam agent.
Preferably, the thickener is polyurethane thickener, acrylate thickening agent, hydrophobically-modified alkali soluble surfactant
One or both of.
The beneficial effects of the invention are as follows:Asphalt has that cohesiveness is excellent, ageing resistance is good, impedance value is high and corrosion current
The low characteristic of density, and raw material be easy to get, it is cheap, as the raw material of anticorrosive paint, for a long time corrosion-resistant field in occupation of
Leading position.However, dropping down cold short feature due to itself there is heat, solvent-borne type anticorrosive paint is all made all the time, the present invention makes
With the asphalt emulsion of independent research, by asphalt emulsification technology, using water as solvent, solve pollution that organic solvent brings and
Acrylic emulsion and styrene-butadiene latex are dispersed in emulsified asphalt by the problem of cost is high, the present invention, in coating drying process,
Pitch is crosslinked the coating for forming network structure with condensate so that emulsified asphalt corrosion resistance coating can be improved further, while more
The weak points such as the poor water resistance of acrylic acid, permeable gas height are mended.The present invention is using anti-corrosion emulsified asphalt, aqueous acrylamide yogurt
Film forming matter is wanted based on liquid, butadiene-styrene rubber emulsion, function additive is added and prepares a kind of environmentally friendly, efficient water-based anticorrosive paint, with
Instead of traditional solvent-borne type anticorrosive paint, by asphalt emulsification technology, using water as solvent, production is solved and molten using opportunity
Environmental pollution and the wasting of resources and the injury to human body that agent volatile zone comes, while the problem of greatly reducing material cost.
Acrylic emulsion and styrene-butadiene latex are dispersed in emulsified asphalt by the present invention, by between pitch, acrylic acid, butadiene-styrene rubber
Crosslinked action, is greatly improved the properties of coating.Pitch has good cohesiveness, ageing resistance and anti-corrosion energy
Power, is allowed to overcome water paint poor water resistance this shortcoming, and carry with aqueous acrylic emulsion, the crosslinking of butadiene-styrene rubber latex composite compounding
The pliability and shock resistance of high film;Possess good stability, water resistance and weatherability, while also reducing aqueous anti-
The cost of rotten coating.
Embodiment
The present invention is described in further details with specific embodiment below, but the present invention is not only limited in detail below in fact
Apply example.
Embodiment one
1)The preparation of anti-corrosion emulsified asphalt:
Each raw material is weighed according to following parts by weight:
60 parts of 70# pitches;
0.5 part of rosin soap;
1.5 parts of emulsifying agent;
0.5 part of sodium hydroxide;
1 part of defoamer;
0.2 part of thickener;
40-50 parts of water.
Each raw material weighed is prepared as follows the anti-corrosion emulsified asphalt:By rosin soap, emulsifying agent, hydroxide
Sodium, defoamer, thickener and water are added in reactor A, are stirred, be heated to 50-70 DEG C it is standby;Meanwhile, 70# is dripped
Green grass or young crops add be heated in reactor B 100-120 DEG C it is standby;Finally the raw material in reactor A, B is mixed by colloid mill at a high speed
It is standby that shearing can be prepared by anti-corrosion emulsified asphalt;
2)The preparation of soluble asphalt anticorrosive paint:
Weigh each raw material of following parts by weight:
90 parts of anti-corrosion emulsified asphalt;
12 parts of acrylic emulsion;
12 parts of styrene-butadiene latex;
0.1 part of defoamer;
3 parts of coalescents;
1 part of levelling agent;
Anti- 0.2 part of flash rusting agent;
1 part of thickener.
The preparation method of the soluble asphalt anticorrosive paint is as follows:First by the acrylic emulsion weighed, styrene-butadiene latex and
Anti-corrosion emulsified asphalt is added in paint mixing tank and is well mixed, and then adds defoamer, coalescents, levelling agent, anti-flash rusting agent and increasing
Thick dose of stirring is well mixed for 10-20 minutes, you can soluble asphalt anticorrosive paint is made;
The coalescents are one or both of alcohol ester 12, propylene glycol.
Embodiment two
1)The preparation of anti-corrosion emulsified asphalt:
Each raw material is weighed according to following parts by weight:
55 parts of 70# pitches;
0.5 part of rosin soap;
1.5 parts of carboxylic acid type emulsifying agent;
0.5 part of sodium hydroxide;
1 part of mineral oil antifoam agent;
0.2 part of polyurethane thickener;
40 parts of water.
Each raw material weighed is prepared as follows the anti-corrosion emulsified asphalt:Rosin soap, carboxylic acid type are emulsified
Agent, sodium hydroxide, mineral oil antifoam agent, polyurethane thickener and water are added in reactor A, are stirred, are heated to 50-
70 DEG C standby;Meanwhile, it is standby by being heated to 100-120 DEG C in 70# pitches addition reactor B;Finally by the original in reactor A, B
It is standby that material mixing can be prepared by anti-corrosion emulsified asphalt by colloid mill high speed shear;
2)The preparation of soluble asphalt anticorrosive paint:
Weigh each raw material of following parts by weight:
70 parts of anti-corrosion emulsified asphalt;
8 parts of acrylic emulsion;
8 parts of styrene-butadiene latex;
0.3 part of defoamer;
12 parts of alcohol ester;
0.5 part of polyurethane levelling agent;
Aqueous anti-60 0.1 parts of flash rusting auxiliary agent Raybo;
0.3 part of thickener.
The preparation method of the soluble asphalt anticorrosive paint is as follows:First by the acrylic emulsion weighed, styrene-butadiene latex and
Anti-corrosion emulsified asphalt is added in paint mixing tank and is well mixed, and then adds defoamer, alcohol ester 12, polyurethane levelling agent, aqueous anti-
Flash rusting auxiliary agent Raybo 60 and thickener are stirred 10-20 minutes and are well mixed, you can soluble asphalt anticorrosive paint is made.
Embodiment three
1)The preparation of anti-corrosion emulsified asphalt:
Each raw material is weighed according to following parts by weight:
60 parts of 70# pitches;
1.5 parts of rosin soap;
1.5 parts of sulfonate type emulsifying agent;
0.5 part of sodium hydroxide;
1 part of defoamer;
0.2 part of thickener;
50 parts of water.
Each raw material weighed is prepared as follows the anti-corrosion emulsified asphalt:Rosin soap, sulfonate type are emulsified
Agent, sodium hydroxide, defoamer, thickener and water are added in reactor A, are stirred, be heated to 50-70 DEG C it is standby;Together
When, it is standby by being heated to 100-120 DEG C in 70# pitches addition reactor B;Finally the raw material in reactor A, B is mixed and passed through
It is standby that colloid mill high speed shear can be prepared by anti-corrosion emulsified asphalt;
2)The preparation of soluble asphalt anticorrosive paint:
Weigh each raw material of following parts by weight:
78 parts of anti-corrosion emulsified asphalt;
12 parts of acrylic emulsion;
5 parts of styrene-butadiene latex;
0.5 part of defoamer;
1 part of coalescents;
1 part of levelling agent;
Anti- 0.1 part of flash rusting agent;
0.3 part of thickener.
The preparation method of the soluble asphalt anticorrosive paint is as follows:First by the acrylic emulsion weighed, styrene-butadiene latex and
Anti-corrosion emulsified asphalt is added in paint mixing tank and is well mixed, and then adds defoamer, coalescents, levelling agent, anti-flash rusting agent and increasing
Thick dose of stirring is well mixed for 10-20 minutes, you can soluble asphalt anticorrosive paint, gained soluble asphalt anticorrosive paint performance is made
It is as shown in the table:
It can be seen that, the present invention possess good stability, water resistance and weatherability, with it is environmentally friendly, efficient the characteristics of.
It the above is only the feature implementation example of the present invention, the scope of the present invention be not limited in any way.It is all to use same
Deng technical scheme formed by exchange or equivalence replacement, all fall within rights protection scope of the present invention.
Claims (10)
1. a kind of soluble asphalt anticorrosive paint, it is characterised in that:Mainly it is made up of each raw material of following parts by weight:
65-90 parts of anti-corrosion emulsified asphalt;
5-12 parts of acrylic emulsion;
5-12 parts of styrene-butadiene latex;
0.1-0.5 parts of defoamer;
1-3 parts of coalescents;
0.5-1 parts of levelling agent;
Anti- 0.1-0.2 parts of flash rusting agent;
0.3-1 parts of thickener.
2. soluble asphalt anticorrosive paint according to claim 1, it is characterised in that:The system of the soluble asphalt anticorrosive paint
Preparation Method is as follows:Acrylic emulsion, styrene-butadiene latex and anti-corrosion emulsified asphalt are added in paint mixing tank first and are well mixed, Ran Houjia
Enter defoamer, coalescents, levelling agent, anti-flash rusting agent and thickener stirring to be well mixed for 10-20 minutes, you can aqueous drip is made
Blue or green anticorrosive paint.
3. soluble asphalt anticorrosive paint according to claim 2, it is characterised in that:The coalescents be alcohol ester 12,
One or both of propylene glycol.
4. soluble asphalt anticorrosive paint according to claim 3, it is characterised in that:The levelling agent is organosilicon levelling agent
Or polyurethane levelling agent.
5. soluble asphalt anticorrosive paint according to claim 4, it is characterised in that:The anti-flash rusting agent is U.S. Rui Baosheng
The aqueous anti-flash rusting agent Raybo 60 of production.
6. soluble asphalt anticorrosive paint according to claim 1, it is characterised in that:The anti-corrosion emulsified asphalt is by following heavy
The raw material of amount number is made:
50-60 parts of 70# pitches;
0.5-1.5 parts of rosin soap;
0.5-1.5 parts of emulsifying agent;
0.1-0.5 parts of sodium hydroxide;
0.2-1 parts of defoamer;
0.2-0.8 parts of thickener;
40-50 parts of water.
7. soluble asphalt anticorrosive paint according to claim 6, it is characterised in that:The preparation side of the anti-corrosion emulsified asphalt
Method is as follows:Rosin soap, emulsifying agent, sodium hydroxide, defoamer, thickener and water are added in reactor A, stirred, is heated
Be warming up to 50-70 DEG C it is standby;Meanwhile, it is standby by being heated to 100-120 DEG C in 70# pitches addition reactor B;Finally by reactor
Colloid mill high speed shear is passed through in raw material mixing in A, B.
8. soluble asphalt anticorrosive paint according to claim 7, it is characterised in that:Described emulsifying agent is carboxylic acid type breast
One or more in agent, sulfonate type emulsifying agent, sodium sulfovinate emulsifier, nonionic emulsifier.
9. the soluble asphalt anticorrosive paint according to claim 1 or 6, it is characterised in that:The defoamer disappears for organosilicon
One or both of infusion, mineral oil antifoam agent.
10. the soluble asphalt anticorrosive paint according to claim 1 or 6, it is characterised in that:The thickener is polyurethane
Thick dose, acrylate thickening agent, one or both of hydrophobically-modified alkali soluble surfactant.
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CN201710609382.1A CN107298944B (en) | 2017-07-25 | 2017-07-25 | Soluble asphalt anticorrosive paint |
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CN201710609382.1A CN107298944B (en) | 2017-07-25 | 2017-07-25 | Soluble asphalt anticorrosive paint |
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CN107298944B CN107298944B (en) | 2019-05-17 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107936839A (en) * | 2017-12-14 | 2018-04-20 | 沧州市临港隆达化工有限公司 | Elastomer asphalt waterproofing paint and preparation method thereof |
CN109054519A (en) * | 2018-06-06 | 2018-12-21 | 广州集泰化工股份有限公司 | A kind of water soluble acrylic acid anticorrosive paint and preparation method thereof containing pitch |
CN109054643A (en) * | 2018-06-06 | 2018-12-21 | 广州集泰化工股份有限公司 | A kind of soluble asphalt anticorrosive paint and preparation method thereof |
CN109266224A (en) * | 2018-08-28 | 2019-01-25 | 安徽华丽涂料有限公司 | A kind of water-repellent paint and its use construction method |
CN110408274A (en) * | 2019-08-23 | 2019-11-05 | 山东北方创信防水科技股份有限公司 | A kind of single-component water-based rubber asphalt quick-drying water-repellent paint |
CN111621204A (en) * | 2020-04-16 | 2020-09-04 | 西卡(上海)管理有限公司 | Liquid sound insulation coating |
CN112745766A (en) * | 2021-01-19 | 2021-05-04 | 浙江欣苗化工有限公司 | Outdoor floor bi-component water-based asphalt anticorrosive paint and preparation method thereof |
CN114774001A (en) * | 2022-05-30 | 2022-07-22 | 云南瑞三投资有限公司 | Production method of steel bridge deck SMA high-elasticity modified asphalt |
CN116218376A (en) * | 2023-03-17 | 2023-06-06 | 江西省高精科技有限公司 | Asphalt paint capable of being thick coated and rust-proof, and preparation method and application thereof |
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CN104449381A (en) * | 2014-12-19 | 2015-03-25 | 锦州东方雨虹建筑材料有限责任公司 | Composite emulsified asphalt waterproof coating and preparation method thereof |
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CN104449381A (en) * | 2014-12-19 | 2015-03-25 | 锦州东方雨虹建筑材料有限责任公司 | Composite emulsified asphalt waterproof coating and preparation method thereof |
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Cited By (13)
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CN107936839B (en) * | 2017-12-14 | 2020-01-14 | 沧州市临港隆达化工有限公司 | High-elasticity rubber asphalt waterproof coating and preparation method thereof |
CN107936839A (en) * | 2017-12-14 | 2018-04-20 | 沧州市临港隆达化工有限公司 | Elastomer asphalt waterproofing paint and preparation method thereof |
CN109054519A (en) * | 2018-06-06 | 2018-12-21 | 广州集泰化工股份有限公司 | A kind of water soluble acrylic acid anticorrosive paint and preparation method thereof containing pitch |
CN109054643A (en) * | 2018-06-06 | 2018-12-21 | 广州集泰化工股份有限公司 | A kind of soluble asphalt anticorrosive paint and preparation method thereof |
CN109266224A (en) * | 2018-08-28 | 2019-01-25 | 安徽华丽涂料有限公司 | A kind of water-repellent paint and its use construction method |
WO2021036799A1 (en) * | 2019-08-23 | 2021-03-04 | 山东北方创信防水科技集团股份有限公司 | Single-component aqueous rubber asphalt quick-drying waterproof paint |
CN110408274A (en) * | 2019-08-23 | 2019-11-05 | 山东北方创信防水科技股份有限公司 | A kind of single-component water-based rubber asphalt quick-drying water-repellent paint |
CN111621204A (en) * | 2020-04-16 | 2020-09-04 | 西卡(上海)管理有限公司 | Liquid sound insulation coating |
CN111621204B (en) * | 2020-04-16 | 2021-11-09 | 西卡(上海)管理有限公司 | Liquid sound insulation coating |
CN112745766A (en) * | 2021-01-19 | 2021-05-04 | 浙江欣苗化工有限公司 | Outdoor floor bi-component water-based asphalt anticorrosive paint and preparation method thereof |
CN114774001A (en) * | 2022-05-30 | 2022-07-22 | 云南瑞三投资有限公司 | Production method of steel bridge deck SMA high-elasticity modified asphalt |
CN116218376A (en) * | 2023-03-17 | 2023-06-06 | 江西省高精科技有限公司 | Asphalt paint capable of being thick coated and rust-proof, and preparation method and application thereof |
CN116218376B (en) * | 2023-03-17 | 2024-04-16 | 江西省高精科技有限公司 | Asphalt paint capable of being thick coated and rust-proof, and preparation method and application thereof |
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