CN107287943A - A kind of printing assistant and printing technology - Google Patents

A kind of printing assistant and printing technology Download PDF

Info

Publication number
CN107287943A
CN107287943A CN201710540902.8A CN201710540902A CN107287943A CN 107287943 A CN107287943 A CN 107287943A CN 201710540902 A CN201710540902 A CN 201710540902A CN 107287943 A CN107287943 A CN 107287943A
Authority
CN
China
Prior art keywords
printing
assistant
drying
urea
uni
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710540902.8A
Other languages
Chinese (zh)
Other versions
CN107287943B (en
Inventor
丁彩玲
孔健
丁翠侠
陈超
陈青
祝亚丽
张伟红
李慧
刘美朋
刘晓飞
王春霞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG RUYI TECHNOLOGY GROUP CO LTD
Original Assignee
SHANDONG RUYI TECHNOLOGY GROUP CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANDONG RUYI TECHNOLOGY GROUP CO LTD filed Critical SHANDONG RUYI TECHNOLOGY GROUP CO LTD
Priority to CN201710540902.8A priority Critical patent/CN107287943B/en
Publication of CN107287943A publication Critical patent/CN107287943A/en
Application granted granted Critical
Publication of CN107287943B publication Critical patent/CN107287943B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/67341Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6491(Thio)urea or (cyclic) derivatives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8209Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing amide groups

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a kind of printing assistant and printing technology, consist of the following composition:Ammonium sulfate, acetic acid, urea, UNI, guar gum, AP defoamers, AR reducing agents.The printing assistant of the present invention improves the heavier composition of the smell commonly used in existing auxiliary agent, and stamp smell is reduced while printing quality is ensured, has practicality using upper in industrial production, is adapted to popularization and application.

Description

A kind of printing assistant and printing technology
Technical field
The present invention relates to the textile printing technical field such as cashmere, wool, nylon, knitting, more particularly to a kind of stamp gas Taste is small, the high printing assistant of printing quality and the printing technology using the auxiliary agent.
Background technology
During existing fabric printing process, printing assistant is essential, and printing assistant includes printing gum, pigment printing Adhesive, crosslinking agent, defoamer, anti-decorative pattern imbibition agent, discharging agent, resist agent, color fixing agent, the soil resistant washing of PRINTED FABRIC Agent, net photoresists processed etc..Smell weight during the printing assistant generally existing production used now, the problem of environmental protection is not up to standard, this The technical problem that invention is solved is how to improve printing assistant collocation reduction stamp smell while printing quality is ensured.
The content of the invention
The present invention provides a kind of printing assistant and printing technology aiming at above-mentioned defect.The stamp of the present invention Auxiliary agent improves the heavier composition of the smell commonly used in existing auxiliary agent, and stamp smell is reduced while printing quality is ensured, There is practicality using upper in industrial production, be adapted to popularization and application.
A kind of printing assistant and printing technology technical scheme of the present invention is that a kind of printing assistant is consisted of the following composition: Ammonium sulfate, acetic acid, urea, UNI, guar gum, AP defoamers, AR reducing agents.
A kind of described printing assistant, is made up of following component by weight percentage:Ammonium sulfate 1.5-2.5%, acetic acid 2%th, urea 10%, UNI 1%, guar gum 1%, AP defoamers 0.1%, AR reducing agents 0.5%, surplus is water.
Described a kind of printing assistant, it is preferred that be made up of following component by weight percentage:Ammonium sulfate 2%, acetic acid 2%th, urea 10%, UNI 1%, guar gum 1%, AP defoamers 0.1%, AR reducing agents 0.5%, surplus is water.
A kind of described printing assistant, can also be preferred, it is made up of following component by weight percentage:Ammonium sulfate 2.5%th, acetic acid 2%, urea 10%, UNI 1%, guar gum 1%, AP defoamers 0.1%, AR reducing agents 0.5%, surplus is Water.
A kind of printing technology, using above-mentioned printing assistant, is comprised the following steps that:Perching, starching, for the first time drying 90 DEG C, printing, second of 80 DEG C of drying is evaporated, twice cold water is washed, 40-50 DEG C of warm water is soaped, 40-50 DEG C of * 5 minutes fixation, 40- 50 DEG C of warm water are washed, 130 DEG C of drying-examine, wherein, sizing process adds printing assistant of the present invention.
During starching, pick-up 80%-100%.
In drying course, the moisture regain of drying control for the first time:Wool or cashmere 14-20%, silk 10-15%, nylon 3- 6%.
In drying course, second of drying control moisture regain:Wool or cashmere 10-15%, silk 7-12%, nylon 2-4%.
Evaporate process 103 DEG C 30 minutes, humidity 80 ± 2%.
PH controls 4.5-5.5 in laking process.
Beneficial effects of the present invention are:The present invention printing assistant improve in existing auxiliary agent commonly use smell it is heavier into Point, stamp smell is reduced while printing quality is ensured, there is practicality using upper in industrial production, suitable promote should With.
Embodiment:
For a better understanding of the present invention, technical scheme is described in detail with instantiation below, but originally Invention is not limited thereto.
Experimental example 1
Experiment purpose:Reduce stamp smell, it is ensured that printing quality
Use equipment:Starching machine, Mei Jiani printing machines, share rapid steamer (7# techniques)
Use fabric:100%90S wool cloths
It is adjuvant used:Ammonium sulfate technical grade, citric acid industry level, urea industry level, UNI (Hensel is graceful), guar gum work Industry level, AP (Hensel is graceful), AR (Hensel is graceful)
The analysis of causes:HAC, urea, this four factors of AP, AR are as follows
Odor source 1, AP defoamers
Odor source 2, AR reducing agents
Odor source 3, HAC
Odor source 4, urea (moisture absorption solubilising, it is possible to decrease consumption)
Experimental program is as shown in table 1:
Table 1
For above smell, the irritant smell of B8 slurries, the scheme corrected one's mistakes almost does not have from 1 to No. 6 smell, test Coloured light tinctorial yield data are following (this 7 pieces contrast schemes, except slurry is different, other conditions are consistent)
Seven kinds of K/S Value Datas are as shown in table 2 above:
Table 2
Protocol Numbers Test result K/S values (red) Test result K/S values (blueness)
1 1.029 0.873
2 1.086 0.834
3 0.941 0.824
4 1.059 0.834
5 1.030 0.813
6 1.029 0.794
B8 1.016 0.842
Conclusion:It is preferred that No. 2, No. 4 schemes (with reference to visually observing).
First, according to No. 3 schemes of above test result and other schemes than color it is low be result that urea is greatly reduced, urine It is indubitable that element, which can increase tinctorial yield,.
2nd, AP is to play froth breaking infiltration, and consumption, which is reduced, can't reduce tinctorial yield, and slurry smell is reduced on the contrary.
3rd, 4 and No. 5 scheme ratios, citric acid does not have the acidity of acetic acid strong, it is necessary to increase consumption.
4th, acetic acid is volatile acid in No. 1 scheme, is easily disturbed in drying course by extraneous factor, without sulphur Sour ammonium resistivity is strong.
5th, No. 4 schemes and B8 slurries ratio, reduce the high on the contrary with color is measured of ammonium sulfate, it was demonstrated that B8 slurries pH value is present Hidden danger.(dark effect deviation)
It is recommended that:1st, AP consumptions (odor source) are reduced on the basis of B8 slurries, other parameters are moved less in principle.
2nd, 95 DEG C of gas of * 60 minutes that this time experiment is selected steam technique.
Experimental example 2
Experimental program is as shown in table 3:
Table 3
For above smell, the scheme 13 corrected one's mistakes, 14 smells almost do not have, and test coloured light tinctorial yield data are following, and (this 5 Block contrasts scheme, and except slurry is different, other conditions are consistent)
Five kinds of scheme K/S data are as shown in table 4 above:
Table 4
Conclusion:Comprehensive Assessment 13 can be substituted with No. 4 schemes to B8 slurries.(bulk production is verified).
Embodiment 1
Use equipment:Starching machine, Mei Jiani printing machines, share rapid steamer (7# techniques)
Use fabric:100%90S wool cloths
Printing assistant:It is made up of following component by weight percentage:Ammonium sulfate 2%, acetic acid 2%, urea 10%, UNI 1%th, guar gum 1%, AP defoamers 0.1%, AR reducing agents 0.5%, surplus is water.By the printing assistant and B8 of above composition Auxiliary agent is compared as shown in table 5:
Table 5
Scheme is contrasted above, and K/S Value Datas are as shown in table 6
Table 6
Embodiment 2
Use equipment:Starching machine, Mei Jiani printing machines, share rapid steamer (7# techniques)
Use fabric:100% cloth of real silk
Printing assistant:It is made up of following component by weight percentage:Ammonium sulfate 2.5%, acetic acid 2%, urea 10%, UNI 1%, guar gum 1%, AP defoamers 0.1%, AR reducing agents 0.5%, surplus is water.By the printing assistant of above composition It is compared as shown in table 7 with B8 auxiliary agents:
Table 7
Scheme is contrasted above, and K/S Value Datas are as shown in table 8
Table 8
Embodiment 3
Use equipment:Starching machine, Mei Jiani printing machines, share rapid steamer (7# techniques)
Use fabric:100% nylon cloth
Printing assistant:It is made up of following component by weight percentage:Ammonium sulfate 2.5%, acetic acid 2%, urea 10%, UNI 1%, guar gum 1%, AP defoamers 0.1%, AR reducing agents 0.5%, surplus is water.By the printing assistant of above composition It is compared as shown in table 9 with B8 auxiliary agents:
Table 9
Scheme is contrasted above, and K/S Value Datas are as shown in table 10
Table 10
Above example 1-3 technological processes:The embodiment of the present invention 1 or embodiment 2 or embodiment 3 are added during perching → starching The auxiliary agent (pick-up 80%-100%) → first time dries 90 DEG C of (moisture regain control is shown in Table 11) → printing → second and dried 80 DEG C (moisture regain control be shown in Table 12) → evaporate (103 DEG C * 30 minutes, humidity 80% or so) → cold water washes (twice) → 40-50 DEG C Warm water soaps (alkalescence condition) → and 40-50 DEG C of * 5 minutes fixation (PH controls 5 or so) → 40-50 DEG C of warm water is washed → dry 130 DEG C → examine
Table 11
Raw material Control moisture regain (%)
Wool/cashmere class 14-20
Silk 10-15
Nylon 3-6
Table 12

Claims (10)

1. a kind of printing assistant, it is characterised in that consist of the following composition:Ammonium sulfate, acetic acid, urea, UNI, guar gum, AP Defoamer, AR reducing agents.
2. a kind of printing assistant according to claim 1, it is characterised in that by following component group by weight percentage Into:Ammonium sulfate 1.5-2.5%, acetic acid 2%, urea 10%, UNI 1%, guar gum 1%, AP defoamers 0.1%, AR reduction Agent 0.5%, surplus is water.
3. a kind of printing assistant according to claim 1, it is characterised in that by following component group by weight percentage Into:Ammonium sulfate 2%, acetic acid 2%, urea 10%, UNI 1%, guar gum 1%, AP defoamers 0.1%, AR reducing agents 0.5%, surplus is water.
4. a kind of printing assistant according to claim 1, it is characterised in that by following component group by weight percentage Into:Ammonium sulfate 2.5%, acetic acid 2%, urea 10%, UNI 1%, guar gum 1%, AP defoamers 0.1%, AR reducing agents 0.5%, surplus is water.
5. a kind of printing technology, it is characterised in that use printing assistant as claimed in claim 1, comprise the following steps that: Perching, starching, 90 DEG C of drying for the first time, printing, second of 80 DEG C of drying is evaporated, twice cold water is washed, 40-50 DEG C of warm water is soaped, 40-50 DEG C of * 5 minutes fixation, 40-50 DEG C of warm water is washed, 130 DEG C of drying-examine, wherein, sizing process is added described in claim 1 Printing assistant.
6. a kind of printing technology according to claim 5, it is characterised in that during starching, pick-up 80%-100%.
7. a kind of printing technology according to claim 5, it is characterised in that in drying course, for the first time drying is controlled back Tide:Wool or cashmere 14-20%, silk 10-15%, nylon 3-6%.
8. a kind of printing technology according to claim 5, it is characterised in that in drying course, second of drying is controlled back Tide:Wool or cashmere 10-15%, silk 7-12%, nylon 2-4%.
9. a kind of printing technology according to claim 5, it is characterised in that evaporate process 103 DEG C 30 minutes, humidity 80 ± 2%.
10. a kind of printing technology according to claim 5, it is characterised in that pH controls 4.5-5.5 in laking process.
CN201710540902.8A 2017-07-05 2017-07-05 A kind of printing assistant and printing technology Active CN107287943B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710540902.8A CN107287943B (en) 2017-07-05 2017-07-05 A kind of printing assistant and printing technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710540902.8A CN107287943B (en) 2017-07-05 2017-07-05 A kind of printing assistant and printing technology

Publications (2)

Publication Number Publication Date
CN107287943A true CN107287943A (en) 2017-10-24
CN107287943B CN107287943B (en) 2019-11-12

Family

ID=60100258

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710540902.8A Active CN107287943B (en) 2017-07-05 2017-07-05 A kind of printing assistant and printing technology

Country Status (1)

Country Link
CN (1) CN107287943B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107956146A (en) * 2017-12-15 2018-04-24 苏州润弘贸易有限公司 Environment-friendly type printing assistant

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000003080A1 (en) * 1998-07-08 2000-01-20 Ciba Specialty Chemicals Holding Inc. Method for printing fibrous textile materials using the ink jet technique
JP4513255B2 (en) * 2002-12-03 2010-07-28 セイコーエプソン株式会社 Ink composition for inkjet printing, printing method, and printed fabric
CN104233874A (en) * 2013-06-17 2014-12-24 无锡市东新织造有限公司 Digital printing process for wool fabric
CN106049115A (en) * 2016-03-31 2016-10-26 南通纺织丝绸产业技术研究院 Method for preparing fabric through inkjet and discharge printing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000003080A1 (en) * 1998-07-08 2000-01-20 Ciba Specialty Chemicals Holding Inc. Method for printing fibrous textile materials using the ink jet technique
JP4513255B2 (en) * 2002-12-03 2010-07-28 セイコーエプソン株式会社 Ink composition for inkjet printing, printing method, and printed fabric
CN104233874A (en) * 2013-06-17 2014-12-24 无锡市东新织造有限公司 Digital printing process for wool fabric
CN106049115A (en) * 2016-03-31 2016-10-26 南通纺织丝绸产业技术研究院 Method for preparing fabric through inkjet and discharge printing

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
乔学胜等: "LYOPRINT AP在印花中解决印花鱼鳞斑的应用", 《染整技术》 *
房宽峻等: "《染料应用手册》", 31 July 2013, 中国纺织出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107956146A (en) * 2017-12-15 2018-04-24 苏州润弘贸易有限公司 Environment-friendly type printing assistant

Also Published As

Publication number Publication date
CN107287943B (en) 2019-11-12

Similar Documents

Publication Publication Date Title
Bechtold et al. Natural dyes in modern textile dyehouses—how to combine experiences of two centuries to meet the demands of the future?
CN105926318A (en) Digital printing technology for worsted cashmere fabrics
CN106544902A (en) A kind of digit printing technique of fleece fabrics
CN105648793B (en) A kind of high chlorine-resistant print paste and preparation method and application
CN106049115A (en) Method for preparing fabric through inkjet and discharge printing
CN105926319A (en) Active ink digital printing pretreating size for woolen fabric
CN100582358C (en) Process for manufacturing batik household textile lining
CN107338660A (en) Digital ink-jet discharge printing handling process
CN107287943A (en) A kind of printing assistant and printing technology
CN105780543B (en) Sepiolite printing gum and sepiolite print paste and its preparation method and application
CN103114456B (en) Ramine socks and treatment method thereof
CN105926320A (en) Acidic ink digital printing anti-bleeding size for woolen fabric
CN108374289A (en) A kind of dyeing of national costume cloth
CN107083698B (en) Padding liquid for wet transfer printing of chinlon fabric and its compounding process
CN105442346A (en) Manufacture technology for photochromic fragrant printed fabric
CN101532241A (en) Nano-silver antibacterial finishing process for textile
CN106835763A (en) A kind of cashmere fiber digit printing slurry and preparation method thereof
DE2438143A1 (en) PROCESS AND PLANT FOR STABILIZING AND PRE-SHRINKING A HULLED PRODUCT IN THE FORM OF AN ENDLESS HOSE CONTAINING SYNTHETIC FIBERS STABILIZED BY HEAT
CN102767079A (en) Weaving slurry and preparation method thereof
US1622496A (en) Cellulose-fiber product treated with a size embodying soy-bean flour and process of making the same
CN106758401A (en) A kind of real silk fabric pretreatment and with the method for natural plant dye stamp
CN104532609B (en) Printing paste for locking jeans elasticity and preventing bleaching and application thereof
CN108049209B (en) Active digital printing paste and preparation method and application thereof
CN106400479A (en) Method for improving wet rubbing fastness of dark cotton or polyester-cotton waterproof oilproof woven fabric
CN112239955A (en) Preparation method of fabric capable of changing color when meeting water

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PP01 Preservation of patent right
PP01 Preservation of patent right

Effective date of registration: 20210218

Granted publication date: 20191112

PD01 Discharge of preservation of patent
PD01 Discharge of preservation of patent

Date of cancellation: 20240218

Granted publication date: 20191112

PP01 Preservation of patent right
PP01 Preservation of patent right

Effective date of registration: 20240218

Granted publication date: 20191112