CN107287943B - A kind of printing assistant and printing technology - Google Patents
A kind of printing assistant and printing technology Download PDFInfo
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- CN107287943B CN107287943B CN201710540902.8A CN201710540902A CN107287943B CN 107287943 B CN107287943 B CN 107287943B CN 201710540902 A CN201710540902 A CN 201710540902A CN 107287943 B CN107287943 B CN 107287943B
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- printing
- printing technology
- assistant
- drying
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- 238000007639 printing Methods 0.000 title claims abstract description 61
- 238000005516 engineering process Methods 0.000 title claims abstract description 17
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 39
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004202 carbamide Substances 0.000 claims abstract description 15
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 13
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 13
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 13
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 12
- 229920002907 Guar gum Polymers 0.000 claims abstract description 11
- 229960002154 guar gum Drugs 0.000 claims abstract description 11
- 235000010417 guar gum Nutrition 0.000 claims abstract description 11
- 239000000665 guar gum Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 12
- 238000009955 starching Methods 0.000 claims description 9
- 210000002268 wool Anatomy 0.000 claims description 8
- 239000004677 Nylon Substances 0.000 claims description 7
- 229920001778 nylon Polymers 0.000 claims description 7
- 210000000085 cashmere Anatomy 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 208000028804 PERCHING syndrome Diseases 0.000 claims description 3
- 238000004513 sizing Methods 0.000 claims description 2
- 244000303965 Cyamopsis psoralioides Species 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 abstract description 9
- 239000004615 ingredient Substances 0.000 abstract description 5
- 238000009776 industrial production Methods 0.000 abstract description 3
- 230000035943 smell Effects 0.000 description 13
- 239000004744 fabric Substances 0.000 description 10
- 239000002002 slurry Substances 0.000 description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241001269238 Data Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000012769 bulk production Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6491—(Thio)urea or (cyclic) derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8209—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing amide groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of printing assistant and printing technologies, consist of the following compositions: ammonium sulfate, acetic acid, urea, UNI, guar gum, AP defoaming agent, AR reducing agent.Printing assistant of the invention improves the heavier ingredient of common smell in existing auxiliary agent, reduces stamp smell while guaranteeing printing quality, has practicability using upper in industrial production, is suitble to promote and apply.
Description
Technical field
The present invention relates to the textile printings technical fields such as cashmere, wool, nylon, knitting, more particularly to a kind of stamp gas
Taste is small, the high printing assistant of printing quality and the printing technology using the auxiliary agent.
Background technique
During existing fabric printing process, printing assistant is essential, and printing assistant includes printing gum, pigment printing
Adhesive, crosslinking agent, defoaming agent, anti-decorative pattern imbibition agent, discharging agent, resist agent, color fixing agent, the soil resistant washing of PRINTED FABRIC
Agent, net photoresists processed etc..Smell weight when the printing assistant used now generally existing production, environmental protection problem not up to standard, this
The technical issues of invention solves is how that improving printing assistant collocation while guaranteeing printing quality reduces stamp smell.
Summary of the invention
The present invention provides a kind of printing assistant and printing technology aiming at above-mentioned defect.Stamp of the invention
Auxiliary agent improves the heavier ingredient of common smell in existing auxiliary agent, reduces stamp smell while guaranteeing printing quality,
There is practicability using upper in industrial production, be suitble to promote and apply.
A kind of printing assistant of the invention and printing technology technical solution are that a kind of printing assistant consists of the following compositions:
Ammonium sulfate, acetic acid, urea, UNI, guar gum, AP defoaming agent, AR reducing agent.
A kind of printing assistant, is made of following component by weight percentage: ammonium sulfate 1.5-2.5%, acetic acid
2%, urea 10%, UNI 1%, guar gum 1%, AP defoaming agent 0.1%, AR reducing agent 0.5%, surplus are water.
A kind of printing assistant, it is preferred that be made of following component by weight percentage: ammonium sulfate 2%, acetic acid
2%, urea 10%, UNI 1%, guar gum 1%, AP defoaming agent 0.1%, AR reducing agent 0.5%, surplus are water.
A kind of printing assistant, can also be preferred, is made of following component by weight percentage: ammonium sulfate
2.5%, acetic acid 2%, urea 10%, UNI 1%, guar gum 1%, AP defoaming agent 0.1%, AR reducing agent 0.5%, surplus are
Water.
A kind of printing technology is comprised the following steps that using above-mentioned printing assistant: perching, starching, for the first time drying 90
DEG C, printing, second of 80 DEG C of drying is evaporated, twice cold water is washed, and 40-50 DEG C of warm water is soaped, 40-50 DEG C of * 5 minutes fixation, 40-
50 DEG C of warm water are washed, and 130 DEG C of drying-is examined, wherein printing assistant of the present invention is added in sizing process.
When starching, pick-up 80%-100%.
In drying course, the resurgence of drying control for the first time: wool or cashmere 14-20%, silk 10-15%, nylon 3-
6%.
In drying course, second of drying control resurgence: wool or cashmere 10-15%, silk 7-12%, nylon 2-4%.
103 DEG C of process 30 minutes are evaporated, humidity 80 ± 2%.
PH controls 4.5-5.5 in laking process.
The invention has the benefit that printing assistant of the invention improve common smell in existing auxiliary agent it is heavier at
Point, stamp smell is reduced while guaranteeing printing quality, there is practicability using upper in industrial production, suitable popularization is answered
With.
Specific embodiment:
For a better understanding of the present invention, below with specific example come the technical solution that the present invention will be described in detail, but this
Invention is not limited thereto.
Experimental example 1
Experiment purpose: reducing stamp smell, guarantees printing quality
Use equipment: starching machine, Mei Jiani printing machine, share rapid steamer (7# technique)
Use fabric: 100%90S wool cloth
It is adjuvant used: ammonium sulfate technical grade, citric acid industry grade, urea industry grade, UNI (Hensel is graceful), guar gum work
Industry grade, AP (Hensel is graceful), AR (Hensel is graceful)
The analysis of causes: HAC, urea, this four factors of AP, AR are as follows
Odor source 1, AP defoaming agent
Odor source 2, AR reducing agent
Odor source 3, HAC
Odor source 4, urea (moisture absorption solubilising, dosage can be reduced)
Experimental program is as shown in table 1:
Table 1
For the above smell, the irritant smell of B8 slurry, from 1 to No. 6 smell of the scheme corrected one's mistakes is almost without test
Coloured light tinctorial yield data are following (this 7 pieces comparison schemes, in addition to slurry difference, other conditions are consistent)
Seven kinds of K/S Value Datas are as shown in table 2 above:
Table 2
Protocol Numbers | Test result K/S value (red) | Test result K/S value (blue) |
1 | 1.029 | 0.873 |
2 | 1.086 | 0.834 |
3 | 0.941 | 0.824 |
4 | 1.059 | 0.834 |
5 | 1.030 | 0.813 |
6 | 1.029 | 0.794 |
B8 | 1.016 | 0.842 |
Conclusion: preferably No. 2, No. 4 schemes (in conjunction with visually observing).
It one, is that urea is greatly reduced as a result, urine than it is low to obtain color with other schemes according to No. 3 schemes of the above test result
It is indubitable that element, which can increase tinctorial yield,.
Two, AP only plays defoaming infiltration, and dosage reduction can't reduce tinctorial yield, reduce slurry smell instead.
Three, 4 and No. 5 scheme ratios, citric acid do not have the acidity of acetic acid strong, need to increase dosage.
Four, acetic acid is volatile acid in No. 1 scheme, the interference by extraneous factor is easy during the drying process, without sulphur
Sour ammonium resistivity is strong.
Five, No. 4 schemes and B8 slurry ratio, reduce the high instead with color is measured of ammonium sulfate, it was demonstrated that B8 slurry pH value exists
Hidden danger.(dark effect deviation)
It is recommended that: 1, it B8 slurry on the basis of reduces AP dosage (odor source), moves other parameters less in principle.
2,95 DEG C of * 60 minutes gas that this time experiment is selected steam technique.
Experimental example 2
Experimental program is as shown in table 3:
Table 3
For the above smell, the scheme 13 corrected one's mistakes, 14 smells are almost without test coloured light tinctorial yield data are following, and (this 5
Block compares scheme, and in addition to slurry difference, other conditions are consistent)
Five kinds of scheme K/S data are as shown in table 4 above:
Table 4
Conclusion: Comprehensive Assessment 13 can substitute B8 slurry with No. 4 schemes.(bulk production is verified).
Embodiment 1
Use equipment: starching machine, Mei Jiani printing machine, share rapid steamer (7# technique)
Use fabric: 100%90S wool cloth
Printing assistant: it is made of following component by weight percentage: ammonium sulfate 2%, acetic acid 2%, urea 10%, UNI
1%, guar gum 1%, AP defoaming agent 0.1%, AR reducing agent 0.5%, surplus are water.By the printing assistant and B8 of the above ingredient
Auxiliary agent is compared as shown in table 5:
Table 5
Scheme is compared above, and K/S Value Data is as shown in table 6
Table 6
Embodiment 2
Use equipment: starching machine, Mei Jiani printing machine, share rapid steamer (7# technique)
Use fabric: 100% cloth of real silk
Printing assistant: be made of following component by weight percentage: ammonium sulfate 2.5%, acetic acid 2%, urea 10%,
UNI 1%, guar gum 1%, AP defoaming agent 0.1%, AR reducing agent 0.5%, surplus are water.By the printing assistant of the above ingredient
It is compared with B8 auxiliary agent as shown in table 7:
Table 7
Scheme is compared above, and K/S Value Data is as shown in table 8
Table 8
Embodiment 3
Use equipment: starching machine, Mei Jiani printing machine, share rapid steamer (7# technique)
Use fabric: 100% nylon cloth
Printing assistant: be made of following component by weight percentage: ammonium sulfate 2.5%, acetic acid 2%, urea 10%,
UNI 1%, guar gum 1%, AP defoaming agent 0.1%, AR reducing agent 0.5%, surplus are water.By the printing assistant of the above ingredient
It is compared with B8 auxiliary agent as shown in table 9:
Table 9
Scheme is compared above, and K/S Value Data is as shown in table 10
Table 10
Above embodiments 1-3 process flow: the embodiment of the present invention 1 or embodiment 2 or embodiment 3 are added when perching → starching
The auxiliary agent (pick-up 80%-100%) → first time dries 90 DEG C of (resurgence control is shown in Table 11) → printing → second and dries
80 DEG C (resurgence control be shown in Table 12) → evaporate (103 DEG C * 30 minutes, humidity 80% or so) → cold water wash (twice) → 40-50 DEG C
Warm water soaps (alkaline condition) → and 40-50 DEG C of * 5 minutes fixation (PH control 5 or so) → 40-50 DEG C of warm water is washed → dry 130 DEG C
→ examine
Table 11
Raw material | Control resurgence (%) |
Wool/cashmere class | 14-20 |
Silk | 10-15 |
Nylon | 3-6 |
Table 12
Claims (8)
1. a kind of printing technology, which is characterized in that the printing assistant that a kind of printing technology uses, the stamp help
Agent consists of the following compositions by weight percentage: ammonium sulfate 1.5-2.5%, acetic acid 2%, urea 10%, UNI1%, cluster bean
Glue 1%, AP defoaming agent 0.1%, AR reducing agent 0.5%, surplus are water;
A kind of printing technology is comprised the following steps that using the printing assistant: perching, starching, is dried for the first time
Dry 90 DEG C, printing, second of 80 DEG C of drying is evaporated, and twice cold water is washed, and 40-50 DEG C of warm water is soaped, 40-50 DEG C fixation 5 minutes,
40-50 DEG C of warm water is washed, and 130 DEG C of drying-is examined, wherein the printing assistant is added in sizing process.
2. a kind of printing technology according to claim 1, which is characterized in that by following component group by weight percentage
At: ammonium sulfate 2%, acetic acid 2%, urea 10%, UNI1%, guar gum 1%, AP defoaming agent 0.1%, AR reducing agent 0.5%,
Surplus is water.
3. a kind of printing technology according to claim 1, which is characterized in that by following component group by weight percentage
At: ammonium sulfate 2.5%, acetic acid 2%, urea 10%, UNI1%, guar gum 1%, AP defoaming agent 0.1%, AR reducing agent
0.5%, surplus is water.
4. a kind of printing technology according to claim 1, which is characterized in that when starching, pick-up 80%-100%.
5. a kind of printing technology according to claim 1, which is characterized in that in drying course, drying is controlled back for the first time
Tide: wool or cashmere 14-20%, silk 10-15%, nylon 3-6%.
6. a kind of printing technology according to claim 1, which is characterized in that in drying course, second of drying is controlled back
Tide: wool or cashmere 10-15%, silk 7-12%, nylon 2-4%.
7. a kind of printing technology according to claim 1, which is characterized in that it evaporates 103 DEG C of process 30 minutes, humidity 80 ±
2%.
8. a kind of printing technology according to claim 1, which is characterized in that pH controls 4.5-5.5 in laking process.
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CN201710540902.8A CN107287943B (en) | 2017-07-05 | 2017-07-05 | A kind of printing assistant and printing technology |
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CN107287943B true CN107287943B (en) | 2019-11-12 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000003080A1 (en) * | 1998-07-08 | 2000-01-20 | Ciba Specialty Chemicals Holding Inc. | Method for printing fibrous textile materials using the ink jet technique |
JP4513255B2 (en) * | 2002-12-03 | 2010-07-28 | セイコーエプソン株式会社 | Ink composition for inkjet printing, printing method, and printed fabric |
CN104233874A (en) * | 2013-06-17 | 2014-12-24 | 无锡市东新织造有限公司 | Digital printing process for wool fabric |
CN106049115A (en) * | 2016-03-31 | 2016-10-26 | 南通纺织丝绸产业技术研究院 | Method for preparing fabric through inkjet and discharge printing |
-
2017
- 2017-07-05 CN CN201710540902.8A patent/CN107287943B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000003080A1 (en) * | 1998-07-08 | 2000-01-20 | Ciba Specialty Chemicals Holding Inc. | Method for printing fibrous textile materials using the ink jet technique |
JP4513255B2 (en) * | 2002-12-03 | 2010-07-28 | セイコーエプソン株式会社 | Ink composition for inkjet printing, printing method, and printed fabric |
CN104233874A (en) * | 2013-06-17 | 2014-12-24 | 无锡市东新织造有限公司 | Digital printing process for wool fabric |
CN106049115A (en) * | 2016-03-31 | 2016-10-26 | 南通纺织丝绸产业技术研究院 | Method for preparing fabric through inkjet and discharge printing |
Non-Patent Citations (1)
Title |
---|
LYOPRINTAP在印花中解决印花鱼鳞斑的应用;乔学胜等;《染整技术》;20100320;第31卷(第3期);第46-48页 * |
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