CN105926319A - Active ink digital printing pretreating size for woolen fabric - Google Patents

Active ink digital printing pretreating size for woolen fabric Download PDF

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Publication number
CN105926319A
CN105926319A CN201610329186.4A CN201610329186A CN105926319A CN 105926319 A CN105926319 A CN 105926319A CN 201610329186 A CN201610329186 A CN 201610329186A CN 105926319 A CN105926319 A CN 105926319A
Authority
CN
China
Prior art keywords
active ink
agent
pretreatment slurry
digit printing
wool spinning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610329186.4A
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Chinese (zh)
Inventor
曹敬农
孙丽萍
陶晓华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Sunshine Group Co Ltd
Original Assignee
Jiangsu Sunshine Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Sunshine Group Co Ltd filed Critical Jiangsu Sunshine Group Co Ltd
Priority to CN201610329186.4A priority Critical patent/CN105926319A/en
Publication of CN105926319A publication Critical patent/CN105926319A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/628Compounds containing nitrogen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6491(Thio)urea or (cyclic) derivatives

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The invention discloses active ink digital printing pretreating size for a woolen fabric. The pretreating size is prepared from 0.5%-3% of modified starch, 2%-5% of urea, 1%-2% of ammonium sulfate, 0.2%-1.4% of a thickening agent, an acidity pH value regulator and the balance water, wherein the pH value of the pretreating size is 4-5, and the thickening agent is selected from at least one of sodium alginate, konjac glucomannan, xanthan gum, guar gum and carrageenan. According to the active ink digital printing pretreating size for the woolen fabric, chitosan in the prior art is replaced with the water-soluble thickening agent, the characteristics of being hydrophilic, capable of forming a film and high in stability of sodium alginate, konjac glucomannan, xanthan gum, guar gum, carrageenan and the like are utilized, paste materials in the fabric which is pretreated by the pretreating size, subjected to digital printing and steamed are easy to wash and remove, and the fabric free of residual paste materials is soft in handfeel.

Description

A kind of wool spinning fabric active ink digit printing pretreatment slurry
Technical field
The present invention relates to textile production technical field, be specifically related to a kind of wool spinning fabric active ink digit printing and locate in advance Reason slurry.
Background technology
Worsted fabric has the feel of sliding glutinous exquisiteness, soft gloss, excellent quality, the noble quality after dyeing or stamp Color and luster, is favored by consumers in general deeply.Digital ink-jet printed effective, environmental protection, therefore at textile printing industry development Rapidly, by the substantial amounts of stamp being applied to the high-grade fabrics such as cashmere, Pilus Caprae seu Ovis, real silk.But cashmere digit printing is raw at enterprise practical Product yet suffers from dyestuff imbibition is more serious, the clear fineness of decorative pattern not, vividness and the most high series of problems of tinctorial yield. The technical scheme improved adds chitosan in slurry, utilize chitosan to the electrostatic attraction of Pilus Caprae seu Ovis face table and anti-microbial property, The wool textile fabric through digit printing is made to have excellent anti-microbial property and color fastness.But, chitosan can not be directly dissolved in Water, can only be dissolved in some organic acid and mineral acid, and after being therefore unfavorable for stamp and decatize, the cleaning removal to thickener processes, meeting Fabric feel is made to harden.
Summary of the invention
It is an object of the invention to overcome defect present in prior art, it is provided that a kind of wool spinning fabric active ink is digital Stamp pretreatment slurry, the thickener in fabric after above-mentioned slurry processes readily washes off, little on the impact of fabric feel.
For realizing above-mentioned technique effect, the technical scheme is that a kind of wool spinning fabric active ink digit printing is pre- Process slurry, it is characterised in that including: modified starch 0.5~3%, carbamide 2~5%, ammonium sulfate 1~2%, thickening agent 0.2~ 1.4%, acidic pH adjustor and excess water, the pH value of pretreatment slurry is 4~5;Thickening agent is selected from sodium alginate, Rhizoma amorphophalli At least one in glucomannan, xanthan gum, guar gum, carrageenan.
Preferably technical scheme is, thickening agent is at least one in xanthan gum and carrageenan and konjak glucomannan Compositions, in described thickening agent, the percentage by weight of konjak glucomannan is 60~85%.
Preferably technical scheme is, acidic pH adjustor be in citric acid, acetic acid, malic acid and lactic acid at least A kind of.
Preferably technical scheme is also to include moisture absorption cosolvent 3~7% in pretreatment slurry.
Preferably technical scheme is that moisture absorption cosolvent is at least one in glycerol and 2,2'-ethylenedioxybis(ethanol)..
Preferably technical scheme is also to include at least in penetrating agent, waterproofing agent and migration inhibitor in pretreatment slurry Kind.
Preferably technical scheme is that penetrating agent is phosphoric acid-2-Octyl Nitrite;Waterproofing agent is AG710 waterproofing agent;Anti-migration Agent is CAM-2 antishifting agent.
Advantages of the present invention and having the beneficial effects that:
In the present invention, wool spinning fabric active ink digit printing pretreatment slurry uses water miscible thickening agent to substitute prior art In chitosan, utilizing that sodium alginate, konjak glucomannan, xanthan gum, guar gum, carrageenan etc. are hydrophilic can film forming, heat The feature that stability is high, in the fabric after this pretreatment slurry pretreatment, digit printing, decatize, thickener cleans and removes simply, Fabric feel without thickener residual is soft glutinous.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is further described.Following example are only used for more Add and clearly demonstrate technical scheme, and can not limit the scope of the invention with this.
Embodiment 1
For realizing above-mentioned technique effect, wool spinning fabric active ink digit printing pretreatment slurry in embodiment 1, including: degeneration Starch 0.5%, carbamide 2%, ammonium sulfate 1%, thickening agent 0.2%, acidic pH adjustor and excess water, the pH value of pretreatment slurry is 4;Thickening agent is sodium alginate.
Acidic pH adjustor is citric acid.
Pretreatment slurry also includes moisture absorption cosolvent 3%.
Moisture absorption cosolvent is glycerol.
Pretreatment slurry also includes penetrating agent, waterproofing agent and migration inhibitor.
Penetrating agent is phosphoric acid-2-Octyl Nitrite;Waterproofing agent is AG710 waterproofing agent;Migration inhibitor is CAM-2 antishifting agent.
Embodiment 2
Embodiment 2 is distinguished as with embodiment 1:
The composition of wool spinning fabric active ink digit printing pretreatment slurry includes: modified starch 3%, carbamide 5%, ammonium sulfate 2%, Thickening agent 1.4%, acidic pH adjustor and excess water, the pH value of pretreatment slurry is 5;
Thickening agent is the compositions of xanthan gum and konjak glucomannan, the percentage by weight of konjak glucomannan in thickening agent It is 85%.
Acidic pH adjustor is acetic acid.
Pretreatment slurry also includes moisture absorption cosolvent 7%.
Moisture absorption cosolvent is 2,2'-ethylenedioxybis(ethanol)..
Pretreatment slurry also includes penetrating agent, waterproofing agent and migration inhibitor.
Penetrating agent is phosphoric acid-2-Octyl Nitrite;Waterproofing agent is AG710 waterproofing agent;Migration inhibitor is CAM-2 antishifting agent.
Embodiment 3
Embodiment 3 is distinguished as with embodiment 1:
The composition of wool spinning fabric active ink digit printing pretreatment slurry includes: modified starch 1.75%, carbamide 3.5%, sulphuric acid Ammonium 1.5%, thickening agent 0.8%, acidic pH adjustor and excess water, the pH value of pretreatment slurry is 4.5;
Thickening agent is the compositions in carrageenan with konjak glucomannan, the weight percent of konjak glucomannan in thickening agent Ratio is 85%.
Acidic pH adjustor citric acid and the mixing of acetic acid 1:1.
Pretreatment slurry also includes moisture absorption cosolvent 5%.
Moisture absorption cosolvent is glycerol and the mixing of 2,2'-ethylenedioxybis(ethanol). 1:1.
Pretreatment slurry also includes penetrating agent, waterproofing agent and migration inhibitor.
Penetrating agent is phosphoric acid-2-Octyl Nitrite;Waterproofing agent is AG710 waterproofing agent;Migration inhibitor is CAM-2 antishifting agent.
Embodiment 4
Embodiment 4 is with the difference of embodiment 3: thickening agent is the compositions in carrageenan with konjak glucomannan, thickening In agent, the percentage by weight of konjak glucomannan is 73%.
Comparative example
Comparative example uses chitosan as thickening agent, and consumption is same as in Example 3, and other constituent contents are with embodiment 3.
The addition of penetrating agent, waterproofing agent and migration inhibitor can improve thickener respectively to the infiltration wettability of fabric and minimizing Dyestuff imbibition phenomenon in digital dyeing course.
On manual landing slab, scrape starching with 80 eye mesh screens, scrape 6~8 cuttves, it is desirable to do not reveal the exact details, web surface fine hair Docile is on surface.Dry temperature 100 DEG C, then use the active ink of technical grade that fabric is carried out spray printing, be specially by color Card generates Software Create cyan (C:100, M:0, Y:0, K:0), red (C:0, M:100, Y:0, K:0), Huang Color (C:0, M:0, Y:100, K:0) prints respectively.Print conditions is: two-way, 4 passages, then drying, steaming Change (102 DEG C, 20~30 min), cold water is washed, neutrality is soaped, cold water is washed and drying and processing, obtains digit printing dyestuff.
After testing, the de-paste rate of embodiment 1-4 is respectively 85.2%, 87.6%, 89.2%, 90.1%, and the de-paste of comparative example Rate is 81.5%, main reason is that have adsorptivity and cohesive between chitosan and wool fiber or blend fibre, neutral Washing cannot be removed.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, on the premise of without departing from the technology of the present invention principle, it is also possible to make some improvements and modifications, these improvements and modifications Also should be regarded as protection scope of the present invention.

Claims (7)

1. a wool spinning fabric active ink digit printing pretreatment slurry, it is characterised in that including: modified starch 0.5~3%, Carbamide 2~5%, ammonium sulfate 1~2%, thickening agent 0.2~1.4%, acidic pH adjustor and excess water, the pH value of pretreatment slurry It is 4~5;Thickening agent is at least in sodium alginate, konjak glucomannan, xanthan gum, guar gum, carrageenan Kind.
Wool spinning fabric active ink digit printing pretreatment slurry the most according to claim 1, it is characterised in that thickening agent For the compositions of at least one in xanthan gum and carrageenan Yu konjak glucomannan, in described thickening agent, konjac mannan gathers The percentage by weight of sugar is 60~85%.
Wool spinning fabric active ink digit printing pretreatment slurry the most according to claim 1, it is characterised in that acid pH Value regulator is at least one in citric acid, acetic acid, malic acid and lactic acid.
Wool spinning fabric active ink digit printing pretreatment slurry the most according to claim 1, it is characterised in that pretreatment Slurry also includes moisture absorption cosolvent 3~7%.
Wool spinning fabric active ink digit printing pretreatment slurry the most according to claim 4, it is characterised in that moisture absorption helps Solvent is at least one in glycerol and 2,2'-ethylenedioxybis(ethanol)..
Wool spinning fabric active ink digit printing pretreatment slurry the most according to claim 1, it is characterised in that pretreatment Slurry also includes at least one in penetrating agent, waterproofing agent and migration inhibitor.
Wool spinning fabric active ink digit printing pretreatment slurry the most according to claim 6, it is characterised in that penetrating agent For phosphoric acid-2-Octyl Nitrite;Waterproofing agent is AG710 waterproofing agent;Migration inhibitor is CAM-2 antishifting agent.
CN201610329186.4A 2016-05-18 2016-05-18 Active ink digital printing pretreating size for woolen fabric Pending CN105926319A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108166252A (en) * 2018-01-05 2018-06-15 苏州经贸职业技术学院 A kind of digit printing cotton pretreatment agent and preparation method thereof
WO2018184394A1 (en) * 2017-04-07 2018-10-11 黄庄芳容 Padding liquid for use in nylon fabric wet transfer printing and preparation method therefor
CN108755193A (en) * 2018-06-07 2018-11-06 浙江瑞灿科技有限公司 Colorant and its production technology for fleece fabrics digit printing
CN108914647A (en) * 2018-05-28 2018-11-30 江苏阳光股份有限公司 A kind of wool fabric printing paste composition and preparation method thereof
CN109056379A (en) * 2018-08-06 2018-12-21 江苏联宏纺织有限公司 A kind of wool fabric reactive dye digit printing pretreatment slurry and printing technology
WO2019242669A1 (en) * 2018-06-22 2019-12-26 双键化工股份有限公司 Fabric pre-treatment agent, digital jet printer, and digital jet printing method using same
CN112111983A (en) * 2020-08-26 2020-12-22 浙江真爱毯业科技有限公司 Preparation method of digital printing blanket
CN112981989A (en) * 2021-02-26 2021-06-18 杭州华丝夏莎纺织科技有限公司 Printing and dyeing additive and method for dyeing real silk/viscose composite fabric
CN113914121A (en) * 2020-07-08 2022-01-11 柯尼卡美能达株式会社 Ink set for ink jet textile printing and ink jet textile printing method

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018184394A1 (en) * 2017-04-07 2018-10-11 黄庄芳容 Padding liquid for use in nylon fabric wet transfer printing and preparation method therefor
CN108166252A (en) * 2018-01-05 2018-06-15 苏州经贸职业技术学院 A kind of digit printing cotton pretreatment agent and preparation method thereof
CN108914647A (en) * 2018-05-28 2018-11-30 江苏阳光股份有限公司 A kind of wool fabric printing paste composition and preparation method thereof
CN108755193A (en) * 2018-06-07 2018-11-06 浙江瑞灿科技有限公司 Colorant and its production technology for fleece fabrics digit printing
WO2019242669A1 (en) * 2018-06-22 2019-12-26 双键化工股份有限公司 Fabric pre-treatment agent, digital jet printer, and digital jet printing method using same
CN109056379A (en) * 2018-08-06 2018-12-21 江苏联宏纺织有限公司 A kind of wool fabric reactive dye digit printing pretreatment slurry and printing technology
CN113914121A (en) * 2020-07-08 2022-01-11 柯尼卡美能达株式会社 Ink set for ink jet textile printing and ink jet textile printing method
CN113914121B (en) * 2020-07-08 2024-02-13 柯尼卡美能达株式会社 Ink set for inkjet printing and inkjet printing method
CN112111983A (en) * 2020-08-26 2020-12-22 浙江真爱毯业科技有限公司 Preparation method of digital printing blanket
WO2022042551A1 (en) * 2020-08-26 2022-03-03 浙江真爱毯业科技有限公司 Digital printed blanket production method
CN112981989A (en) * 2021-02-26 2021-06-18 杭州华丝夏莎纺织科技有限公司 Printing and dyeing additive and method for dyeing real silk/viscose composite fabric

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Application publication date: 20160907

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