CN107287679A - A kind of fishing net with good dyeability - Google Patents
A kind of fishing net with good dyeability Download PDFInfo
- Publication number
- CN107287679A CN107287679A CN201710581039.0A CN201710581039A CN107287679A CN 107287679 A CN107287679 A CN 107287679A CN 201710581039 A CN201710581039 A CN 201710581039A CN 107287679 A CN107287679 A CN 107287679A
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- Prior art keywords
- nylon
- fishing net
- diatomaceous earth
- good dyeability
- master batch
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of fishing net with good dyeability, it is related to fishing net technical field, a kind of fishing net with good dyeability is made up of following component:Activated diatomaceous earth and nylon 6 mixing master batch, polyamide fibre, basalt fibre, nano silicon, plasticizer, polyethylene, acrylamide, metatitanic acid matter coupling agent, filler;A kind of fishing net with good dyeability of the present invention, not only with good comprehensive mechanical property, its dyeing rate is fast, and upper dye amount is high.
Description
Technical field
The invention belongs to fishing net technical field, and in particular to a kind of fishing net with good dyeability.
Background technology
Fishing net is the net of fishing, and men of old uses coarse cloth, as raw material, fishnet to be made by the method for tying volume plus fiber crops.
Although this fishing net is perishable, toughness is poor, and it is fished efficiency and greatly improved.With the development of fishery, fishing and hunting
Object is more than fish, and the instrument fished for also grows with each passing hour.Men of old uses coarse cloth plus fiber crops as raw material, the method by tying volume
Fishnet is made.Although this fishing net is perishable, toughness is poor, and it is fished efficiency and greatly improved.With the hair of fishery
Exhibition, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.
Modern fishing net is mainly processed using polyethylene, the raw material such as nylon, there is longer usage cycles, and higher is caught
Efficiency is dragged for, according to the demand in market, the fishing net of nylon 6 is needed to carry out different dyeing processing, its performance is improved, but it is existing
Some fishing net dyeings of nylon 6, the dyeability of the fishing net of nylon 6 is general, during dyed on dye amount it is relatively low, contaminate
Color degree is shallow.
The content of the invention
The purpose of the present invention is that there is provided a kind of fishing net with good dyeability the problem of being directed to existing.
The present invention is achieved by the following technical solutions:
A kind of fishing net with good dyeability, is made up of following component by weight:Activated diatomaceous earth and nylon 6 mixing
Master batch 100-110, polyamide fibre 6-10, basalt fibre 2-4, nano silicon 0.5-0.7, plasticizer 1.5-2.0, polyethylene 2-
4th, acrylamide 0.2-0.5, metatitanic acid matter coupling agent 0.1-0.3, filler 5-10;
The activated diatomaceous earth presses 1-3 with nylon 6 mixing master batch by activated diatomaceous earth and nylon 6:After the mixing of 60-70 mass ratios
It is added to extruding pelletization in extruder to be made;
The basalt fibre is 1 with polyethylene mass ratio:1.
Further, the activated diatomaceous earth preparation method is:Diatomite is calcined into 30min at 500 DEG C, it is then natural
Room temperature is cooled to, then the absolute ethyl alcohol of its quality 10% is added into diatomite, after stirring, 2-3 hours are ground, so
After be dried, cross 1200 mesh, then ultrasonic disperse is into deionized water, stirred 1.5 hours with 500r/min rotating speeds, stood
10min, is made diatomite suspension slurry, then add the sodium hydroxide of diatomite quality 0.5%, 0.35% acrylic acid and 0.12%
Nonionic surfactant, be heated to 95 DEG C, stir 3 hours, be then centrifuged, be dried under vacuum to moisture content extremely
10-12%, then crushed, 1200 mesh are crossed, are produced.
Further, the nonionic surfactant is high-carbon fatty alcohol polyoxyethylene ether.
Further, the activated diatomaceous earth and nylon 6 mixing master batch by activated diatomaceous earth mixed with nylon 6 after be added to
Extruding pelletization is made specially in extruder:Activated diatomaceous earth, nylon 6 are added in single screw extrusion machine by proportioning and extruded,
Feeding section to die temperature is followed successively by 190 DEG C, 200 DEG C, 210 DEG C, 210 DEG C, and screw speed is 150r/min, is granulated, and is obtained
To activated diatomaceous earth and nylon 6 mixing master batch.
Further, the plasticizer is diisononyl phthalate.
Further, the nano silicon granularity is 50-60nm.
Further, filler is sericite in powder, and the sericite in powder granularity is 1000 mesh.
The present invention has advantages below compared with prior art:The present invention is by diatomaceous activation process, enabling to
These diatomite have higher ion exchange capacity and good adsorption capacity, can at normal temperatures and pressures, with ion and salt
Class and partial organic substances, form intricately diatomite inorganic complex and diatomite organic complex, and diatomite crystal grain is thin
It is small, with larger external surface area, simultaneously because interfloor distance is increased and interlaminar action power weakens, in water or the work of other solvents
Can be expanded, peeled off with lower interlayer, be cleaved into thinner monocrystalline lamella, make diatomite have bigger specific surface area, by
Under alkalescence condition, acrylic acid and high-carbon fatty alcohol polyoxyethylene ether collaboration activation form activated centre, can further improve
Porosity between diatomaceous physicochemical structure, increase diatomaceous earth particle, then by the way that the diatomite after activation is entered with nylon 6
Row blending granulation, enables to diatomite to carry out intercalation in the molecule of nylon 6, and scattered is more uniform, passes through activated diatomaceous earth
The fishing net being made with nylon 6 mixing master batch can significantly improve its dyeability, and dye molecule can be entered more easily
In diatomaceous earth particle hole, by the synergy of acrylamide, dye molecule can be promoted to be combined with diatomaceous earth particle, carried
Its high adhesion, can not only also significantly improve dye amount, simultaneously as activation silicon to fishing net dyeing kinetics are improved
The active function of diatomaceous earth, can uniform fishing net molecular weight, improve fishing net molecular structure, improve the comprehensive mechanical property of fishing net.
Embodiment
Embodiment 1
A kind of fishing net with good dyeability, is made up of following component by weight:Activated diatomaceous earth and nylon 6 mixing
Master batch 100, polyamide fibre 6, basalt fibre 2, nano silicon 0.5, plasticizer 1.5, polyethylene 2, acrylamide 0.2, metatitanic acid
Matter coupling agent 0.1, filler 5;
The activated diatomaceous earth presses 1 with nylon 6 mixing master batch by activated diatomaceous earth and nylon 6:Added after the mixing of 60 mass ratios
Into extruder, extruding pelletization is made;
The basalt fibre is 1 with polyethylene mass ratio:1.
Further, the activated diatomaceous earth preparation method is:Diatomite is calcined into 30min at 500 DEG C, it is then natural
Room temperature is cooled to, then the absolute ethyl alcohol of its quality 10% is added into diatomite, after stirring, 2 hours are ground, then
It is dried, crosses 1200 mesh, then ultrasonic disperse is into deionized water, is stirred 1.5 hours with 500r/min rotating speeds, stands 10min,
Be made diatomite suspension slurry, then add the sodium hydroxide of diatomite quality 0.5%, 0.35% acrylic acid and 0.12% it is non-from
Sub- surfactant, is heated to 95 DEG C, stirs 3 hours, is then centrifuged, is dried under vacuum to moisture content to 10-12%,
Crushed again, cross 1200 mesh, produce.
Further, the nonionic surfactant is high-carbon fatty alcohol polyoxyethylene ether.
Further, the activated diatomaceous earth and nylon 6 mixing master batch by activated diatomaceous earth mixed with nylon 6 after be added to
Extruding pelletization is made specially in extruder:Activated diatomaceous earth, nylon 6 are added in single screw extrusion machine by proportioning and extruded,
Feeding section to die temperature is followed successively by 190 DEG C, 200 DEG C, 210 DEG C, 210 DEG C, and screw speed is 150r/min, is granulated, and is obtained
To activated diatomaceous earth and nylon 6 mixing master batch.
Further, the plasticizer is diisononyl phthalate.
Further, the nano silicon granularity is 50nm.
Further, filler is sericite in powder, and the sericite in powder granularity is 1000 mesh.
Embodiment 2
A kind of fishing net with good dyeability, is made up of following component by weight:Activated diatomaceous earth and nylon 6 mixing
Master batch 110, polyamide fibre 10, basalt fibre 4, nano silicon 0.7, plasticizer 2.0, polyethylene 4, acrylamide 0.5, metatitanic acid
Matter coupling agent 0.3, filler 10;
The activated diatomaceous earth presses 3 with nylon 6 mixing master batch by activated diatomaceous earth and nylon 6:Added after the mixing of 70 mass ratios
Into extruder, extruding pelletization is made;
The basalt fibre is 1 with polyethylene mass ratio:1.
Further, the activated diatomaceous earth preparation method is:Diatomite is calcined into 30min at 500 DEG C, it is then natural
Room temperature is cooled to, then the absolute ethyl alcohol of its quality 10% is added into diatomite, after stirring, 3 hours are ground, then
It is dried, crosses 1200 mesh, then ultrasonic disperse is into deionized water, is stirred 1.5 hours with 500r/min rotating speeds, stands 10min,
Be made diatomite suspension slurry, then add the sodium hydroxide of diatomite quality 0.5%, 0.35% acrylic acid and 0.12% it is non-from
Sub- surfactant, is heated to 95 DEG C, stirs 3 hours, is then centrifuged, is dried under vacuum to moisture content to 12%, then enter
Row is crushed, and is crossed 1200 mesh, is produced.
Further, the nonionic surfactant is high-carbon fatty alcohol polyoxyethylene ether.
Further, the activated diatomaceous earth and nylon 6 mixing master batch by activated diatomaceous earth mixed with nylon 6 after be added to
Extruding pelletization is made specially in extruder:Activated diatomaceous earth, nylon 6 are added in single screw extrusion machine by proportioning and extruded,
Feeding section to die temperature is followed successively by 190 DEG C, 200 DEG C, 210 DEG C, 210 DEG C, and screw speed is 150r/min, is granulated, and is obtained
To activated diatomaceous earth and nylon 6 mixing master batch.
Further, the plasticizer is diisononyl phthalate.
Further, the nano silicon granularity is 60nm.
Further, filler is sericite in powder, and the sericite in powder granularity is 1000 mesh.
Embodiment 3
A kind of fishing net with good dyeability, is made up of following component by weight:Activated diatomaceous earth and nylon 6 mixing
Master batch 105, polyamide fibre 8, basalt fibre 3, nano silicon 0.6, plasticizer 1.8, polyethylene 3, acrylamide 0.3, metatitanic acid
Matter coupling agent 0.2, filler 8;
The activated diatomaceous earth presses 5 with nylon 6 mixing master batch by activated diatomaceous earth and nylon 6:Added after the mixing of 68 mass ratios
Into extruder, extruding pelletization is made;
The basalt fibre is 1 with polyethylene mass ratio:1.
Further, the activated diatomaceous earth preparation method is:Diatomite is calcined into 30min at 500 DEG C, it is then natural
Room temperature is cooled to, then the absolute ethyl alcohol of its quality 10% is added into diatomite, after stirring, 2.5 hours are ground, so
After be dried, cross 1200 mesh, then ultrasonic disperse is into deionized water, stirred 1.5 hours with 500r/min rotating speeds, stood
10min, is made diatomite suspension slurry, then add the sodium hydroxide of diatomite quality 0.5%, 0.35% acrylic acid and 0.12%
Nonionic surfactant, be heated to 95 DEG C, stir 3 hours, be then centrifuged, be dried under vacuum to moisture content extremely
11%, then crushed, 1200 mesh are crossed, are produced.
Further, the nonionic surfactant is high-carbon fatty alcohol polyoxyethylene ether.
Further, the activated diatomaceous earth and nylon 6 mixing master batch by activated diatomaceous earth mixed with nylon 6 after be added to
Extruding pelletization is made specially in extruder:Activated diatomaceous earth, nylon 6 are added in single screw extrusion machine by proportioning and extruded,
Feeding section to die temperature is followed successively by 190 DEG C, 200 DEG C, 210 DEG C, 210 DEG C, and screw speed is 150r/min, is granulated, and is obtained
To activated diatomaceous earth and nylon 6 mixing master batch.
Further, the plasticizer is diisononyl phthalate.
Further, the nano silicon granularity is 55nm.
Further, filler is sericite in powder, and the sericite in powder granularity is 1000 mesh.
Comparative example 1:The common untreated diatom that activated diatomaceous earth is replaced with to equivalent is differed only in embodiment 1
Soil.
Comparative example 2:Differed only in embodiment 1 and activated diatomaceous earth and nylon 6 mixing master batch are replaced with into activation diatom
Soil is mixed with the master batch General Physics of nylon 6.
Comparative example 3:Differed only in embodiment 1 without acrylamide.
Experiment
Using infrared high-temperature overflow dyeing machine, dyestuff is cationic red 5BL, and the fishing net of the embodiment to equivalent and comparative example enters respectively
Row dyeing, bath raio is 1:50, dyeing condition is:50 DEG C enter dye, and 2 DEG C of heating per minute, to 90 DEG C of stoppings, being cooled to 60 DEG C
Fishing net surface loose colour 15min is cleaned, is dried at 60 DEG C to constant weight, it is close using ultraviolet specrophotometer test dyeing stoste light
Degree, records dye liquor raffinate absorbance, and amount of dye is contaminated on the fishing net for calculating dyeing time 2min, 5min and 10min:
Table 1
Amount of dye mg/g is contaminated on the fishing net of 2min nylon 6 | Amount of dye mg/g is contaminated on the fishing net of 5min nylon 6 | Amount of dye mg/g is contaminated on the fishing net of 10min nylon 6 | |
Embodiment 1 | 6.68 | 16.12 | 24.10 |
Embodiment 2 | 6.62 | 16.08 | 24.03 |
Embodiment 3 | 6.59 | 16.05 | 24.06 |
Comparative example 1 | 4.52 | 12.36 | 18.17 |
Comparative example 2 | 3.12 | 10.25 | 15.34 |
Comparative example 3 | 5.89 | 14.76 | 22.67 |
Control group | 2.15 | 4.67 | 8.86 |
Control group is:The fishing net of nylon 6 is made using the common untreated master batch of nylon 6 to be dyed;
As can be seen from Table 1, the present invention cooperates with the effect energy of acrylamide by using activated diatomaceous earth with nylon 6 mixing master batch
The upper dye amount of dye of fishing net is enough significantly improved, the dyeability of fishing net is improved.
Claims (7)
1. a kind of fishing net with good dyeability, it is characterised in that be made up by weight of following component:Activate diatom
Soil and nylon 6 mixing master batch 100-110, polyamide fibre 6-10, basalt fibre 2-4, nano silicon 0.5-0.7, plasticizer
1.5-2.0, polyethylene 2-4, acrylamide 0.2-0.5, metatitanic acid matter coupling agent 0.1-0.3, filler 5-10;
The activated diatomaceous earth presses 1-3 with nylon 6 mixing master batch by activated diatomaceous earth and nylon 6:After the mixing of 60-70 mass ratios
It is added to extruding pelletization in extruder to be made;
The basalt fibre is 1 with polyethylene mass ratio:1.
2. a kind of fishing net with good dyeability according to claim 1, it is characterised in that the activated diatomaceous earth
Preparation method is:Diatomite is calcined into 30min at 500 DEG C, room temperature is then naturally cooled to, then adds into diatomite its matter
The absolute ethyl alcohol of amount 10%, after stirring, is ground 2-3 hours, is then dried, and crosses 1200 mesh, then ultrasonic disperse is arrived
In deionized water, stirred 1.5 hours with 500r/min rotating speeds, stand 10min, diatomite suspension slurry is made, then add diatom
The sodium hydroxide of soil property amount 0.5%, 0.35% acrylic acid and 0.12% nonionic surfactant, are heated to 95 DEG C, stirring 3
Hour, then it is centrifuged, is dried under vacuum to moisture content to 10-12%, then crushed, 1200 mesh are crossed, are produced.
3. a kind of fishing net with good dyeability according to claim 2, it is characterised in that the non-ionic surface
Activating agent is high-carbon fatty alcohol polyoxyethylene ether.
4. a kind of fishing net with good dyeability according to Claims 2 or 3, it is characterised in that the activation silicon
Diatomaceous earth and nylon 6 mixing master batch by activated diatomaceous earth mixed with nylon 6 after be added to extruding pelletization in extruder and be made specially:
By activated diatomaceous earth, nylon 6 by proportioning be added in single screw extrusion machine extrude, feeding section to die temperature be followed successively by 190 DEG C,
200 DEG C, 210 DEG C, 210 DEG C, screw speed is 150r/min, is granulated, and obtains activated diatomaceous earth and nylon 6 mixing master batch.
5. a kind of fishing net with good dyeability according to claim 1, it is characterised in that the plasticizer is neighbour
Phthalic acid dinonyl.
6. a kind of fishing net with good dyeability according to claim 1, it is characterised in that the nanometer titanium dioxide
Silicon grain degree is 50-60nm.
7. a kind of fishing net with good dyeability according to claim 1, it is characterised in that filler is sericite
Powder, the sericite in powder granularity is 1000 mesh.
Priority Applications (1)
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CN201710581039.0A CN107287679A (en) | 2017-07-17 | 2017-07-17 | A kind of fishing net with good dyeability |
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CN201710581039.0A CN107287679A (en) | 2017-07-17 | 2017-07-17 | A kind of fishing net with good dyeability |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108691025A (en) * | 2018-04-11 | 2018-10-23 | 巢湖市瀚海渔具有限公司 | A kind of fishing net of the ester modified far-infrared ceramic powder filled nylon of sulfonic acid |
CN111171451A (en) * | 2020-02-26 | 2020-05-19 | 佛山市永信功成塑料有限公司 | High-strength wear-resistant plastic bottle material |
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CN101067245A (en) * | 2007-06-12 | 2007-11-07 | 江苏盛虹化纤有限公司 | Fishing nylon |
CN104562249A (en) * | 2014-06-30 | 2015-04-29 | 巢湖市翔宇渔具有限公司 | Fishing net wire molding process |
CN104562287A (en) * | 2014-06-25 | 2015-04-29 | 巢湖市荷花渔网有限公司 | Formula of fishing thread |
CN105754263A (en) * | 2016-04-14 | 2016-07-13 | 巢湖市荷花渔网有限公司 | High-toughness antibacterial fishing net |
CN105801973A (en) * | 2016-04-14 | 2016-07-27 | 巢湖市荷花渔网有限公司 | Antifouling fishing net |
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2017
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CN101067245A (en) * | 2007-06-12 | 2007-11-07 | 江苏盛虹化纤有限公司 | Fishing nylon |
CN104562287A (en) * | 2014-06-25 | 2015-04-29 | 巢湖市荷花渔网有限公司 | Formula of fishing thread |
CN104562249A (en) * | 2014-06-30 | 2015-04-29 | 巢湖市翔宇渔具有限公司 | Fishing net wire molding process |
CN105754263A (en) * | 2016-04-14 | 2016-07-13 | 巢湖市荷花渔网有限公司 | High-toughness antibacterial fishing net |
CN105801973A (en) * | 2016-04-14 | 2016-07-27 | 巢湖市荷花渔网有限公司 | Antifouling fishing net |
Non-Patent Citations (3)
Title |
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SHU-CHUAN LIAO ET AL: "Surface Graft Polymerization of Acrylamide onto Plasma Activated Nylon Microfiber Artificial Leather for Improving Dyeing Properties", 《INTERNATIONAL JOURNAL OF CHEMICAL ENGINEERING AND APPLICATIONS》 * |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108691025A (en) * | 2018-04-11 | 2018-10-23 | 巢湖市瀚海渔具有限公司 | A kind of fishing net of the ester modified far-infrared ceramic powder filled nylon of sulfonic acid |
CN111171451A (en) * | 2020-02-26 | 2020-05-19 | 佛山市永信功成塑料有限公司 | High-strength wear-resistant plastic bottle material |
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Application publication date: 20171024 |