CN1072815A - The agricultural chemical preparations that can on the water surface, move and sprawl - Google Patents
The agricultural chemical preparations that can on the water surface, move and sprawl Download PDFInfo
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- CN1072815A CN1072815A CN92114250A CN92114250A CN1072815A CN 1072815 A CN1072815 A CN 1072815A CN 92114250 A CN92114250 A CN 92114250A CN 92114250 A CN92114250 A CN 92114250A CN 1072815 A CN1072815 A CN 1072815A
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- preparaton
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The agricultural chemical preparations that can on the water surface, move and sprawl, its composition is the core that particle is formed, and its each apparent specific gravity is coated with the agricultural chemicals active matter less than 1 on it, also be coated with a kind of material, the interfacial tension between air and the water reduced by means of oily mater.
Description
The present invention relates to the agricultural chemical preparations that can on the water surface, move and sprawl,, still can move and spread on the whole water surface, therefore, active substance can be discharged in the water in rice field quickly and evenly even be applied on the local water surface.
General its form of the agricultural chemical preparations of using in the rice field has dust agent, particle, wettable powder, mobile concentrating agents, water solube powder, water-soluble liquid, emulsion or the like.
Recently, labour and environmental protection are quite paid attention to saving in the present technique field, so use the graininess preparaton being on the increase.But under the situation of using granule, the diffusion of contained active matter or distribution speed are still limited in each.The result is that when using these preparatons, agricultural author has to often in the rice field.
In recent years, save the labour during people's strong request dispenser, so urgent insecticide-applying way of wishing that development is following, for example low dose of dispenser (dispersion volume is a per hectare 30-10 kilogram), mechanical type dispenser and " big part (the jumbo) " preparaton that is used to throw dispenser.
The big part preparaton of throwing dispenser just stood on the ridge that the fritter rice field forms medicament thrown into fritter Tanaka being used to of having developed, and its active matter is evenly distributed in the water in rice field.
More detailed saying, the test that these preparatons carried out is to use the tablets, spherical dose of weight 100 or 50 grams, the forms such as particle of filling, formulated together active matter and aqueous solvent and/or foaming agent in these parts, they are dispersed in the water in rice field easily.
But, such preparation is compared with conventional formula granule, and in fact the former needs the longer time just active matter to be dispersed in the water in rice field, otherwise they can not distribute equably all over the monoblock rice field area, consequently make the effect performance insufficient, or cause dunsiekte.
As above-mentioned, the so-called big part preparaton that is used to throw dispenser originally is intended to save the labour, but the difficulty of being met is to be difficult to make active matter to scatter fast and equably in paddy field water either, provides solution so this area urgently is required to be this difficult problem.
At an above-mentioned difficult problem, the present inventor has successfully finished the present invention through going deep into broad research, and the Agrotechnical formulation that use can be moved when floating on the water surface in rice field, thereby can disperse equably and spread all over the whole surface in this piece rice field.
Therefore, the present invention relates to the agricultural chemical preparations that can move and sprawl at the water surface, its composition is the core that particle is formed, its each apparent specific gravity is less than 1, be coated with the agricultural chemicals active matter on it, also be coated with a kind of material, the interfacial tension between air and the water reduced by means of oily mater; Or this preparaton wrapped up with water-solubility membrane, be bundled into every 10 to 200 gram; Or, make for example plate-like, column, positive parallelepiped and cube this preparaton shaping.
(annotate: above-mentioned apparent specific gravity is different with bulk specific weight, and the former is that the quality (gram) with a particle with internal pore space is a denominator, is that denominator is tried to achieve with the volume that comprises this internal pore space.）
Say that more specifically in preparation of the present invention, this surfactant is not on the whole surface attached to particle cores, but is attached on its part surface, so the interfacial tension that changes with direction takes place in the water in the external world.Therefore, the preparation that is applied in the rice field moved at the water surface of resistance less than the inside of water before this, thereby the effect that preparation disperses to side direction takes place, and active matter dissolves to water from water surface then, is dispersed throughout this piece field until them.
That is to say that mode of the present invention is not that point from the surface, rice field disperses, but from the whole area generation peptizaiton in this piece field, thereby active matter thoroughly and is effectively distributed.
The person of advancing, because self exclusive mobility of this preparaton, can be in the some dispenser in a rice field, thus realize processing to all surfaces.
When throwing preparaton of the present invention in the rice field, single preparation granules moves with at random direction at the water surface, because contained interfacial tension reducing agent is dissolved in the water in the preparation, the result makes those particles scatter quickly and evenly at the rice field water surface.
That is to say, when preparation moves on the water surface, the agricultural chemicals active matter is disperseed and be dissolved in the water.Because to disengage active matter from preparaton rather quick, even its particle cores is to stay on the water surface and owing to wind-force drifts about, that in a moment active matter disengage already so that any inhomogeneous broadening effect can not take place, so can avoid taking place the dunsiekte problem.
Preparaton of the present invention is considered from its carrying operation and dispersibility, serves as preferred with the graininess formulation, but if consider to have flow behavior in the water, then can be mixed with and spread dust agent, fine grained, tablet or the like.
Preparation of the present invention can be with the former state preparation to jettisoning or to use giver by hand.Also can be packaged in them in the water-soluble bag, bag is thrown in the rice field.In addition, also can use the preparation of tablet and so on.Preparation light pressure the in mould that is about to scheduled volume forms.
Agricultural chemicals active matter used in the preparation of the present invention is not limited to specific kind, but can be exemplified below:
(1) 2-[4-morpholinodithio-2-base oxygen base-N-methyl phenylacetamide,
(2) α-(4,6-dimethoxypyridin-2-base carbamoyl sulfamoyl)-0-toluic acid methyl esters,
(3) 1-(α, α-Er Jiajibianji)-the 3-(p-methylphenyl) urea,
(4) 5-(4,6-dimethoxypyridin-2-base carbamoyl sulfamoyl)-1-methylpyrazole-4-carboxylic acid, ethyl ester,
(5) 2-isopropyl phenyl-N-methyl carbamate,
(6) 1-(6-chloro-3-picolyl)-N-nitroimidazole alkane-2-inner salt neamine,
(7) 0,0-dimethyl-0-[3-methyl-4-(methyl mercapto) phenyl] thiophosphate,
(8) 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-the 2-butanone
(9) all-racemic-1-(biphenyl-4-base oxygen base)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl) fourth-2-alcohol,
(10) propylidene-two-zinc dithiocarbamate.
Above-listed agricultural chemicals active matter can use separately, is used by two kinds or multiple mixing when perhaps needing.
In the present invention, as the carrier that forms particle cores, its apparent specific gravity is less than 1, and that can mention for example has float stone, roasting perlite, roasting obsidian, roasting float stone, vermiculite, plastics, wax, wood chip and rubber, also be not limited to above-mentioned these.
What be used as in the present invention that interfacial tension reducing agent can mention for example has an alkylbenzenesulfonate, alkylnaphthalene sulfonate, alkylphosphonic, the polyoxyethylene alkyl ether, fatty glyceride, sorbitan fatty acid ester, alkyl sulfo succinate, lignosulphonates, napsylate-formaldehyde condensation products, alkylammonium salt, alkylamine salt, the alkyl glycinate, alanine salt, polysiloxane-polyether series activator, alkylaryl sulfonates, camphor or the like, but be not limited to above-listed person, they can use separately, or with two kinds or multiple mixture use, its blending ratio can be chosen wantonly.
In the present invention, used interfacial tension reducing agent can be heavy for 0.1-50%(), it is heavy to be preferably 1-20%(), being with the preparaton gross weight is benchmark.
In preparaton of the present invention, the oily mater that is used to apply active matter and interfacial tension reducing agent for example has: paraffin, glyceride, polyethylene glycol, polyvinyl alcohol, acrylic emulsions, natural or synthetic rubber, animal or plant grease, dextrin, butadiene bobbin oil, nylon, gelatin, sugar or the like, but also be not limited to above-listed person, they also can use separately, or two or multiple blending use.
In order to realize effective pesticide supplying effect, preparaton of the present invention can be processed into water-solubility membrane wraps up in packing of bag, each part 10-200 gram.
Be used as the water-solubility membrane of wrapping up in the packaging material material in the present invention, water-soluble poval, carboxymethyl cellulose, dextrin, starch, hydroxyethylcellulose are for example arranged.
Preparaton of the present invention can be mold formed, is placed in the mould by every 10-200 gram material, heats then and/or suppress, and makes the molded preparaton of big part.Molded like this preparaton shape can be a dish type, and cylindricality, positive parallelepiped, cube are not limited to above-listed shape but be used for the present invention.
When molded, can use following material as binding agent, but be not limited to these kinds:
Polyethylene glycol, sugar, natural rubber, polyvinyl alcohol, synthetic rubber or the like.
Below be by embodiments of the invention, but be not limiting the scope of the invention.
Preparaton example 1
Agricultural chemicals active matter (1) 10.0%(is heavy)
Sodium alkyl benzene sulfonate 2.0%(is heavy)
Atoleine 8.0%(is heavy)
Float stone 80.0%(is heavy)
In disc type dressing machine, atoleine is absorbed in the float stone, coat agricultural chemicals active matter (1) and Powdered sodium alkyl benzene sulfonate then thereon, become preparaton.
Preparaton example 2
Agricultural chemicals active matter (1) 10.0%(is heavy)
NaLS 2.0%(is heavy)
Bobbin oil 2.0%(is heavy)
Roasting perlite 86.0%(is heavy)
Water-soluble poval film (as wrapping up in the packaging material material)
In disc type dressing machine, bobbin oil is absorbed in the roasting perlite, coat agricultural chemicals active matter (1) and Powdered NaLS then thereon, become preparaton.Relatively large made preparaton is wrapped up with the water-soluble poval film.
Preparaton example 3
Agricultural chemicals active matter (1) 10.0%(is heavy)
Sorbitan fatty acid ester 2.0%(is heavy)
Soybean oil 2.0%(is heavy)
Water-soluble poval 2.0%(is heavy)
Vermiculite 84.0%(is heavy)
In disc type dressing machine, soybean oil is absorbed in the vermiculite, coat agricultural chemicals active matter (1), Powdered sorbitan fatty acid ester and water-soluble poval then thereon, become preparaton.Relatively large preparaton is placed in the mould, is heated to 80 ℃, with about 5 kilograms/square centimeter pressure compacting, form molded preparaton simultaneously.
Comparison example 1
Agricultural chemicals active matter (1) 10.0%(is heavy)
Bobbin oil 2.0%(is heavy)
Roasting perlite 88.0%(is heavy)
In disc type dressing machine, bobbin oil is absorbed in the roasting perlite, coat the agricultural chemicals active matter then thereon, make preparaton.The relatively large preparaton of making is packed with the water-soluble poval film, become the preparaton of packing.
Comparison example 2
Agricultural chemicals active matter 10.0%(is heavy)
Sodium alkyl benzene sulfonate 0.5%(is heavy)
Powdered bentonite 30.0%(is heavy)
Clay powders 59.5%(is heavy)
Agricultural chemicals active matter (1) is mixed with above-mentioned other components, knead to wherein adding water then.The product that to knead with extruder pushes and granulates, and uses the fluidized bed dryer drying then, becomes particle.
Annotate: above-mentioned agricultural chemicals active matter (1) is 2-[4-morpholinodithio-2-base oxygen base-N-methyl phenylacetamide.
Below be experimental example:
Test examples 1(distributed test)
As shown in Figure 1, with a concrete sump, 4.1 meters of its length, wide 2.6 meters are put into the about 7.5 centimetres bottle of 7 diameters as barrier, and Xiang Chizhong pours 500 premium on currency into, makes about 5 centimetres of the depth of water.Be thrown into the preparaton (every 6.0 gram) of packing then in the pond, it is and wrap up in bag person prepared by example 2 and comparison example 1.Measure the active matter deployment conditions then as follows, promptly by the time interval in the regulation site (1 to 6, as shown in Figure 1) get the water sample of scheduled volume, measure the concentration of this active matter.Gained the results are shown in table 1, and the unit of concentration numerical value is ppm.
Table 1
| Elapsed time (minute) | |
|||||
| 1 | 3 | 4 | ||||
| Formulation examples 2 | Comparison example 1 | Formulation examples 2 | Comparison example 1 | Formulation examples 2 | Comparison example 1 | |
| 0 10 20 30 60 120 240 | 0 1.29 1.51 1.49 0.93 0.91 1.04 | 0 1.68 1.03 1.11 1.16 1.25 1.01 | 0 0.33 1.03 0.94 1.10 1.13 0.98 | 0 0.10 0.28 0.31 0.32 0.58 0.35 | 0 0.15 0.55 1.02 0.88 0.82 0.98 | 0 0 0 0.04 0.04 0.05 0.14 |
Test examples 2(distributed test)
Press the same way as of test examples 1, difference is to use the preparaton of comparison example 2 to test.The results are shown in table 2, gained concentration numerical value is ppm.
Table 2
| Elapsed time (minute) | |
|||||
| 1 | 3 | 4 | ||||
| Formulation examples 2 | Comparison example 1 | Formulation examples 2 | Comparison example 1 | Formulation examples 2 | Comparison example 1 | |
| 0 10 20 30 60 120 240 | 0 0.72 1.11 0.12 1.16 1.01 1.00 | 0 0.31 0.13 0.14 0.19 0.82 0.86 | 0 0.89 0.95 0.91 1.05 1.00 1.04 | 0 0.21 0.23 0.32 0.37 0.65 0.66 | 0 0.17 2.05 1.73 1.62 1.28 1.18 | 0 0.16 0.16 0.14 0.16 0.15 0.28 |
Can see that from above form when being used for test examples and throwing in the rice field by preparaton of the present invention, sprawl rapidly and evenly, other preparaton examples also reach similar effect on the whole surface in this piece field.In addition, dunsiekte not taking place, can expect to reach complete and satisfied result.
As mentioned above, preparaton of the present invention reaches excellent in the spreading ability of the rice field water surface, therefore must the middle body of preparation throwing in a rice field only do not needed throw near the ridge between the fritter rice field, can carry out extermination of disease and insect pest work the gross area in this piece rice field.
Fig. 1 is test examples 1 and 2 millpond peace face figure, and wherein P is the site of throwing in preparaton, and (1) to (6) is the site of collecting water sample.The distance that a to e represents in the pond (rice) is as follows:
A=0.5 rice
B=1.0 rice
C=1.5 rice
D=2.6 rice
E=4.1 rice
Be barrier, use 500 milliliters of vials, about 7.5 centimetres of each bottle diameter.
Claims (3)
1, the agricultural chemical preparations that can on the water surface, move and sprawl, its composition is the core that particle is formed, and its each apparent specific gravity is coated with the agricultural chemicals active matter less than 1 on it, also be coated with a kind of material, the interfacial tension between air and the water reduced by means of oily mater.
2, the agricultural chemical preparations of claim 1, wherein said preparaton are by water-solubility membrane parcel member, and the amount of each part is the 10-200 gram.
3, the agricultural chemical preparations of claim 1, wherein said preparaton are through shaping, and its formed thereby shape comprises plate-like, column, positive parallelepiped and cube.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP348549/91 | 1991-12-06 | ||
| JP3348549A JPH05155703A (en) | 1991-12-06 | 1991-12-06 | Preparation of traveling agent on water surface |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1072815A true CN1072815A (en) | 1993-06-09 |
Family
ID=18397765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92114250A Pending CN1072815A (en) | 1991-12-06 | 1992-12-05 | The agricultural chemical preparations that can on the water surface, move and sprawl |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPH05155703A (en) |
| KR (1) | KR930011812A (en) |
| CN (1) | CN1072815A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1104194C (en) * | 1994-08-04 | 2003-04-02 | 三共株式会社 | Granular agrochemical formulations |
| CN1105495C (en) * | 1994-08-04 | 2003-04-16 | 三共株式会社 | granular carriers and granular agrochemical formulations |
| CN1292654C (en) * | 2000-08-08 | 2007-01-03 | 拜尔作物科学有限公司 | Floating type formulation of agricultural agents |
| CN105707068A (en) * | 2016-01-26 | 2016-06-29 | 刘圣泉 | Pesticide for being sprayed by unmanned plane and preparation method thereof |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05163102A (en) * | 1991-12-12 | 1993-06-29 | Mikasa Kagaku Kogyo Kk | Agricultural chemical for paddy field and its production |
| JPH07233002A (en) * | 1993-12-28 | 1995-09-05 | Takeda Chem Ind Ltd | Agrochemical formulation |
| US5833733A (en) * | 1995-05-12 | 1998-11-10 | Nihon Bayer Agrochem K.K. | Agrochemical formulations for water surface application |
| JP3535429B2 (en) * | 1998-12-25 | 2004-06-07 | 三共アグロ株式会社 | Pesticide composition for water application |
| TW200503616A (en) * | 2003-04-30 | 2005-02-01 | Syngenta Participations Ag | Process for the preparation of a pesticidal formulation |
| JP2020075909A (en) * | 2018-10-11 | 2020-05-21 | 三井化学アグロ株式会社 | Agrochemical composition for submerged application |
| KR102175634B1 (en) * | 2019-02-18 | 2020-11-06 | (주)쿠첸 | Cooker improving operation stability and operating method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5399327A (en) * | 1977-02-04 | 1978-08-30 | Nissan Chem Ind Ltd | Pesticide preparations for water surface spreading use |
| JPS5822122B2 (en) * | 1979-04-17 | 1983-05-06 | 日本農薬株式会社 | How to control planthoppers and leafhoppers |
| JPS5865203A (en) * | 1981-10-12 | 1983-04-18 | Mikasa Kagaku Kogyo Kk | Composition containing physioligically active substance that floats on water surface |
| JP2870042B2 (en) * | 1988-09-13 | 1999-03-10 | 武田薬品工業株式会社 | Waterborne suspended solid pesticide formulation |
| JPH05194105A (en) * | 1991-09-25 | 1993-08-03 | Sankyo Co Ltd | Agricultural chemical composition and its application |
-
1991
- 1991-12-06 JP JP3348549A patent/JPH05155703A/en active Pending
-
1992
- 1992-12-02 KR KR1019920023050A patent/KR930011812A/en not_active Application Discontinuation
- 1992-12-05 CN CN92114250A patent/CN1072815A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1104194C (en) * | 1994-08-04 | 2003-04-02 | 三共株式会社 | Granular agrochemical formulations |
| CN1105495C (en) * | 1994-08-04 | 2003-04-16 | 三共株式会社 | granular carriers and granular agrochemical formulations |
| CN1292654C (en) * | 2000-08-08 | 2007-01-03 | 拜尔作物科学有限公司 | Floating type formulation of agricultural agents |
| CN105707068A (en) * | 2016-01-26 | 2016-06-29 | 刘圣泉 | Pesticide for being sprayed by unmanned plane and preparation method thereof |
| CN105707068B (en) * | 2016-01-26 | 2018-05-18 | 刘圣泉 | A kind of pesticide sprayed for unmanned plane and preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| KR930011812A (en) | 1993-07-20 |
| JPH05155703A (en) | 1993-06-22 |
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