CN1076166C - Granular moth-proofing material - Google Patents
Granular moth-proofing material Download PDFInfo
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- CN1076166C CN1076166C CN94120720A CN94120720A CN1076166C CN 1076166 C CN1076166 C CN 1076166C CN 94120720 A CN94120720 A CN 94120720A CN 94120720 A CN94120720 A CN 94120720A CN 1076166 C CN1076166 C CN 1076166C
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Abstract
To obtain a non-bulky insecticidal material for wool products utilizing the paper powder of waste material, extracted grounds of coffee extracted solution and tea dregs as a carrier for an insecticide, especially for transpiring empenthrin. This granular insecticidal material is obtained by forming at least one waste material selected from extracted grounds of coffee extracted solution, tea dregs and paper powder of waste material, a highly water-absorbing resin in an amount smaller than that of the waste material and an insecticide into a granular state. The granular insectional material is alternatively obtained by forming a granulated part containing at least one waste material selected from extracted grounds of coffee extracted solution, tea dregs and paper powder of waste material and a highly water-absorbing resin in an amount smaller than that of the waste material and a coating layer part which covers the surface of the granulated part and contains an insecticide into a granular state. Further, an insecticide map be added to the granulated part to give a granular insecticidal material.
Description
The present invention relates to a kind of granular moth-proofing material that utilizes waste material and make, particularly relate to a kind of to fiber, as the effective granular moth-proofing material of wool fibre.In addition, the present invention relates to a kind ofly can be widely used in the protective hair goods, avoid the granular moth-proofing material of harmful insect as wool fabric, particularly a kind of civilian granular moth-proofing material with moisture-proof characteristic to its infringement.
When storing wool fabric, the favorable moth-proof agent that common use can distil as camphor, naphthalene and paracide, is avoided insect pest with the protective hair fabric.These favorable moth-proof agent all produce a kind of special niff, harmful insect is produced the respiration inhibition effect, these insects, as the moth (Attagenus japonicus REITTER) and the erythema eye moth (Anthrenus verbasci LINNE) of little clothes moth (Tineola bisselliella HUMMEL), clothes moth (Tinea), felt casting skin, and these insects had the effect of dispersing.In addition, known synthetic pyrethroid as insect disinfestation component is because be used warm-blooded animal is harmless relatively, and it has the contact toxicity effect to these insects.Also have, also used to be mixed with volatile medicine empenthrin (empenthrin) paper and nonwoven fibrous web, they are placed in the drawer in cabinet to prevent that the thing in the cabinet from being encroached on by above-mentioned insect.This volatile medicine is tasteless, and its acting duration longer than dichloro-benzenes, in addition its concentration very low also be like this.
In above-mentioned favorable moth-proof agent, the favorable moth-proof agent of distillation is used with its mold pressing form, and the persistence of its favorable moth-proof effect is subjected to packing the influence of sealing of their container usually, for example distillation fully in container, and its persistence is a some months.Owing to this reason, the favorable moth-proof agent of these distillations needs to replenish through new favorable moth-proof agent commonly used.
In addition, the time that the effect of volatile medicine empenthrin continues is longer relatively, but it needs carrier (as paper or adhesive-bonded fabric) to wrap up.This carrier should have high absorbing power and suitable softness.Therefore, the carrier that is mixed with the volatile medicine empenthrin should be placed in the plastic container, thereby the problem of this favorable moth-proof agent is the significant proportion that the required cost of container accounts for favorable moth-proof agent price.
On the other hand, demand to beverage increases day by day at present, coffee beverage for example, as listening packed coffee beverage and instant coffee beverage, tea beverage as listening packed tea beverage and instant tea beverage, comes thus, after refining, these beverages then remain a large amount of corresponding refinement residues, as coffee grounds and tealeaf residue.Therefore need sizable expense to carry out its post processing or processing, this also is a very important problem to be solved in beverage industry.Particularly coffee grounds contains a large amount of fat that can only disappear and ruin with fire, and this has caused air pollution.
Cut the waste paper that forms behind the commercial paper and perforation waste paper that commercial paper perforation is formed also is very a large amount of with cutter mill, this waste paper also is used for disappearing ruining with certain cost equally.
In tissue industry, because the increase of paper handkerchief demand equally also produces a large amount of powdery waste paper in preparation paper handkerchief process.Also have, this powdery waste paper intractable is because it contains the resin of the not usefulness with high-hydroscopicity.Therefore, this powdery waste paper also disappears with fire with certain cost and ruins and go out of use, and this also is a problem to be solved.
Also have, in the sawmilling process, can produce a large amount of scoots, as the sawdust of wood chip and/or arhat cypress (Thujopsis dolabrata lumber).Therefore yet this Thujopsis dolabrata (hiba) oil has favorable moth-proof and antisepsis, and this culled wood is difficult to rot, and is also difficult, because so, this scoot itself disappears with fire with certain cost too and ruins and discard, and this also becomes a problem.
The present invention attempts to solve above-mentioned problem about waste material post processing and processing, as coffee grounds, tealeaf residue, paper scrap and the scoot that produces by the arhat cypress, and the related problem of moth-proofing material commonly used.
Therefore, the purpose of this invention is to provide a kind of moth-proofing material, it can effectively utilize waste material, it is paper scrap, coffee grounds and tealeaf residue carrier as the favorable moth-proof agent, the carrier of volatile medicine empenthrin particularly, it can be made into the moth-proofing material of woollen goods or analog, and it is non-loose.
According to the present invention, a kind of granular moth-proofing material is provided, it contains at least a waste material that is selected from coffee grounds, tealeaf residue and paper scrap, and a kind of content is less than the resin with high-hydroscopicity and the favorable moth-proof agent of this waste material content, and this material is made into granular; A kind of granular moth-proofing material is provided, it comprises granulation part and contains the favorable moth-proof agent and be coated on the coating layer portion of this granulation part surface, and this granulation partly contains at least a waste material that is selected from coffee grounds, tealeaf residue and paper scrap and a kind of content resin with high-hydroscopicity less than this waste material content; A kind of granular moth-proofing material also is provided; it comprises granulation part and contains the favorable moth-proof agent and be coated on the coating layer portion of this granulation part surface, and this granulation partly contains at least a resin with high-hydroscopicity and a kind of favorable moth-proof agent that is selected from the waste material of coffee grounds, tealeaf residue and paper scrap, a kind of content less than this waste material content.
According to the present invention, a kind of granular moth-proofing material also is provided, it comprises the granulation part and is coated on the coating layer portion of this granulation part surface, this granulation partly contains at least a waste material that is selected from coffee grounds, tealeaf residue and paper scrap and the content resin with high-hydroscopicity less than this waste material content, and this coating layer portion contains the wood chip and the favorable moth-proof agent of chamenol or Thujopsis dolabrata (hiba) oil; A kind of granular moth-proofing material is provided; it comprises the granulation part and is coated on the coating layer portion of this granulation part surface; this granulation partly contains at least a the be selected from waste material of coffee grounds, tealeaf residue and paper scrap, a kind of resin and a kind of favorable moth-proof agent with high-hydroscopicity content less than this waste material content, and this coating layer portion contains wood chip and a kind of favorable moth-proof agent of chamenol or arhat pitch.
In the present invention, this moth-proofing material is made into granular.More specifically say, this moth-proofing material contains resin with high-hydroscopicity and the favorable moth-proof agent less than this waste material content of at least a waste material that is selected from coffee grounds, tealeaf residue and paper scrap, content, as volatile medicine empenthrin, naphthalene, camphor or paracide, they are made into granular.In the present invention; this pelletized product contains at least a waste material that is selected from coffee grounds, tealeaf residue and paper scrap, the content mixture less than the resin with high-hydroscopicity of this waste material content and favorable moth-proof agent by water is joined, and then this mixture granulation is made.
In addition, in the present invention, this mode of moth-proofing material is made into granular, and promptly the granular moth-proofing material of gained contains and makes granular part, i.e. granulation part and be coated on the coating layer portion that contains the favorable moth-proof agent of this granulation part surface.In the present invention; this granular part contains at least a waste material that is selected from coffee grounds, tealeaf residue and paper scrap, the content mixture less than the resin with high-hydroscopicity of this waste material content and favorable moth-proof agent by water is joined, and then this mixture granulation is made.
Here can use anti-insect component as the composition of the coating layer portion of moth-proofing material, for example favorable moth-proof agent, as volatile medicine empenthrin, naphthalene, camphor and paracide, and preferred volatile medicine empenthrin is as the favorable moth-proof agent.When being attached to solid-state favorable moth-proof agent in the moth-proofing material, with this favorable moth-proof agent itself and waste material (being coffee grounds, tealeaf residue or paper scrap) or have the mixed with resin of high-hydroscopicity and combine, when being attached to the agent of volatility favorable moth-proof in this material, at first be with the agent of volatility favorable moth-proof, be dissolved in as empenthrin and obtain its solution in the solvent, then with gained solution spraying waste material or have the resin of high-hydroscopicity, perhaps waste material or resin are dipped in this solution to mix and ooze with this solution.
In addition, moth-proofing material of the present invention is made into granular, and therefore, the preferred use contained the wood chip of chamenol or arhat pitch and the combination of favorable moth-proof agent empenthrin, and this favorable moth-proof agent is as the anti-insect component of coating layer portion.In the present invention, can obtain the wood chip of Thujopsis dolabrata or Japanese cypress wood from sawmill, they are ground into the particle with the sizing of giving, and as the wood chip that contains chamenol or arhat pitch.In this situation, its particle size is more preferably less than 0.3mm preferably less than 0.5mm.This wood chip can be obtained by waste material, i.e. the wood chip of the Thujopsis dolabrata of sawmill or Japanese cypress wood, and correspondingly, the cost of making moth-proofing material has reduced.
The wood chip that contains chamenol or arhat pitch that combines with the favorable moth-proof agent that the present invention uses has deodorizing and favorable moth-proof performance, and distributes pleasant smell.Therefore, when using wood chip and favorable moth-proof agent, during as the combination of volatile medicine empenthrin, preferentially make coating layer portion, because this wood chip has the effect of anti-insect (as the camphor tree dung beetle), present bactericidal action and deodorization, produce pleasant smell, and help of the favorable moth-proof effect of gained moth-proofing material insect.As discussed above, if make coating layer portion with volatile medicine empenthrin and the mixture that contains the wood chip of chamenol or arhat pitch, then can obtain having the granular moth-proofing material of strong favorable moth-proof effect, it is for a long time sustainable, and have bactericidal action and deodorization simultaneously, and produce pleasant smell.This can reduce the consumption of volatile medicine empenthrin, but and also any generation of mould fungus inhibition.Being used for volatile medicine empenthrin of the present invention is a kind of synthetic plan desinsection chrysanthemum ester, with arriving chemical formulation down:
It is the favorable moth-proof component with contact toxicity effect, but it is harmless relatively to warm-blooded animal.Therefore, it has been widely used as the favorable moth-proof agent.
Under the damp condition of 25-30 ℃ temperature and 50-80%, can be increased usually by the quantity of the woollen goods that above-mentioned insect damaged.Therefore, the preferred moisture absorption of coating layer portion of moth-proofing material of the present invention, preventing any generation of mould, and reduce humidity in the drawer of cabinet.For this purpose, preferably calcium chloride, sodium chloride and silica gel are attached in the coating layer portion as hygroscopic agent among the present invention.
In the present invention, can prevent the generation of any mould of lay up period with the moth-proofing material drying so that its moisture content is reduced to less than 10% (weight).
In the present invention, the resin with high-hydroscopicity is used to strengthen the characteristic of the inhibition water of moth-proofing material, also is molded into super fatting agent effect in the granular process at mixture, and it is combined with coffee grounds, tealeaf residue, paper scrap or their mixture.In this respect; resin with high-hydroscopicity can be anyly can make the resin of making lubricant in coffee grounds, tealeaf residue, paper scrap or their the mixture granulation in granulator; preferred usage amount is counted less than 20% (weight) with the gross weight of the granular part of gained, particularly less than 10% (weight).
In the present invention, the water that the resin with high-hydroscopicity that is used for moth-proofing material granulation part exists by absorbing material granulation part surrounding environment and water is kept here and expanded, therefore, resin can be used for controlling the humidity of surrounding environment.
According to the present invention, the resin with high-hydroscopicity that combines with moth-proofing material is the resin that can keep its original shape, even tens to about 200 times amount of water, still keep its original shape when what absorbed himself weight, its special example comprises the copolymer of saponification of vinyl esters and ethylenically unsaturated carboxylic acids or their derivative, starch and acrylic acid graft polymers: polyacrylic cross-linking products; Vinyl alcohol and acrylic acid copolymer; The partial hydrolysate of polyacrylonitrile; The cross-linking products of carboxymethyl cellulose: the cross-linking products of polyethylene glycol: the salt of chitosan and amylopectin glue, they can single use or at least two kinds be used in combination.
In the present invention, those resins that can use the water imbibition difference are as resin Composition, and promptly the water absorption rate factor is less than 200g/g, and these resins can not use (being substandard products) as having super absorbent resin usually.The substandard products of the polyacrylic resin of this water imbibition difference can obtain by the waste product in the towel products technology is classified, or those non-compliant polyacrylic resin products.
Being used for coffee grounds and the tealeaf residue that uses with waste product of the present invention is produced by beverage production process; and have high absorbing capacity, these beverages are as instant coffee, tinned coffee, fast thawing tea and tinned tea; therefore, they give the granulation part of gained with deodorization.In addition, can obtain from the tissue industry waste product as the paper scrap of a kind of use in the waste product, it has high-hydroscopicity.Therefore, because use can reduce the used content with super absorbent resin from the paper scrap of tissue industry waste product.
In the present invention, the amount that is used in the wood chip that contains chamenol or arhat pitch in the coating layer portion is no less than 10% (weight), preferably is no less than 20% (weight), and purpose is in order to increase the effect of anti-insect material.
Gross weight with granulation part is a base, the granulation that is attached to moth-proofing material of the present invention in partly the coffee grounds that uses with waste product or the amount ranges of tealeaf residue be 10-30% (weight), be preferably 17-23% (weight).In addition, the paper scrap consumption that uses with waste product is restricted to 75% (weight) that is not more than the granulation part.Paper scrap as waste product has hygroscopicity, therefore, if its content increases, then makes the moth-proofing material of gained have hygroscopicity and moisture resistance.
In the present invention, for coating layer portion has deodorizing and moisture-proof characteristic, Smellnark (trade name is produced by Tokai Kosan Co.Ltd) and/or flavonoids can be joined coating layer portion as deodorant, and propane diols is joined coating layer portion as wetting agent.
The granulation goods of moth-proofing material of the present invention are preserved less than being dry state for 10% time in humidity at lay up period, therefore, preferably remove the fine powder part of granulation part, as particle size less than those of 3mm, to prevent the generation of powder at lay up period.
In the present invention; material with bonding effect can be attached in the granulation part; be bonded to each other together with the particle of coffee grounds, tealeaf residue or the paper scrap that will use with waste product and resin particle with high-hydroscopicity; so that these particle agglomeration become bulk form, and prevent the efflorescence in actual use of this blocky-shaped particle.This class examples of material with bonding effect comprises the water-soluble of paper grade (stock) or water dispersible paper pulp, papermaking body refuse, the paper pulp waste material that contains activated carbon, paper pulp body refuse, gelatin, vinyl esters and zeolite, considers from product cost, preferred waste material.These materials can use separately or with any combination form.In addition, this material can be the pure soluble material with bonding effect equally, as hydroxyethylcellulose (HEC), hydroxypropyl cellulose (HPC) and polyvinylpyrrolidone (PVP).These pure soluble materials can separately or be used in combination equally.
The consumption that is attached to the material with bonding effect in the granular moth-proofing material of the present invention is not more than 10% (weight), preferably is not more than 5% (weight), is base with the gross weight of the granulation of moth-proofing material part.At least two kinds combination of each or they with these materials of bonding effect can join in the mixture of raw material or in the granulation goods; perhaps; before the mixed material process or before the raw material granulation, join in the raw material, therefrom adhesives is joined in the granulation part or coating layer portion of granular moth-proofing material.
In addition, in the present invention, the dry and granulation goods of the coffee grounds that uses with waste product itself have adsorption capacity, but the clothes in the wardrobe can be permeated by caf.Reason for this reason, when coffee grounds being attached in the granular moth-proofing material of the present invention, preferably will have absorbefacient material is attached in the moth-proofing material, has absorbefacient examples of substances for containing activated carbon paper pulp waste material, black wooden carbon filtrate waste material as the auxiliary deodorant of conduct in the tobacco, its consumption is not more than 5% (weight), and purpose is that the caf that clothes adsorbs is reduced as much as possible.
The granulation of moth-proofing material of the present invention part is granulated into different shape by the mixture that uses granulator and will contain coffee grounds, tealeaf residue and/or the paper scrap that uses with waste product and have a resin of high-hydroscopicity, as sphere, prismatic, particulate and granular and make.For this purpose, Chang Yong known extruding granulator can be used as this granulator.Yet, also can be with other various granulators, as plate shape, tubular and fluid bed shape granulator.In these granulators; preferably cover the surface of the granulation part that makes thus with first coating material; the volatile medicine empenthrin is bonded on the surface of granulation part being convenient to, this first coating material contains hygroscopic agent, has super absorbent resin and paper scrap or contains chamenol or the wood chip of arhat pitch.Further, second coating material that contains paper scrap and wood chip mixture can be formed on or be bonded on the first coating material coating, with performance volatile medicine empenthrin and the effect that contains the wood chip of chamenol or arhat pitch, i.e. the former favorable moth-proof and bactericidal action and the latter's anti-insect effect.The wood chip that contains chamenol or arhat pitch that exists on the granulation product surface can prevent the generation of its lip-deep any mould in for a long time.
In the present invention; when the coating layer portion that covers the granulation part contains the volatile medicine empenthrin and contains the wood chip of chamenol or arhat pitch; at first the volatile medicine empenthrin is sticked to the surface of granulation part by spraying; contain the wood chip of chamenol or arhat pitch and the mixture of paper scrap in its surface sprinkling then; perhaps; use wetting agent; surface as the moistening granulation goods of polyvinyl alcohol; spray the wood chip that contains chamenol or arhat pitch then; perhaps; volatile medicine empenthrin and above-mentioned wood chip are dispersed in the suspension; spray this granulation product surface with suspension then, simultaneously these components are bonded on the surface thus.If use contains the wood chip of chamenol or arhat pitch and the mixture of paper scrap applies the granulation goods, then the wood chip content in the mixture is preferably adjusted to and is not less than 50% (weight), more preferably 60-70% (weight).Be used for of the present inventionly containing the wood chip of chamenol or arhat pitch and the particle size of paper scrap is not more than 0.5mm, preferably be not more than 0.3mm.If first and second coating materials are adhered to the surface of granulation of the present invention part, these coatings should be designed to that they are difficult for being stripped from dry processing procedure subsequently.
Moth-proofing material of the present invention contains and at least aly is selected from the waste material of coffee grounds, tealeaf residue and paper scrap, a kind of resin and favorable moth-proof agent with high-hydroscopicity, and is made into granular.Further; granular moth-proofing material of the present invention can be designed to following form; promptly comprise granulation part and the coating layer portion that is coated on this granulation part surface; this granulation partly contains at least a the be selected from waste material of coffee grounds, tealeaf residue and paper scrap, a kind of resin and conduct favorable moth-proof agent of component arbitrarily with high-hydroscopicity; this coating layer portion contains the favorable moth-proof agent identical or different with aforementioned favorable moth-proof agent, to replenish the favorable moth-proof effect of granulation part.Also have, in insect protected material of the present invention, the volatile medicine empenthrin that will contain as the favorable moth-proof agent is applied to the granulation product surface that particle size is not less than 3mm with the coating layer portion that contains the wood chip of chamenol or arhat pitch.Therefore, this moth-proofing material has in for a long time being harmful to repulsion and the killing action as the insect of wool fibre or fabric, particularly to the favorable moth-proof effect of wool fabric, this is because as the favorable moth-proof effect of the volatile medicine empenthrin of favorable moth-proof agent and contain chamenol or the sterilization of the wood chip of arhat pitch and favorable moth-proof effect.In addition, granular because moth-proofing material of the present invention will be made, thereby be easy to very much the material with hygroscopic effect, deodorization and waterproof action of any amount is attached in this moth-proofing material.Thereby be easy to control suitably the atmosphere and the humidity of the clothes surrounding environment of storing, thereby reduce these clothes by degree that insect damaged.
Also have, granular by moth-proofing material of the present invention is made, the present invention can farthest utilize combustible waste, and as paper scrap, coffee grounds and tealeaf residue, they produce in large quantities and its processing is a problem.Therefore, this moth-proofing material has also farthest utilized the effect of these waste materials, and as adsorption capacity, and its post processing or dispose also is very easy to because used moth-proofing material only contain combustible.
In the present invention, because it is granular, thereby the material with bonding effect is incorporated in the moth-proofing material at an easy rate.Therefore, join in the moth-proofing material, then can avoid any efflorescence in the actual use of this moth-proofing material effectively if will have the material of bonding effect.Also have, if this moth-proofing material also presents adsorption capacity, the deodorant in joining coating layer portion has the deodorization, and this material also has deodorization, promptly absorbs the smell of clothes, and prevents that clothes is subjected to any insect pest.Also have, the wood chip that contains chamenol or arhat pitch that is used for moth-proofing material of the present invention also has bactericidal action.Therefore, this moth-proofing material also has the effect that suppresses any mould generation, and correspondingly can use for a long time, can store clothes for a long time.
Because moth-proofing material of the present invention is made into granular, the present invention can use waste material as the favorable moth-proof agent, and as the carrier of volatile medicine empenthrin, these waste materials produce in manufacturing process in a large number, as paper scrap, super absorbent resin and coffee grounds, they become the difficult problem of processing.Therefore, moth-proofing material of the present invention is compared inexpensive with moth-proofing material commonly used, moth-proofing material commonly used is to use the favorable moth-proof agent, makes as volatile medicine empenthrin and those useful materials, or is contained in the moth-proofing material that could use afterwards in the bag for the favorable moth-proof purpose.
In addition, hygroscopic agent, deodorant and/or wetting agent can easily be incorporated in the moth-proofing material of the present invention, to give moth-proofing material with moisture absorption, deodorizing and damp proof effect.
In addition, the present invention farthest utilizes combustible waste, adsorption capacity as paper scrap, coffee grounds, tealeaf residue and Thujopsis dolabrata wood chip, these waste materials produce in a large number in process of production and it has been processed into a difficult problem, these waste materials by being used in combination with the favorable moth-proof agent as the raw material of moth-proofing material.Also have, all the components of this moth-proofing material all is combustible materials, so this can not cause the difficult problem of any processing.
Because it is granular that moth-proofing material of the present invention is made into, therefore the compounding ingredient that is easy to have bonding effect is attached in this moth-proofing material.This can significantly reduce the possibility of the crushing of this moth-proofing material in the actual use and efflorescence after this.Also have, the material with adsorption capacity can be attached in the moth-proofing material of the present invention.Therefore, different with moth-proofing material commonly used, moth-proofing material of the present invention has deodorization, therefore can absorb the smell that clothes produces, and can protect clothes to avoid the insect infringement thus.In addition, also bactericide can be joined in the moth-proofing material of the present invention.Any generation that this can prevent mould is different from moth-proofing material commonly used, and therefore this moth-proofing material can use for a long time and can guarantee for example storage of wool fabric.
Fig. 1 is for the schematic flow sheet of expression preparation moth-proofing material technology, as an example of the present invention.
Fig. 2 is for the schematic flow sheet of expression preparation moth-proofing material technology, as another example of the present invention.
Fig. 3 is for the schematic flow sheet of expression preparation moth-proofing material technology, as another example of the present invention.
Label implication among the figure is:
The quantitative hopper of 1-paper scrap
2-carries the conveyer belt of paper scrap
The quantitative hopper of 3-super absorbent resin
4-carries the conveyer belt of super absorbent resin
5-carries the discharge port end of the conveyer belt of paper scrap
6-carries the discharge port end of the conveyer belt of super absorbent resin
The 7-mixing arrangement
The mixture discharging opening of 8-mixing arrangement 7
0-carries the conveyer belt of mixture
10-pushes granulator
11-gives mixing arrangement
The 12-feed pipe
The 13-mould
14-garden shape sieve
15-carries the conveyer belt of granulation goods
The oversize grain discharging opening of 16-garden shape sieve 14
17-carries the conveyer belt of oversize grain
18-vibration particle size Selection device
The undersize particle discharging opening of 19-garden shape sieve 14
20-carries the conveyer belt by the undersize particle of garden shape sieve 14
The sieve of 21-vibration particle size Selection device 18
22-carries the conveyer belt by the undersize particle of sieve 21
The oversize grain discharging opening of 23-sieve 21
24-carries the conveyer belt of staying the oversize grain above the sieve 21
25-first applies the device of granulated product
The 26-sorter
27-second applies the device of granulated product
28-the 3rd applies the device of granulated product
29-is positioned at the sorter at the first coating granulated product device discharging opening place
30-is positioned at the sorter at the second coating granulated product device discharging opening place
31-first spray equipment
32-second spray equipment
33-the 3rd spray equipment
The hopper of 34-first sprayed coating
35-contains the container of coating solution
The hopper of 36-the 3rd sprayed coating
37-carries the conveyer belt of the granulated product that applies
The 38-drier
The discharging opening of 39-dry products
40-carries the conveyer belt of dry granulated product
41-abounds with the container of product
The conveyer belt of 42-conveying products
The 43-bagging area
44-carries the conveyer belt of high hydroscopic resin and benzoic acid mixture
The discharge port end of 45-conveyer belt 44
The quantitative hopper of 46-coffee grounds
47-carries the conveyer belt of coffee grounds
The discharge port end of 48-conveyer belt 47
Embodiment
Embodiment of the present invention are described in detail in detail below, but the present invention is not subjected to following explanation and specific
The restriction of embodiment.
Fig. 1 is that Fig. 2 is the flow chart for preparing moth-proofing material technology by another embodiment of the invention illustrative by the new schematic diagram of preserving material technology of one embodiment of the invention illustrative preparation.
In Fig. 1, the quantitative hopper 1 of paper scrap places on the conveying channel of conveyer belt 2, so that this paper scrap can be given conveyer belt 2 by feed.
In addition, the resin hopper 3 that will have a high-hydroscopicity is placed in the scope of conveying channel of conveyer belt 4, so that this resin can be given conveyer belt 4 by feed.In this embodiment, will be used for the discharging opening 5 of conveyer belt 2 of paper supply bits and the discharging opening 6 that is used for the conveyer belt 4 of confession super absorbent resin is connected with the charging aperture of mixing arrangement 7 respectively independently.Will by conveyer belt 2 and 4 runnings be transported to the paper scrap of mixing arrangement 7 and high hydroscopic resin mixes, and the discharging opening 8 by mixing arrangement 7 is transferred to the mixture of these paper scraps and high hydroscopic resin on the conveyer belt 9 that is positioned at the transmission mixture below the mixing arrangement 7.
For the mixture that provides by mixed-hopper 7 is provided; conveyer belt 9 is connected to the mixture discharging opening 8 of mixing arrangement 7 and by conveyer belt 9 runnings of carrying mixture the above-mentioned composition that mixes in mixing arrangement 7 is transferred in the pre-mixing apparatus 11 that pushes granulator 10, in pre-mixing apparatus 11 by the feed water mixture of paper scrap and high hydroscopic resin of feed pipe 12.The paper scrap and the super absorbent resin lipoprotein mixture of mixing water are incorporated in the extruding granulator 10, and are squeezed into the prismatic granulated product by mould 13.The pelletized product of carrying and shifting extruding is below garden shape is sieved the mould 13 that 14 conveyer belt 15 is placed in granulator 10.In this embodiment, the mesh of garden shape sieve 14 equals 4mm, stays oversize grain in the sieve and discharges and deliver to by the discharging opening 16 that is positioned at the sieve upside and transport on the conveyer belt 17 oversize grain, that connect discharging opening 16.
The conveyer belt 17 that transports oversize grain connects vibration particle size Selection device 18.Vibration particle size Selection device 18 unclamps agglomerate by vibration, to reduce the efflorescence of gained grain products between the actual operating period as far as possible.The running of oversize grain by conveyer belt 17 of staying in the sieve is sent in the vibration particle size Selection device 18.
The particle of undersize that on the other hand, can be by garden shape sieve 14 is returned to by the conveyer belt 20 that places the not enough particle of delivery size below the lower discharging opening 19 (be positioned at sieve below) and is used to carry the conveyer belt 9 of mixture to granulator 10.
The granulated product of transferring to vibration particle size Selection device 18 is by the released one-tenth of vibration effect of vibration particle size Selection device 18 single particle and discharge.In this embodiment; mesh is that the sieve 21 of 4mm is installed in vibration particle size Selection device 18 discharge port ends; connect to carry the conveyer belt 22 of the not enough particle of delivery size of mixture conveyer belt 9 to be placed in below the sieve 21 lower discharging openings, the particle of undersize that can be by sieve 21 turns back on the conveyer belt 9 of the conveying mixture that connects granulator 10 by the conveyer belt 22 of the not enough particle of delivery size.
In vibration particle size Selection device 18, the particle that particle size is not less than 4mm is transported by the conveyer belt 24 of carrying oversize grain, and this conveyer belt 24 connects the top discharge mouth 23 of sieve.Carry the discharging opening of the conveyer belt 24 of oversize grain to connect the sorter 26 that applies granulated product equipment 25 for the first time.
In vibration particle size Selection device 18; the particle that particle size is not less than 4mm is transported and deliver to connect by the conveyer belt 24 of the conveying oversize grain that connects sieve top discharge mouth 23 carries first of oversize grain conveyer belt 24 to apply the sorter 26 of granulated product equipment 25, so that apply the surface of this particle with silica gel, super absorbent resin and paper scrap.
First, second of Shi Yonging and the 3rd equipment 25,27 and 28 that applies granulated product all are the oscillating mode coating units in this embodiment, and in this embodiment, these three apply granulated product equipment 25,27 and 28 and are linked in sequence.Be placed in first discharging opening of sorter 29 that applies the discharging opening of granulated product equipment 25 and connect second and apply granulated product equipment 27, connect the 3rd equipment 28 that applies granulated product and be placed in second discharging opening that applies the sorter 30 of efflorescence product facility 27 discharging openings.
In this embodiment; first applies granulated product equipment 25 is equipped with to the first spraying sieve 31 that vibrates the conveyer access portal; the second coating granulated product equipment 27 is equipped with the second spraying sieve 32 to vibration conveyer access portal, and the 3rd coating granulated product equipment 28 is equipped with to the 3rd spraying sieve 33 that vibrates the conveyer access portal.Mixture with calcium chloride, super absorbent resin and paper scrap sprays the granulation particles by the first spraying sieve 31; spray again by the second spraying sieve 32 with volatile medicine empenthrin and polyvinyl alcohol weak solution, spray again by the 3rd spraying sieve 33 with the Thujopsis dolabrata wood powder.
Apply in the granulated product equipment at each, vibrate granulated product to cover the surface of this granulated product with corresponding coating material spraying.First spray equipment 31 connects the first spray coating material dispenser 34 of supplying with the mixture that comprises calcium chloride, super absorbent resin and paper scrap, second spray equipment 32 connects two containers 35 (one of them does not illustrate) of supplying with volatile medicine empenthrin and polyvinyl alcohol weak solution respectively, and the 3rd spray pipe 33 connects the dispenser 36 of the 3rd spray coating material of supplying with the Thujopsis dolabrata wood powder.
Each spraying sieve or spray equipment be design by this way all, promptly always in order to give fixed and the proportional spray coating material spraying of granulated product granulated product.
Carry the conveyer belt 37 of the granulated product that applies to connect the 3rd coating granulated product device 28, and the granulated product of the coating in coating unit 28 transmit and transfer to the drier 38 that connects conveyer belt 37 by conveyer belt 37.
The granulated product of Tu Fuing is by they being introduced drier 38 like this, and is for example dry in the hot air dryer, and the conveyer belt 40 of the conveying dry granulation product by being installed in dry products discharging opening 39 is fed in the container 41 that last products obtained therefrom is provided then.The conveyer belt 42 for carry this product of dried granules product below the lower discharge port that is positioned at product and provides container 41 transferred to bagging station 43 and pack, sends then.
Because the equipment of this embodiment has said structure, it is as described below to prepare moth-proofing material of the present invention,, the paper scrap of scheduled volume is added to quantitative hopper 1 that is, and the high hydroscopic resin with scheduled volume is added to quantitative hopper 3 simultaneously.
In this stage, conveyer belt 4 operations of carrying the conveyer belt 2 of paper scrap and transporting high hydroscopic resin are delivered to the Thujopsis dolabrata wood powder and the high hydroscopic resin of scheduled volume in the mixed-hopper 7 like this.The paper scrap that forms in mixing arrangement 7 and the mixture of high hydroscopic resin are transferred to the conveyer belt 9 of the conveying mixture of operation, and are sent to again in the pre-mixing apparatus 11.Also have by feed pipe 12 except paper scrap and high hydroscopic resin and supply water to pre-mixing apparatus, these compositions are mixed equably in pre-mixing apparatus 11.Then the homogeneous mixture that obtains is delivered to granulator 10.
In this embodiment, granulator 10 is extruding granulators, and uniform here mixture is squeezed into particle by the turning effort of leading screw, and the cross section of each particle is corresponding with the hole of mould 13, and length is corresponding with the thickness of mould 13.
The granulation particle of mould 13 extruding by granulator 10 is by carrying granulated product conveyer belt 15 to transfer to garden shape sieve 14, and here particle is classified into oversize grain and undersize particle.Particle size turns back to conveying mixture conveyer belt 9 less than the undersize particle of 4mm by the not enough particle conveyer belt 20 of delivery size.On the other hand; the oversize grain that particle size is not less than 4mm is transferred to vibration particle size Selection device 18 by carrying oversize grain conveyer belt 17; here oversize grain is scattered; and the particle that the particle size that obtains is not less than 4mm is transferred to first and applies granulated product device 25 by sieving 21 conveying oversize grain conveyer belt 24, and here first coating material of predetermined composition applies this granulated product.
On the other hand; the particle size that loose operating period obtains in vibration particle size Selection device 18 is passed through the undersize particle discharging opening and the not enough particle conveyer belt 22 of delivery size of sieve 21 less than the particle of 4mm; by carrying mixture conveyer belt 9 to be returned to granulator 10, here granulate again.
Apply the granulation particle that applies with first coating material in the granulated product device 25 first and be transferred to the second coating granulated product device 27 by the sorter 29 that places first coating unit, 25 discharging openings; use second coating material here, i.e. the dilute solution sprayed particle.Granulation particle with the spraying of second dilute solution is transferred to the 3rd coatingization product device 28 by the sorter 30 that places second coating unit, 27 discharging openings, here applies with having the 3rd coating material that is predetermined to be branch.
The granulation particle that applies with the 3rd coating material is transferred to drier 38, here with the granulation particle drying.Dry temperature remains on 100 ℃ the level that is not less than.Gan Zao granulated product is sent to supplying products container 41 by carrying dry granulation product conveyer belt 40 like this, is packaged into final products then and is ready for sending.
In embodiment shown in Figure 2, granulated product also comprises coffee grounds to add/or tealeaf residue and as the benzoic acid of bactericide except that paper scrap and super absorbent resin.
So; in embodiment shown in Figure 2, except the raw material supply process to the pelletization in granulator 10, the corresponding technical process of carrying out in technical process and the embodiment shown in Figure 1 is identical; so all devices same as shown in Figure 1 all have identical label number.For this reason, in embodiment shown in Figure 2, the raw material supply process will describe in detail below to the pelletization in granulator 10.
In Fig. 2, the quantitative hopper 1 of paper scrap is placed on the transfer passage of conveyer belt 2 in the mode that paper scrap can be fed to conveyer belt 2.And, mix high hydroscopic resin and benzoic quantitative hopper 3 and be installed on the transfer passage of conveyer belt 4 in the mode that super absorbent resin and benzoic mixture can supply to conveyer belt 4.Conveyer belt 2 and 4 discharging opening 5 and 6 relatively are placed on the conveyer belt 44 of the mixture of carrying paper scrap and super absorbent resin and benzoic mixture.Carry the discharging opening of mixture conveyer belt 44 to place above the mixing arrangement 7.
In this embodiment, the quantitative hopper 46 that extracts the coffee grounds of back acquisition is installed on the transfer passage of conveyer belt 47, so that coffee grounds can be sent on the conveyer belt 47.Carry the discharging opening 48 of the conveyer belt 47 of coffee grounds to place above the mixing arrangement 7.So; in this embodiment; paper scrap, high hydroscopic resin, benzoic acid and coffee grounds are mixed in mixing arrangement 7 together, and these mixture of ingredients of being discharged by mixing arrangement 7 are transferred in the pre-mixing apparatus 11 of granulator 10 by the running of carrying mixture conveyer belt 9.In pre-mixing apparatus 11,, and in pre-mixing apparatus 11, mixed equably together by feed pipe 12 mixture of paper scrap, high hydroscopic resin, benzoic acid and coffee grounds that supplies water.Mixture is supplied to granulator 10 uniformly then.Then, by above-mentioned embodiment same way as shown in Figure 1, mixture stands the particle size selection by the vibration action of granulator 10, applies with coating material, and is dry then, obtains moth-proofing material of the present invention.
In the embodiment depicted in fig. 3, except paper scrap and super absorbent resin, granulated product also comprises coffee grounds and as the benzoic acid of bactericide.
Embodiment shown in Figure 3 and embodiment shown in Figure 2 do not exist together and only are to save the 3rd coating granulated product device among the former; but the corresponding technical process of carrying out in other technical process and the embodiment shown in Fig. 2 is identical; so all devices same as shown in Figure 2 all have identical label number.For this reason, will describe in detail below to the drying process that in drier 38, carries out from the technical process of vibration particle size Selection device 18, carrying out in the embodiment depicted in fig. 3.
The particle that the particle size that obtains by the loosening technique process in vibration particle size Selection device 18 is not less than 4mm is transferred to first by the action of sieving 21 conveying oversize grain conveyer belt 24 and applies in the granulated product device 25, applies this particle with having first coating material that is predetermined to be branch here.
On the other hand; the particle size of carrying out obtaining behind the loosening technique in vibration particle size Selection device 18 is passed through the undersize particle discharging opening and the not enough particle conveyer belt 22 of delivery size of sieve 21 less than the particle of 4mm; by carrying mixture conveyer belt 9 to be returned to granulator 10, carry out granulated processed as embodiment shown in Fig. 1 and 2 here then.
The granulation particle that will apply with first coating material in the first coated particle product device 25 is transferred to second by the sorter 29 that places coating unit 25 discharging openings and is applied granulated product device 27, sprays them with the second dilution coating solution here.Sorter 30 with the granulation particle of second coating solution spraying discharging opening by placing second coating unit 27 is transferred to drier 38 like this, and here they are dried, and obtain final products.The temperature of drier 38 remains on 100 ℃ the level that is not less than.The granulated product of such drying is delivered to product supply container 41 by carrying dry granulation product conveyer belt 40, be packaged into final products then and be ready for sending.
This is the embodiment of an embodiment shown in Figure 1.At first, put the paper scrap of 90 parts of (weight) particle size 0.1-0.5mm into paper scrap quantitative hopper 1, put 10 parts of (weight) high hydroscopic resins into high hydroscopic resin quantitative hopper 3 simultaneously.After paper scrap and high hydroscopic resin are put hopper 1 and 3 respectively into, start conveyer belt 2 and 4, then 90 parts of (weight) paper scraps and 10 parts of (weight) resins are introduced mixing arrangement 7 to mix them.The mixtures that comprise 90% (weight) paper scrap and 10% (weight) resin in device 7 preparations supply to the pre-mixing apparatus 11 of granulator 10 like this, here, mixture are evenly disperseed after adding 15 parts of (weight) water.
The homogeneous mixture of paper scrap, high hydroscopic resin and water of preparation is like this transferred to granulator 10 from pre-mixing apparatus 11, and here extruding mixture is granulated by mould 13, is cut into the particle with appropriate length by a cutting machine (not illustrating) simultaneously.The wet granulated product of the Thujopsis dolabrata wood powder of preparation is sent to garden shape sieve 14 by the action of carrying granulated product conveyer belt 15 in granulator 10.By the granulated product classification of will wetting of the garden shape sieve 14 with mesh 4mm.Have particle size and be returned on the conveying mixture conveyer belt 9 that is connected granulator 10 by undersize particle discharging opening 19 and the not enough particle conveyer belt 20 of delivery size less than the wet granulated product of 4mm, and granulation again in granulator 10.
On the other hand, the wet granulated product that particle size is not less than 4mm is sent to conveying oversize grain conveyer belt 17 by oversize grain discharging opening 16, transfers to vibration particle size Selection device 18 then.The vibration action of the caking that exists in wet over dimensioning granulated product by selector 18 be by the single granulation particle of loose one-tenth, and be sent to the sieve with 4mm mesh 21 of selector 18, and here granulation particle that will be loose is classified.Have particle size and be returned to the conveying mixture conveyer belt 9 that is connected granulator 10 by sieving 21 undersize particle discharging opening with the not enough particle conveyer belt 22 of delivery size less than the wet granulated product of 4mm, and granulation again in granulator 10.On the other hand, have particle size and be not less than the oversize grain discharging opening 23 of the wet granulated product of 4mm, be sent to first by the effect of carrying oversize grain conveyer belt 24 and apply in the granulated product device 25 by sieve 21.
In this embodiment, with content 7-3% (weight), the coating material of preferred about 5% (weight) (in wet granulation particle weight) is by the wet granulation particle of spray coating in the first coating granulated product device 25.In this embodiment, coating material comprises 30 parts of (weight) paper scraps, 60 parts of (weight) calcium chloride and 10 parts of (weight) high hydroscopic resins, and is supplied with by the first spray coating material hopper 34.
In addition; the granulation particle that applies with above-mentioned coating material in coating unit 25 is transferred to second by the sorter 29 that is installed in device 25 discharging openings and applies granulated product device 27; here use by container 35 and supply with 2% volatile medicine empenthrin weak solution and the rare poly-vinyl alcohol solution of making coating solution; for example concentration is not more than 1%, and preferred about 0.6% polyvinyl alcohol weak solution sprays this particle.
When the weak solution of using the volatile medicine empenthrin and polyvinyl alcohol weak solution sprayed particle, can in the polyvinyl alcohol weak solution, add deodorant: SmellnarK (trade name, TokaiKosan Co., Ltd is on sale), flavonoids and wetting agent: propane diols.
If apply in the granulated product device 27 with the weak solution of volatile medicine empenthrin and the weak solution sprayed particle of polyvinyl alcohol second; the water absorbing capacity of calcium chloride may reduce; but do not reduce among this embodiment, because added paper powder and high hydroscopic resin.
Applying the particle that sprays with volatile medicine empenthrin weak solution and polyvinyl alcohol weak solution in the granulated product device 27 second is transferred in the 3rd coating granulated product device 28; in this embodiment, in the 3rd coating unit 28, spray the granulation particle with the Thujopsis dolabrata wood powder.The Thujopsis dolabrata wood powder of spraying is supplied with by spray coating material hopper 36 in the 3rd coating unit 28, and this particle always sieves 33 sprayings with this coating material by the 3rd spraying with constant ratio.
The Thujopsis dolabrata wood powder that will spray in this embodiment and the ratio of volatile medicine empenthrin are determined according to the pest species that will eliminate.
Granulated product that apply with coating material and that discharge from the 3rd coating granulated product device 28 is admitted to the drier 38, here with its drying.The granulated product of drying is delivered in the container 41 that products obtained therefrom is provided by the conveyer belt 40 of carrying the dry granulation product then, conveyer belt 40 is installed in dry products discharging opening 39 places of drier 38.Transfer to that drying granular product in the container 41 is transferred to packaging area 43 by the conveyer belt 42 that places this product of conveying below the low outlet that this product container 41 is provided and packing is ready for sending.
In this embodiment, use calcium chloride as desiccant, its moisture absorption in the environment is around controlled wherein humidity like this, but can be used silica gel to replace calcium chloride.In addition, this particle applies available Thujopsis dolabrata wood powder spraying in the granulated product device 28 the 3rd, still, but paper powder instead of part Thujopsis dolabrata wood powder.
The product of Huo Deing has fabulous favorable moth-proof effect and deodorization in this embodiment.For example, this product was put into cabinet drawer 6 months, they present the favorable moth-proof effect.The moth-proofing material of this embodiment can directly contact woolen knitwear and other wool product or pack before reality is used.
In addition, the moth-proofing material of this embodiment has fabulous anti-cockroach effect equally, and can prevent any generation of mould in long-time, because this material contains the Thujopsis dolabrata wood powder with this effect.
This is the embodiment of an embodiment shown in Figure 2.In this embodiment, the paper scrap of 25 parts of (weight) particle size 0.1-0.5mm is at first joined in the paper scrap weigh-hatching plant 1,5 parts of (weight) super absorbent resins and 0.05 part of (weight) benzoic acid are joined in metering high hydroscopic resin and the benzoic acid hopper 3, and the coffee grounds of 70 parts of (weight) moistures 65% is joined in the coffee grounds weigh-hatching plant 46.Running conveyer belt 2,4,44 and 46 makes paper scrap like this, and high hydroscopic resin and benzoic mixture and coffee grounds join in the mixing arrangement 7.Be fed to the paper scrap in the mixing arrangement 7, high hydroscopic resin, benzoic acid and coffee grounds are mixed here, and the mixture that obtains is transferred in the pre-mixing apparatus 11 of granulator 10 by the discharging opening 8 of mixing arrangement 7 and the conveyer belt 9 of conveying mixture.The mixture of paper scrap, high hydroscopic resin, benzoic acid and coffee grounds is supplied to pre-mixing apparatus 11, simultaneously 15 parts of (weight) water is delivered to pre-mixing apparatus 11 by feed pipe 12, here these compositions is evenly mixed.
The mixture of mixed uniformly paper scrap, high hydroscopic resin, benzoic acid, coffee grounds and water is transferred to granulator 10 by device 11 in pre-mixing apparatus 11; in granulator, pass through mould 13 extruding mixtures, and be cut into the particle of appropriate length with the cutting machine (not shown).Wet granulated product by the mentioned component granulation in granulator 10 shifts out and transfers to conveying granulated product conveyer belt 15 from granulator, arrives the sieve 14 of the mesh 4mm of garden shape then, so that this granulated product is classified.By the not enough particle conveyer belt 20 of delivery size the undersize transfer of granules is arrived granulator 10,, granulate again therein as embodiment 1.
By carrying wet granulation transfer of granules that oversize grain conveyer belt 17 is not less than particle size 4mm to vibration particle size Selection device 18, the vibration of the selected device 18 of this particle here and loose, and by mesh 4mm sieve 21 classification of selector 18.Can be transferred to granulator 10 by the not enough particle conveyer belt 22 of delivery size by sieving 21 undersize particle, here granulate again as embodiment 1.On the other hand, the oversize grain of staying above the sieve 21 applies granulated product device 25 by carrying oversize grain conveyer belt 17 to be transferred to first.
In this embodiment, apply in the granulated product device 25, be somebody's turn to do wet granulation particle, about 15 parts of (weight) coating materials of the particle of per 85 parts (weight) with the coating material spraying first.In this embodiment, coating material comprise the paper scrap of 80 parts (weight) and 20 parts (weight) calcium chloride mixture and provide by spray coating material hopper 34.
In addition; the granulation particle that applies with above-mentioned coating material in coating unit 25 is transferred to second by the sorter 29 that places first coating unit, 25 discharging opening places and applies granulated product device 27; here with the rare poly-vinyl alcohol solution that contains the volatile medicine empenthrin; for example concentration is not more than 1%; preferably about 0.6% polyvinyl alcohol weak solution sprayed particle, coating solution is supplied with by container 35.In this embodiment, when with polyvinyl alcohol weak solution sprayed particle, (trade name can be purchased the Co. in Tokai Kosan, Ltd.) or flavonoids can to add deodorant: Smellnark in this polyvinyl alcohol weak solution.
Being transferred to the 3rd at second particle that applies the weak solution spraying of using the polyvinyl alcohol that contains the medicine empenthrin in the granulated product device 27 applies in the granulated product device 28.In this embodiment, the mixture with the paper scrap that contains 70 parts of (weight) Thujopsis dolabrata wood powders and 30 parts (weight) sprays this granulation particle in the 3rd coating unit 28.
Granulated product that apply with coating material and that discharged by the 3rd coating granulated product device 28 is introduced in the drier 39, and is dry here.Then the granulated product of drying is delivered in the container 43 that products obtained therefrom is provided by carrying dry granulation product conveyer belt 42, conveyer belt 42 is placed in dry products discharging opening 41 places of drier 39.To be transferred to that dried particles product in the container 43 is transferred to bagging area 35 by the conveyer belt 44 that places this product of conveying below the low outlet that product container 43 is provided and pack is ready for sending.
This is an embodiment of embodiment shown in Figure 3, makes raw material with paper scrap, super absorbent resin, benzoic acid and coffee grounds, in granulator 10, granulate and vibration particle size Selection device 18 in classification, all use among the embodiment 2 in a like fashion.
As embodiment 2, the wet granulation particle that will be not less than the spraying of 4mm with the particle size that embodiment 2 used same way as are carried out granulation and classification is fed into first by the operation of carrying oversize grain conveyer belt 17 and applies granulated product device 25.
In this embodiment, apply in the granulated product device 25 first, with the wet granulated product of coating material spraying, the amount of coating material equals per 85 parts of (weight) particles about 15 parts (weight).In this embodiment, this coating material comprises the mixture of 80 parts of (weight) paper scraps and 20 parts of (weight) calcium chloride, and is provided by spray coating material hopper 34.
In addition; the granulation particle that applies with above-mentioned coating material in coating unit 25 is transferred to second by the sorter 29 that places first coating unit, 25 discharging opening places and applies granulated product device 27; here with containing the rare poly-vinyl alcohol solution of volatile medicine empenthrin; for example concentration is not more than 1%; preferably about 0.6% polyvinyl alcohol weak solution sprays this particle, and coating solution is provided by container 35.In this embodiment, when with polyvinyl alcohol weak solution sprayed particle, can in this polyvinyl alcohol weak solution, add deodorant: Smellnark (trade name: can purchase Co., Ltd.) or flavonoids in Tokai Kosan.
Be introduced in the drier 39 at second particle that applies the weak solution spraying of using the polyvinyl alcohol that contains the medicine empenthrin in the granulated product device 27, use the hot-air drying here.The granulated product of drying is delivered in the container 43 that products obtained therefrom is provided by the conveyer belt 42 of carrying the dry granulation product then; conveyer belt 42 places dry products discharging opening 41 places of drier 39, is transferred to that dry granulation product in the container 43 is transferred to bagging area 35 by the conveyer belt 44 that places this product of conveying below the low outlet that product container 43 is provided and pack is ready for sending.
Claims (7)
1. granular moth-proofing material, this material comprises
A kind of particle of granulation, this particle comprises by coffee grounds, tealeaf residue, the paper powder, a kind of mixture of coffee grounds and tealeaf residue, a kind of mixture of tealeaf residue and paper break flour, a kind of mixture of coffee grounds and paper break flour, perhaps a kind of waste material of a kind of mixture composition of coffee grounds, tealeaf residue and paper break flour;
A kind of resin, this resin have the performance of high suction, and its content is less than the content of above-mentioned waste material; And
Volatile empenthrin (empenthrin),
This moth-proofing material is made into grain shape.
2. granular moth-proofing material, this material comprises:
The part of granulation, wherein comprise by coffee grounds, tealeaf residue, the paper powder, a kind of mixture of coffee grounds and tealeaf residue, a kind of mixture of tealeaf residue and paper break flour, a kind of mixture of coffee grounds and paper break flour, perhaps a kind of waste material of forming of a kind of mixture of coffee grounds, tealeaf residue and paper break flour, and have the high-hydroscopicity energy and its content is less than a kind of resin of this waste material; And
The coat part wherein comprises volatile empenthrin, and
This coat has covered the surface of this granulation part.
3. granular moth-proofing material, this material comprises:
The granulation part, wherein comprise by coffee grounds, tealeaf residue, the paper break flour, a kind of mixture of coffee grounds and tealeaf residue, a kind of mixture of tealeaf residue and paper break flour, a kind of mixture of coffee grounds and paper break flour, perhaps a kind of waste material of forming of a kind of mixture of coffee grounds, tealeaf residue and paper break flour and have the high-hydroscopicity energy and its content is less than a kind of resin of this waste material, and the fast chrysanthemum ester of volatility d-limonene; With
The coat part wherein comprises volatile empenthrin, and
This coat has covered the surface of granulation part.
4. the moth-proofing material of a shape, this material comprises:
The part of granulation, wherein comprise by coffee grounds, tealeaf residue, the paper break flour, a kind of mixture of coffee grounds and tealeaf residue, a kind of mixture of tealeaf residue and paper break flour, a kind of mixture of coffee grounds and paper break flour, the perhaps waste material formed of a kind of mixture of coffee grounds, tealeaf residue and paper break flour, and have the high-hydroscopicity energy and its content is less than a kind of resin of this waste material; With
The coat part wherein comprises wood powder and the volatile empenthrin be made up of chamenol or Thujopsis dolabrata (hiba) oil, and
This coat has covered the surface of granulation part.
5. granular moth-proofing material, this material comprises:
The part of granulation; wherein comprise by coffee grounds; tealeaf residue; the paper break flour, a kind of mixture of coffee grounds and tealeaf residue, a kind of mixture of tealeaf residue and paper break flour; a kind of mixture of coffee grounds and paper break flour; the perhaps waste material formed of a kind of mixture of coffee grounds, tealeaf residue and paper break flour, and have the high-absorbable energy and its content be less than a kind of resin of this waste material content and volatile empenthrin and
The coat part wherein comprises the wood powder and the volatile empenthrin that contain chamenol or Thujopsis dolabrata (hiba) oil, and
This coat has covered the surface of granulation part.
6. the described granular moth-proofing material of each claim of claim 1-5, wherein granular part comprise benzoic acid as a kind of medicament with bactericidal action.
7. the described granular moth-proofing material of each claim of claim 2 to 5, wherein said coat partly comprise calcium chloride or silica gel as hygroscopic agent.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP355002/93 | 1993-12-28 | ||
| JP355002/1993 | 1993-12-28 | ||
| JP35500293A JP2875732B2 (en) | 1993-12-28 | 1993-12-28 | Granular insect repellent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1114858A CN1114858A (en) | 1996-01-17 |
| CN1076166C true CN1076166C (en) | 2001-12-19 |
Family
ID=18441314
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94120720A Expired - Fee Related CN1076166C (en) | 1993-12-28 | 1994-12-28 | Granular moth-proofing material |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2875732B2 (en) |
| CN (1) | CN1076166C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103168777A (en) * | 2011-12-26 | 2013-06-26 | 东北林业大学 | Waterborne hinokitiol wood preservative and preparation method thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1068176C (en) * | 1996-05-20 | 2001-07-11 | 谢建华 | Long effective eating-proof pest repellant and its prepn. method |
| CN109042640A (en) * | 2018-07-19 | 2018-12-21 | 青岛正利纸业有限公司 | A kind of slow-release carrier granular and preparation method thereof |
| CN109168878A (en) * | 2018-09-19 | 2019-01-11 | 贺州市飞龙种养专业合作社 | The method for preventing and treating rainy season plum root moth |
| CN110506757A (en) * | 2019-09-17 | 2019-11-29 | 广西马中粮油有限公司 | Tender leaf is compound to be prevented gnawing expelling parasite protective agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61233603A (en) * | 1986-04-18 | 1986-10-17 | T Hasegawa Co Ltd | Aromatic solid insecticide |
| JPH0393702A (en) * | 1989-09-04 | 1991-04-18 | Nippon Fine Chem Co Ltd | Moth-proofing agent for clothing |
| CN1058696A (en) * | 1990-08-04 | 1992-02-19 | 缪予 | Anti-borer medicine |
| JP3093702B2 (en) * | 1996-12-19 | 2000-10-03 | 晃栄化学工業株式会社 | Flower remover and flowering method |
-
1993
- 1993-12-28 JP JP35500293A patent/JP2875732B2/en not_active Expired - Fee Related
-
1994
- 1994-12-28 CN CN94120720A patent/CN1076166C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61233603A (en) * | 1986-04-18 | 1986-10-17 | T Hasegawa Co Ltd | Aromatic solid insecticide |
| JPH0393702A (en) * | 1989-09-04 | 1991-04-18 | Nippon Fine Chem Co Ltd | Moth-proofing agent for clothing |
| CN1058696A (en) * | 1990-08-04 | 1992-02-19 | 缪予 | Anti-borer medicine |
| JP3093702B2 (en) * | 1996-12-19 | 2000-10-03 | 晃栄化学工業株式会社 | Flower remover and flowering method |
Non-Patent Citations (1)
| Title |
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| 植物化学保护第一版 1983.5.1 华南农学院农业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103168777A (en) * | 2011-12-26 | 2013-06-26 | 东北林业大学 | Waterborne hinokitiol wood preservative and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07196427A (en) | 1995-08-01 |
| CN1114858A (en) | 1996-01-17 |
| JP2875732B2 (en) | 1999-03-31 |
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