CN107267298A - 清洗剂组合物 - Google Patents

清洗剂组合物 Download PDF

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CN107267298A
CN107267298A CN201710381064.4A CN201710381064A CN107267298A CN 107267298 A CN107267298 A CN 107267298A CN 201710381064 A CN201710381064 A CN 201710381064A CN 107267298 A CN107267298 A CN 107267298A
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cleansing composition
water
hpma
phosphonate
alkyl amido
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滕晓明
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/78—Neutral esters of acids of phosphorus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0031—Carpet, upholstery, fur or leather cleansers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2082—Polycarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/385—Cationic compounds containing P
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

本发明涉及一种清洗剂组合物，包括磷酸三钠、腐植酸钠、缓蚀剂烷基酰胺磷酸酯、水解聚马来酸酐、片碱、膦酸盐、水，各组分的质量份数为：磷酸三钠10‑40、腐植酸钠1‑5、缓蚀剂烷基酰胺磷酸酯10‑20、水解聚马来酸酐6‑15、片碱5‑14、膦酸盐8‑10、水40‑50。本发明对人体皮肤无伤害，无残留，对食物、环境无污染；本发明中无起泡剂，漂洗方便，节省用水量；适用广泛，如陶瓷器具、织物、家具的清洗，水果外皮消毒，环境消毒，卫生间改味等。

Description

清洗剂组合物
技术领域
本发明涉及一种清洗剂领域，具体地讲，本发明涉及一种清洗剂组合物。
背景技术
现有的清洁产品以化工原料为主，大量采用强氧化剂，使用过程中对人的皮肤有伤害，会有残留，对食物、环境有污染。
发明内容
针对现有技术中存在的上述不足，本发明所要解决的技术问题是提供一种效果好的清洗剂组合物。
本发明解决其技术问题所采用的技术方案是：提供一种清洗剂组合物，包括磷酸三钠、腐植酸钠、缓蚀剂烷基酰胺磷酸酯、水解聚马来酸酐、片碱、膦酸盐、水，各组分的质量份数为：磷酸三钠10-40、腐植酸钠1-5、缓蚀剂烷基酰胺磷酸酯10-20、水解聚马来酸酐6-15、片碱5-14、膦酸盐8-10、水40-50。
作为优选，所述的清洗剂组合物，其特征在于：所述清洗剂组合物各组分的质量份数为：磷酸三钠27、腐植酸钠3、缓蚀剂烷基酰胺磷酸酯15、水解聚马来酸酐9、片碱5、膦酸盐8、水50。
作为优选，所述的清洗剂组合物，其特征在于：所述磷酸三钠为非离子表面活性剂和阳离子表面活性剂。
作为优选，所述清洗剂组合物的制备方法，其特征在于包括下述步骤 ：
1) 将磷酸三钠、腐植酸钠加入搅拌缸中，加入缓蚀剂烷基酰胺磷酸酯，搅拌均匀 ；
2) 向搅拌缸均匀加入水解聚马来酸酐，高速搅拌分散 ；
3)在酸催化剂下使片碱与膦酸盐产生加成反应。；
4) 倒入所给质量份数的水，加热20分钟即可。
本发明对人体皮肤无伤害，无残留，对食物、环境无污染 ；本发明中无起泡剂，漂洗方便，节省用水量 ；适用广泛，如陶瓷器具、织物、家具的清洗，水果外皮消毒，环境消毒，卫生间改味等。
具体实施方式
本发明提供的一种清洗剂组合物，包括磷酸三钠、腐植酸钠、缓蚀剂烷基酰胺磷酸酯、水解聚马来酸酐、片碱、膦酸盐、水，各组分的质量份数为：磷酸三钠10-40、腐植酸钠1-5、缓蚀剂烷基酰胺磷酸酯10-20、水解聚马来酸酐6-15、片碱5-14、膦酸盐8-10、水40-50。
作为优选，所述的清洗剂组合物，其特征在于：所述清洗剂组合物各组分的质量份数为：磷酸三钠27、腐植酸钠3、缓蚀剂烷基酰胺磷酸酯15、水解聚马来酸酐9、片碱5、膦酸盐8、水50。
作为优选，所述的清洗剂组合物，其特征在于：所述磷酸三钠为非离子表面活性剂和阳离子表面活性剂。
作为优选，所述清洗剂组合物的制备方法，其特征在于包括下述步骤 ：
1) 将磷酸三钠、腐植酸钠加入搅拌缸中，加入缓蚀剂烷基酰胺磷酸酯，搅拌均匀 ；
2) 向搅拌缸均匀加入水解聚马来酸酐，高速搅拌分散 ；
3)在酸催化剂下使片碱与膦酸盐产生加成反应。；
4) 倒入所给质量份数的水，加热20分钟即可。
以上所述，仅是对本发明的较佳实施例而已，并非对本发明做其他形式的限制，任何熟悉本专业的技术人员可能利用上述揭示的技术内容加以变更或改型为同等变化的等效实施例。凡是未脱离本发明方案内容，依据本发明的技术实质对以上实施例所做的任何简单修改、等同变化与改型，均落在本发明的保护范围内。

Claims (4)

1.一种清洗剂组合物，其特征在于：包括磷酸三钠、腐植酸钠、缓蚀剂烷基酰胺磷酸酯、水解聚马来酸酐、片碱、膦酸盐、水，各组分的质量份数为：磷酸三钠10-40、腐植酸钠1-5、缓蚀剂烷基酰胺磷酸酯10-20、水解聚马来酸酐6-15、片碱5-14、膦酸盐8-10、水40-50。
2.根据权利要求1所述的清洗剂组合物，其特征在于：所述清洗剂组合物各组分的质量份数为：磷酸三钠27、腐植酸钠3、缓蚀剂烷基酰胺磷酸酯15、水解聚马来酸酐9、片碱5、膦酸盐8、水50。
3.根据权利要求2所述的清洗剂组合物，其特征在于：所述磷酸三钠为非离子表面活性剂和阳离子表面活性剂。
4.权利要求 1 -3所述清洗剂组合物的制备方法，其特征在于包括下述步骤 ：
1) 将磷酸三钠、腐植酸钠加入搅拌缸中，加入缓蚀剂烷基酰胺磷酸酯，搅拌均匀 ；
2) 向搅拌缸均匀加入水解聚马来酸酐，高速搅拌分散 ；
3)在酸催化剂下使片碱与膦酸盐产生加成反应；
4) 倒入所给质量份数的水，加热20分钟即可。
CN201710381064.4A 2017-05-25 2017-05-25 清洗剂组合物 Pending CN107267298A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108148681A (zh) * 2017-11-30 2018-06-12 石永明 多用途清洗剂组合物
CN111575125A (zh) * 2020-04-21 2020-08-25 中国铁道科学研究院集团有限公司金属及化学研究所 一种用于列车集便器的清洗剂及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059172A (zh) * 1990-08-18 1992-03-04 曹立斌 铝壶高效除垢剂
CN1421518A (zh) * 2000-11-22 2003-06-04 上海白猫有限公司 商业洗碗机专用液体餐具洗涤剂
CN101012415A (zh) * 2007-02-01 2007-08-08 大连三达奥克化学有限公司 安全在线除垢清洗剂
CN106010819A (zh) * 2016-05-21 2016-10-12 俞凤鸣 清洗剂组合物
CN106635446A (zh) * 2016-09-26 2017-05-10 浙江工商大学 一种生物膜清洁剂及其制备和应用

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059172A (zh) * 1990-08-18 1992-03-04 曹立斌 铝壶高效除垢剂
CN1421518A (zh) * 2000-11-22 2003-06-04 上海白猫有限公司 商业洗碗机专用液体餐具洗涤剂
CN101012415A (zh) * 2007-02-01 2007-08-08 大连三达奥克化学有限公司 安全在线除垢清洗剂
CN106010819A (zh) * 2016-05-21 2016-10-12 俞凤鸣 清洗剂组合物
CN106635446A (zh) * 2016-09-26 2017-05-10 浙江工商大学 一种生物膜清洁剂及其制备和应用

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108148681A (zh) * 2017-11-30 2018-06-12 石永明 多用途清洗剂组合物
CN111575125A (zh) * 2020-04-21 2020-08-25 中国铁道科学研究院集团有限公司金属及化学研究所 一种用于列车集便器的清洗剂及其制备方法
CN111575125B (zh) * 2020-04-21 2021-10-15 中国铁道科学研究院集团有限公司金属及化学研究所 一种用于列车集便器的清洗剂及其制备方法

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Application publication date: 20171020