CN107267292A - A kind of environment-protection ground board cleaning agent - Google Patents
A kind of environment-protection ground board cleaning agent Download PDFInfo
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- CN107267292A CN107267292A CN201710510719.3A CN201710510719A CN107267292A CN 107267292 A CN107267292 A CN 107267292A CN 201710510719 A CN201710510719 A CN 201710510719A CN 107267292 A CN107267292 A CN 107267292A
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- cleaning agent
- environment
- filtrate
- coring
- protection ground
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/14—Other polishing compositions based on non-waxy substances
- C09G1/16—Other polishing compositions based on non-waxy substances on natural or synthetic resins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
Abstract
The invention discloses a kind of environment-protection ground board cleaning agent, belong to clean technologies field.The present invention is to count by weight, 70~80 parts of water, 5~10 parts of self-control surfactants, 5~8 portions of concentrates, 8~10 portions of boiling concentrates, 5~7 parts of citric acids and 1~2 part of chitin is weighed to be put into batch mixer, 1~2h of irradiation under uviol lamp is placed on after 30~40min of stirring mixing, environment-protection ground board cleaning agent is produced after bottling.The beneficial effects of the invention are as follows：Environment-protection ground board cleaning agent of the present invention is environmentally friendly, degradable, will not produce harm, and excellent storage stability to environment and human body, can effectively delay the decomposition of cleaning agent active ingredient, extend its action time.
Description
Technical field
The present invention relates to a kind of environment-protection ground board cleaning agent, belong to clean technologies field.
Background technology
The floor as the improvement of people's living standards, increasing home and office intranets have been mated formation.Cleaning floor is most passed
The method of system is cleaned using flat board floor mop, is specifically clipped in the strong slubbing wiping cloth of dry crude fibre, concave-convex sense flat
On plate floor mop, and some dust adsorption agent are sprayed on wiping cloth, then wipe floor surface, hair and dust are received into slubbing
On wiping cloth, after completion, wiping cloth is taken, cleaned at pond, dries stand-by, but cleaning effect is poor, and dirt-removing power is weak.So,
Floor cleaner arises at the historic moment.
Floor cleaner is by surfactant, bactericide, essence and unique bright factor by scientific allocation
Cleaning products；With characteristics such as good cleaning force, bright properties, it is suitable for the cleaning of all kinds of smooth crusts, is particularly suitable for
The cleaning of the various floor surfaces such as Modern Family, office building, hotel and public place of entertainment.But there are the following problems：Used in cleaning agent
The most surfactant sodium alkyl benzene sulfonate degradability of amount is poor, residual quantity is big, and health poisonous, to human body produces damage；
Bin stability is poor, easy decomposition failure, causes to be deteriorated using rear dirt-removing power and antibacterial effect；Antibiotic rate is low, and action time is short；
Cleaning floor is dipped in cleaning agent with wet mop often and directly wiped, because detergent surfactants concentration is higher, after mopping
Dust is easily infected with semi-moist floor, and the moisture of wet mop can be through the crack of floor surface, paint breakage and corner infiltration
To floor nexine, cause floor to warp, it is mouldy rot.Therefore, a kind of necessary degradability of exploitation is good, bin stability is good,
The floor cleaner of long action time.
The content of the invention
Present invention mainly solves technical problem：For the most surface-active of consumption in floor cleaner common at present
Agent sodium alkyl benzene sulfonate degradability is poor, poisonous, can produce damage to the health of human body, bin stability is poor, cause easily decomposition
Failure, there is provided a kind of environment-protection ground board cleaning agent for action time short defect.
In order to solve the above technical problems, the present invention is using technical scheme as described below：
A kind of environment-protection ground board cleaning agent, including self-control surfactant, concentrate and boiling concentrate, described boiling concentration
Liquid is that gained is concentrated after the fermentate boiling after digitalis coring, balloonflower root coring and chicken gizzard mixed fermentation.
Fermentate after described digitalis coring, balloonflower root coring and chicken gizzard mixed fermentation is through the following steps that be made
's：The digitalis and balloonflower root of quality such as weigh, prune cauline leaf and collect coring, gained coring is washed off into soil with water, then will
Coring after cleaning is minced with knife, is 1 in mass ratio by the coring after mincing, chicken gizzard and water:1:Load fermentation tank after 10 mixing
In, tank mouth heat-preservation fermentation 7~10 days at 30~40 DEG C are sealed, fermentate is obtained.
The operating method concentrated after described fermentate boiling is：Fermentate is fitted into marmite, it is heated to 110~
120 DEG C of 3~5h of cooking, are filtered, isolated filtrate after the completion of cooking, then filtrate is put into vacuum concentration pot, are concentrated into filtrate
The 1/5 of original volume, obtains boiling concentrate.
Described concentrate is as made from following methods：
（1）Cut into slices after weighing the peeling of 400~500g lotus rhizomes, gained carrot piece is laid in stainless steel pallet, liquid nitrogen spraying is used
1~2min is freezed, then the carrot piece after freezing is put into tissue mashing machine, 1~2h is smashed to pieces and obtains rhizoma nelumbinis gruel；
（2）It is 1 in mass ratio:The gruel of above-mentioned rhizoma nelumbinis and mass fraction are to be put into sonic oscillation instrument after 75% ethanol solution is mixed by 5,
With 40~50kHz frequency ultrasound 1~2h of oscillation treatment at 40~50 DEG C, after sonic oscillation terminates, removal filter cake is separated by filtration,
Filtrate is obtained, gained filtrate is transferred to Rotary Evaporators, 20~30min of concentrated by rotary evaporation, obtains concentrate at 70~80 DEG C.
Described self-control surfactant is as made from following methods：
（1）It is beaten after weighing 300~400g soybean, 400~500g Kiwi berrys and the mixing of 400~500mL water, obtains mixed slurry
And be fitted into fermentation tank, sealing and fermenting 20~30 days at normal temperatures；
（2）After after above-mentioned fermentation ends, taking out fermentate and being filtrated to get filtrate, by filtrate centrifugal treating, isolated upper strata
Liquid, measures upper liquid obtained by 100~200mL and 40~50mL acetone is fitted into four-hole boiling flask, at 15~25 DEG C with 100~
150r/min rotating speeds are stirred；
（3）In above-mentioned whipping process, 3~5mL lauroyl chlorides are added dropwise into four-hole boiling flask, then with concentration be 0.5mol/L hydrogen-oxygens
Change sodium solution regulation pH to 8.8~9.2, continue 1~2h of stirring reaction, after the completion of reaction with concentration be 0.5mol/L hydrochloric acid adjust
Reaction product pH is separated by filtration with petroleum ether and water washing 3~5 times to 1.0~2.0, then successively and is obtained filter residue；
（4）It is 1 in mass ratio by above-mentioned filter residue and absolute ethyl alcohol:Load beaker, then the matter such as addition filter residue into beaker after 5 mixing
The sodium hydroxide of amount, with magnetic stirring apparatus with 200~300r/min rotating speed 30~40min of stirring reaction, mistake at 50~60 DEG C
Filter off and remove filtrate, obtain filter cake, as make surfactant by oneself.
The preparation method of described environment-protection ground board cleaning agent is：Count by weight, weigh 70~80 parts of water, 5~10
Part self-control surfactant, 5~8 portions of concentrates, 8~10 portions of boiling concentrates, 5~7 parts of citric acids and 1~2 part of chitin are put
Enter in batch mixer, be placed on 1~2h of irradiation under uviol lamp after 30~40min of stirring mixing, environment-friendly type floor produced after bottling clear
Lotion.
The beneficial effects of the invention are as follows：
（1）The present invention obtains amino acid content rich first with fermentation is beaten after the soybean rich in amino acid and Kiwi berry mixing
Rich ferment filtrate, ferment filtrate and lauroyl chloride are reacted amino acid type surfactant is made in the basic conditions, utilize
It replaces traditional sodium alkylphenylsulfonateas as surfactant, will not be to ring because amino acid type surfactant degradability is excellent
Border and human body produce harm；
（2）The present invention extracts lotus rhizome tannin from lotus rhizome, tannin is added into cleaning agent, it is possible to use tannin and floor surface
Spot is attracted each other combination between texture gap, and after wiping, spot is removed, and can play scavenging effect can reach that polishing is made again
With, and the inoxidizability of tannin can improve the bin stability of cleaning agent；
（3）The present invention extracts the mixing concentrate for obtaining rich Nitrogen-and Phosphorus-containing sulphur, this mixing concentration from digitalis, balloonflower root and chicken gizzard
Thing can produce one layer of fine and close polarized film, this layer of polarized film has inoxidizability, Ke Yiyan when contacting friction with floor surface
The decomposition of slow cleaning agent active ingredient, extends its action time, has broad application prospects.
Embodiment
Weigh to be put into soy bean milk making machine after 300~400g soybean, 400~500g Kiwi berrys and the mixing of 400~500mL water and be beaten
20~30min, obtains mixed slurry and is fitted into fermentation tank, seals tank mouth, at normal temperatures sealing and fermenting 20~30 days；Wait to ferment
After end, take out fermentate and be separated by filtration and obtain filtrate, by filtrate with centrifuge with 2000~3000r/min rotating speed centrifugations at
10~15min is managed, isolated upper liquid, measures upper liquid obtained by 100~200mL and 40~50mL acetone loads with dropping liquid
In the four-hole boiling flask of funnel and agitator, it is stirred at 15~25 DEG C with 100~150r/min rotating speeds；In whipping process
In, 3~5mL lauroyl chlorides are added dropwise into four-hole boiling flask by dropping funel, then with concentration be 0.5mol/L sodium hydroxide solutions
Adjust pH to 8.8~9.2, continue 1~2h of stirring reaction, after the completion of reaction with concentration be 0.5mol/L hydrochloric acid regulation reaction product
PH to 1.0~2.0, is finally separated by filtration with petroleum ether and water washing 3~5 times successively and is obtained filter residue；By filter residue and absolute ethyl alcohol
It is 1 in mass ratio:Load beaker after 5 mixing, then the sodium hydroxide of the quality such as filter residue is added into beaker, used at 50~60 DEG C
Magnetic stirring apparatus is removed filtrate, is obtained filter cake, as made by oneself with 200~300r/min rotating speed 30~40min of stirring reaction, filtering
Surfactant；Cut into slices after weighing the peeling of 400~500g lotus rhizomes, gained carrot piece is laid in stainless steel pallet, liquid nitrogen is used
1~2min of spray refrigeration, then the carrot piece after freezing is put into tissue mashing machine, smash 1~2h to pieces and obtain rhizoma nelumbinis gruel；By quality
Than for 1:5 is rotten and mass fraction is to be put into sonic oscillation instrument after 75% ethanol solution is mixed by rhizoma nelumbinis, at 40~50 DEG C with 40~
50kHz frequency ultrasound 1~2h of oscillation treatment, after sonic oscillation terminates, are separated by filtration removal filter cake, obtain filtrate, gained is filtered
Liquid is transferred to Rotary Evaporators, and 20~30min of concentrated by rotary evaporation, obtains concentrate at 70~80 DEG C；Weigh 400~500g digitalis
With 400~500g balloonflower roots, prune cauline leaf and collect coring, gained coring is washed off into soil with water, then the coring after cleaning
10~15min is minced with knife, is 1 in mass ratio by the coring after mincing, chicken gizzard and water:1:It is fitted into after 10 mixing in fermentation tank,
Seal tank mouth heat-preservation fermentation 7~10 days at 30~40 DEG C；After after fermentation ends, taking out fermentate and being fitted into marmite, heat
110~120 DEG C of 3~5h of cooking are warming up to, are filtered after the completion of cooking, isolated filtrate, then filtrate is put into vacuum concentration pot,
The 1/5 of filtrate original volume is concentrated into, boiling concentrate is obtained；Count by weight, weigh 70~80 parts of water, 5~10 parts of filter residues,
5~8 portions of concentrates, 8~10 portions of boiling concentrates, 5~7 parts of citric acids and 1~2 part of chitin are put into batch mixer, and stirring is mixed
Close and 1~2h of irradiation under uviol lamp is placed on after 30~40min, environment-protection ground board cleaning agent is produced after bottling.
Example 1
Weigh to be put into soy bean milk making machine after 300g soybean, 400g Kiwi berrys and the mixing of 400mL water and be beaten 20min, obtain mixed slurry
And be fitted into fermentation tank, tank mouth is sealed, at normal temperatures sealing and fermenting 20 days；Divide after after fermentation ends, taking out fermentate and filtering
From filtrate is obtained, by filtrate with centrifuge with 2000r/min rotating speed centrifugal treating 10min, isolated upper liquid is measured
Upper liquid and 40mL acetone obtained by 100mL are fitted into the four-hole boiling flask with dropping funel and agitator, with 100r/ at 15 DEG C
Min rotating speeds are stirred；In whipping process, 3mL lauroyl chlorides are added dropwise into four-hole boiling flask by dropping funel, then use concentration
PH to 8.8 is adjusted for 0.5mol/L sodium hydroxide solutions, continues stirring reaction 1h, with concentration is 0.5mol/L salt after the completion of reaction
Acid regulation reaction product pH to 1.0, is finally separated by filtration with petroleum ether and water washing 3 times successively and is obtained filter residue；By filter residue and nothing
Water-ethanol is 1 in mass ratio:Load beaker after 5 mixing, then the sodium hydroxide of the quality such as filter residue is added into beaker, at 50 DEG C
With magnetic stirring apparatus with 200r/min rotating speed stirring reaction 30min, filtering removes filtrate, obtains filter cake, is to be lived from control surface
Property agent；Cut into slices after weighing the peeling of 400g lotus rhizomes, gained carrot piece is laid in stainless steel pallet, freezed with liquid nitrogen spraying
1min, then the carrot piece after freezing is put into tissue mashing machine, smash 1h to pieces and obtain rhizoma nelumbinis gruel；It is 1 in mass ratio:5 by rhizoma nelumbinis
Rotten and mass fraction is to be put into sonic oscillation instrument after 75% ethanol solution is mixed, with 40kHz frequency ultrasound oscillation treatments at 40 DEG C
1h, after sonic oscillation terminates, is separated by filtration removal filter cake, obtains filtrate, gained filtrate is transferred into Rotary Evaporators, at 70 DEG C
Concentrated by rotary evaporation 20min, obtains concentrate；400g digitalis and 400g balloonflower roots are weighed, cauline leaf is pruned and collects coring, by gained coring
Wash off soil with water, then the coring after cleaning minces 10min with knife, by the coring after mincing, chicken gizzard and water by quality
Than for 1:1:It is fitted into after 10 mixing in fermentation tank, sealing tank mouth heat-preservation fermentation 7 days at 30 DEG C；After after fermentation ends, hair is taken out
Ferment thing is simultaneously fitted into marmite, is heated to 110 DEG C of cooking 3h, is filtered after the completion of cooking, isolated filtrate, then filtrate is put
Enter vacuum concentration pot, be concentrated into the 1/5 of filtrate original volume, obtain boiling concentrate；Count by weight, weigh 70 parts of water, 5 parts
Filter residue, 5 portions of concentrates, 8 portions of boiling concentrates, 5 parts of citric acids and 1 part of chitin are put into batch mixer, after stirring mixing 30min
It is placed under uviol lamp and irradiates 1h, environment-protection ground board cleaning agent is produced after bottling.
When cleaning floor, first the dust of floor surface is removed with mop, then by solid-liquid mass ratio 1:120, by water with
The well mixed obtained dilution of environment-protection ground board cleaning agent produced by the present invention, then mop is put into soaked in dilution after over the ground
Plate is cleaned, and cleaning is finished, and is dried with dry wipe.
Example 2
Weigh to be put into soy bean milk making machine after 350g soybean, 450g Kiwi berrys and the mixing of 450mL water and be beaten 25min, obtain mixed slurry
And be fitted into fermentation tank, tank mouth is sealed, at normal temperatures sealing and fermenting 25 days；Divide after after fermentation ends, taking out fermentate and filtering
From filtrate is obtained, by filtrate with centrifuge with 2500r/min rotating speed centrifugal treating 13min, isolated upper liquid is measured
Upper liquid and 45mL acetone obtained by 150mL are fitted into the four-hole boiling flask with dropping funel and agitator, with 130r/ at 20 DEG C
Min rotating speeds are stirred；In whipping process, 4mL lauroyl chlorides are added dropwise into four-hole boiling flask by dropping funel, then use concentration
PH to 9.0 is adjusted for 0.5mol/L sodium hydroxide solutions, continues stirring reaction 2h, with concentration is 0.5mol/L salt after the completion of reaction
Acid regulation reaction product pH to 1.5, is finally separated by filtration with petroleum ether and water washing 4 times successively and is obtained filter residue；By filter residue and nothing
Water-ethanol is 1 in mass ratio:Load beaker after 5 mixing, then the sodium hydroxide of the quality such as filter residue is added into beaker, at 55 DEG C
With magnetic stirring apparatus with 250r/min rotating speed stirring reaction 35min, filtering removes filtrate, obtains filter cake, is to be lived from control surface
Property agent；Cut into slices after weighing the peeling of 450g lotus rhizomes, gained carrot piece is laid in stainless steel pallet, freezed with liquid nitrogen spraying
2min, then the carrot piece after freezing is put into tissue mashing machine, smash 2h to pieces and obtain rhizoma nelumbinis gruel；It is 1 in mass ratio:5 by rhizoma nelumbinis
Rotten and mass fraction is to be put into sonic oscillation instrument after 75% ethanol solution is mixed, with 45kHz frequency ultrasound oscillation treatments at 45 DEG C
2h, after sonic oscillation terminates, is separated by filtration removal filter cake, obtains filtrate, gained filtrate is transferred into Rotary Evaporators, at 75 DEG C
Concentrated by rotary evaporation 25min, obtains concentrate；450g digitalis and 450g balloonflower roots are weighed, cauline leaf is pruned and collects coring, by gained coring
Wash off soil with water, then the coring after cleaning minces 13min with knife, by the coring after mincing, chicken gizzard and water by quality
Than for 1:1:It is fitted into after 10 mixing in fermentation tank, sealing tank mouth heat-preservation fermentation 9 days at 35 DEG C；After after fermentation ends, hair is taken out
Ferment thing is simultaneously fitted into marmite, is heated to 115 DEG C of cooking 4h, is filtered after the completion of cooking, isolated filtrate, then filtrate is put
Enter vacuum concentration pot, be concentrated into the 1/5 of filtrate original volume, obtain boiling concentrate；Count by weight, weigh 75 parts of water, 8 parts
Filter residue, 7 portions of concentrates, 9 portions of boiling concentrates, 6 parts of citric acids and 2 parts of chitins are put into batch mixer, after stirring mixing 35min
It is placed under uviol lamp and irradiates 2h, environment-protection ground board cleaning agent is produced after bottling.
When cleaning floor, first the dust of floor surface is removed with mop, then by solid-liquid mass ratio 1:80, Jiang Shui with this
The well mixed obtained dilution of the obtained environment-protection ground board cleaning agent of invention, then mop is put into soaked in dilution after to floor
Cleaned, cleaning is finished, dried with dry wipe.
Example 3
Weigh to be put into soy bean milk making machine after 400g soybean, 500g Kiwi berrys and the mixing of 500mL water and be beaten 30min, obtain mixed slurry
And be fitted into fermentation tank, tank mouth is sealed, at normal temperatures sealing and fermenting 30 days；Divide after after fermentation ends, taking out fermentate and filtering
From filtrate is obtained, by filtrate with centrifuge with 3000r/min rotating speed centrifugal treating 15min, isolated upper liquid is measured
Upper liquid and 50mL acetone obtained by 200mL are fitted into the four-hole boiling flask with dropping funel and agitator, with 150r/ at 25 DEG C
Min rotating speeds are stirred；In whipping process, 5mL lauroyl chlorides are added dropwise into four-hole boiling flask by dropping funel, then use concentration
PH to 9.2 is adjusted for 0.5mol/L sodium hydroxide solutions, continues stirring reaction 2h, with concentration is 0.5mol/L salt after the completion of reaction
Acid regulation reaction product pH to 2.0, is finally separated by filtration with petroleum ether and water washing 5 times successively and is obtained filter residue；By filter residue and nothing
Water-ethanol is 1 in mass ratio:Load beaker after 5 mixing, then the sodium hydroxide of the quality such as filter residue is added into beaker, at 60 DEG C
With magnetic stirring apparatus with 300r/min rotating speed stirring reaction 40min, filtering removes filtrate, obtains filter cake, is to be lived from control surface
Property agent；Cut into slices after weighing the peeling of 500g lotus rhizomes, gained carrot piece is laid in stainless steel pallet, freezed with liquid nitrogen spraying
2min, then the carrot piece after freezing is put into tissue mashing machine, smash 2h to pieces and obtain rhizoma nelumbinis gruel；It is 1 in mass ratio:5 by rhizoma nelumbinis
Rotten and mass fraction is to be put into sonic oscillation instrument after 75% ethanol solution is mixed, with 50kHz frequency ultrasound oscillation treatments at 50 DEG C
2h, after sonic oscillation terminates, is separated by filtration removal filter cake, obtains filtrate, gained filtrate is transferred into Rotary Evaporators, at 80 DEG C
Concentrated by rotary evaporation 30min, obtains concentrate；500g digitalis and 500g balloonflower roots are weighed, cauline leaf is pruned and collects coring, by gained coring
Wash off soil with water, then the coring after cleaning minces 15min with knife, by the coring after mincing, chicken gizzard and water by quality
Than for 1:1:It is fitted into after 10 mixing in fermentation tank, sealing tank mouth heat-preservation fermentation 10 days at 40 DEG C；After after fermentation ends, hair is taken out
Ferment thing is simultaneously fitted into marmite, is heated to 120 DEG C of cooking 5h, is filtered after the completion of cooking, isolated filtrate, then filtrate is put
Enter vacuum concentration pot, be concentrated into the 1/5 of filtrate original volume, obtain boiling concentrate；Count by weight, weigh 80 parts of water, 10
Part filter residue, 8 portions of concentrates, 10 portions of boiling concentrates, 7 parts of citric acids and 2 parts of chitins are put into batch mixer, stirring mixing
It is placed on after 40min under uviol lamp and irradiates 2h, environment-protection ground board cleaning agent is produced after bottling.
When cleaning floor, first the dust of floor surface is removed with mop, then by solid-liquid mass ratio 1:160, by water with
The well mixed obtained dilution of environment-protection ground board cleaning agent produced by the present invention, then mop is put into soaked in dilution after over the ground
Plate is cleaned, and cleaning is finished, and is dried with dry wipe.
Reference examples：By surfactant sodium alkyl benzene sulfonate, chitin, essence, tricresyl phosphate（Butoxyethyl group）Ester is made
Floor cleaner.
Environment-protection ground board cleaning agent obtained by above-described embodiment is detected with floor cleaner obtained by reference examples, as a result such as
Shown in table one.
Table one：
As seen from the above table, environment-protection ground board cleaning agent of the present invention is environmentally friendly, degradable, will not produce harm to environment and human body, and
Excellent storage stability, can effectively delay the decomposition of cleaning agent active ingredient, extend its action time.
Claims (6)
1. a kind of environment-protection ground board cleaning agent, including self-control surfactant, concentrate and boiling concentrate, it is characterised in that：
Described boiling concentrate is to concentrate institute after the fermentate boiling after digitalis coring, balloonflower root coring and chicken gizzard mixed fermentation
.
2. a kind of environment-protection ground board cleaning agent according to claim 1, it is characterised in that：Described digitalis coring, tangerine
The fermentate obstructed after coring and chicken gizzard mixed fermentation is through the following steps that obtained：The digitalis and balloonflower root of quality such as weigh,
Prune cauline leaf and collect coring, gained coring is washed off into soil with water, then the coring after cleaning is minced with knife, after mincing
Coring, chicken gizzard and water in mass ratio be 1:1:It is fitted into after 10 mixing in fermentation tank, sealing tank mouth is incubated hair at 30~40 DEG C
Ferment 7~10 days, obtains fermentate.
3. a kind of environment-protection ground board cleaning agent according to claim 1, it is characterised in that：It is dense after described fermentate boiling
The operating method of contracting is：Fermentate is fitted into marmite, 110~120 DEG C of 3~5h of cooking, mistake after the completion of cooking are heated to
Filter, isolated filtrate, then filtrate is put into vacuum concentration pot, the 1/5 of filtrate original volume is concentrated into, boiling concentrate is obtained.
4. a kind of environment-protection ground board cleaning agent according to claim 1, it is characterised in that：Described concentrate is by following
Made from method：
（1）Cut into slices after weighing the peeling of 400~500g lotus rhizomes, gained carrot piece is laid in stainless steel pallet, liquid nitrogen spraying is used
1~2min is freezed, then the carrot piece after freezing is put into tissue mashing machine, 1~2h is smashed to pieces and obtains rhizoma nelumbinis gruel；
（2）It is 1 in mass ratio:The gruel of above-mentioned rhizoma nelumbinis and mass fraction are to be put into sonic oscillation instrument after 75% ethanol solution is mixed by 5,
With 40~50kHz frequency ultrasound 1~2h of oscillation treatment at 40~50 DEG C, after sonic oscillation terminates, removal filter cake is separated by filtration,
Filtrate is obtained, gained filtrate is transferred to Rotary Evaporators, 20~30min of concentrated by rotary evaporation, obtains concentrate at 70~80 DEG C.
5. a kind of environment-protection ground board cleaning agent according to claim 1, it is characterised in that：Described self-control surfactant
It is as made from following methods：
（1）It is beaten after weighing 300~400g soybean, 400~500g Kiwi berrys and the mixing of 400~500mL water, obtains mixed slurry
And be fitted into fermentation tank, sealing and fermenting 20~30 days at normal temperatures；
（2）After after above-mentioned fermentation ends, taking out fermentate and being filtrated to get filtrate, by filtrate centrifugal treating, isolated upper strata
Liquid, measures upper liquid obtained by 100~200mL and 40~50mL acetone is fitted into four-hole boiling flask, at 15~25 DEG C with 100~
150r/min rotating speeds are stirred；
（3）In above-mentioned whipping process, 3~5mL lauroyl chlorides are added dropwise into four-hole boiling flask, then with concentration be 0.5mol/L hydrogen-oxygens
Change sodium solution regulation pH to 8.8~9.2, continue 1~2h of stirring reaction, after the completion of reaction with concentration be 0.5mol/L hydrochloric acid adjust
Reaction product pH is separated by filtration with petroleum ether and water washing 3~5 times to 1.0~2.0, then successively and is obtained filter residue；
（4）It is 1 in mass ratio by above-mentioned filter residue and absolute ethyl alcohol:Load beaker, then the matter such as addition filter residue into beaker after 5 mixing
The sodium hydroxide of amount, with magnetic stirring apparatus with 200~300r/min rotating speed 30~40min of stirring reaction, mistake at 50~60 DEG C
Filter off and remove filtrate, obtain filter cake, as make surfactant by oneself.
6. a kind of environment-protection ground board cleaning agent, it is characterised in that preparation method is：Count by weight, weigh 70~80 parts of water, 5
~10 parts of self-control surfactants, 5~8 portions of concentrates, 8~10 portions of boiling concentrates, 5~7 parts of citric acids and 1~2 part of crust
Element is put into batch mixer, is placed on 1~2h of irradiation under uviol lamp after 30~40min of stirring mixing, environment-protection ground is produced after bottling
Board cleaning agent.
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