CN107267088A - A kind of luring property of environment-friendly type mythimna separata offset plate and preparation method thereof - Google Patents

A kind of luring property of environment-friendly type mythimna separata offset plate and preparation method thereof Download PDF

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Publication number
CN107267088A
CN107267088A CN201710509964.2A CN201710509964A CN107267088A CN 107267088 A CN107267088 A CN 107267088A CN 201710509964 A CN201710509964 A CN 201710509964A CN 107267088 A CN107267088 A CN 107267088A
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China
Prior art keywords
polyisobutene
insect
environment
offset plate
mythimna separata
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Pending
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CN201710509964.2A
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Chinese (zh)
Inventor
李兴才
王之霖
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Changzhou City Xiongtu Textile Co Ltd
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Changzhou City Xiongtu Textile Co Ltd
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Priority to CN201710509964.2A priority Critical patent/CN107267088A/en
Publication of CN107267088A publication Critical patent/CN107267088A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09J123/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/02Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/14Catching by adhesive surfaces
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M2200/00Kind of animal
    • A01M2200/01Insects
    • A01M2200/012Flying insects
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00Presence of polyolefin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2493/00Presence of natural resin

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Insects & Arthropods (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of luring property of environment-friendly type mythimna separata offset plate and preparation method thereof, belong to techniques of pest control field.The present invention is by changing the insect pheromone attractant added, a variety of pest and disease damages can be directed to, prevention effect reaches more than 86%, and it is nontoxic using polyisobutene, molecular backbone is free of double bond, light fastness aging is excellent, tack, high adhesive force, the advantages of hold good, water-fast, cold-resistant, ageing-resistant viscous time length, chemical stability and UV resistant, cooperate with rosin resin, terpene resin, further improve durability and adhesive property, obtained insect sticker is nonpoisonous and tasteless, permanent tack, reduces environmental pollution, has broad application prospects.

Description

A kind of luring property of environment-friendly type mythimna separata offset plate and preparation method thereof
Technical field
The present invention relates to a kind of luring property of environment-friendly type mythimna separata offset plate and preparation method thereof, belong to techniques of pest control field.
Background technology
With the development of society, enhancing of the people to environmental consciousness, people gradually have found can be to environment using chemical pesticide Destructive influences are produced with the ecosystem.So-called non-environmental pollution control method refers to prophylactico-therapeutic measures to people, animal, fowl, fish, honeybee And beneficial insect (i.e. the natural enemy of insect) safe fanout free region, while to the ecological balance without destruction, agricultural product meet nuisanceless Agricultural is required.So, the preventing and treating of the insect produced now for influence agriculture and forestry by chemical method also by turning to without public affairs merely Harmful prevention and controls.Therefore, it is particularly important using non-harmful prevention and controls in the prevention and control of plant diseases, pest control of agriculture and forestry.
There is the habit of context tree using many insects, the preventing and treating that nuisanceless insect sticker carries out insect is smeared in trunk, can The effect got twice the result with half the effort with receiving.Therefore, non-environmental pollution control measure is studied and applied, the environment dirt that control of insect is caused is reduced Dye, has become people's common recognition, is also Future Development direction.
Forest disease and pest is prevented and treated as one of non-environmental pollution control method by the use of insect sticker, is increasingly valued by people. But the mythimna separata plastic sheet product having been commercialized now, all different degrees of presence be difficult construction, irritant smell, easily trickling, Sticky poor, validity period is short and the shortcomings of temperature in use narrow range, therefore, be badly in need of developing a kind of low, nuisanceless cost, blowing-resistant, Exposure to Sunlight, drench with rain, the strong and lasting mythimna separata offset plate of viscosity.
The content of the invention
The technical problems to be solved by the invention:It is difficult to apply for all different degrees of presence of existing mythimna separata plastic sheet product The problem of work, irritant smell, easy trickling, short sticky poor, validity period and temperature in use narrow range, the invention provides one kind Environment-friendly type luring property mythimna separata offset plate and preparation method thereof.
In order to solve the above technical problems, the technical solution adopted by the present invention is:
A kind of luring property of environment-friendly type mythimna separata offset plate, including plastic base, insect sticker, conduction oil, it is characterised in that the insect sticker by Following raw material compositions:Mineral oil, polyisobutene, rosin resin, terpene resin, vaseline, age resistor, insect pheromone are lured Agent.
The parts by weight of the insect sticker constitutive material are 150~210 parts of mineral oil, 300~360 parts of polyisobutene, 100~ 120 parts of rosin resins, 80~100 parts of terpene resins, 50~80 parts of vaseline, 3~5 parts of age resistor, 1~2 part of insect pheromone Attractant.
The insect sticker preparation process is heated to 150~160 DEG C, addition portion to take part mineral oil to be fitted into reactor Segregation isobutene, stirring is completely dissolved to polyisobutene, adds rosin resin, remaining mineral oil is cooled to after stirring 120~130 DEG C, remaining polyisobutene is added, terpene resin, vaseline, age resistor, insect pheromone attractant keeps temperature It is made after degree stirring 30~40min, 1~2h of standing and defoaming.
The polyisobutene is polyisobutene PB2400, polyisobutene B12, one or more in polyisobutene B100.
The insect pheromone attractant is fly type pests insect pheromone attractant, and nocturnal moth class insect pheromone is lured One kind in agent, moth property pest insects pheromone attractant.
The age resistor is one kind in age resistor 350, antioxidant 264, age resistor 445, antioxidant 4010.
The preparation method of described a kind of luring property of environment-friendly type mythimna separata offset plate, it is characterised in that detailed process is:In mass ratio 1:1 insect sticker is well mixed with conduction oil after be fitted into hot melt coating machine, be heated to 120~140 DEG C, glue is melt into stream Body, then the insect sticker is uniformly coated on plastic plate, 0.5~1.0mm of control coating layer thickness.
The method have the benefit that:
(1)The present invention can be directed to a variety of pest and disease damages by changing the insect pheromone attractant added, and prevention effect reaches 86% More than;
(2)The present invention is nontoxic using polyisobutene, and molecular backbone is free of double bond, and light fastness aging is excellent, tack, high attachment Power, the advantages of hold good, water-fast, cold-resistant, ageing-resistant viscous time length, chemical stability and UV resistant, collaboration rosin resin, terpenes Resin, further improves durability and adhesive property;
(3)Insect sticker produced by the present invention is nonpoisonous and tasteless, permanent tack, reduces environmental pollution, has broad application prospects.
Embodiment
Take 100~150g mineral oil to be fitted into reactor, be heated to 150~160 DEG C, add 250~300g polyisobutene, Stirred to polyisobutene and be completely dissolved with 300~400r/min, add 100~120g rosin resins, 50~60g mineral oil, Continue to be cooled to 120~130 DEG C after stirring, add 50~60g polyisobutene, 80~100g terpene resins, 50~80g Vaseline, 3~5g age resistor, 1~2g insect pheromone attractants, keeping temperature with 500~600r/min stirring 30~ 40min, is then continued in vacuum drying chamber, 1~2h of standing and defoaming, obtains insect sticker, in mass ratio 1:1 by insect sticker and conduction oil It is fitted into after well mixed in hot melt coating machine, is heated to 120~140 DEG C, glue is melt into fluid, then by the insect sticker equably It is coated on plastic plate, controls 0.5~1.0mm of coating layer thickness, obtain mythimna separata offset plate.The polyisobutene is polyisobutene One or more in PB2400, polyisobutene B12, polyisobutene B100, the insect pheromone attractant is fly type pests elder brother One kind in worm pheromone attractant, nocturnal moth class insect pheromone attractant, moth property pest insects pheromone attractant.It is described anti- Old agent is one kind in age resistor 350, antioxidant 264, age resistor 445, antioxidant 4010.
Example 1
Take 100g mineral oil to be fitted into reactor, be heated to 150 DEG C, add 250g polyisobutene PB2400, stirred with 300r/min Mix to polyisobutene and be completely dissolved, add 100g rosin resins, 50g mineral oil continues to be cooled to 120 DEG C after stirring, 50g polyisobutene B12,80g terpene resin is added, 50g vaseline, 3g age resistor 350,1g fly type pests insect pheromones draw Lure, keeping temperature stirs 30min with 500r/min, then continues in vacuum drying chamber, standing and defoaming 1h obtains insect sticker, pressed Mass ratio 1:1 insect sticker is well mixed with conduction oil after be fitted into hot melt coating machine, be heated to 120 DEG C, glue is melt into stream Body, then the insect sticker is uniformly coated on plastic plate, coating layer thickness 0.5mm is controlled, mythimna separata offset plate is obtained.
Example 2
Take 120g mineral oil to be fitted into reactor, be heated to 155 DEG C, add 270g polyisobutene PB2400, stirred with 300r/min Mix to polyisobutene and be completely dissolved, add 110g rosin resins, 55g mineral oil continues to be cooled to 125 DEG C after stirring, 55g polyisobutene B100,90g terpene resin is added, 60g vaseline, 4g antioxidant 264s, 1g nocturnal moth class insect pheromones draw Lure, keeping temperature stirs 30min with 500r/min, then continues in vacuum drying chamber, standing and defoaming 1h obtains insect sticker, pressed Mass ratio 1:1 insect sticker is well mixed with conduction oil after be fitted into hot melt coating machine, be heated to 130 DEG C, glue is melt into stream Body, then the insect sticker is uniformly coated on plastic plate, coating layer thickness 0.8mm is controlled, mythimna separata offset plate is obtained.
Example 3
Take 150g mineral oil to be fitted into reactor, be heated to 160 DEG C, add 300g polyisobutene, stirred with 400r/min to poly- Isobutene is completely dissolved, and adds 120g rosin resins, and 60g mineral oil continues to be cooled to 130 DEG C after stirring, added 60g polyisobutene, 100g terpene resins, 80g vaseline, 5g antioxidant 4010s, 2g moths property pest insects pheromone attractant is protected Hold temperature and 40min is stirred with 600r/min, then continue in vacuum drying chamber, standing and defoaming 2h obtains insect sticker, in mass ratio 1: 1 insect sticker is well mixed with conduction oil after be fitted into hot melt coating machine, be heated to 140 DEG C, glue is melt into fluid, then should Insect sticker is uniformly coated on plastic plate, is controlled coating layer thickness 1.0mm, is obtained mythimna separata offset plate.
Example is detected, specific testing result such as table 1
Table 1
Project Example 1 Example 2 Example 3
Flies eradicative rate % 94.1 86.5 88.7
Nocturnal moth class eradicative rate % 89.1 95.2 87.8
Moth property pest type eradicative rate % 87.5 89.4 98.3
Persistence/the moon 9.2 9.5 9.8
As shown in Table 1, luring property of environment-friendly type mythimna separata offset plate control rate of the present invention is high, good endurance.

Claims (7)

1. a kind of luring property of environment-friendly type mythimna separata offset plate, including plastic base, insect sticker, conduction oil, it is characterised in that the insect sticker It is made up of following raw materials:Mineral oil, polyisobutene, rosin resin, terpene resin, vaseline, age resistor, insect pheromone are lured Agent.
2. a kind of luring property of environment-friendly type mythimna separata offset plate as claimed in claim 1, it is characterised in that the insect sticker constitutive material Parts by weight are 150~210 parts of mineral oil, 300~360 parts of polyisobutene, 100~120 parts of rosin resins, 80~100 parts of terpenes Resin, 50~80 parts of vaseline, 3~5 parts of age resistor, 1~2 part of insect pheromone attractant.
3. a kind of luring property of environment-friendly type mythimna separata offset plate as claimed in claim 1, it is characterised in that the insect sticker preparation process is Take part mineral oil to be fitted into reactor, be heated to 150~160 DEG C, add part polyisobutene, stir complete to polyisobutene Dissolving, adds rosin resin, remaining mineral oil is cooled to 120~130 DEG C, adds remaining polyisobutene after stirring, Terpene resin, vaseline, age resistor, insect pheromone attractant, keeping temperature is stirred after 30~40min, 1~2h of standing and defoaming It is made.
4. a kind of luring property of environment-friendly type mythimna separata offset plate as claimed in claim 1, it is characterised in that the polyisobutene is poly- isobutyl It is one or more in alkene PB2400, polyisobutene B12, polyisobutene B100.
5. a kind of luring property of environment-friendly type mythimna separata offset plate as claimed in claim 1, it is characterised in that the insect pheromone attractant For fly type pests insect pheromone attractant, nocturnal moth class insect pheromone attractant, in moth property pest insects pheromone attractant One kind.
6. a kind of luring property of environment-friendly type mythimna separata offset plate as claimed in claim 1, it is characterised in that the age resistor is age resistor 350th, one kind in antioxidant 264, age resistor 445, antioxidant 4010.
7. a kind of preparation method of luring property of environment-friendly type mythimna separata offset plate as described in any one of claim 1~6, it is characterised in that Detailed process is:In mass ratio 1:1 insect sticker is well mixed with conduction oil after be fitted into hot melt coating machine, be heated to 120 ~140 DEG C, glue is melt into fluid, then the insect sticker is uniformly coated on plastic plate, 0.5~1.0mm of control coating layer thickness .
CN201710509964.2A 2017-06-28 2017-06-28 A kind of luring property of environment-friendly type mythimna separata offset plate and preparation method thereof Pending CN107267088A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108611021A (en) * 2018-05-21 2018-10-02 贵州曌梅果蔬种植有限公司 A kind of walnut insect-prevention method
CN109280538A (en) * 2018-09-21 2019-01-29 佛山市森昂生物科技有限公司 A kind of trunk insect sticker
CN113980590A (en) * 2021-10-27 2022-01-28 上海昶法新材料有限公司 Novel biodegradable insect attracting plate and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN201075956Y (en) * 2007-04-30 2008-06-25 厦门大学 Tea plantation special armyworm slab rubber
CN102618190A (en) * 2012-04-10 2012-08-01 浙江固特热熔胶有限公司 Pollution-free efficient insect sticker for vegetables and orchards and preparation method thereof
CN105153971A (en) * 2015-09-28 2015-12-16 郑州欧柯奇仪器制造有限公司 Efficient hot-melt sticky insect glue and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN201075956Y (en) * 2007-04-30 2008-06-25 厦门大学 Tea plantation special armyworm slab rubber
CN102618190A (en) * 2012-04-10 2012-08-01 浙江固特热熔胶有限公司 Pollution-free efficient insect sticker for vegetables and orchards and preparation method thereof
CN105153971A (en) * 2015-09-28 2015-12-16 郑州欧柯奇仪器制造有限公司 Efficient hot-melt sticky insect glue and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108611021A (en) * 2018-05-21 2018-10-02 贵州曌梅果蔬种植有限公司 A kind of walnut insect-prevention method
CN109280538A (en) * 2018-09-21 2019-01-29 佛山市森昂生物科技有限公司 A kind of trunk insect sticker
CN113980590A (en) * 2021-10-27 2022-01-28 上海昶法新材料有限公司 Novel biodegradable insect attracting plate and preparation method thereof

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