CN107254806A - Label leather paper and its preparation method and application - Google Patents
Label leather paper and its preparation method and application Download PDFInfo
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- CN107254806A CN107254806A CN201710438674.3A CN201710438674A CN107254806A CN 107254806 A CN107254806 A CN 107254806A CN 201710438674 A CN201710438674 A CN 201710438674A CN 107254806 A CN107254806 A CN 107254806A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/55—Polyamides; Polyaminoamides; Polyester-amides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention provides a kind of label leather paper, including body paper and glue application solution, described body paper is counted including 30 50 parts of corn stalk fiber by weight, 45 60 parts of bleached cotton starch, 5 10 parts of viscose rayon, 0.1 4 parts of auxiliary agent amphiprotic polyacrylamide, 0.2 0.8 parts of modified starch precipitated calcium carbonate, 5 10 parts of 0.5 5 parts of the polyethylene glycol oxide with 2,500,000~3,000,000 molecular weight, 0 0.2 parts of defoamer and latex；Described latex is silicon propane, Carboxy emulsion, styrene-acrylic emulsion, aqueous polyurethane emulsion, any one of acrylic acid ester emulsion.The label leather paper has that wearability is good, pliability is good, and tensile strength is high, and moisture-inhibiting, permeability are good, because a quality is similar to leather.
Description
Technical field
The present invention relates to paper technology field, and in particular to a kind of label leather paper and its preparation method and application.
Background technology
Leather paper is commonly called as water-fastness brown paper, be a kind of high intensity, it is washable, printable, can stamp, lamination, coating,
The Low-carbon environment-friendlymaterial material of silk-screen.Its comfortable feel, is to be adapted to interiors of products or the outside ideal material used, extensively close to leather
It is general to be used for garment tag, drop, skin board, business card, high-grade suitcase, belt, carnival hat, handbag, Note-book cover, footwear material, high-grade production
The fields such as product decoration, stationery, art work packaging.
With the increasingly raising of people's life requirement, it is required for taking the label of clothes on the clothes of modern industrial process
The name of an article, particularly jeans series, it is desirable that it is a kind of can more resistant to washing label form.Because denim apparel is in seam
After the completion of process processed, a stone mill washing processing is also carried out, this requires the label on clothes in stone mill water-washing process, no
It is only wear-resisting, but also to maintain enough wet strengths；Jeans will heat gaza and continuous in stone mill water-washing process
Stir, label will bear very big friction and rub together with clothes, therefore it is required that paper used there will be foot under moisture state
Enough toughness and intensity, and now common kraft liner is all difficult to meet this requirement.
The content of the invention
In view of the shortcomings of the prior art, the present invention provides that a kind of wearability is good, pliability is good, and tensile strength is high, moisture-inhibiting, thoroughly
Gas excellent performance, because a quality is similar to the label leather paper of leather；Present invention also offers label leather paper preparation side
Method.
To realize goal of the invention, the present invention uses following technical scheme：
Label leather paper, including body paper and glue application solution, described body paper are counted including corn stalk fiber by weight
30-50 parts, 45-60 parts of bleached cotton starch, 5-10 parts of viscose rayon, 0.1-4 parts of auxiliary agent amphiprotic polyacrylamide, modified starch lightweight
0.2-0.8 parts of calcium carbonate, 0.5-5 parts of the polyethylene glycol oxide with 2,500,000~3,000,000 molecular weight, 0-0.2 parts of defoamer and latex
5-10 parts；Described latex is silicon propane, Carboxy emulsion, styrene-acrylic emulsion, aqueous polyurethane emulsion, acrylic acid ester emulsion
It is any；
Described glue application solution, by weight meter include above-mentioned latex 5-10 parts, 80-100 parts of oxidized starch, cation ether
Change 5-10 parts of modified polyvinylalcohol drying strengthening agent, 2-5 parts of sodium hexametaphosphate dispersant, 0.5-2 parts of degasser, 0.5-2 parts of bactericide.
Preferably, the preparation method of described corn stalk fiber be first maize straw is cleaned, segment, with steaming
Cooking method extracts straw hide fiber, Paper White Degree is met the requirements by bleaching, then makes fibrous refinement by mashing.
Preferably, the preparation method of described amphiprotic polyacrylamide is using chitosan and acrylamide (AM), Malaysia
Sour (MA), MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride (DMC) graft copolymerization, prepare chitosan graft both sexes polyacrylamide
Amine, amphiprotic polyacrylamide is respectively provided with enhancing and retention aid and filtering aid well and auxiliary sizing efficiency to various slurries.
Preferably, the preparation method of described amphiprotic polyacrylamide is in 70 DEG C of acetic acid chitosans, addition AM,
MA, DMC obtain mixed solution, and chitosan, AM, MA, DMC mol ratio are drawn for 1: 9: 5: 1,80 DEG C toward addition ternary in mixed solution
Agent (sodium peroxydisulfate, sodium hydrogensulfite, ammonium ceric nitrate) is sent out, 4h is reacted.
Preferably, the preparation method of described modified starch precipitated calcium carbonate is (relative to light by starch consumption 28%
Matter calcium carbonate) and precipitated calcium carbonate filler burn cup mixing, add water, be mixed into solid content be 28% solution, use glass
Rod stirs 5min, and mixture is then put into oven, and temperature sets 90 DEG C, and 45~60min of boiling stirrings form colloid substance.
Preparation method of the present invention on label leather paper, takes following technological means：
The preparation method of label leather paper, comprises the following steps：
Step 1: corn stalk fiber, bleached cotton starch and viscose rayon are discongested in deflaker by dosage
Mashing, then concentration 3.5-5.5%, pH value 6-8 slurry is being made with stock tank dilution；
Step 2: toward the amphiprotic polyacrylamide that dosage is added in slurry, modified starch precipitated calcium carbonate, with 250
The polyethylene glycol oxide of ten thousand~3,000,000 molecular weight, defoamer and latex, are stirred the slurry for being mixed to get concentration 2.5-4.8%；
Step 3: the slurry that step 2 is obtained routinely manufacture paper with pulp and squeeze and obtain body paper by condition online；
Step 4: body paper is cleaned with EtOH Sonicate, dried at (30~60) DEG C, it is standby, by EtOH Sonicate, by particulate
Deng removing；
Step 5: preparing sizing agent, oxidized starch and water are carried out stirring to be mixed with 90~95 DEG C of heating to be contained
Starch quality concentration is 10-20% glue, when under the bright orange state that is translucent, and adds latex, the etherification modified poly- second of cation
Enol drying strengthening agent, sodium hexametaphosphate dispersant, degasser and bactericide continuation cross the sieved filter of vibration and obtain sizing agent after stirring；
Step 6: the body paper that step 4 is handled carries out positive coating again after being coated with through sizing applicator reverse side, it is positive during coating
Resin added control at 3~4 grams/m, the resin added of reverse side is controlled at 2~3 grams/m, then through drying, batch, it is multiple
Volume cutting glue.
The label leather paper of the present invention uses corn stalk fiber, and body paper is made in bleached cotton starch and viscose rayon,
Existing China's timber resources wherein can be solved using corn stalk fiber more poor, it is necessary to dependent on import pulp, corn
Stalk fibre, which substitutes wood pulp cellulose, has the characteristics of economizing on resources, reduce cost, and cotton pulp is a kind of resourceful, renewable
, non-wood material extremely leaved for development, special.Cotton pulp has its unique distinction compared with wood pulp, straw pulp, its containing cellulose compared with
Pure, fiber is elongated and flexible, tough and tensile folding, soft, and absorbent properties are good, the opacity with height, and can be with prolonged
Preserve, and viscose rayon is essential pure, can be resistant to sunlight exposure, mothproof, high temperature resistant, pair can to chemical substance not allergy
Melt and dissolved dose has good repellence with mould, and synergy, obtained body paper can be played using three kinds of fibers as fibrous raw material
With water-fastness, temperature tolerance, wearability, resistance to acids and bases, the characteristic of light weight.
Amphiprotic polyacrylamide is added in the preparation process of body paper, various slurries, which can be respectively provided with, strengthens and help well
Stay drainage and auxiliary sizing efficiency.Modified starch precipitated calcium carbonate is added because the whiteness of precipitated calcium carbonate PCC fillers is higher,
So that the whiteness of body paper is also higher, while the filler improves the physical property of body paper, it can not only improve the performance of paper, also
Fibre material can be saved.Polyethylene glycol oxide has the performances, polyoxy such as flocculation, thickening, sustained release, lubrication, scattered, retention, water conservation
Beating time can also be shortened by changing ethene, the paper pulp that beating degree can be used relatively low, the good paper of evenness of manufacturing paper with pulp out, while paper
Page flexibility and intensity are all preferable.The polyethylene glycol oxide of 2500000~3,000,000 molecular weight, its extensibility macromolecular structure is prevented
Contacting with each other for long fibre surface, improves the viscosity of slurry suspension body, therefore limits the generation of fiber flocculation.
Added in sizing agent described latex can be efficiently modified paper tensile strength, tearing strength, water resistant, grease resistance and
Flexibility；The addition of other auxiliary agents make it that paper Bulk coat is thin simultaneously, and elasticity, tackness are good, soft, and intensity is big, resistance to
Mill property and water proofing property are good and paper is had moisture-inhibiting, permeability, accordingly ensure that paper quality is similar to leather.
Embodiment
The invention is further illustrated by the following examples, but the present invention is not limited solely to following examples.
Embodiment 1
Label leather paper, including body paper and glue application solution, described body paper are counted including corn stalk fiber by weight
30 parts, 4 parts of bleached cotton starch, 5 parts of viscose rayon, 0.1 part of auxiliary agent amphiprotic polyacrylamide, 0.2 part of modified starch precipitated calcium carbonate,
5 parts of 0.5 part of polyethylene glycol oxide with 2,500,000~3,000,000 molecular weight and latex；Described latex is Carboxy emulsion；
Described glue application solution, by weight meter include above-mentioned 5 parts of Carboxy emulsion, 80 parts of oxidized starch, cation
5 parts of etherification modified polyvinyl alcohol drying strengthening agent, 2 parts of sodium hexametaphosphate dispersant, 0.5 part of degasser, 0.5 part of bactericide.
The preparation method of described corn stalk fiber be first maize straw is cleaned, segment, extracted with cooking process
Straw hide fiber, makes Paper White Degree meet the requirements by bleaching, then makes fibrous refinement by mashing.
The preparation method of described amphiprotic polyacrylamide is, in 70 DEG C of acetic acid chitosans, to add acrylamide
(AM), maleic acid (MA), MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride (DMC) obtain mixed solution, chitosan, AM, MA, DMC
Mol ratio for 1: 9: 5: 1,80 DEG C toward addition ternary initiator (sodium peroxydisulfate, sodium hydrogensulfite, cerous nitrate in mixed solution
Ammonium), reaction 4h is made.
The preparation method of described modified starch precipitated calcium carbonate is by starch consumption 28% (relative to precipitated calcium carbonate)
Cup mixing is being burnt with precipitated calcium carbonate filler, water is added, the solution that solid content is 28% is being mixed into, is stirred with glass bar
Mixture, is then put into oven by 5min, and temperature sets 90 DEG C, and 45~60min of boiling stirrings form colloid substance.
The preparation method of label leather paper, comprises the following steps：
Step 1: by above-mentioned dosage by corn stalk fiber, bleached cotton starch, viscose rayon deflaker is discongested
Mashing, then concentration 3.5%, pH value 6-8 slurry is being made with stock tank dilution；
Step 2: toward the amphiprotic polyacrylamide that above-mentioned dosage is added in slurry, modified starch precipitated calcium carbonate and tool
There are the polyethylene glycol oxide and Carboxy emulsion of 2,500,000~3,000,000 molecular weight, be stirred the slurry for being mixed to get concentration 2.5%
Material；
Step 3: the slurry that step 2 is obtained routinely manufacture paper with pulp and squeeze and obtain body paper by condition online；
Step 4: body paper is cleaned with EtOH Sonicate, dried at (30~60) DEG C, it is standby, by EtOH Sonicate, by particulate
Deng removing；
Step 5: preparing sizing agent, oxidized starch and water are carried out stirring to be mixed with 90~95 DEG C of heating to be contained
Starch quality concentration is 10% glue, when under the bright orange state that is translucent, and adds latex, cation etherification modified polyvinyl alcohol
Drying strengthening agent, sodium hexametaphosphate dispersant, degasser and bactericide continuation cross the sieved filter of vibration and obtain sizing agent after stirring；
Step 6: the body paper that step 4 is handled carries out positive coating again after being coated with through sizing applicator reverse side, it is positive during coating
Resin added control at 3~4 grams/m, the resin added of reverse side is controlled at 2~3 grams/m, then through drying, batch, it is multiple
Volume cutting glue.
Embodiment 2
Label leather paper, including body paper and glue application solution, described body paper are counted including corn stalk fiber by weight
50 parts, 60 parts of bleached cotton starch, 10 parts of viscose rayon, 4 parts of auxiliary agent amphiprotic polyacrylamide, 0.8 part of modified starch precipitated calcium carbonate,
10 parts of 5 parts of the polyethylene glycol oxide with 2,500,000~3,000,000 molecular weight, 0.2 part of defoamer and latex；Described latex is phenylpropyl alcohol
Emulsion；
Described glue application solution, by weight meter include above-mentioned 10 parts of styrene-acrylic emulsion, 100 parts of oxidized starch, cation ether
Change 10 parts of modified polyvinylalcohol drying strengthening agent, 5 parts of sodium hexametaphosphate dispersant, 2 parts of degasser, 2 parts of bactericide.
The preparation method of described corn stalk fiber be first maize straw is cleaned, segment, extracted with cooking process
Straw hide fiber, makes Paper White Degree meet the requirements by bleaching, then makes fibrous refinement by mashing.
The preparation method of described amphiprotic polyacrylamide is, in 70 DEG C of acetic acid chitosans, to add acrylamide
(AM), maleic acid (MA), MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride (DMC) obtain mixed solution, chitosan, AM, MA, DMC
Mol ratio for 1: 9: 5: 1,80 DEG C toward addition ternary initiator (sodium peroxydisulfate, sodium hydrogensulfite, cerous nitrate in mixed solution
Ammonium), reaction 4h is made.
The preparation method of described modified starch precipitated calcium carbonate is by starch consumption 28% (relative to precipitated calcium carbonate)
Cup mixing is being burnt with precipitated calcium carbonate filler, water is added, the solution that solid content is 28% is being mixed into, is stirred with glass bar
Mixture, is then put into oven by 5min, and temperature sets 90 DEG C, and 45~60min of boiling stirrings form colloid substance.
The preparation method of label leather paper, comprises the following steps：
Step 1: corn stalk fiber, bleached cotton starch and viscose rayon are discongested in deflaker by dosage
Mashing, then concentration 5.5%, pH value 6-8 slurry is being made with stock tank dilution；
Step 2: toward the amphiprotic polyacrylamide that dosage is added in slurry, modified starch precipitated calcium carbonate, with 250
The polyethylene glycol oxide of ten thousand~3,000,000 molecular weight, defoamer and styrene-acrylic emulsion, are stirred the slurry for being mixed to get concentration 4.8%；
Step 3: the slurry that step 2 is obtained routinely manufacture paper with pulp and squeeze and obtain body paper by condition online；
Step 4: body paper is cleaned with EtOH Sonicate, dried at (30~60) DEG C, it is standby, by EtOH Sonicate, by particulate
Deng removing；
Step 5: preparing sizing agent, oxidized starch and water are carried out stirring to be mixed with 90~95 DEG C of heating to be contained
Starch quality concentration is 20% glue, when under the bright orange state that is translucent, and adds latex, cation etherification modified polyvinyl alcohol
Drying strengthening agent, sodium hexametaphosphate dispersant, degasser and bactericide continuation cross the sieved filter of vibration and obtain sizing agent after stirring；
Step 6: the body paper that step 4 is handled carries out positive coating again after being coated with through sizing applicator reverse side, it is positive during coating
Resin added control at 3~4 grams/m, the resin added of reverse side is controlled at 2~3 grams/m, then through drying, batch, it is multiple
Volume cutting glue.
Embodiment 3
Label leather paper, including body paper and glue application solution, described body paper are counted including corn stalk fiber by weight
45 parts, 50 parts of bleached cotton starch, 6 parts of viscose rayon, 3 parts of auxiliary agent amphiprotic polyacrylamide, 0.6 part of modified starch precipitated calcium carbonate,
8 parts of 1.5 parts of the polyethylene glycol oxide with 2,500,000~3,000,000 molecular weight, 0.1 part of defoamer and latex；Described latex is propylene
Acid esters emulsion；
Described glue application solution, by weight meter include 8 parts of acrylic acid ester emulsion, 90 parts of oxidized starch, cation etherificate
7 parts of modified polyvinylalcohol drying strengthening agent, 3 parts of sodium hexametaphosphate dispersant, 1.5 parts of degasser, 1.2 parts of bactericide.
The preparation method of described corn stalk fiber be first maize straw is cleaned, segment, extracted with cooking process
Straw hide fiber, makes Paper White Degree meet the requirements by bleaching, then makes fibrous refinement by mashing.
The preparation method of described amphiprotic polyacrylamide is, in 70 DEG C of acetic acid chitosans, to add acrylamide
(AM), maleic acid (MA), MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride (DMC) obtain mixed solution, chitosan, AM, MA, DMC
Mol ratio for 1: 9: 5: 1,80 DEG C toward addition ternary initiator (sodium peroxydisulfate, sodium hydrogensulfite, cerous nitrate in mixed solution
Ammonium), reaction 4h is made.
The preparation method of described modified starch precipitated calcium carbonate is by starch consumption 28% (relative to precipitated calcium carbonate)
Cup mixing is being burnt with precipitated calcium carbonate filler, water is added, the solution that solid content is 28% is being mixed into, is stirred with glass bar
Mixture, is then put into oven by 5min, and temperature sets 90 DEG C, and 45~60min of boiling stirrings form colloid substance.
The preparation method of label leather paper, comprises the following steps：
Beaten Step 1: by corn stalk fiber bleached cotton starch and viscose rayon deflaker discongest by dosage
Slurry, then concentration 1.5%, pH value 6-8 slurry is being made with stock tank dilution；
Step 2: toward the amphiprotic polyacrylamide that dosage is added in slurry, modified starch precipitated calcium carbonate, with 250
The polyethylene glycol oxide of ten thousand~3,000,000 molecular weight, defoamer and acrylic acid ester emulsion, are stirred and are mixed to get concentration 1.3%
Slurry；
Step 3: the slurry that step 2 is obtained routinely manufacture paper with pulp and squeeze and obtain body paper by condition online；
Step 4: body paper is cleaned with EtOH Sonicate, dried at (30~60) DEG C, it is standby, by EtOH Sonicate, by particulate
Deng removing；
Step 5: preparing sizing agent, oxidized starch and water are carried out stirring to be mixed with 90~95 DEG C of heating to be contained
Starch quality concentration is 17% glue, when under the bright orange state that is translucent, addition acrylic acid ester emulsion, cation are etherification modified
Polyvinyl alcohol drying strengthening agent, sodium hexametaphosphate dispersant, degasser and bactericide continuation are crossed the sieved filter of vibration and are glued after stirring
Agent；
Step 6: the body paper that step 4 is handled carries out positive coating again after being coated with through sizing applicator reverse side, it is positive during coating
Resin added control at 3~4 grams/m, the resin added of reverse side is controlled at 2~3 grams/m, then through drying, batch, it is multiple
Volume cutting glue.
Label made from above-described embodiment is as shown in the table with leather paper technical indicator：
The quality of above-mentioned leather paper all meets the intensity requirement of the wet-strength paper of national regulation, and outward appearance papery is soft, without broken
Hole, lumps, after soaking firmly rub 80 times it is not stratified.
The leather-like paper with high wet strength provided by the present invention compared with prior art, with more preferable intensity and water-fastness
Function, is suitably applied the label name of an article on the clothes of modern industrial process, particularly jeans series, is suitable as one
Plant more resistant, more resistant to the label raw material of washing.
Finally illustrate, preferred embodiment above is merely illustrative of the technical solution of the present invention and unrestricted, although logical
Cross above preferred embodiment the present invention is described in detail, it is to be understood by those skilled in the art that can be
Various changes are made to it in form and in details, without departing from claims of the present invention limited range.
Claims (5)
1. label leather paper, including body paper and glue application solution, described body paper are counted including corn stalk fiber 30- by weight
50 parts, 45-60 parts of bleached cotton starch, 5-10 parts of viscose rayon, 0.1-4 parts of auxiliary agent amphiprotic polyacrylamide, modified starch lightweight carbon
Sour calcium 0.2-0.8 parts, 0.5-5 parts of the polyethylene glycol oxide with 2,500,000~3,000,000 molecular weight, 0-0.2 parts of defoamer and latex 5-
10 parts；Described latex is times of silicon propane, Carboxy emulsion, styrene-acrylic emulsion, aqueous polyurethane emulsion, acrylic acid ester emulsion
What is a kind of；
Described glue application solution, by weight meter include above-mentioned latex 5-10 parts, and 80-100 parts of oxidized starch, cation etherificate changes
Property 5-10 parts of polyvinyl alcohol drying strengthening agent, 2-5 parts of sodium hexametaphosphate dispersant, 0.5-2 parts of degasser, 0.5-2 parts of bactericide.
2. label leather paper according to claim 1, it is characterised in that the preparation side of described amphiprotic polyacrylamide
Method is using chitosan and acrylamide AM, maleic acid MA, MethacryloyloxyethylTrimethyl Trimethyl Ammonium Chloride DMC graft copolymerizations, system
For chitosan graft amphiprotic polyacrylamide is gone out, amphiprotic polyacrylamide is respectively provided with enhancing and retention well to various slurries and helped
Filter and auxiliary sizing efficiency.
3. label leather paper according to claim 2, it is characterised in that the preparation side of described amphiprotic polyacrylamide
Method is, in 70 DEG C of acetic acid chitosans, to add AM, MA, DMC and obtain mixed solution, chitosan, AM, MA, DMC mol ratio are 1:
9: 5: 1,80 DEG C, toward addition ternary initiator sodium peroxydisulfate, sodium hydrogensulfite, ammonium ceric nitrate in mixed solution, are reacted 4h.
4. label leather paper according to claim 1, it is characterised in that the system of described modified starch precipitated calcium carbonate
Preparation Method is that 28% starch and precipitated calcium carbonate filler of precipitated calcium carbonate consumption are being burnt into cup mixing, adds water, mixing
Into the solution that solid content is 28%, 5min is stirred with glass bar, mixture is then put into oven, temperature sets 90 DEG C, boiling 45
~60min is stirred, and forms colloid substance.
5. the preparation method of the label leather paper as described in Claims 1-4 is any, it is characterised in that comprise the following steps：
Step 1: carry out discongesting mashing in deflaker by corn stalk fiber, bleached cotton starch and viscose rayon by dosage,
Concentration 3.5-5.5%, pH value 6-8 slurry is being made with stock tank dilution again；
Step 2: toward the amphiprotic polyacrylamide that dosage is added in slurry, modified starch precipitated calcium carbonate, with 2,500,000~
The polyethylene glycol oxide of 3000000 molecular weight, defoamer and latex, are stirred the slurry for being mixed to get concentration 2.5-4.8%；
Step 3: the slurry that step 2 is obtained routinely manufacture paper with pulp and squeeze and obtain body paper by condition online；
Step 4: body paper is cleaned with EtOH Sonicate, dried at (30~60) DEG C, it is standby, by EtOH Sonicate, particulate etc. is removed
Go；
Step 5: preparing sizing agent, oxidized starch and water are carried out stirring to be mixed with 90~95 DEG C of heating to obtain starch-containing
Mass concentration is 10-20% glue, when under the bright orange state that is translucent, and adds latex, cation etherification modified polyvinyl alcohol
Drying strengthening agent, sodium hexametaphosphate dispersant, degasser and bactericide continuation cross the sieved filter of vibration and obtain sizing agent after stirring；
Step 6: the body paper that step 4 is handled carries out positive coating again after being coated with through sizing applicator reverse side, it is positive during coating to apply
The control of glue amount is at 3~4 grams/m, and the resin added of reverse side is controlled at 2~3 grams/m, then through drying, batch, rewinding point
Cut glue.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110344276A (en) * | 2019-06-29 | 2019-10-18 | 华南理工大学 | A kind of pure plain leather of biology base high gloss and its manufacturing method |
| CN110904736A (en) * | 2019-12-06 | 2020-03-24 | 淄博欧木特种纸业有限公司 | Color fiber leather-like paper and preparation method thereof |
| CN112721306A (en) * | 2020-12-30 | 2021-04-30 | 江苏洋河集团包装材料有限公司 | Production process of corrugated carton for packaging high-strength white spirit |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101161929A (en) * | 2007-10-26 | 2008-04-16 | 黄寒 | Paint for coating chromatic bobbin printed sheet and preparation method thereof |
| CN101215807A (en) * | 2008-01-08 | 2008-07-09 | 陕西科技大学 | Method for preparing cationic polyvinyl alcohol paper intensifier |
| CN102587202A (en) * | 2012-02-23 | 2012-07-18 | 富阳市茂宏纸业有限公司 | Preparation technology for craft paper and paint for coating craft paper |
| CN102978996A (en) * | 2012-12-08 | 2013-03-20 | 杭州特种纸业有限公司 | Method for preparing high wet strength leather paper |
| CN103833862A (en) * | 2014-02-27 | 2014-06-04 | 华南理工大学 | Oxidized glutinous rice starch as well as preparation method and application thereof |
| CN104846689A (en) * | 2015-05-04 | 2015-08-19 | 杭州特种纸业有限公司 | High-wet-intensity leather paper and preparation method and application thereof |
-
2017
- 2017-06-12 CN CN201710438674.3A patent/CN107254806A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101161929A (en) * | 2007-10-26 | 2008-04-16 | 黄寒 | Paint for coating chromatic bobbin printed sheet and preparation method thereof |
| CN101215807A (en) * | 2008-01-08 | 2008-07-09 | 陕西科技大学 | Method for preparing cationic polyvinyl alcohol paper intensifier |
| CN102587202A (en) * | 2012-02-23 | 2012-07-18 | 富阳市茂宏纸业有限公司 | Preparation technology for craft paper and paint for coating craft paper |
| CN102978996A (en) * | 2012-12-08 | 2013-03-20 | 杭州特种纸业有限公司 | Method for preparing high wet strength leather paper |
| CN103833862A (en) * | 2014-02-27 | 2014-06-04 | 华南理工大学 | Oxidized glutinous rice starch as well as preparation method and application thereof |
| CN104846689A (en) * | 2015-05-04 | 2015-08-19 | 杭州特种纸业有限公司 | High-wet-intensity leather paper and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 朱阳阳、金二锁等: "两性聚丙烯酰胺的性质、合成与应用研究进展", 《化工进展》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110344276A (en) * | 2019-06-29 | 2019-10-18 | 华南理工大学 | A kind of pure plain leather of biology base high gloss and its manufacturing method |
| CN110904736A (en) * | 2019-12-06 | 2020-03-24 | 淄博欧木特种纸业有限公司 | Color fiber leather-like paper and preparation method thereof |
| CN110904736B (en) * | 2019-12-06 | 2022-02-18 | 淄博欧木特种纸业有限公司 | Color fiber leather-like paper and preparation method thereof |
| CN112721306A (en) * | 2020-12-30 | 2021-04-30 | 江苏洋河集团包装材料有限公司 | Production process of corrugated carton for packaging high-strength white spirit |
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Application publication date: 20171017 |