CN107419577B - A kind of preparation method of high intensity paper twine body paper - Google Patents

A kind of preparation method of high intensity paper twine body paper Download PDF

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Publication number
CN107419577B
CN107419577B CN201710894153.9A CN201710894153A CN107419577B CN 107419577 B CN107419577 B CN 107419577B CN 201710894153 A CN201710894153 A CN 201710894153A CN 107419577 B CN107419577 B CN 107419577B
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parts
paper
sent
weight
chemical fibre
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CN107419577A (en
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江峰
陈君花
严金英
周兆祥
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Zhejiang Shunpu New Materials Technology Co Ltd
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Zhejiang Shunpu New Materials Technology Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21BFIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00Fibrous raw materials or their mechanical treatment
    • D21B1/04Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D21B1/30Defibrating by other means
    • D21B1/34Kneading or mixing; Pulpers
    • D21B1/345Pulpers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/12Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/14Polyalkenes, e.g. polystyrene polyethylene
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18Reinforcing agents
    • D21H21/20Wet strength agents

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Paper (AREA)

Abstract

The present invention provides a kind of preparation methods of high-intensitive paper twine body paper, needlebush wood pulp is placed in pulper, dyestuff, beating consistency 3-5% are added, it is beaten 40-45 ° of SR of beating degree, it is sent into mud pit, color fixing agent, wet strength agent is added, ionic liquid remover, it is sufficiently mixed, slurry is sent into net cage, PVC chemical fibre dispersion liquid is sent into net cage;Become page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, 90-100 DEG C heating 5-15 hours, obtain paper twine body paper.

Description

A kind of preparation method of high intensity paper twine body paper
Technical field
The present invention relates to establishment paper field, especially a kind of preparation method of high-intensitive paper twine body paper.
Background technique
Weave paper is a kind of emerging technique textile material.It is with easy to process, handsome in appearance, bright in colour, durable Without fading, the main dry various paper strings of braiding are made various sudd caps, paper cloth, summer sleeping mat, fold pillow mat, wall cloth and various Decorative craft.With ventilated ability of sweat absorption, and durability is good, the variation of cold-resistant hot weather, energy recycling and reusing, no Pollute environment.Traditional establishment paper is by the mutual winding of fiber and longitudinal arrangement to reach required intensity, these paper The paper slip that can only generally cut into 6mm or more is opened, rag paper rope can only be worked out.
Paper yarn body paper is also referred to as paper twine body paper, often using safety and environmental protection, good toughness plant fiber as raw material, by specific item Part is processed into paper paper slip, and paper slip is twisted or wound into paper yarn;The paper yarn of sub-thread further can also be twisted bifilar or multiply Paper yarn, to meet the requirement of different fabrics.Paper yarn body paper have the characteristics that it is quantitative it is low, intensity is high, elongation is larger, can slitting At narrow serial obbbin.
CN101440588B discloses a kind of base paper of paper yarn for textile and preparation process, is with following weight percent Raw material is made: bleached softwood wood sulfate pulpboard 60-80%, jute pulp or/and bamboo pulp 20-30%, water soluble fiber 3-8%, owns Group subtotaling 100%.The preparation process of base paper of paper yarn for textile, benefit in the upper cylinder half process before being batched in paper pulp copy paper technique The film before batching is given to spread colloid to increase the dry and wet intensity of body paper with glue spreader.Product of the present invention has water suction fast, ventilative Property good, light and comfortable, machine washable, cut twist it is functional, be a kind of reproducible environment-friendly products.
CN103741556A discloses a kind of preparation process of base paper of paper yarn for textile, in the raw material, water soluble fiber, Wood pulp, bleached softwood wood sulfate pulpboard, bacterial fibers proportion are as follows: water soluble fiber 3%~8%, wood pulp 25%~35%, bleaching needle Leaf wood sulfate pulpboard 50%~85%, bacterial fibers 2.5%~5%, all components total 100%.The present invention is mainly using bleaching needle Leaf wood sulfate pulpboard avoids the bleaching of sulfur dioxide as main slurries, so that product is not easy to turn to be yellow, influences appearance;And The present invention is added with non-plant fibre, that is, bacterial fibers, and by the synergistic effect of auxiliary agent in the process of making, makes the object of body paper Reason intensity greatly improves, and while the dry strength and wet strength that ensure that into paper, and has preferable water imbibition and flexibility.
CN101280532B discloses the preparation process of base paper of paper yarn for textile, and water-solubility PVA synthetic fibers exist first It is impregnated in water;Then bacterial cellulose wet-coating is soaked in NaOH solution, then wood pulp cellulose is discongested with Valley beater Then it is mixed with by pretreated water-solubility PVA synthetic fibers, refining is carried out in PFI fiberizer by cutting, finally plus Enter bacterial fibers, PEO, CMC, PAE be uniformly mixed, by approach system, paper is manufactured paper with pulp into using usual manner.The present invention is using non- Plant fiber, that is, bacterial fibers, WATER-SOLUBLE PVA FIBER are mixed in proportion with wood pulp plant fiber and are manufactured paper with pulp.Using methods of beating to each Kind fiber has carried out different mashing processing to improve the ru nnability of fiber, binding force between reinforcing fiber;And by manufacturing paper with pulp The synergistic effect of auxiliary agent in the process greatly improves the physical strength of body paper.
The dry strength and wet strength of the paper yarn body paper produced now are all not up to standard, currently used as the hydrocarbon of corrugation removing auxiliary agent Oil is incompatible with creping adhesives, it is therefore desirable to improve Wrinkling stripping-agent, and water imbibition and flexibility be not also up to standard, page is contaminating Xerotripsis during color, wet rubbing, grade is low, and wet strength is low.Therefore the development of some related textile industries is also constrained.
Summary of the invention
The object of the present invention is to provide a kind of processing and fabricatings to be easy, and strong operability, paper strength is high, and water-fastness is a kind of high The preparation method of intensity paper twine body paper.
There is provided a kind of preparation method of high-intensitive paper twine body paper, it is characterised in that following steps:
(1) by weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.01-0.5 parts of dyestuffs, be beaten Concentration 2-10% is beaten 40-45 ° of SR of beating degree, is sent into mud pit, and 0.1-1 parts of color fixing agent, 3-10 parts of wet strength agents, 0.1- is added 0.5 part of ionic liquid remover, is sufficiently mixed;
(2) by weight, by 100 parts of PVC chemical fibres, 3000-7000 parts of water are stirred 2-8 hours, obtain PVC chemical fibre point Dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 100-500 parts of PVC chemical fibre dispersion liquids is sent into Net cage;Become page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats at 90-100 DEG C 5-15 hours, obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: by weight: 100 parts of ethylene glycol, 0.5-2 parts of tall oil acids and mostly Asia Alkyl polyamine reactant, 0.1-1 parts of trimethyl hydroxyethylammonium ammonium hexafluorophosphates, 0.01-0.1 parts of aphthenic acids cerium salts, 30-60 DEG C mixed It closes 1-5 hours, obtains ionic liquid remover.
The color fixing agent, wet strength agent are auxiliary agent commonly used in the art, are commercial product, the present invention is with no restrictions.
The ethylene glycol, tall oil acid and polyalkylenepolyamines reactant, trimethyl hydroxyethylammonium ammonium hexafluorophosphate, cycloalkanes Sour cerium salt is commercial product.
Product of the invention has the advantages that
A kind of preparation method of high-intensitive paper twine body paper of the present invention, remover are obtained with creping adhesives compatibility Improve, while solving page xerotripsis in dyeing course, wet rubbing, grade is low, the low problem of wet strength.
Specific embodiment
Following instance is only to further illustrate the present invention, is not limitation the scope of protection of the invention.
Embodiment 1
Pink paper twine body paper preparation method, it is characterised in that following steps:
(1) by weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.02 part of pink color, beats Concentration 4% is starched, 43 ° of SR of beating degree are beaten, is sent into mud pit, 0.3 part of color fixing agent, 7 parts of wet strength agents, 0.4 part of ionic liquid stripping is added From agent, it is sufficiently mixed;
(2) by weight, by 100 parts of PVC chemical fibres, 5000 parts of water stir 5 hours, obtain PVC chemical fibre dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 250 parts of PVC chemical fibre dispersion liquids is sent into net Case;Becoming page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats 8 hours at 94 DEG C, Obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: by weight: 100 parts of ethylene glycol, 1 part of tall oil acid and polyalkylene Polyamine reactant, 0.3 part of trimethyl hydroxyethylammonium ammonium hexafluorophosphate, 0.05 part of aphthenic acids cerium salt, 40 DEG C mix 3 hours, obtain Ionic liquid remover.
Page is detected, Gan Kangqiang index 101Nm/g, wet to resist strong index 46.8Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 Grade.
Embodiment 2
There is provided a kind of preparation method of high-intensitive paper twine body paper, it is characterised in that following steps:
(1) by weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.01 part of dyestuff, beating consistency 2%, 40 ° of SR of beating degree are beaten, mud pit is sent into, 0.1 part of color fixing agent, 3 parts of wet strength agents is added, 0.1 part of ionic liquid remover fills Divide mixing;
(2) by weight, by 100 parts of PVC chemical fibres, 3000 parts of water stir 2 hours, obtain PVC chemical fibre dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 100 parts of PVC chemical fibre dispersion liquids is sent into net Case;Becoming page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats 5 hours at 90 DEG C, Obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: by weight: 100 parts of ethylene glycol, 0.5 part of tall oil acid and more alkylenes Quito amine reactant, 0.1 part of trimethyl hydroxyethylammonium ammonium hexafluorophosphate, 0.01 part of aphthenic acids cerium salt, 30 DEG C mix 5 hours, obtain To ionic liquid remover.
Page is detected, Gan Kangqiang index 98Nm/g, wet to resist strong index 45.4Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Embodiment 3
(1) by weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.5 part of dyestuff, beating consistency 10%, 45 ° of SR of beating degree are beaten, mud pit is sent into, 1 part of color fixing agent, 10 parts of wet strength agents is added, 0.5 part of ionic liquid remover fills Divide mixing;
(2) by weight, by 100 parts of PVC chemical fibres, 7000 parts of water stir 8 hours, obtain PVC chemical fibre dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 500 parts of PVC chemical fibre dispersion liquids is sent into net Case;Become page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, small in 100 DEG C of heating 15 When, obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: by weight: 100 parts of ethylene glycol, 2 parts of tall oil acids and polyalkylene Polyamine reactant, 1 part of trimethyl hydroxyethylammonium ammonium hexafluorophosphate, 0.1 part of aphthenic acids cerium salt, obtain ion at 60 DEG C of mixing hours Liquid remover.
Page is detected, Gan Kangqiang index 112Nm/g, wet to resist strong index 48.5Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 Grade.
Embodiment 4
The preparation method of grey paper twine body paper, it is characterised in that following steps:
(1) by weight, 100 parts of Canadian North Sea needlebush wood pulps are placed in pulper, add 0.3 part of grey Dyestuff, beating consistency 5% are beaten 42 ° of SR of beating degree, are sent into mud pit, are added 0.2 part of color fixing agent, 7 parts of wet strength agents, and 0.15 part Ionic liquid remover, is sufficiently mixed;
(2) by weight, by 100 parts of PVC chemical fibres, 3000-7000 parts of water are stirred 2-8 hours, obtain PVC chemical fibre point Dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 260 parts of PVC chemical fibre dispersion liquids is sent into net Case;Becoming page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats 6 hours at 95 DEG C, Obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: 100 parts of ethylene glycol, 0.77 part of tall oil acid and polyalkylenepolyamines are anti- Object is answered, 0.6 part of trimethyl hydroxyethylammonium ammonium hexafluorophosphate, 0.04 part of aphthenic acids cerium salt, 50 DEG C mix 3 hours, obtain ionic liquid Remover.
Page is detected, Gan Kangqiang index 103Nm/g, wet to resist strong index 44Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Comparative example 1
It is added without tall oil acid and polyalkylenepolyamines reactant, other conditions are the same as embodiment 1.
Page is detected, Gan Kangqiang index 95Nm/g, wet to resist strong index 40Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Comparative example 2
It is added without trimethyl hydroxyethylammonium ammonium hexafluorophosphate, other conditions are the same as embodiment 1.
Page is detected, Gan Kangqiang index 93Nm/g, wet to resist strong index 41Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Comparative example 3
It is added without aphthenic acids cerium salt, other conditions are the same as embodiment 1.
Page is detected, Gan Kangqiang index 94Nm/g, wet to resist strong index 40Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Comparative example 4
Ionic liquid remover is replaced using ethylene glycol, other conditions are the same as embodiment 1.
Page is detected, Gan Kangqiang index 89Nm/g, wet to resist strong index 35Nm/g, wet rubbing: 3 grades;Xerotripsis: 3 grades.
The above is only specific embodiments of the present invention, but technical characteristic of the invention is not limited thereto.It is any with this hair Based on bright, to solve essentially identical technical problem, essentially identical technical effect is realized, made simple change, etc. With replacement or modification etc., all it is covered by among protection scope of the present invention.

Claims (3)

1. a kind of preparation method of high intensity paper twine body paper, it is characterised in that following steps:
Step 1
By weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.01-0.5 parts of dyestuffs, beating consistency 2- 10%, be beaten 40-45 ° of SR of beating degree, be sent into mud pit, be added 0.1-1 parts of color fixing agent, 3-10 parts of wet strength agents, 0.1-0.5 parts from Sub- liquid remover, is sufficiently mixed;
Step 2
By weight, by 100 parts of PVC chemical fibres, 3000-7000 parts of water stir 2-8 hours, obtain PVC chemical fibre dispersion liquid;
Step 3
By weight, the slurry of 100 parts of steps 1 is sent into net cage, 100-500 parts of PVC chemical fibre dispersion liquids is sent into net cage;Through Dehydration forming becomes page, and PVC chemical fibre is uniformly attached to page surface, then through press dewatering, small in 90-100 DEG C of heating 5-15 When, obtain paper twine body paper;
The ionic liquid remover is the preparation method comprises the following steps: by weight: 100 parts of ethylene glycol, 0.5-2 parts of tall oil acids and polyalkylene Polyamine reactant, 0.1-1 parts of trimethyl hydroxyethylammonium ammonium hexafluorophosphates, 0.01-0.1 parts of aphthenic acids cerium salts, 30-60 DEG C of mixing 1- 5 hours, obtain ionic liquid remover.
2. a kind of preparation method of high-intensitive paper twine body paper described in claim 1, it is characterised in that: further include a kind of grey coloured paper The preparation method of yarn body paper, comprising the following steps:
Step 1
By weight, 100 parts of Canadian North Sea needlebush wood pulps are placed in pulper, add 0.3 part of gray dyes, beats Concentration 4% is starched, 42 ° of SR of beating degree are beaten, is sent into mud pit, 0.2 part of color fixing agent, 7 parts of wet strength agents, 0.15 part of ionic liquid stripping is added From agent, it is sufficiently mixed;
Step 2
By weight, by 100 parts of PVC chemical fibres, 3000-7000 parts of water stir 2-8 hours, obtain PVC chemical fibre dispersion liquid;
Step 3
By weight, the slurry of 100 parts of steps 1 is sent into net cage, 260 parts of PVC chemical fibre dispersion liquids is sent into net cage;Through being dehydrated Molding becomes page, and PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats 6 hours at 95 DEG C, obtain paper twine Body paper.
3. a kind of preparation method of high-intensitive paper twine body paper described in claim 1, it is characterised in that: further include a kind of pink Paper twine body paper preparation method, comprising the following steps:
Step 1
By weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.02 part of pink color, beating consistency 4%, 43 ° of SR of beating degree are beaten, mud pit is sent into, 0.3 part of color fixing agent, 7 parts of wet strength agents is added, 0.4 part of ionic liquid remover fills Divide mixing;
Step 2
By weight, by 100 parts of PVC chemical fibres, 5000 parts of water stir 5 hours, obtain PVC chemical fibre dispersion liquid;
Step 3
By weight, the slurry of 100 parts of steps 1 is sent into net cage, 250 parts of PVC chemical fibre dispersion liquids is sent into net cage;Through being dehydrated Molding becomes page, and PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats 8 hours at 94 DEG C, obtain paper twine Body paper.
CN201710894153.9A 2017-09-28 2017-09-28 A kind of preparation method of high intensity paper twine body paper Active CN107419577B (en)

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CN109183512A (en) * 2018-08-16 2019-01-11 何炽斌 A kind of production method of dye pure natural colorful paper processed
CN110318282B (en) * 2019-06-12 2020-11-10 浙江舜浦新材料科技有限公司 Preparation method of uvioresistant woven base paper
CN111021135A (en) * 2019-12-06 2020-04-17 安徽天扬纺织品有限公司 Preparation method of high-strength recyclable paper socks
CN115726219A (en) * 2021-08-31 2023-03-03 温岭市丝美达草艺厂 Preparation method of nano paper yarns with good waterproof performance
CN113863055A (en) * 2021-10-13 2021-12-31 浙江舜浦新材料科技有限公司 Preparation method of colored paper yarn base paper
CN115821629B (en) * 2022-10-20 2023-10-17 浙江舜浦新材料科技有限公司 Method for preparing high-color-fastness paper yarn base paper by deep coloring of water-based nano organic pigment

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CN104818651A (en) * 2015-04-10 2015-08-05 浙江舜浦纸业有限公司 Technology for producing light color technical braiding paper

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