A kind of preparation method of high intensity paper twine body paper
Technical field
The present invention relates to establishment paper field, especially a kind of preparation method of high-intensitive paper twine body paper.
Background technique
Weave paper is a kind of emerging technique textile material.It is with easy to process, handsome in appearance, bright in colour, durable
Without fading, the main dry various paper strings of braiding are made various sudd caps, paper cloth, summer sleeping mat, fold pillow mat, wall cloth and various
Decorative craft.With ventilated ability of sweat absorption, and durability is good, the variation of cold-resistant hot weather, energy recycling and reusing, no
Pollute environment.Traditional establishment paper is by the mutual winding of fiber and longitudinal arrangement to reach required intensity, these paper
The paper slip that can only generally cut into 6mm or more is opened, rag paper rope can only be worked out.
Paper yarn body paper is also referred to as paper twine body paper, often using safety and environmental protection, good toughness plant fiber as raw material, by specific item
Part is processed into paper paper slip, and paper slip is twisted or wound into paper yarn;The paper yarn of sub-thread further can also be twisted bifilar or multiply
Paper yarn, to meet the requirement of different fabrics.Paper yarn body paper have the characteristics that it is quantitative it is low, intensity is high, elongation is larger, can slitting
At narrow serial obbbin.
CN101440588B discloses a kind of base paper of paper yarn for textile and preparation process, is with following weight percent
Raw material is made: bleached softwood wood sulfate pulpboard 60-80%, jute pulp or/and bamboo pulp 20-30%, water soluble fiber 3-8%, owns
Group subtotaling 100%.The preparation process of base paper of paper yarn for textile, benefit in the upper cylinder half process before being batched in paper pulp copy paper technique
The film before batching is given to spread colloid to increase the dry and wet intensity of body paper with glue spreader.Product of the present invention has water suction fast, ventilative
Property good, light and comfortable, machine washable, cut twist it is functional, be a kind of reproducible environment-friendly products.
CN103741556A discloses a kind of preparation process of base paper of paper yarn for textile, in the raw material, water soluble fiber,
Wood pulp, bleached softwood wood sulfate pulpboard, bacterial fibers proportion are as follows: water soluble fiber 3%~8%, wood pulp 25%~35%, bleaching needle
Leaf wood sulfate pulpboard 50%~85%, bacterial fibers 2.5%~5%, all components total 100%.The present invention is mainly using bleaching needle
Leaf wood sulfate pulpboard avoids the bleaching of sulfur dioxide as main slurries, so that product is not easy to turn to be yellow, influences appearance;And
The present invention is added with non-plant fibre, that is, bacterial fibers, and by the synergistic effect of auxiliary agent in the process of making, makes the object of body paper
Reason intensity greatly improves, and while the dry strength and wet strength that ensure that into paper, and has preferable water imbibition and flexibility.
CN101280532B discloses the preparation process of base paper of paper yarn for textile, and water-solubility PVA synthetic fibers exist first
It is impregnated in water;Then bacterial cellulose wet-coating is soaked in NaOH solution, then wood pulp cellulose is discongested with Valley beater
Then it is mixed with by pretreated water-solubility PVA synthetic fibers, refining is carried out in PFI fiberizer by cutting, finally plus
Enter bacterial fibers, PEO, CMC, PAE be uniformly mixed, by approach system, paper is manufactured paper with pulp into using usual manner.The present invention is using non-
Plant fiber, that is, bacterial fibers, WATER-SOLUBLE PVA FIBER are mixed in proportion with wood pulp plant fiber and are manufactured paper with pulp.Using methods of beating to each
Kind fiber has carried out different mashing processing to improve the ru nnability of fiber, binding force between reinforcing fiber;And by manufacturing paper with pulp
The synergistic effect of auxiliary agent in the process greatly improves the physical strength of body paper.
The dry strength and wet strength of the paper yarn body paper produced now are all not up to standard, currently used as the hydrocarbon of corrugation removing auxiliary agent
Oil is incompatible with creping adhesives, it is therefore desirable to improve Wrinkling stripping-agent, and water imbibition and flexibility be not also up to standard, page is contaminating
Xerotripsis during color, wet rubbing, grade is low, and wet strength is low.Therefore the development of some related textile industries is also constrained.
Summary of the invention
The object of the present invention is to provide a kind of processing and fabricatings to be easy, and strong operability, paper strength is high, and water-fastness is a kind of high
The preparation method of intensity paper twine body paper.
There is provided a kind of preparation method of high-intensitive paper twine body paper, it is characterised in that following steps:
(1) by weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.01-0.5 parts of dyestuffs, be beaten
Concentration 2-10% is beaten 40-45 ° of SR of beating degree, is sent into mud pit, and 0.1-1 parts of color fixing agent, 3-10 parts of wet strength agents, 0.1- is added
0.5 part of ionic liquid remover, is sufficiently mixed;
(2) by weight, by 100 parts of PVC chemical fibres, 3000-7000 parts of water are stirred 2-8 hours, obtain PVC chemical fibre point
Dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 100-500 parts of PVC chemical fibre dispersion liquids is sent into
Net cage;Become page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats at 90-100 DEG C
5-15 hours, obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: by weight: 100 parts of ethylene glycol, 0.5-2 parts of tall oil acids and mostly Asia
Alkyl polyamine reactant, 0.1-1 parts of trimethyl hydroxyethylammonium ammonium hexafluorophosphates, 0.01-0.1 parts of aphthenic acids cerium salts, 30-60 DEG C mixed
It closes 1-5 hours, obtains ionic liquid remover.
The color fixing agent, wet strength agent are auxiliary agent commonly used in the art, are commercial product, the present invention is with no restrictions.
The ethylene glycol, tall oil acid and polyalkylenepolyamines reactant, trimethyl hydroxyethylammonium ammonium hexafluorophosphate, cycloalkanes
Sour cerium salt is commercial product.
Product of the invention has the advantages that
A kind of preparation method of high-intensitive paper twine body paper of the present invention, remover are obtained with creping adhesives compatibility
Improve, while solving page xerotripsis in dyeing course, wet rubbing, grade is low, the low problem of wet strength.
Specific embodiment
Following instance is only to further illustrate the present invention, is not limitation the scope of protection of the invention.
Embodiment 1
Pink paper twine body paper preparation method, it is characterised in that following steps:
(1) by weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.02 part of pink color, beats
Concentration 4% is starched, 43 ° of SR of beating degree are beaten, is sent into mud pit, 0.3 part of color fixing agent, 7 parts of wet strength agents, 0.4 part of ionic liquid stripping is added
From agent, it is sufficiently mixed;
(2) by weight, by 100 parts of PVC chemical fibres, 5000 parts of water stir 5 hours, obtain PVC chemical fibre dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 250 parts of PVC chemical fibre dispersion liquids is sent into net
Case;Becoming page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats 8 hours at 94 DEG C,
Obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: by weight: 100 parts of ethylene glycol, 1 part of tall oil acid and polyalkylene
Polyamine reactant, 0.3 part of trimethyl hydroxyethylammonium ammonium hexafluorophosphate, 0.05 part of aphthenic acids cerium salt, 40 DEG C mix 3 hours, obtain
Ionic liquid remover.
Page is detected, Gan Kangqiang index 101Nm/g, wet to resist strong index 46.8Nm/g, wet rubbing: 3 grades;Xerotripsis: 4
Grade.
Embodiment 2
There is provided a kind of preparation method of high-intensitive paper twine body paper, it is characterised in that following steps:
(1) by weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.01 part of dyestuff, beating consistency
2%, 40 ° of SR of beating degree are beaten, mud pit is sent into, 0.1 part of color fixing agent, 3 parts of wet strength agents is added, 0.1 part of ionic liquid remover fills
Divide mixing;
(2) by weight, by 100 parts of PVC chemical fibres, 3000 parts of water stir 2 hours, obtain PVC chemical fibre dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 100 parts of PVC chemical fibre dispersion liquids is sent into net
Case;Becoming page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats 5 hours at 90 DEG C,
Obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: by weight: 100 parts of ethylene glycol, 0.5 part of tall oil acid and more alkylenes
Quito amine reactant, 0.1 part of trimethyl hydroxyethylammonium ammonium hexafluorophosphate, 0.01 part of aphthenic acids cerium salt, 30 DEG C mix 5 hours, obtain
To ionic liquid remover.
Page is detected, Gan Kangqiang index 98Nm/g, wet to resist strong index 45.4Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Embodiment 3
(1) by weight, 100 parts of needlebush wood pulps are placed in pulper, add 0.5 part of dyestuff, beating consistency
10%, 45 ° of SR of beating degree are beaten, mud pit is sent into, 1 part of color fixing agent, 10 parts of wet strength agents is added, 0.5 part of ionic liquid remover fills
Divide mixing;
(2) by weight, by 100 parts of PVC chemical fibres, 7000 parts of water stir 8 hours, obtain PVC chemical fibre dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 500 parts of PVC chemical fibre dispersion liquids is sent into net
Case;Become page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, small in 100 DEG C of heating 15
When, obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: by weight: 100 parts of ethylene glycol, 2 parts of tall oil acids and polyalkylene
Polyamine reactant, 1 part of trimethyl hydroxyethylammonium ammonium hexafluorophosphate, 0.1 part of aphthenic acids cerium salt, obtain ion at 60 DEG C of mixing hours
Liquid remover.
Page is detected, Gan Kangqiang index 112Nm/g, wet to resist strong index 48.5Nm/g, wet rubbing: 3 grades;Xerotripsis: 4
Grade.
Embodiment 4
The preparation method of grey paper twine body paper, it is characterised in that following steps:
(1) by weight, 100 parts of Canadian North Sea needlebush wood pulps are placed in pulper, add 0.3 part of grey
Dyestuff, beating consistency 5% are beaten 42 ° of SR of beating degree, are sent into mud pit, are added 0.2 part of color fixing agent, 7 parts of wet strength agents, and 0.15 part
Ionic liquid remover, is sufficiently mixed;
(2) by weight, by 100 parts of PVC chemical fibres, 3000-7000 parts of water are stirred 2-8 hours, obtain PVC chemical fibre point
Dispersion liquid.
(3) by weight, the slurry of 100 parts of steps 1 is sent into net cage, 260 parts of PVC chemical fibre dispersion liquids is sent into net
Case;Becoming page through dehydration forming, PVC chemical fibre is uniformly attached to page surface, then through press dewatering, heats 6 hours at 95 DEG C,
Obtain paper twine body paper.
The ionic liquid remover is the preparation method comprises the following steps: 100 parts of ethylene glycol, 0.77 part of tall oil acid and polyalkylenepolyamines are anti-
Object is answered, 0.6 part of trimethyl hydroxyethylammonium ammonium hexafluorophosphate, 0.04 part of aphthenic acids cerium salt, 50 DEG C mix 3 hours, obtain ionic liquid
Remover.
Page is detected, Gan Kangqiang index 103Nm/g, wet to resist strong index 44Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Comparative example 1
It is added without tall oil acid and polyalkylenepolyamines reactant, other conditions are the same as embodiment 1.
Page is detected, Gan Kangqiang index 95Nm/g, wet to resist strong index 40Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Comparative example 2
It is added without trimethyl hydroxyethylammonium ammonium hexafluorophosphate, other conditions are the same as embodiment 1.
Page is detected, Gan Kangqiang index 93Nm/g, wet to resist strong index 41Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Comparative example 3
It is added without aphthenic acids cerium salt, other conditions are the same as embodiment 1.
Page is detected, Gan Kangqiang index 94Nm/g, wet to resist strong index 40Nm/g, wet rubbing: 3 grades;Xerotripsis: 4 grades.
Comparative example 4
Ionic liquid remover is replaced using ethylene glycol, other conditions are the same as embodiment 1.
Page is detected, Gan Kangqiang index 89Nm/g, wet to resist strong index 35Nm/g, wet rubbing: 3 grades;Xerotripsis: 3 grades.
The above is only specific embodiments of the present invention, but technical characteristic of the invention is not limited thereto.It is any with this hair
Based on bright, to solve essentially identical technical problem, essentially identical technical effect is realized, made simple change, etc.
With replacement or modification etc., all it is covered by among protection scope of the present invention.