CN107254254A - A kind of high conjugation environment-friendlydurable durable wood wax oil and preparation method thereof - Google Patents
A kind of high conjugation environment-friendlydurable durable wood wax oil and preparation method thereof Download PDFInfo
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- CN107254254A CN107254254A CN201710424702.6A CN201710424702A CN107254254A CN 107254254 A CN107254254 A CN 107254254A CN 201710424702 A CN201710424702 A CN 201710424702A CN 107254254 A CN107254254 A CN 107254254A
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- Prior art keywords
- oil
- wax
- friendlydurable
- environment
- linseed
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- 239000002023 wood Substances 0.000 title claims abstract description 46
- 230000021615 conjugation Effects 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000001993 wax Substances 0.000 claims abstract description 89
- 235000004426 flaxseed Nutrition 0.000 claims abstract description 43
- 239000003921 oil Substances 0.000 claims abstract description 39
- 235000019198 oils Nutrition 0.000 claims abstract description 39
- 239000007788 liquid Substances 0.000 claims abstract description 35
- 240000006240 Linum usitatissimum Species 0.000 claims abstract description 26
- 235000004431 Linum usitatissimum Nutrition 0.000 claims abstract description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002131 composite material Substances 0.000 claims abstract description 15
- 239000004359 castor oil Substances 0.000 claims abstract description 7
- 235000019438 castor oil Nutrition 0.000 claims abstract description 7
- 238000001914 filtration Methods 0.000 claims abstract description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 7
- 239000000944 linseed oil Substances 0.000 claims abstract description 7
- 235000021388 linseed oil Nutrition 0.000 claims abstract description 7
- 239000004203 carnauba wax Substances 0.000 claims abstract description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 28
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000006184 cosolvent Substances 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims description 6
- 235000011046 triammonium citrate Nutrition 0.000 claims description 6
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 6
- 239000008158 vegetable oil Substances 0.000 claims description 6
- 240000000972 Agathis dammara Species 0.000 claims description 5
- 229920002871 Dammar gum Polymers 0.000 claims description 5
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 4
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 4
- 229940043265 methyl isobutyl ketone Drugs 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000001293 FEMA 3089 Substances 0.000 claims description 2
- 241000238631 Hexapoda Species 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 235000013871 bee wax Nutrition 0.000 claims description 2
- 239000012166 beeswax Substances 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- 239000001393 triammonium citrate Substances 0.000 claims description 2
- 229940032991 zinc picolinate Drugs 0.000 claims description 2
- NHVUUBRKFZWXRN-UHFFFAOYSA-L zinc;pyridine-2-carboxylate Chemical compound C=1C=CC=NC=1C(=O)O[Zn]OC(=O)C1=CC=CC=N1 NHVUUBRKFZWXRN-UHFFFAOYSA-L 0.000 claims description 2
- 235000002710 Ilex cornuta Nutrition 0.000 claims 1
- 241001310146 Ilex cornuta Species 0.000 claims 1
- 235000010326 Osmanthus heterophyllus Nutrition 0.000 claims 1
- 244000055346 Paulownia Species 0.000 claims 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- MJYQFWSXKFLTAY-OVEQLNGDSA-N (2r,3r)-2,3-bis[(4-hydroxy-3-methoxyphenyl)methyl]butane-1,4-diol;(2r,3r,4s,5s,6r)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O.C1=C(O)C(OC)=CC(C[C@@H](CO)[C@H](CO)CC=2C=C(OC)C(O)=CC=2)=C1 MJYQFWSXKFLTAY-OVEQLNGDSA-N 0.000 abstract description 17
- 239000010903 husk Substances 0.000 abstract description 17
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract description 14
- 239000003973 paint Substances 0.000 abstract description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract description 10
- 238000001035 drying Methods 0.000 abstract description 7
- 239000000284 extract Substances 0.000 abstract description 6
- 239000002383 tung oil Substances 0.000 abstract description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000725 suspension Substances 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 3
- -1 it is size-reduced Substances 0.000 abstract description 2
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 abstract 1
- 239000005839 Tebuconazole Substances 0.000 abstract 1
- 238000013019 agitation Methods 0.000 abstract 1
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 abstract 1
- 238000012545 processing Methods 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000000287 crude extract Substances 0.000 description 8
- 239000012065 filter cake Substances 0.000 description 8
- 230000008014 freezing Effects 0.000 description 8
- 238000007710 freezing Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000003643 water by type Substances 0.000 description 8
- 125000005909 ethyl alcohol group Chemical group 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000007605 air drying Methods 0.000 description 5
- 229960001777 castor oil Drugs 0.000 description 5
- 239000000706 filtrate Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical class CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 240000000528 Ricinus communis Species 0.000 description 4
- 235000004443 Ricinus communis Nutrition 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/005—Drying oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of high conjugation environment-friendlydurable durable wood wax oil and preparation method thereof, belong to technical field of paint preparation.The present invention is using flax seed husk as raw material, it is size-reduced, extract, hurds seed wax is made in the processes such as revolving, with normal heptane agitation and filtration after hurds seed wax is handled through ash disposal again, collect filter residue and standing is mixed with hydrogen peroxide, and collect suspension air-dry to obtain exquisite linseed wax, again by Firebrake ZB, Tebuconazole etc. is mixed with mildew-retarding liquid, and add by tetraethyl orthosilicate, in the mixed liquor that ethanol solution is made, obtain composite mildewproof liquid, again by tung oil, linseed oil, exquisite linseed wax is continuously added after castor oil heating, Brazil wax etc. is stirred, eventually pass elimination and remove after insoluble matter and mixed with composite mildewproof liquid etc., high conjugation environment-friendlydurable durable wood wax oil can be obtained, wood wax oil produced by the present invention has rate of drying fast, dry film hardness is high, the advantage of good endurance, and wood wax oil and timber conjugation are high, wearability is good, have broad application prospects.
Description
Technical field
The invention discloses a kind of high conjugation environment-friendlydurable durable wood wax oil and preparation method thereof, belong to coating preparation technology
Field.
Background technology
Now, people mostly carry out application to the decoration of building, timber buildings and indoor and outdoor now using traditional paint,
But it is main when traditional paint is used out of doors to be closed in timber top layer in one layer of physicochemical property of wood surface formation very strong paint film,
Prevent timber from breathing, easy to crack over time, paint film is easy to fall off, when by sunlight and ultraviolet irradiation, easily produce yellow
Become, and weatherability, durability are poor.In addition, traditional paint coating raw material is generally chemical product, contain a large amount of toxicity and thorn
Swash property composition, do harm to huamn body can not meet requirement of the people for health environment-friendly instantly.
Wood wax oil is gradually paid attention to as natural kind coating by people, and wood wax oil is a kind of similar paint and is different from oil
The natural woodwork coating of paint, without toxic components such as triphen, formaldehyde and heavy metals, the smell not being pungent.Wood wax oil can lead to
Cross and penetrate into wood internal, humidity exchange can be carried out to the pit of timber, carry out deep layer and moisten maintenance, while wax can be with wood
Material fibre compact is combined, and timber will not be enable in wood surface formation paint film by strengthening case hardness, water proof anti-soil, and wood wax oil
It is enough freely to breathe, good maintenance action is played to wood surface.But, slow drying speed after existing wood wax oil application is applied
Layer dry film hardness is low, while not high enough with timber conjugation, wearability is not good, and the durability of wood wax oil is poor, over time
Increase, wood wax oil gradually reduces to the protection of timber, causes it to use limited.It would therefore be highly desirable to develop a kind of wear-resisting, durable
Property it is good, dry film hardness is high, and the haze tallow oil product high with base material conjugation.
The content of the invention
Present invention mainly solves technical problem：It is low for coating dry film hardness after existing wood wax oil application, while with
Timber conjugation is not high enough, and wearability is not good, and there is provided a kind of high conjugation environmental protection is resistance to for the poor defect of durability of wood wax oil
Long type wood wax oil and preparation method thereof.
In order to solve technical problem, the technical solution adopted in the present invention is：
A kind of high conjugation environment-friendlydurable durable wood wax oil, feed components count by weight including：55~80 parts of vegetable oil, 5
~8 parts of gum dammars, 9~12 parts of cosolvents, 10~15 parts of exquisite linseed waxes, 8~13 parts of biowaxes, 5~6 parts of composite mildewproofs
Liquid, 0.5~0.8 part of drier；
The exquisite linseed wax is the combination of linseed outer layer wax and internal layer wax.
The vegetable oil is a variety of in tung oil, linseed oil, castor oil, turpentine oil, cottonseed oil.
The cosolvent is a variety of in isopropyl ester, acetone, absolute ethyl alcohol, methyl iso-butyl ketone (MIBK).
The biowax is the one or more in Brazil wax, candelila wax, beeswax or insect wax.
The composite mildewproof liquid is the Ludox of load mildew-retarding liquid.
The mildew-retarding liquid is by 3~4 parts of Firebrake ZBs, and 30~50 parts of mass fractions are 1% hydrochloric acid, and 2~3 parts of Tebuconazoles and 0.2~
0.5 part of Triammonium citrate composition.
The drier is one or both of ferrum citricum, zinc picolinate.
A kind of preparation method of high conjugation environment-friendlydurable durable wood wax oil, is concretely comprised the following steps：
S1. dispensing；
S2. vegetable oil, gum dammar, cosolvent are mixed and heated to 130~140 DEG C, with 200~300r/min stirring 10~
After 20min, 100~120 DEG C are cooled to, is added after exquisite linseed wax, biowax, 20~30min of insulated and stirred, with 600
The insulation filtering of mesh filter removes insoluble matter, is cooled to after room temperature and adds composite mildewproof liquid and drier, is made after stirring.
The beneficial effects of the invention are as follows：
（1）The present invention utilizes the compatible of internal layer wax and wood raw material by the linseed outer layer wax and internal layer wax of extraction
Property, wood internal can be goed deep into, timber and the conjugation of wood wax oil are improved in wetting timber duct, while compound bio wax, regulation paint
The pliability on film surface, and haze tallow paint films hardness, both can make coating surface hardness moderate at compounding, the feel given people relax
It is suitable, and possess the ability of the chemical mediators such as preferable durability and acid and alkali-resistance, adapt to extraneous different environment；
（2）The present invention is combined wood wax oil infiltration timber using Ludox, and combines the wax layer migrated to wood surface, in timber table
Face forms diaphragm, it is to avoid impurity is directly contacted with woodwork, slows down the influence that friction is produced to woodwork, is improved and is covered with paint, lacquer, colour wash, etc. table
Face glossiness and anti-wear performance.
Embodiment
300~400kg linseeds are weighed, natural air drying after 2~3 times is washed with deionized, then at -30~-20 DEG C
10~20h of freezing processing, freezing processing is placed in peeling machine after finishing, and decortication 30 is carried out to linseed with 200~300r/min
~50min, obtains flax seed husk, and flax seed husk is added in pulverizer and crushed, and crosses 40 mesh sieves, obtains flax seed husk powder, weigh 10
~12kg flax seed husk powder is immersed in 30~40min in 30~40L ether, filters and collects precipitation, precipitation is immersed in into 35
In the mixed liquor of~40L petroleum ethers and 35~40L absolute ethyl alcohols, at 70~75 DEG C extract 5~6h after filter, obtain crude extract and
Filter cake, then will filter cake add 35~40L chloroforms in, at 50~55 DEG C extract 5~6h after filter, collect filtrate, by filtrate with
Crude extract is fitted into rotary evaporated to dryness in Rotary Evaporators after merging, then will be evaporated product and be added to and fill 1~2L normal heptanes
In flask, 20~24h is stood after sealing bottleneck at 0~4 DEG C, standing is filtered after terminating, and hurds seed wax is obtained, by hurds seed
Wax adds 400~500mL mass fractions in 10% hydrochloric acid, under 90~95 DEG C of waters bath with thermostatic control, 1 is stirred with 300~400r/min
~2h, filters to obtain upper strata material, is placed in drying box, and 3~4h is dried at 70~80 DEG C, obtains ash disposal processing hurds seed
Wax, then weigh in 30~50g ash disposal processing hurds seed wax addition 750~1000mL normal heptanes, at 25~30 DEG C, with 300
~400r/min stirs 3~5h, filters to obtain filter residue, filter residue is added during 300~500mL mass fractions are 30% hydrogen peroxide, 80
Stirred at~90 DEG C with 200~300r/min after 1~2h, stand 3~5 days, filtered to obtain and exquisite Asia is obtained after suspension, natural air drying
Numb seed wax, weighs 3~4g Firebrake ZBs, adds 30~50mL mass fractions in 1% hydrochloric acid, to stir and mix with 300~400r/min
20~30min, adds 2~3g Tebuconazoles, and 0.2~0.5g Triammonium citrates continue to stir 1~2h, obtain mildew-retarding liquid, then weigh
20~30g tetraethyl orthosilicates, are added during 180~200mL mass fractions are 40% ethanol solution, under 50~60 DEG C of waters bath with thermostatic control,
20~30min is stirred with 300~400r/min, mixed liquor is obtained, then with mass fraction be 1% hydrochloric acid regulation pH of mixed be 3.0~
After 4.0, mildew-retarding liquid is added dropwise into mixed liquor with 1~2mL/min speed, after continuing to stir 30~40min after completion of dropping, must be answered
Close mildew-retarding liquid, finally take 15~20g tung oil, 20~30g linseed oil, 20~30g castor oil, 5~8g gum dammars, 5~6g without
Water-ethanol, 2~3g isopropanols, 2~3g acetone is mixed and heated to 130~140 DEG C, with 200~300r/min stirring 10~
After 20min, 100~120 DEG C are cooled to, the exquisite linseed waxes of 10~15g, 5~8g Brazil waxs, 3~5g castor-oil plants is added
Sub- wax, continues 20~30min of insulated and stirred, then removes insoluble matter with the insulation filtering of 600 mesh filters, is cooled to after room temperature and adds
5~6g composite mildewproof liquid, 0.5~0.8g ferrum citricums obtain high conjugation environment-friendlydurable durable wood wax oil after stirring.
Example 1
300kg linseeds are weighed, are washed with deionized at natural air drying after 2 times, then the freezing processing 10h at -30 DEG C, freezing
Reason is placed in peeling machine after finishing, and is carried out decortication 30min to linseed with 200r/min, is obtained flax seed husk, by flax seed husk plus
Enter in pulverizer and crush, cross 40 mesh sieves, obtain flax seed husk powder, weigh 10kg flax seed husk powder and be immersed in 30L ether
30min, filters and collects precipitation, will precipitate and is immersed in 35L petroleum ethers with the mixed liquor of 35L absolute ethyl alcohols, being carried at 70 DEG C
Take and filtered after 5h, obtain crude extract and filter cake, then filter cake is added in 35L chloroforms, extract and filtered after 5h at 50 DEG C, collect filter
Liquid, is fitted into rotary evaporated to dryness in Rotary Evaporators after filtrate is merged with crude extract, then will be evaporated product and be added to and fill 1L
In the flask of normal heptane, 20h is stood after sealing bottleneck at 0 DEG C, standing is filtered after terminating, and hurds seed wax is obtained, by hurds
Seed wax adds 400mL mass fractions in 10% hydrochloric acid, under 90 DEG C of waters bath with thermostatic control, to stir 1h with 300r/min, filter to obtain upper strata
Material, is placed in drying box, and 3h is dried at 70 DEG C, obtains ash disposal processing hurds seed wax, then weigh the thick Asia of 30g ash disposal processing
Numb seed wax is added in 750mL normal heptanes, at 25 DEG C, is stirred 3h with 300r/min, is filtered to obtain filter residue, filter residue is added into 300mL
Mass fraction is stood 3 days, filters to obtain suspension, natural wind in 30% hydrogen peroxide, to be stirred at 80 DEG C with 200r/min after 1h
Exquisite linseed wax is obtained after dry, 3g Firebrake ZBs are weighed, adds 30mL mass fractions in 1% hydrochloric acid, to stir and mix with 300r/min
20min, adds 2g Tebuconazoles, 0.2g Triammonium citrates, continues to stir 1h, obtains mildew-retarding liquid, then weighs 20g tetraethyl orthosilicates,
180mL mass fractions are added in 40% ethanol solution, under 50 DEG C of waters bath with thermostatic control, to stir 20min with 300r/min, must mix
Liquid, then with mass fraction be that 1% hydrochloric acid regulation pH of mixed is that after 3.0, mildew-retarding liquid is added dropwise into mixed liquor with 1mL/min speed,
After continuing to stir 30min after completion of dropping, composite mildewproof liquid is obtained, 15g tung oil is finally taken, 20g linseed oil, 20g castor oil, 5g reaches
Saqima resin, 5g absolute ethyl alcohols, 2g isopropanols, 2g acetone is mixed and heated to 130 DEG C, after 200r/min stirrings 10min, drop
Temperature adds the exquisite linseed waxes of 10g to 100 DEG C, and 5g Brazil waxs, 3g castor bean waxes continue insulated and stirred 20min, then
Insoluble matter is removed with the insulation filtering of 600 mesh filters, addition 5g composite mildewproof liquid after room temperature is cooled to, 0.5g ferrum citricums are stirred
High conjugation environment-friendlydurable durable wood wax oil is obtained after mixing uniformly.
Example 2
350kg linseeds are weighed, are washed with deionized at natural air drying after 2 times, then the freezing processing 15h at -25 DEG C, freezing
Reason is placed in peeling machine after finishing, and is carried out decortication 40min to linseed with 250r/min, is obtained flax seed husk, by flax seed husk plus
Enter in pulverizer and crush, cross 40 mesh sieves, obtain flax seed husk powder, weigh 11kg flax seed husk powder and be immersed in 35L ether
35min, filters and collects precipitation, will precipitate and is immersed in 38L petroleum ethers with the mixed liquor of 38L absolute ethyl alcohols, being carried at 73 DEG C
Take and filtered after 5h, obtain crude extract and filter cake, then filter cake is added in 38L chloroforms, extract and filtered after 5h at 53 DEG C, collect filter
Liquid, is fitted into rotary evaporated to dryness in Rotary Evaporators after filtrate is merged with crude extract, then will be evaporated product and be added to and fill 1L
In the flask of normal heptane, 22h is stood after sealing bottleneck at 2 DEG C, standing is filtered after terminating, and hurds seed wax is obtained, by hurds
Seed wax adds 450mL mass fractions in 10% hydrochloric acid, under 93 DEG C of waters bath with thermostatic control, to stir 1h with 350r/min, filter to obtain upper strata
Material, is placed in drying box, and 3h is dried at 75 DEG C, obtains ash disposal processing hurds seed wax, then weigh the thick Asia of 40g ash disposal processing
Numb seed wax is added in 875mL normal heptanes, at 28 DEG C, is stirred 4h with 350r/min, is filtered to obtain filter residue, filter residue is added into 400mL
Mass fraction is stood 4 days, filters to obtain suspension, natural wind in 30% hydrogen peroxide, to be stirred at 85 DEG C with 250r/min after 1h
Exquisite linseed wax is obtained after dry, 3g Firebrake ZBs are weighed, adds 40mL mass fractions in 1% hydrochloric acid, to stir and mix with 350r/min
25min, adds 2g Tebuconazoles, 0.4g Triammonium citrates, continues to stir 1h, obtains mildew-retarding liquid, then weighs 25g tetraethyl orthosilicates,
190mL mass fractions are added in 40% ethanol solution, under 55 DEG C of waters bath with thermostatic control, to stir 25min with 350r/min, must mix
Liquid, then with mass fraction be that 1% hydrochloric acid regulation pH of mixed is that after 3.5, mildew-retarding liquid is added dropwise into mixed liquor with 1mL/min speed,
After continuing to stir 35min after completion of dropping, composite mildewproof liquid is obtained, 18g tung oil is finally taken, 25g linseed oil, 25g castor oil, 7g reaches
Saqima resin, 5g absolute ethyl alcohols, 2g isopropanols, 2g acetone is mixed and heated to 135 DEG C, after 250r/min stirrings 15min, drop
Temperature adds the exquisite linseed waxes of 13g to 110 DEG C, and 7g Brazil waxs, 4g castor bean waxes continue insulated and stirred 25min, then
Insoluble matter is removed with the insulation filtering of 600 mesh filters, addition 5g composite mildewproof liquid after room temperature is cooled to, 0.7g ferrum citricums are stirred
High conjugation environment-friendlydurable durable wood wax oil is obtained after mixing uniformly.
Example 3
400kg linseeds are weighed, are washed with deionized at natural air drying after 3 times, then the freezing processing 20h at -20 DEG C, freezing
Reason is placed in peeling machine after finishing, and is carried out decortication 50min to linseed with 300r/min, is obtained flax seed husk, by flax seed husk plus
Enter in pulverizer and crush, cross 40 mesh sieves, obtain flax seed husk powder, weigh 12kg flax seed husk powder and be immersed in 40L ether
40min, filters and collects precipitation, will precipitate and is immersed in 40L petroleum ethers with the mixed liquor of 40L absolute ethyl alcohols, being carried at 75 DEG C
Take and filtered after 6h, obtain crude extract and filter cake, then filter cake is added in 40L chloroforms, extract and filtered after 6h at 55 DEG C, collect filter
Liquid, is fitted into rotary evaporated to dryness in Rotary Evaporators after filtrate is merged with crude extract, then will be evaporated product and be added to and fill 2L
In the flask of normal heptane, 24h is stood after sealing bottleneck at 4 DEG C, standing is filtered after terminating, and hurds seed wax is obtained, by hurds
Seed wax adds 500mL mass fractions in 10% hydrochloric acid, under 95 DEG C of waters bath with thermostatic control, to stir 2h with 400r/min, filter to obtain upper strata
Material, is placed in drying box, and 4h is dried at 80 DEG C, obtains ash disposal processing hurds seed wax, then weigh the thick Asia of 50g ash disposal processing
Numb seed wax is added in 1000mL normal heptanes, at 30 DEG C, is stirred 5h with 400r/min, is filtered to obtain filter residue, filter residue is added into 500mL
Mass fraction is stood 5 days, filters to obtain suspension, natural wind in 30% hydrogen peroxide, to be stirred at 90 DEG C with 300r/min after 2h
Exquisite linseed wax is obtained after dry, 4g Firebrake ZBs are weighed, adds 50mL mass fractions in 1% hydrochloric acid, to stir and mix with 400r/min
30min, adds 3g Tebuconazoles, 0.5g Triammonium citrates, continues to stir 2h, obtains mildew-retarding liquid, then weighs 30g tetraethyl orthosilicates,
200mL mass fractions are added in 40% ethanol solution, under 60 DEG C of waters bath with thermostatic control, to stir 30min with 400r/min, must mix
Liquid, then with mass fraction be that 1% hydrochloric acid regulation pH of mixed is that after 4.0, mildew-retarding liquid is added dropwise into mixed liquor with 2mL/min speed,
After continuing to stir 40min after completion of dropping, composite mildewproof liquid is obtained, 20g tung oil is finally taken, 30g linseed oil, 30g castor oil, 8g reaches
Saqima resin, 6g absolute ethyl alcohols, 3g isopropanols, 3g acetone is mixed and heated to 140 DEG C, after 300r/min stirrings 20min, drop
Temperature adds the exquisite linseed waxes of 15g to 120 DEG C, and 8g Brazil waxs, 5g castor bean waxes continue insulated and stirred 30min, then
Insoluble matter is removed with the insulation filtering of 600 mesh filters, addition 6g composite mildewproof liquid after room temperature is cooled to, 0.8g ferrum citricums are stirred
High conjugation environment-friendlydurable durable wood wax oil is obtained after mixing uniformly.
Carry out performance detection to high conjugation environment-friendlydurable durable wood wax oil made from example 1~3, and with Qie Ruixi wood wax oils
（Comparative example）Performance comparison is carried out, detailed results see the table below 1：
The different wood wax oil the performance test results of table 1
In summary, high conjugation environment-friendlydurable durable wood wax oil produced by the present invention have that rate of drying is fast, dry film hardness is high, with
The characteristics of base material conjugation is high, and wood wax oil durability of the present invention is preferably, and preferable protective effect can be played to base material, can effectively be prolonged
Long substrate service life.
Claims (8)
1. a kind of high conjugation environment-friendlydurable durable wood wax oil, it is characterised in that feed components count by weight including：55~
80 parts of vegetable oil, 5~8 parts of gum dammars, 9~12 parts of cosolvents, 10~15 parts of exquisite linseed waxes, 8~13 parts of biowaxes, 5
~6 parts of composite mildewproof liquid, 0.5~0.8 part of drier；
The exquisite linseed wax is the combination of linseed outer layer wax and internal layer wax.
2. a kind of high conjugation environment-friendlydurable durable wood wax oil as claimed in claim 1, it is characterised in that the vegetable oil is paulownia
It is a variety of in oil, linseed oil, castor oil, turpentine oil, cottonseed oil.
3. a kind of high conjugation environment-friendlydurable durable wood wax oil as claimed in claim 1, it is characterised in that the cosolvent is different
It is a variety of in propyl ester, acetone, absolute ethyl alcohol, methyl iso-butyl ketone (MIBK).
4. a kind of high conjugation environment-friendlydurable durable wood wax oil as claimed in claim 1, it is characterised in that the biowax is bar
One or more in western palm wax, candelila wax, beeswax or insect wax.
5. a kind of high conjugation environment-friendlydurable durable wood wax oil as claimed in claim 1, it is characterised in that the composite mildewproof liquid
To load the Ludox of mildew-retarding liquid.
6. a kind of high conjugation environment-friendlydurable durable wood wax oil as claimed in claim 5, it is characterised in that the mildew-retarding liquid is by 3
~4 parts of Firebrake ZBs, 30~50 parts of mass fractions are 1% hydrochloric acid, 2~3 parts of Tebuconazoles and 0.2~0.5 part of Triammonium citrate composition.
7. a kind of high conjugation environment-friendlydurable durable wood wax oil as claimed in claim 1, it is characterised in that the drier is Chinese holly
One or both of rafter acid iron, zinc picolinate.
8. a kind of preparation method of high conjugation environment-friendlydurable durable wood wax oil as described in any one of claim 1~7, its feature
It is to concretely comprise the following steps：
S1. dispensing；
S2. vegetable oil, gum dammar, cosolvent are mixed and heated to 130~140 DEG C, with 200~300r/min stirring 10~
After 20min, 100~120 DEG C are cooled to, is added after exquisite linseed wax, biowax, 20~30min of insulated and stirred, with 600
The insulation filtering of mesh filter removes insoluble matter, is cooled to after room temperature and adds composite mildewproof liquid and drier, is made after stirring.
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| CN108544626A (en) * | 2018-03-30 | 2018-09-18 | 东莞市挪亚家家具有限公司 | English walnut wood gas grinding process |
| CN110144171A (en) * | 2019-06-03 | 2019-08-20 | 林彬 | A kind of wood carving craft protection wax oil manufacture craft |
| CN110452617A (en) * | 2019-08-30 | 2019-11-15 | 北京林业大学 | A kind of environmental protection quick-drying wood wax oil and preparation method thereof |
| CN111438787A (en) * | 2020-05-08 | 2020-07-24 | 上海宅匠环保科技有限公司 | Method for oiling solid wood surface, solid wood formed by same and solid wood furniture |
| CN111571752A (en) * | 2020-04-30 | 2020-08-25 | 林远毅 | Method for producing plate-type wooden furniture with improved use strength |
| CN112795312A (en) * | 2021-01-27 | 2021-05-14 | 徐嘉程 | Preparation method of water-based nano material for woodware veneer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111571752A (en) * | 2020-04-30 | 2020-08-25 | 林远毅 | Method for producing plate-type wooden furniture with improved use strength |
| CN111438787A (en) * | 2020-05-08 | 2020-07-24 | 上海宅匠环保科技有限公司 | Method for oiling solid wood surface, solid wood formed by same and solid wood furniture |
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| CN112795312A (en) * | 2021-01-27 | 2021-05-14 | 徐嘉程 | Preparation method of water-based nano material for woodware veneer |
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