CN108247806A - A kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde - Google Patents
A kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde Download PDFInfo
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- CN108247806A CN108247806A CN201810040677.6A CN201810040677A CN108247806A CN 108247806 A CN108247806 A CN 108247806A CN 201810040677 A CN201810040677 A CN 201810040677A CN 108247806 A CN108247806 A CN 108247806A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/04—Manufacture of substantially flat articles, e.g. boards, from particles or fibres from fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27J—MECHANICAL WORKING OF CANE, CORK, OR SIMILAR MATERIALS
- B27J1/00—Mechanical working of cane or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/005—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process employing compositions comprising microparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/007—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process employing compositions comprising nanoparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/04—Combined bleaching or impregnating and drying of wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
- B27N1/02—Mixing the material with binding agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/10—Moulding of mats
- B27N3/12—Moulding of mats from fibres
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
Abstract
The present invention relates to a kind of preparation methods of the not mould non-ignitable bamboo fiberboard of no aldehyde, belong to artificial bamboo board field.The preparation method of the above-mentioned not mould non-ignitable bamboo fiberboard of no aldehyde includes the following steps：(1) bamboo section is produced；(2) bamboo section vertical profile and bamboo block remove tabasheer and internal segment；(3) bamboo block is chipped；(4) bamboo chip prepares bamboo fibre；(5) the mould proof processing of bamboo fibre；(6) mould proof bamboo fibre drying；(7) mould proof bamboo fibre applies without the non-ignitable cementing material of aldehyde；(8) sizing bamboo fibre is mated formation；(9) slab precompressed；(10) slab hot pressing；(11) post-processing.Bamboo fiberboard prepared by the present invention is free of formaldehyde, is not easy to go mouldy, while have nonflammable characteristic；Mycotic infection value can reach 0, and burning behavior class reaches A2 grades non-ignitable.
Description
Technical field
The invention belongs to artificial bamboo board fields, and in particular to a kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde.
Background technology
The bamboo processing technology and level of China occupy rank first, and artificial bamboo board is the major product of bamboo processing
And core.Wherein bamboo fibreboard is excellent because having the characteristics that even structure, processing performance, in the industries such as building, furniture once
Through obtaining more application.But bamboo fiberboard manufacture is substantially all using formaldehydes adhesive, production, use in bamboo fiberboard
Harmful substance formaldehyde can be discharged in the process, larger harm is caused to the health of practitioner and consumer, it would be highly desirable to research and develop
Without aldehyde type bamboo fiberboard.In addition, nutriment necessary to the moulds such as contained carbohydrate, starch, protein is long-range in itself for bamboo wood
In timber, bamboo fiberboard is caused to be easier to go mouldy more than wood fiberboard in the larger area of humidity and moist place, not only
The performance of product is reduced, and pollution is caused to application environment, it would be highly desirable to research and develop mould-proof-type bamboo fiberboard.In addition, bamboo fibre
Plate is mainly used for the fields such as furniture, construction and decoration, however bamboo fiberboard belongs to combustible material, easily burns, once it builds
Fire, it is most likely that cause casualties and property loss, it would be highly desirable to research and develop flame retardant type bamboo fiberboard.
CN107032740A discloses a kind of bamboo fibre magnesium oxysulfide plate and preparation method thereof, which includes
Following materials in percentage by mass：Distiller liquor 20~30%, cement 20~35%, bamboo fibre 20~35%, flyash 20~35%,
Curing agent 2~3% and strength assistant agent 0.5~2%, the bamboo fibre magnesium oxysulfide plate which is provided have A grades of fire-retardant fireproofs, prevent
Damp, anticorrosive, insect prevention, a variety of advantages such as durable, zero formaldehyde is environmentally protective, preparation method is simple, environmental protection, pollution-free.
But the bamboo fiberboard prepared in the prior art is mostly to have the function of in a certain respect, such as mould proof or without aldehyde, work(
It can be single.Therefore, current develop has without formaldehyde, is not easy to go mouldy and not only compel very much with the needs of nonflammable bamboo fiberboard
It cuts, and for widening the application range of Recombined bamboo and realizing more extensive use etc. of Recombined bamboo all with extremely important
Realistic meaning.
Invention content
For solve in the prior art bamboo fiberboard contain formaldehyde, easily go mouldy, easily burn the problems such as, the present invention offer one
Preparation method of the kind without the not mould non-ignitable bamboo fiberboard of aldehyde, bamboo fiberboard produced by the present invention are excellent with no aldehyde, mould proof, fire-retardant etc.
Point.
In order to solve the above technical problems, present invention offer technical solution is as follows：
On the one hand, the present invention provides a kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde, includes the following steps：
(1) bamboo section is produced
Using the bamboo wood of the small diameter grades such as Cluster Bamboo, miscellaneous bamboo as raw material, after at its sawed-off bamboo section for certain length, it is placed in small
Rotary-cut is carried out on type rotary trunk-layer stripping machine without clamper, revolves after removing and stops substantially in the bamboo blueness of bamboo section outer surface and bamboo acromere；
(2) bamboo section vertical profile and bamboo block remove tabasheer and internal segment
It will revolve to cut open except the bamboo section longitudinal direction of bamboo blueness and acromere and cut as 2-3 block bamboo blocks, and reject tabasheer and internal segment on bamboo block later；
(3) bamboo block is chipped
By the bamboo block without bamboo blueness, tabasheer and ring, it is sent into the drum chipper of positive feed and chips, bamboo block is cut into
The bamboo chip that length is 15-25mm, width 15-20mm, thickness are 2-3mm, bamboo chip moisture content are maintained between 30-50%；
(4) bamboo chip prepares bamboo fibre
Bamboo chip is separated by bamboo fibre using thermomechanical method, the temperature of wherein steam heating boiling is 160-180 DEG C, is steamed
Boil time 4-8min；
(5) the mould proof processing of bamboo fibre
It, later will by metering pump or flow valve by bamboo fibre with being sent into round roller of the inside with blender
Mould inhibitor is applied to by the top of roller on bamboo fibre, and applying mould inhibitor, blender persistently stirs simultaneously, makes mould inhibitor and bamboo
Fiber uniformly mixes, and the applied amount of mould inhibitor is the 2-6% of over dry bamboo fibre quality；
(6) mould proof bamboo fibre drying
It is dried aqueous to the bamboo fibre Jing Guo mould proof processing using the vertical Air Dried System drying of duct type two level
Rate is controlled in the range of 5-10%；
(7) mould proof bamboo fibre applies without the non-ignitable cementing material of aldehyde
Bamboo fibre is applied without the non-ignitable cementing material of aldehyde, the applied amount of no non-ignitable cementing material of aldehyde using pipeline resin application methods
Solid weight for glue accounts for the 30-45% of over dry bamboo fibre quality；
(8) sizing bamboo fibre is mated formation
The bamboo fibre of cementing material will be applied, and be paved on belt with mechanical forming machine and obtain slab；
(9) slab precompressed
Continuous precompressed is carried out to the slab after mating formation using Continuous Roller press, makes slab just one-step forming；
(10) slab hot pressing
Carry out hot pressing to shaping slab using the double steel band hot presses of continous way, heat pressing process in existing continous way timber
The technological parameter of density fiber board production is identical, and the flash plate without the not mould non-ignitable bamboo fiberboard of aldehyde can be obtained after hot pressing；
(11) post-processing
By the flash plate of the not mould non-ignitable bamboo fiberboard of no aldehyde, it is placed in and combines in length and breadth on edge cutting machine to the length of fiberboard flash plate
Degree and width are processed to get the sketch-plate of the not mould non-ignitable bamboo fiberboard of no aldehyde；Sketch-plate is placed in temperature as 30-40 again
DEG C, carry out in the balance room that humidity is 50-70% after modifier treatment 36-96h to get the not mould non-ignitable bamboo fiberboard finished product of no aldehyde.
On the other hand, the present invention also provides a kind of mould inhibitors, can be applied to the preparation method process of above-mentioned bamboo fiberboard
In, the mould inhibitor is Chinese herbal medicine mould inhibitor, nanometer silver-colored zinc composite mildew inhibitor or Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor.
Further, the preparation method of the Chinese herbal medicine mould inhibitor is：
By medicinal herb soak in 40-70% ethanol solutions, the mass ratio of the Chinese herbal medicine and ethyl alcohol is 1:5-20, heating
To 50-80 DEG C, filter residue is filtered to remove after heating 30-120min, the Chinese herbal medicine for obtaining a concentration of 50-100mg/ml of Chinese herbal medicine is mould proof
Agent；
The Chinese herbal medicine is made of following parts by weight of component：20-30 parts of thyme, 50-60 parts of flos caryophylli, cinnaldehydrum 10-
15 parts and 5-10 parts of dried orange peel.
Further, the preparation method of the nanometer silver-colored zinc composite mildew inhibitor is：
Weigh zinc acetate or zinc nitrate or 60-75 parts of zinc sulfate, natrium carbonicum calcinatum 15-20,5-15 parts of silver nitrate and 12
5-10 parts of sodium alkyl benzene sulfonate is respectively put into mortar and grinds uniformly mixing, then washed respectively with deionized water, absolute ethyl alcohol,
It is dry after filtering, it puts it in high-temperature roasting furnace and to be sintered at a temperature of 250-500 DEG C to get to nanometer silver zinc complex later
Mould inhibitor；
Alternatively, using zinc acetate or zinc nitrate or zinc sulfate, silver nitrate as raw material, ammonium hydrogen carbonate prepares nano silver for precipitating reagent
Zinc composite mildew inhibitor：First, when the temperature of reaction vessel reaches 20-50 DEG C, pipette a concentration of 1-4mol/l's of 50-100ml
The ammonium bicarbonate soln of same concentrations is added dropwise in anti-in reaction vessel in zinc acetate or zinc nitrate or solution of zinc sulfate while stirring
It answers in container, zinc acetate or zinc nitrate or the molar ratio of zinc sulfate and ammonium hydrogen carbonate are 1:2-5 adds in ammonium hydrogen carbonate by this calculating
Amount, reaction time 2-5h；Later, be added dropwise respectively while stirring 50-100ml a concentration of 0.2-0.4mol/l silver nitrate and
For ammonium bicarbonate soln in reaction vessel, the molar ratio of silver nitrate and ammonium hydrogen carbonate is 1:1.5-4.5 adds in nitric acid by this calculating
The amount of silver, reaction time 0.5-1.5h；Then, it washs, centrifuge to obtain first polymers；Finally, the drying of first polymers is placed on height
In warm roaster, 1-3h is roasted at a temperature of 350-550 DEG C, obtains a nanometer silver-colored zinc composite mildew inhibitor.
Further, the preparation method of the Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor is：
30-50 parts of 50-70 parts of Chinese herbal medicine mould inhibitor and nanometer silver-colored zinc composite mildew inhibitor are weighed in proportion, Chinese herbal medicine is mould proof
Agent is placed in the container with blender, nanometer silver-colored zinc composite mildew inhibitor is added in while stirring, until nanometer silver-colored zinc composite mildewproof
Agent is evenly spread in Chinese herbal medicine mould inhibitor to get Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor.
In another aspect, the present invention also provides a kind of no non-ignitable cementing material of aldehyde, the system of above-mentioned bamboo fiberboard can be applied to
During Preparation Method, it is made of A agent, B agent and C agent；
The A agent includes 5-15 parts of 65-80 parts of magnesia, 15-25 parts of magnesium sulfate and calcium silicates；
The B agent is epsom salt；
The C agent is sodium metasilicate, neoprene, vinyl urethane or vinylacetate.
Preferably, the C agent is sodium metasilicate, and the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A agent
40-50 parts, 40-50 parts of B agent, 5-10 parts of C agent；
Alternatively, the C agent is neoprene, the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A agent
40-45 parts, 40-45 parts of B agent, 5-15 parts of C agent；
Alternatively, the C agent be vinyl urethane, the no non-ignitable cementing material of aldehyde by following parts by weight component group
Into：40-50 parts of A agent, 40-50 parts of B agent, 2-8 parts of C agent；
Alternatively, the C agent is vinylacetate, the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A
40-45 parts of agent, 40-45 parts of B agent, 5-15 parts of C agent.
The present invention also provides a kind of preparation methods of the above-mentioned no non-ignitable cementing material of aldehyde, and each component in A agent is respectively placed in
After being ground in grinder, screened with the sieve of 200-400 mesh, then mixed in proportion；Then by A agent, B agent
It is mixed in proportion with C agent to get the non-ignitable cementing material of no aldehyde.
The present invention provides a kind of preparation methods of the not mould non-ignitable bamboo fiberboard of no aldehyde, have the advantages that：
1) bamboo fiberboard prepared by the present invention is free of formaldehyde, is not easy to go mouldy, while have nonflammable characteristic；Mould sense
Dye value can reach 0, and burning behavior class reaches A2 grades non-ignitable；
2) Chinese herbal medicine provided by the invention/nanometer silver-colored zinc composite mildew inhibitor is answered by Chinese herbal medicine mould inhibitor and nanometer silver-colored zinc
The collective effect of condensation material makes its fungicidal properties better than most commercially available mould inhibitors, and preparation method is simple, and raw material is easy to get；
3) the non-ignitable cementing material of no aldehyde provided by the invention solves adhesive in the prior art and contains a certain amount of formaldehyde
The problem of, and by the rational proportion of three kinds of components, reach preferable flame retardant property.
Specific embodiment
To make the technical problem to be solved in the present invention, technical solution and advantage clearer, below in conjunction with specific implementation
Example is described in detail.
Said program is described further below in conjunction with specific embodiment.It should be understood that these embodiments are for illustrating
The present invention and be not limited to limit the scope of the invention.The implementation condition used in embodiment can be done according to the condition of specific producer
Further adjustment, the implementation condition being not specified is usually the condition in routine experiment.
The materials, reagents and the like used in the following examples is commercially available.
On the one hand, the present invention provides a kind of Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor, specific substance dosage and experimentation
Referring to following embodiments.
Embodiment 1：
A kind of preparation method of Chinese herbal medicine mould inhibitor is：By medicinal herb soak in 70% ethanol solution, the Chinese herbal medicine
Mass ratio with ethyl alcohol is 1:5,50 DEG C are warming up to, filter residue is filtered to remove after heating 120min, obtains a concentration of 98.2mg/ of Chinese herbal medicine
The Chinese herbal medicine mould inhibitor of ml；
Said herbal medicine is made of following parts by weight of component：20 parts of thyme, 50 parts of flos caryophylli, 15 parts of cinnaldehydrum and dried orange peel
10 parts.
Embodiment 2：
A kind of preparation method of Chinese herbal medicine mould inhibitor is：By medicinal herb soak in 40% ethanol solution, the Chinese herbal medicine
Mass ratio with ethyl alcohol is 1:20,80 DEG C are warming up to, filter residue is filtered to remove after heating 30min, obtains a concentration of 52.7mg/ of Chinese herbal medicine
The Chinese herbal medicine mould inhibitor of ml；
Said herbal medicine is made of following parts by weight of component：30 parts of thyme, 60 parts of flos caryophylli, 10 parts of cinnaldehydrum and dried orange peel
5 parts.
Embodiment 3：
The preparation method of a kind of nanometer of silver-colored zinc composite mildew inhibitor is：Weigh 75 parts of zinc acetate, natrium carbonicum calcinatum 15, silver nitrate
5 parts and 10 parts of neopelex are respectively put into mortar and grind uniformly mixing, then respectively with deionized water, anhydrous second
Alcohol washs, dry after filtering, puts it in high-temperature roasting furnace and to be sintered at a temperature of 250-500 DEG C to get to nanometer later
Silver zinc complex mould inhibitor.
Embodiment 4：
The preparation method of a kind of nanometer of silver-colored zinc composite mildew inhibitor is：Weigh 60 parts of zinc nitrate, natrium carbonicum calcinatum 20, silver nitrate
15 parts and 5 parts of neopelex are respectively put into mortar and grind uniformly mixing, then respectively with deionized water, anhydrous second
Alcohol washs, dry after filtering, puts it in high-temperature roasting furnace and to be sintered at a temperature of 250-500 DEG C to get to nanometer later
Silver zinc complex mould inhibitor.
Embodiment 5：
The preparation method of a kind of nanometer of silver-colored zinc composite mildew inhibitor is：Using zinc sulfate, silver nitrate as raw material, ammonium hydrogen carbonate is heavy
Shallow lake agent prepares nanometer silver-colored zinc composite mildew inhibitor：First, when the temperature of reaction vessel reaches 20 DEG C, it is a concentration of to pipette 100ml
The ammonium bicarbonate soln of same concentrations is added dropwise in reaction vessel in reaction vessel in the solution of zinc sulfate of 1mol/l while stirring
In, zinc acetate or zinc nitrate or the molar ratio of zinc sulfate and ammonium hydrogen carbonate are 1:2, the amount of ammonium hydrogen carbonate is added in by this calculating, instead
It is 2h between seasonable；Later, be added dropwise respectively while stirring 100ml a concentration of 0.2mol/l silver nitrate and ammonium bicarbonate soln in anti-
It answers in container, the molar ratio of silver nitrate and ammonium hydrogen carbonate is 1:1.5, the amount of silver nitrate, reaction time 0.5h are added in by this calculating；
Then, it washs, centrifuge to obtain first polymers；Finally, the drying of first polymers is placed in high-temperature roasting furnace, in 350 DEG C of temperature
Lower roasting 3h obtains a nanometer silver-colored zinc composite mildew inhibitor.
Embodiment 6：
The preparation method of a kind of nanometer of silver-colored zinc composite mildew inhibitor is：Using zinc acetate, silver nitrate as raw material, ammonium hydrogen carbonate is heavy
Shallow lake agent prepares nanometer silver-colored zinc composite mildew inhibitor：First, when the temperature of reaction vessel reaches 50 DEG C, it is a concentration of to pipette 50ml
The ammonium hydrogen carbonate of same concentrations is added dropwise in reaction vessel in the zinc acetate or zinc nitrate or solution of zinc sulfate of 4mol/l while stirring
For solution in reaction vessel, zinc acetate or zinc nitrate or the molar ratio of zinc sulfate and ammonium hydrogen carbonate are 1:5, add in carbon by this calculating
The amount of sour hydrogen ammonium, reaction time 5h；Later, the silver nitrate and carbonic acid of a concentration of 0.4mol/l of 50ml is added dropwise respectively while stirring
For hydrogen ammonium salt solution in reaction vessel, the molar ratio of silver nitrate and ammonium hydrogen carbonate is 1:4.5, the amount of silver nitrate is added in by this calculating,
Reaction time 1.5h；Then, it washs, centrifuge to obtain first polymers；Finally, the drying of first polymers is placed in high-temperature roasting furnace,
1h is roasted at a temperature of 550 DEG C, obtains a nanometer silver-colored zinc composite mildew inhibitor.
Embodiment 7：
A kind of Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor, weigh in proportion the preparation of embodiment 1 mould proof 70 parts of Chinese herbal medicine and
50 parts of nanometer silver-colored zinc composite mildew inhibitor prepared by embodiment 3, Chinese herbal medicine mould inhibitor is placed in the container with blender, while stirring
It mixes side and adds in nanometer silver-colored zinc composite mildew inhibitor, until nanometer silver-colored zinc composite mildew inhibitor is evenly spread in Chinese herbal medicine mould inhibitor, i.e.,
Obtain Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor.
Embodiment 8：
A kind of Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor weighs 70 parts of the Chinese herbal medicine mould inhibitor of the preparation of embodiment 2 in proportion
30 parts of the nanometer silver-colored zinc composite mildew inhibitor prepared with embodiment 6, Chinese herbal medicine mould inhibitor is placed in the container with blender, side
It stirs side and adds in nanometer silver-colored zinc composite mildew inhibitor, until nanometer silver-colored zinc composite mildew inhibitor is evenly spread in Chinese herbal medicine mould inhibitor,
Up to Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor.
Comparative example 1：
It is commercially available mould inhibitor in this comparative example.
Embodiment 1-8, the mould inhibitor of comparative example 1 and without mould inhibitor control group, according to GB/T18261-2013《Mould inhibitor pair
Timber mould and the test method of stain fungus preventing efficiency》The infection value of test mould inhibitor is shown in Table 1, and the control effect of mould inhibitor is shown in
Table 2.
Table 1
Note：Infection value is 0, and specimen surface is without mycelia, mildew；
Infection value is 1, specimen surface infection area ＜ 1/4；
Infection value is 2, specimen surface infection area 1/4~1/2；
Infection value is 3, specimen surface infection area 1/2~3/4；
Infection value is 4, specimen surface infection area ＞ 3/4.
Table 2
| Serial number | Control of mold effect/% | Stain fungi control effect/% |
| Embodiment 1 | 90.9 | 75 |
| Embodiment 2 | 90.9 | 100 |
| Embodiment 3 | 90.9 | 100 |
| Embodiment 4 | 90.9 | 100 |
| Embodiment 5 | 90.9 | 100 |
| Embodiment 6 | 90.9 | 100 |
| Embodiment 7 | 100 | 100 |
| Embodiment 8 | 100 | 100 |
| Comparative example 1 | 63.6 | 75 |
Preventing efficiency calculates according to the following formula：
Wherein：E- preventing efficiencies, %；
D1The average infection value of chemicals treatment sample；
D0The average infection value of untreated control sample.
By above-mentioned Tables 1 and 2 it is found that the anti-mold effect of mould inhibitor for preparing of the present invention is much better than comparative example and existing commercially available
Mould inhibitor.
On the other hand, the present invention also provides a kind of no non-ignitable cementing material of aldehyde and preparation method thereof, specific embodiment is as follows.
Embodiment 9：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is 15 parts of 65 parts of magnesia, 20 parts of magnesium sulfate and calcium silicates；
The B agent is epsom salt；
The C agent is sodium metasilicate；
The non-ignitable cementing material of no aldehyde is made of the component of following parts by weight：40 parts of A agent, 50 parts of B agent, 10 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde, each component in A agent is respectively placed in grinder and is ground
Afterwards, it is screened with the sieve of 200-400 mesh, is then mixed in proportion；Then A agent, B agent and C agent are mixed in proportion
Uniformly to get the non-ignitable cementing material of no aldehyde.
Embodiment 10：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is 5 parts of 80 parts of magnesia, 15 parts of magnesium sulfate and calcium silicates；
The B agent is epsom salt；
The C agent is sodium metasilicate；
The non-ignitable cementing material of no aldehyde is made of the component of following parts by weight：50 parts of A agent, 45 parts of B agent, 5 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 11：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is 10 parts of 65 parts of magnesia, 25 parts of magnesium sulfate and calcium silicates；
The B agent is epsom salt；
The C agent is sodium metasilicate；
The non-ignitable cementing material of no aldehyde is made of the component of following parts by weight：50 parts of A agent, 40 parts of B agent, 10 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 12：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is the same as embodiment 7；
The B agent is epsom salt；
The C agent is neoprene；
The non-ignitable cementing material of no aldehyde is made of the component of following parts by weight：40 parts of A agent, 45 parts of B agent, 15 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 13：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is the same as embodiment 8；
The B agent is epsom salt；
The C agent is neoprene；
The non-ignitable cementing material of no aldehyde is made of the component of following parts by weight：45 parts of A agent, 40 parts of B agent, 15 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 14：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is the same as embodiment 9；
The B agent is epsom salt；
The C agent is neoprene；
The non-ignitable cementing material of no aldehyde is made of the component of following parts by weight：45 parts of A agent, 45 parts of B agent, 5 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 15：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is the same as embodiment 7；
The B agent is epsom salt；
The C agent is vinyl urethane, and the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A agent
40 parts, 50 parts of B agent, 8 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 16：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is the same as embodiment 8；
The B agent is epsom salt；
The C agent is vinyl urethane；
The non-ignitable cementing material of no aldehyde is made of the component of following parts by weight：50 parts of A agent, 40 parts of B agent, 8 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 17：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is the same as embodiment 9；
The B agent is epsom salt；
The C agent is vinyl urethane；
The non-ignitable cementing material of no aldehyde is made of the component of following parts by weight：50 parts of A agent, 50 parts of B agent, 2 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 18：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is the same as embodiment 7；
The B agent is epsom salt；
The C agent is vinylacetate, and the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A agent 45
Part, 40 parts of B agent, 15 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 19：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is the same as embodiment 8；
The B agent is epsom salt；
The C agent is vinylacetate, and the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A agent 45
Part, 45 parts of B agent, 10 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Embodiment 20：
A kind of non-ignitable cementing material of no aldehyde, is made of A agent, B agent and C agent；
A agent is the same as embodiment 9；
The B agent is epsom salt；
The C agent is vinylacetate, and the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A agent 40
Part, 45 parts of B agent, 5 parts of C agent.
The preparation method of the above-mentioned non-ignitable cementing material of no aldehyde is the same as embodiment 9.
Because length is limited, to further illustrate the present invention the performance without the non-ignitable cementing material of aldehyde of preparation, clothes made of brocade embodiment
10th, structure comparative example is as follows for 13,16,19.
Comparative example 2：
A agent is contained only in this comparative example.
Comparative example 3：
This comparative example contains only A agent and B agent, remaining is same as in Example 10.
Comparative example 4：
This comparative example contains only A agent and C agent, remaining is same as in Example 10.
Comparative example 5：
This comparative example contains only A agent and C agent, remaining is identical with embodiment 13.
Comparative example 6：
This comparative example contains only A agent and C agent, remaining is identical with embodiment 16.
Comparative example 7：
This comparative example contains only A agent and C agent, remaining is identical with embodiment 19.
Comparative example 8：
This comparative example contains only B agent and C agent, remaining is same as in Example 10.
Comparative example 9：
This comparative example contains only B agent and C agent, remaining is identical with embodiment 13.
Comparative example 10：
This comparative example contains only B agent and C agent, remaining is identical with embodiment 16.
Comparative example 11：
This comparative example contains only B agent and C agent, remaining is identical with embodiment 19.
Cementing material prepared by embodiment 9-20 and comparative example 2-11, according to GB 18580-2000《Indoor decorating material
Expect that Form aldehyde release is limited the quantity in wood-based plate and its product》Content of formaldehyde is all zero in test material, and according to JC/T636-1996《Wood
Flooring adhesive》It tests the coating of cementing material and stretches splitting cementing strength and be shown in Table 3.
Table 3
| Serial number | Coating | Stretch splitting cementing strength/N/cm |
| Embodiment 9 | Easily coating, glue-line are uniform | 279 |
| Embodiment 10 | Easily coating, glue-line are uniform | 314 |
| Embodiment 11 | Easily coating, glue-line are uniform | 288 |
| Embodiment 12 | Easily coating, glue-line are uniform | 292 |
| Embodiment 13 | Easily coating, glue-line are uniform | 312 |
| Embodiment 14 | Easily coating, glue-line are uniform | 306 |
| Embodiment 15 | Easily coating, glue-line are uniform | 295 |
| Embodiment 16 | Easily coating, glue-line are uniform | 310 |
| Embodiment 17 | Easily coating, glue-line are uniform | 301 |
| Embodiment 18 | Easily coating, glue-line are uniform | 300 |
| Embodiment 19 | Easily coating, glue-line are uniform | 311 |
| Embodiment 20 | Easily coating, glue-line are uniform | 307 |
| Comparative example 2 | --- | --- |
| Comparative example 3 | --- | --- |
| Comparative example 4 | Do not allow easy to apply, glue-line thickness is uniform | 127 |
| Comparative example 5 | Do not allow easy to apply, glue-line thickness is uniform | 136 |
| Comparative example 6 | Do not allow easy to apply, glue-line thickness is uniform | 125 |
| Comparative example 7 | Do not allow easy to apply, glue-line thickness is uniform | 162 |
| Comparative example 8 | Easily coating, glue-line are uniform | 211 |
| Comparative example 9 | Easily coating, glue-line are uniform | 206 |
| Comparative example 10 | Easily coating, glue-line are uniform | 214 |
| Comparative example 11 | Easily coating, glue-line are uniform | 218 |
As shown in Table 3, what prepared by the present invention without the non-ignitable cementing material of aldehyde there is preferable coating and larger stretching to split
Split cementing strength.Meanwhile the present invention leads to its flame retardant property significantly without a large amount of inorganic material is contained in the non-ignitable cementing material of aldehyde
It improves, and only contains a small amount of organic material in cementing material, formaldehyde is practically free of in system, ensureing its cementing strength
While realize cementing material without aldehyde anti-flammability.
In another aspect, the present invention also provides a kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde, preparation method referring to
Following embodiments.
Embodiment 21：
A kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde, includes the following steps：
(1) bamboo section is produced
Using the bamboo wood of the small diameter grades such as Cluster Bamboo, miscellaneous bamboo (diameter is less than 4cm) as raw material, by its sawed-off bamboo for certain length
It after at section, is placed on small-sized rotary trunk-layer stripping machine without clamper and carries out rotary-cut, revolve after removing and stop substantially in the bamboo blueness of bamboo section outer surface and bamboo acromere
Only；
(2) bamboo section vertical profile and bamboo block remove tabasheer and internal segment
It will revolve to cut open except the bamboo section longitudinal direction of bamboo blueness and acromere and cut as 2-3 block bamboo blocks, and reject tabasheer and internal segment on bamboo block later；
(3) bamboo block is chipped
By the bamboo block without bamboo blueness, tabasheer and ring, it is sent into the drum chipper of positive feed and chips, bamboo block is cut into
The bamboo chip that length is 15-25mm, width 15-20mm, thickness are 2-3mm, bamboo chip moisture content are maintained between 30-50%；
(4) bamboo chip prepares bamboo fibre
Bamboo chip is separated by bamboo fibre using thermomechanical method, the temperature of wherein steam heating boiling is 160-180 DEG C, is steamed
Boil time 4-8min；
(5) the mould proof processing of bamboo fibre
It, later will by metering pump or flow valve by bamboo fibre with being sent into round roller of the inside with blender
Chinese herbal medicine mould inhibitor prepared by embodiment 2 is applied to by the top of roller on bamboo fibre, and applying mould inhibitor, blender is held simultaneously
Continuous stirring, makes mould inhibitor uniformly be mixed with bamboo fibre, and the applied amount of mould inhibitor is the 2-6% of over dry bamboo fibre quality；
(6) mould proof bamboo fibre drying
It is dried aqueous to the bamboo fibre Jing Guo mould proof processing using the vertical Air Dried System drying of duct type two level
Rate is controlled in the range of 5-10%；
(7) mould proof bamboo fibre applies without the non-ignitable cementing material of aldehyde
Using pipeline resin application methods to the bamboo fibre application preparation of embodiment 10 without the non-ignitable cementing material of aldehyde, no aldehyde incombustible glue
The applied amount of knot material accounts for the 30-45% of over dry bamboo fibre quality for the solid weight of glue；
(8) sizing bamboo fibre is mated formation
The bamboo fibre of cementing material will be applied, and be paved on belt with mechanical forming machine and obtain slab；
(9) slab precompressed
Continuous precompressed is carried out to the slab after mating formation using Continuous Roller press, makes slab just one-step forming；
(10) slab hot pressing
Carry out hot pressing to shaping slab using the double steel band hot presses of continous way, heat pressing process in existing continous way timber
The technological parameter of density fiber board production is identical, and the flash plate without the not mould non-ignitable bamboo fiberboard of aldehyde can be obtained after hot pressing；
(11) post-processing
By the flash plate of the not mould non-ignitable bamboo fiberboard of no aldehyde, it is placed in and combines in length and breadth on edge cutting machine to the length of fiberboard flash plate
Degree and width are processed to get the sketch-plate of the not mould non-ignitable bamboo fiberboard of no aldehyde；Sketch-plate is placed in temperature as 30-40 again
DEG C, carry out in the balance room that humidity is 50-70% after modifier treatment 36-96h to get the not mould non-ignitable bamboo fiberboard finished product of no aldehyde.
Embodiment 22：
A kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde, Chinese herbal medicine mould inhibitor prepared by embodiment 2 is replaced with
Nanometer silver-colored zinc composite mildew inhibitor prepared by embodiment 3；By prepared by embodiment 10 embodiment is replaced with without the non-ignitable cementing material of aldehyde
13 prepare without the non-ignitable cementing material of aldehyde；Remaining condition is identical with embodiment 21.
Embodiment 23：
A kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde, Chinese herbal medicine mould inhibitor prepared by embodiment 2 is replaced with
Nanometer silver-colored zinc composite mildew inhibitor prepared by embodiment 6；By prepared by embodiment 10 embodiment is replaced with without the non-ignitable cementing material of aldehyde
16 prepare without the non-ignitable cementing material of aldehyde；Remaining condition is identical with embodiment 21.
Embodiment 24：
A kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde, Chinese herbal medicine mould inhibitor prepared by embodiment 2 is replaced with
Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor prepared by embodiment 8；It is replaced with prepared by embodiment 10 without the non-ignitable cementing material of aldehyde
Embodiment 19 prepare without the non-ignitable cementing material of aldehyde；Remaining condition is identical with embodiment 21.
Because length is limited, to further illustrate the present invention the performance without the not mould non-ignitable bamboo fiberboard of aldehyde of preparation, only with reality
Structure comparative example is as follows for applying example 24.
Comparative example 14：
Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor is replaced with into Chinese herbal medicine mould inhibitor, remaining is identical with embodiment 21.
Comparative example 12：
Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor is replaced with into commercially available mould inhibitor, remaining condition is identical with embodiment 24.
Comparative example 13：
Lauxite will be replaced with without the non-ignitable cementing material of aldehyde, remaining condition is identical with embodiment 24.
Comparative example 14：
Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor is replaced with into commercially available mould inhibitor, will be replaced with without the non-ignitable cementing material of aldehyde
Phenolic resin, remaining condition are identical with embodiment 24.
Bamboo fiberboard prepared by embodiment 20-24 and comparative example 12-14, according to GB/T 11718-2009《Medium density fiber
Plate》Its density, static bending strength, internal bond strength, thickness swelling and burst size of methanal are tested, according to GB 8624-2012《It builds
Build material and product burns grading performance》The combustibility of bamboo fiberboard is tested, test result is shown in Table 4.
Table 4
As shown in Table 4, the bamboo fiberboard for preparing of the present invention have it is not mouldy, without formaldehyde, while burning behavior class reaches
To A2 grades non-ignitable.
In summary, the bamboo fiberboard that prepared by present invention success is free of formaldehyde, is not easy to go mouldy, while have nonflammable
Characteristic；Mycotic infection value can reach 0, and burning behavior class reaches A2 grades non-ignitable；Its fungicidal properties of mould inhibitor provided by the invention
Better than most commercially available mould inhibitors, and preparation method is simple, and raw material is easy to get；The non-ignitable cementing material solution of no aldehyde provided by the invention
Determined the problem of adhesive contains a certain amount of formaldehyde in the prior art, and by the rational proportion of three kinds of components, reach compared with
Good flame retardant property.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
The all possible combination of each technical characteristic in example is applied all to be described, for those skilled in the art,
Without departing from the principles of the present invention, several improvements and modifications can also be made, these improvements and modifications should also regard
For protection scope of the present invention.
Claims (10)
1. a kind of preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde, which is characterized in that include the following steps：
(1) bamboo section is produced
Using the bamboo wood of small diameter grade as raw material, after at its sawed-off bamboo section for certain length, it is placed on small-sized rotary trunk-layer stripping machine without clamper
Rotary-cut is carried out, revolves after removing and stops substantially in the bamboo blueness of bamboo section outer surface and bamboo acromere；
(2) bamboo section vertical profile and bamboo block remove tabasheer and internal segment
It will revolve to cut open except the bamboo section longitudinal direction of bamboo blueness and acromere and cut as 2-3 block bamboo blocks, and reject tabasheer and internal segment on bamboo block later；
(3) bamboo block is chipped
By the bamboo block without bamboo blueness, tabasheer and ring, it is sent into the drum chipper of positive feed and chips, bamboo block is cut into length
The bamboo chip for being 2-3mm for 15-25mm, width 15-20mm, thickness, bamboo chip moisture content are maintained between 30-50%；
(4) bamboo chip prepares bamboo fibre
Bamboo chip is separated by bamboo fibre using thermomechanical method, the temperature of wherein steam heating boiling is 160-180 DEG C, during boiling
Between 4-8min；
(5) the mould proof processing of bamboo fibre；
(6) mould proof bamboo fibre drying；
(7) mould proof bamboo fibre applies without the non-ignitable cementing material of aldehyde；
(8) sizing bamboo fibre is mated formation
The bamboo fibre of cementing material will be applied, and be paved on belt with mechanical forming machine and obtain slab；
(9) slab precompressed
Continuous precompressed is carried out to the slab after mating formation using Continuous Roller press, makes slab just one-step forming；
(10) slab hot pressing
Hot pressing is carried out to shaping slab using continous way double steel band hot presses, can be obtained after hot pressing without the not mould non-ignitable bamboo fiberboard of aldehyde
Flash plate；
(11) post-processing.
2. the preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde according to claim 1, which is characterized in that the step
It (5), later will be anti-by metering pump or flow valve by bamboo fibre with being sent into round roller of the inside with blender in
Mould dose is applied to by the top of roller on bamboo fibre, and applying mould inhibitor, blender persistently stirs simultaneously, makes mould inhibitor fine with bamboo
Dimension uniformly mixing, the applied amount of mould inhibitor are the 2-6% of over dry bamboo fibre quality；
In the step (6), the bamboo fibre Jing Guo mould proof processing using the vertical Air Dried System of duct type two level is dried, is done
Moisture control after dry is in the range of 5-10%.
3. the preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde according to claim 1, which is characterized in that the step
(7) in, bamboo fibre is applied without the non-ignitable cementing material of aldehyde using pipeline resin application methods, the applied amount of the no non-ignitable cementing material of aldehyde is
The solid weight of glue accounts for the 30-45% of over dry bamboo fibre quality；
In the step (11), by the flash plate of the not mould non-ignitable bamboo fiberboard of no aldehyde, it is placed in and combines on edge cutting machine to fiber in length and breadth
The length and width of plate flash plate is processed to get the sketch-plate of the not mould non-ignitable bamboo fiberboard of no aldehyde；Sketch-plate is placed in again
To get the not mould non-ignitable bamboo of no aldehyde after progress modifier treatment 36-96h in the balance room that temperature is 30-40 DEG C, humidity is 50-70%
Stock for fibreboard.
4. the preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde according to claim 1 or 2, which is characterized in that described anti-
Mould dose is Chinese herbal medicine mould inhibitor, nanometer silver-colored zinc composite mildew inhibitor or Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor.
5. the preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde according to claim 4, which is characterized in that the Chinese herbal medicine
The preparation method of mould inhibitor is：
By medicinal herb soak in ethanol solution, the mass ratio of the Chinese herbal medicine and ethyl alcohol is 1:5-20 is filtered after heating heating
Filter residue is removed, obtains the Chinese herbal medicine mould inhibitor of a concentration of 50-100mg/ml of Chinese herbal medicine；
The Chinese herbal medicine is made of following parts by weight of component：20-30 parts of thyme, 50-60 parts of flos caryophylli, 10-15 parts of cinnaldehydrum
With 5-10 parts of dried orange peel.
6. the preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde according to claim 4, which is characterized in that the nano silver
The preparation method of zinc composite mildew inhibitor is：
Weigh zinc acetate or zinc nitrate or 60-75 parts of zinc sulfate, natrium carbonicum calcinatum 15-20,5-15 parts of silver nitrate and dodecyl
5-10 parts of benzene sulfonic acid sodium salt is respectively put into mortar and grinds uniformly mixing, then washed respectively with deionized water, absolute ethyl alcohol, filters
After dry, put it in high-temperature roasting furnace and to be sintered at a temperature of 250-500 DEG C to get to nanometer silver-colored zinc composite mildewproof later
Agent；
Alternatively, using zinc acetate or zinc nitrate or zinc sulfate, silver nitrate as raw material, ammonium hydrogen carbonate prepares nanometer silver-colored zinc for precipitating reagent and answers
Close mould inhibitor：First, when the temperature of reaction vessel reaches 20-50 DEG C, the acetic acid of a concentration of 1-4mol/l of 50-100ml is pipetted
In reaction vessel, the ammonium bicarbonate soln that same concentrations are added dropwise while stirring holds in reaction for zinc or zinc nitrate or solution of zinc sulfate
In device, zinc acetate or zinc nitrate or the molar ratio of zinc sulfate and ammonium hydrogen carbonate are 1:2-5 adds in ammonium hydrogen carbonate by this calculating
Amount, reaction time 2-5h；Later, silver nitrate and the ammonium hydrogen carbonate that a concentration of 0.2-0.4mol/l is added dropwise respectively while stirring are molten
For liquid in reaction vessel, the molar ratio of silver nitrate and ammonium hydrogen carbonate is 1:1.5-4.5 is added in the amount of silver nitrate by this calculating, instead
0.5-1.5h between seasonable；Then, it washs, centrifuge to obtain first polymers；Finally, the drying of first polymers is placed on high-temperature roasting furnace
In, 1-3h is roasted at a temperature of 350-550 DEG C, obtains a nanometer silver-colored zinc composite mildew inhibitor.
7. the preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde according to claim 4, which is characterized in that the medium-height grass
The preparation method of medicine/nanometer silver-colored zinc composite mildew inhibitor is：
30-50 parts of 50-70 parts of Chinese herbal medicine mould inhibitor and nanometer silver-colored zinc composite mildew inhibitor are weighed in proportion, and Chinese herbal medicine mould inhibitor is put
In the container with blender, nanometer silver-colored zinc composite mildew inhibitor is added in while stirring, until nanometer silver-colored zinc composite mildew inhibitor is equal
It is even to be distributed in Chinese herbal medicine mould inhibitor to get Chinese herbal medicine/nanometer silver-colored zinc composite mildew inhibitor.
8. the preparation method without the not mould non-ignitable bamboo fiberboard of aldehyde according to claim 1 or 3, which is characterized in that the nothing
The non-ignitable cementing material of aldehyde is made of A agent, B agent and C agent；
The A agent includes 5-15 parts of 65-80 parts of magnesia, 15-25 parts of magnesium sulfate and calcium silicates；
The B agent is epsom salt；
The C agent is sodium metasilicate, neoprene, vinyl urethane or vinylacetate.
9. the preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde according to claim 8, which is characterized in that the C agent is
Sodium metasilicate, the no non-ignitable cementing material of aldehyde are made of the component of following parts by weight：40-50 parts of A agent, 40-50 parts of B agent, C agent 5-
10 parts；
Alternatively, the C agent is neoprene, the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A agent 40-
45 parts, 40-45 parts of B agent, 5-15 parts of C agent；
Alternatively, the C agent is vinyl urethane, the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A agent
40-50 parts, 40-50 parts of B agent, 2-8 parts of C agent；
Alternatively, the C agent is vinylacetate, the no non-ignitable cementing material of aldehyde is made of the component of following parts by weight：A agent
40-45 parts, 40-45 parts of B agent, 5-15 parts of C agent.
10. the preparation method of the not mould non-ignitable bamboo fiberboard of no aldehyde according to claim 9, which is characterized in that the no aldehyde
The preparation method of non-ignitable cementing material is：Each component in A agent is respectively placed in after being ground in grinder, with 200-400 mesh
Sieve screened, then mix in proportion；Then A agent, B agent and C agent are mixed in proportion to get no aldehyde not
Fire cementing material.
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| CN109986674A (en) * | 2019-04-30 | 2019-07-09 | 黄嘉汉 | A kind of preparation method of long-acting weather-proof Recombined bamboo |
| WO2021195798A1 (en) * | 2020-03-30 | 2021-10-07 | 山东建筑大学 | Crack-resistant inorganic adhesive for bamboo structure and preparation method therefor, and preparation method for recombinant bamboo |
| CN115179380A (en) * | 2022-07-15 | 2022-10-14 | 浙江农林大学 | Preparation method of emerald green mildew-resistant anti-cracking round bamboo |
| CN115741922A (en) * | 2022-11-18 | 2023-03-07 | 千年舟新材科技集团股份有限公司 | Flame-retardant non-dried bean curd stick silk board and preparation method thereof |
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| CN115179380A (en) * | 2022-07-15 | 2022-10-14 | 浙江农林大学 | Preparation method of emerald green mildew-resistant anti-cracking round bamboo |
| CN115179380B (en) * | 2022-07-15 | 2023-09-12 | 浙江农林大学 | Preparation method of emerald green mildew-resistant and crack-resistant round bamboo |
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