CN107254229A - A kind of high fire-retardance liquid wallpaper and preparation method thereof - Google Patents
A kind of high fire-retardance liquid wallpaper and preparation method thereof Download PDFInfo
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- CN107254229A CN107254229A CN201710644610.9A CN201710644610A CN107254229A CN 107254229 A CN107254229 A CN 107254229A CN 201710644610 A CN201710644610 A CN 201710644610A CN 107254229 A CN107254229 A CN 107254229A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of high fire-retardance liquid wallpaper, include the raw material of following parts by weight：12~23 parts of acrylic emulsion, 15~25 parts of silicone acrylic emulsion, 10~30 parts of diatom ooze, 5~10 parts of sisal fiber, 8~14 parts of precipitated calcium carbonate, 2~3 parts of alumina silicate, 1~3 part of calgon, 1.3~2.5 parts of tetrapotassium pyrophosphate, 2~7 parts of titanium dioxide, temperature become 1~2 part of material, 2~5 parts of thickener, 1~2 part of fire retardant, 1.5~2.5 parts of coalescents, 2~3 parts of anionic additive, 1~2 part of activated carbon, 20~40 parts of distilled water.The high fire-retardance liquid wallpaper possesses good fire resistance, water resistance and anticorrosive property, and wearability and adhesive force also increase, and can purify air.
Description
Technical field
The invention belongs to building material technical field, and in particular to a kind of high fire-retardance liquid wallpaper and preparation method thereof.
Background technology
At present, the material that people are used for the wall decoration of indoor and outdoor is wallpaper, wall paper and paint mostly.Paint is not because containing
Harm is produced to health with the organic volatile pollutant of degree, traditional wallpaper, the often price of wall paper are higher, when long
Between using easy jaundice, peeling, colour fading, these defects all limit the popularization that it is applied.
As a kind of new decorative material, liquid wallpaper has nontoxic, free of contamination environmental protection characteristic, and cost performance is higher than tradition
Ornament materials.Liquid wallpaper uses organosilicon-modified acrylic emulsion, and institute does not rouse into glued membrane not yellowing after long-time immersion
Bubble, does not fall off, and surface still has hydrophobic performance, excellent water resistance and dirt-resistant self-cleaning, outstanding resistance to weathering, color
Pattern can flexibly change with the demand of client, realize the variation of traditional decoration material.
But traditional liquid wallpaper water resistance and Corrosion Protection is poor, wearability and the bad shortcoming of adhesive force.
The content of the invention
The invention provides a kind of high fire-retardance liquid wallpaper and preparation method thereof, asking in above-mentioned background technology is solved
Topic, the high fire-retardance liquid wallpaper possesses good fire resistance, water resistance and anticorrosive property, and wearability and adhesive force are also
Improve, and air can be purified.
In order to solve the problem of prior art is present, adopt the following technical scheme that：
A kind of high fire-retardance liquid wallpaper, includes the raw material of following parts by weight：12~23 parts of acrylic emulsion, silicone acrylic emulsion 15~25
Part, 10~30 parts of diatom ooze, 5~10 parts of sisal fiber, 8~14 parts of precipitated calcium carbonate, 2~3 parts of alumina silicate, calgon 1
~3 parts, 1.3~2.5 parts of tetrapotassium pyrophosphate, 2~7 parts of titanium dioxide, temperature become 1~2 part of material, 2~5 parts of thickener, fire retardant 1~
2 parts, 1.5~2.5 parts of coalescents, 2~3 parts of anionic additive, 1~2 part of activated carbon, 20~40 parts of distilled water.
It is preferred that, the high fire-retardance liquid wallpaper includes the raw material of following parts by weight：15~20 parts of acrylic emulsion, silicon
19~22 parts of acrylic emulsion, 18~24 parts of diatom ooze, 6~9 parts of sisal fiber, 11~13 parts of precipitated calcium carbonate, alumina silicate 2.3~
2.8 parts, 1.3~2.8 parts of calgon, 1.7~2.1 parts of tetrapotassium pyrophosphate, 3~6 parts of titanium dioxide, temperature become material 1.2~1.7
Part, 3~4 parts of thickener, 1.2~1.8 parts of fire retardant, 1.7~2.2 parts of coalescents, 2.4~2.6 parts of anionic additive, work
1.3~1.8 parts of charcoal of property, 25~33 parts of distilled water.
It is preferred that, the high fire-retardance liquid wallpaper includes the raw material of following parts by weight：18 parts of acrylic emulsion, the breast of silicon third
20 parts of liquid, 22 parts of diatom ooze, 7 parts of sisal fiber, 12 parts of precipitated calcium carbonate, 2.7 parts of alumina silicate, 2.5 parts of calgon, burnt phosphorus
Sour 1.8 parts of four potassium, 4 parts of titanium dioxide, temperature become 1.5 parts of material, 3.2 parts of thickener, 1.6 parts of fire retardant, 2 parts of coalescents, bear from
Sub- 2.5 parts of additive, 1.6 parts of activated carbon, 28 parts of distilled water.
It is preferred that, the sisal fiber is made by following methods：By 100 kilograms of sisal leaves, 200 kilograms of quality hundred are added to
Divide than in 40% sodium hydroxide liquid, heating was boiled after 30 minutes, is pulled fibre bundle out, is cleaned with clear water, and uses quality percentage
, then, will than in the watery hydrochloric acid for 2% and remaining alkali, then, the sisal hemp beam after cleaning to be cut into 5~10 millimeters of chopped fiber
Chopped fiber is put into water, comb solution of dissociating, as sisal fiber.
It is preferred that, the temperature becomes material into microencapsulation crystal violet lactone, 25 DEG C of its discoloring temperature.
It is preferred that, the coalescents are selected from propane diols phenylate, alcohol ester-12（2,2,4- trimethyl -1,3- pentanediols Dan Yi
Butyrate）In one kind.
It is preferred that, the thickener is any in polyurethanes thickener, alkali soluble is swollen class thickener, polyethers thickener
Kind.
A kind of method for preparing the high fire-retardance liquid wallpaper, comprises the following steps：
（1）Acrylic emulsion, silicone acrylic emulsion, diatom ooze, sisal fiber, precipitated calcium carbonate, alumina silicate, six are weighed by above-mentioned formula
Sodium metaphosphate, tetrapotassium pyrophosphate, titanium dioxide, temperature become material, thickener, fire retardant, coalescents, anionic additive, activity
Charcoal, distilled water, it is standby；
（2）Temperature is become into material and distilled water is mixed, is placed in reactor, is added calgon and tetrapotassium pyrophosphate, be heated to
50~60 DEG C, stirred 12~17 minutes with 200~300r/min speed, obtain temperature change powder slurry；
（3）To step（2）Obtained temperature, which becomes in slurry, sequentially adds coalescents, precipitated calcium carbonate and alumina silicate, with 300~
500r/min speed insulated and stirred 30~60 minutes, then adds acrylic emulsion and silicone acrylic emulsion, is heated to 70~80 DEG C,
Stirred 10~20 minutes with 1000~1200r/min speed, be cooled to room temperature；
（4）To step（3）Sequentially add sisal fiber, diatom ooze, titanium dioxide and activated carbon in the mixture of gained, stirring 15~
25 minutes, thickener, fire retardant and anionic additive are then added, is vacuumized, stirred 10~20 minutes, produce the high resistant
Burning liquid wallpaper.
Compared with prior art, it has the advantages that the present invention：
Described high fire-retardance liquid wallpaper of the present invention possesses good fire resistance, water resistance and anticorrosive property, wearability
Also increased with adhesive force, and air can be purified, it is specific as follows：
（1）High fire-retardance liquid wallpaper of the present invention as raw material, can improve the water resistance, stably of wallpaper using silicone acrylic emulsion
Property, heat resistance and film forming；The silicone acrylic emulsion, its stability is good, and emulsion grain is small, prepares the stain resistance of liquid wallpaper
It is good, there is excellent water resistance and dirt-resistant self-cleaning, excellent resistance to weathering into glued membrane, it is adaptable to inner wall of building；
（2）High fire-retardance liquid wallpaper of the present invention also added diatom ooze, sisal fiber, precipitated calcium carbonate as raw material,
Diatom ooze, sisal fiber, precipitated calcium carbonate and other raw materials mutually act synergistically, the liquid wallpaper wearability and anti-corrosion prepared
Corrosion can be good；
（3）The present invention also added fire retardant and adsorbent charcoal so that the liquid wallpaper can be with formaldehyde adsorption, purification air, tool
There is good fire resistance.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
The present embodiment is related to a kind of high fire-retardance liquid wallpaper, includes the raw material of following parts by weight：12 parts of acrylic emulsion, the breast of silicon third
15 parts of liquid, 10 parts of diatom ooze, 5 parts of sisal fiber, 8 parts of precipitated calcium carbonate, 2 parts of alumina silicate, 1 part of calgon, pyrophosphoric acid four
1.3 parts of potassium, 2 parts of titanium dioxide, temperature become 1 part of material, 2 parts of thickener, 1 part of fire retardant, 1.5 parts of coalescents, anionic additive 2
Part, 1 part of activated carbon, 20 parts of distilled water.
Wherein, the sisal fiber is made by following methods：By 100 kilograms of sisal leaves, 200 kilograms of quality percentages are added to
Than in the sodium hydroxide liquid for 40%, heating was boiled after 30 minutes, is pulled fibre bundle out, is cleaned with clear water, and uses mass percent
, then, will be short in 2% watery hydrochloric acid and remaining alkali, then, the sisal hemp beam after cleaning to be cut into 5~10 millimeters of chopped fiber
Fiber is put into water, comb solution of dissociating, as sisal fiber.
Wherein, the temperature becomes material into microencapsulation crystal violet lactone, 25 DEG C of its discoloring temperature.
Wherein, the coalescents are selected from propane diols phenylate.
Wherein, the thickener is polyurethanes thickener.
A kind of method for preparing the high fire-retardance liquid wallpaper, comprises the following steps：
（1）Acrylic emulsion, silicone acrylic emulsion, diatom ooze, sisal fiber, precipitated calcium carbonate, alumina silicate, six are weighed by above-mentioned formula
Sodium metaphosphate, tetrapotassium pyrophosphate, titanium dioxide, temperature become material, thickener, fire retardant, coalescents, anionic additive, activity
Charcoal, distilled water, it is standby；
（2）Temperature is become into material and distilled water is mixed, is placed in reactor, is added calgon and tetrapotassium pyrophosphate, be heated to
50 DEG C, stirred 12 minutes with 200r/min speed, obtain temperature change powder slurry；
（3）To step（2）Obtained temperature, which becomes in slurry, sequentially adds coalescents, precipitated calcium carbonate and alumina silicate, with 300r/
Min speed insulated and stirred 30 minutes, then adds acrylic emulsion and silicone acrylic emulsion, 70 DEG C is heated to, with 1000r/min's
Speed is stirred 10 minutes, is cooled to room temperature；
（4）To step（3）Sisal fiber, diatom ooze, titanium dioxide and activated carbon are sequentially added in the mixture of gained, 15 points are stirred
Clock, then adds thickener, fire retardant and anionic additive, vacuumizes, and stirs 10 minutes, produces the high fire-retardance liquid wall
Paper.
Embodiment 2
The present embodiment is related to a kind of high fire-retardance liquid wallpaper, includes the raw material of following parts by weight：23 parts of acrylic emulsion, the breast of silicon third
25 parts of liquid, 30 parts of diatom ooze, 10 parts of sisal fiber, 14 parts of precipitated calcium carbonate, 3 parts of alumina silicate, 3 parts of calgon, pyrophosphoric acid
Four 2.5 parts of potassium, 7 parts of titanium dioxide, temperature become 2 parts of material, 5 parts of thickener, 2 parts of fire retardant, 2.5 parts of coalescents, anion addition
3 parts of agent, 2 parts of activated carbon, 40 parts of distilled water.
Wherein, the sisal fiber is made by following methods：By 100 kilograms of sisal leaves, 200 kilograms of quality percentages are added to
Than in the sodium hydroxide liquid for 40%, heating was boiled after 30 minutes, is pulled fibre bundle out, is cleaned with clear water, and uses mass percent
, then, will be short in 2% watery hydrochloric acid and remaining alkali, then, the sisal hemp beam after cleaning to be cut into 5~10 millimeters of chopped fiber
Fiber is put into water, comb solution of dissociating, as sisal fiber.
Wherein, the temperature becomes material into microencapsulation crystal violet lactone, 25 DEG C of its discoloring temperature.
Wherein, the coalescents are selected from alcohol ester-12（2,2,4- trimethyl -1,3- pentanediol mono isobutyrates）.
Wherein, the thickener is the swollen class thickener of alkali soluble.
A kind of method for preparing the high fire-retardance liquid wallpaper, comprises the following steps：
（1）Acrylic emulsion, silicone acrylic emulsion, diatom ooze, sisal fiber, precipitated calcium carbonate, alumina silicate, six are weighed by above-mentioned formula
Sodium metaphosphate, tetrapotassium pyrophosphate, titanium dioxide, temperature become material, thickener, fire retardant, coalescents, anionic additive, activity
Charcoal, distilled water, it is standby；
（2）Temperature is become into material and distilled water is mixed, is placed in reactor, is added calgon and tetrapotassium pyrophosphate, be heated to
60 DEG C, stirred 17 minutes with 300r/min speed, obtain temperature change powder slurry；
（3）To step（2）Obtained temperature, which becomes in slurry, sequentially adds coalescents, precipitated calcium carbonate and alumina silicate, with 500r/
Min speed insulated and stirred 60 minutes, then adds acrylic emulsion and silicone acrylic emulsion, 80 DEG C is heated to, with 1200r/min's
Speed is stirred 20 minutes, is cooled to room temperature；
（4）To step（3）Sisal fiber, diatom ooze, titanium dioxide and activated carbon are sequentially added in the mixture of gained, 25 points are stirred
Clock, then adds thickener, fire retardant and anionic additive, vacuumizes, and stirs 20 minutes, produces the high fire-retardance liquid wall
Paper.
Embodiment 3
The present embodiment is related to a kind of high fire-retardance liquid wallpaper, includes the raw material of following parts by weight：15 parts of acrylic emulsion, the breast of silicon third
19 parts of liquid, 18 parts of diatom ooze, 6 parts of sisal fiber, 11 parts of precipitated calcium carbonate, 2.3 parts of alumina silicate, 1.3 parts of calgon, burnt phosphorus
Sour 1.7 parts of four potassium, 3 parts of titanium dioxide, temperature become 1.2 parts of material, 3 parts of thickener, 1.2 parts of fire retardant, 1.7 parts of coalescents, bear from
Sub- 2.4 parts of additive, 1.3 parts of activated carbon, 25 parts of distilled water.
Wherein, the sisal fiber is made by following methods：By 100 kilograms of sisal leaves, 200 kilograms of quality percentages are added to
Than in the sodium hydroxide liquid for 40%, heating was boiled after 30 minutes, is pulled fibre bundle out, is cleaned with clear water, and uses mass percent
, then, will be short in 2% watery hydrochloric acid and remaining alkali, then, the sisal hemp beam after cleaning to be cut into 5~10 millimeters of chopped fiber
Fiber is put into water, comb solution of dissociating, as sisal fiber.
Wherein, the temperature becomes material into microencapsulation crystal violet lactone, 25 DEG C of its discoloring temperature.
Wherein, the coalescents are selected from propane diols phenylate.
Wherein, the thickener is polyethers thickener.
A kind of method for preparing the high fire-retardance liquid wallpaper, comprises the following steps：
（1）Acrylic emulsion, silicone acrylic emulsion, diatom ooze, sisal fiber, precipitated calcium carbonate, alumina silicate, six are weighed by above-mentioned formula
Sodium metaphosphate, tetrapotassium pyrophosphate, titanium dioxide, temperature become material, thickener, fire retardant, coalescents, anionic additive, activity
Charcoal, distilled water, it is standby；
（2）Temperature is become into material and distilled water is mixed, is placed in reactor, is added calgon and tetrapotassium pyrophosphate, be heated to
53 DEG C, stirred 13 minutes with 220r/min speed, obtain temperature change powder slurry；
（3）To step（2）Obtained temperature, which becomes in slurry, sequentially adds coalescents, precipitated calcium carbonate and alumina silicate, with 350r/
Min speed insulated and stirred 40 minutes, then adds acrylic emulsion and silicone acrylic emulsion, 72 DEG C is heated to, with 10500r/min
Speed stir 13 minutes, be cooled to room temperature；
（4）To step（3）Sisal fiber, diatom ooze, titanium dioxide and activated carbon are sequentially added in the mixture of gained, 18 points are stirred
Clock, then adds thickener, fire retardant and anionic additive, vacuumizes, and stirs 12 minutes, produces the high fire-retardance liquid wall
Paper.
Embodiment 4
The present embodiment is related to a kind of high fire-retardance liquid wallpaper, includes the raw material of following parts by weight：20 parts of acrylic emulsion, the breast of silicon third
22 parts of liquid, 24 parts of diatom ooze, 9 parts of sisal fiber, 13 parts of precipitated calcium carbonate, 2.8 parts of alumina silicate, 2.8 parts of calgon, burnt phosphorus
Sour 2.1 parts of four potassium, 6 parts of titanium dioxide, temperature become 1.7 parts of material, 4 parts of thickener, 1.8 parts of fire retardant, 2.2 parts of coalescents, bear from
Sub- 2.6 parts of additive, 1.8 parts of activated carbon, 33 parts of distilled water.
Wherein, the sisal fiber is made by following methods：By 100 kilograms of sisal leaves, 200 kilograms of quality percentages are added to
Than in the sodium hydroxide liquid for 40%, heating was boiled after 30 minutes, is pulled fibre bundle out, is cleaned with clear water, and uses mass percent
, then, will be short in 2% watery hydrochloric acid and remaining alkali, then, the sisal hemp beam after cleaning to be cut into 5~10 millimeters of chopped fiber
Fiber is put into water, comb solution of dissociating, as sisal fiber.
Wherein, the temperature becomes material into microencapsulation crystal violet lactone, 25 DEG C of its discoloring temperature.
Wherein, the coalescents are selected from alcohol ester-12（2,2,4- trimethyl -1,3- pentanediol mono isobutyrates）.
Wherein, the thickener is polyurethanes thickener.
A kind of method for preparing the high fire-retardance liquid wallpaper, comprises the following steps：
（1）Acrylic emulsion, silicone acrylic emulsion, diatom ooze, sisal fiber, precipitated calcium carbonate, alumina silicate, six are weighed by above-mentioned formula
Sodium metaphosphate, tetrapotassium pyrophosphate, titanium dioxide, temperature become material, thickener, fire retardant, coalescents, anionic additive, activity
Charcoal, distilled water, it is standby；
（2）Temperature is become into material and distilled water is mixed, is placed in reactor, is added calgon and tetrapotassium pyrophosphate, be heated to
58 DEG C, stirred 16 minutes with 270r/min speed, obtain temperature change powder slurry；
（3）To step（2）Obtained temperature, which becomes in slurry, sequentially adds coalescents, precipitated calcium carbonate and alumina silicate, with 450r/
Min speed insulated and stirred 55 minutes, then adds acrylic emulsion and silicone acrylic emulsion, 78 DEG C is heated to, with 1050r/min's
Speed is stirred 17 minutes, is cooled to room temperature；
（4）To step（3）Sisal fiber, diatom ooze, titanium dioxide and activated carbon are sequentially added in the mixture of gained, 23 points are stirred
Clock, then adds thickener, fire retardant and anionic additive, vacuumizes, and stirs 18 minutes, produces the high fire-retardance liquid wall
Paper.
Embodiment 5
The present embodiment is related to a kind of high fire-retardance liquid wallpaper, includes the raw material of following parts by weight：18 parts of acrylic emulsion, the breast of silicon third
20 parts of liquid, 22 parts of diatom ooze, 7 parts of sisal fiber, 12 parts of precipitated calcium carbonate, 2.7 parts of alumina silicate, 2.5 parts of calgon, burnt phosphorus
Sour 1.8 parts of four potassium, 4 parts of titanium dioxide, temperature become 1.5 parts of material, 3.2 parts of thickener, 1.6 parts of fire retardant, 2 parts of coalescents, bear from
Sub- 2.5 parts of additive, 1.6 parts of activated carbon, 28 parts of distilled water.
Wherein, the sisal fiber is made by following methods：By 100 kilograms of sisal leaves, 200 kilograms of quality percentages are added to
Than in the sodium hydroxide liquid for 40%, heating was boiled after 30 minutes, is pulled fibre bundle out, is cleaned with clear water, and uses mass percent
, then, will be short in 2% watery hydrochloric acid and remaining alkali, then, the sisal hemp beam after cleaning to be cut into 5~10 millimeters of chopped fiber
Fiber is put into water, comb solution of dissociating, as sisal fiber.
Wherein, the temperature becomes material into microencapsulation crystal violet lactone, 25 DEG C of its discoloring temperature.
Wherein, the coalescents are selected from alcohol ester-12（2,2,4- trimethyl -1,3- pentanediol mono isobutyrates）.
Wherein, the thickener is the swollen class thickener of alkali soluble.
A kind of method for preparing the high fire-retardance liquid wallpaper, comprises the following steps：
（1）Acrylic emulsion, silicone acrylic emulsion, diatom ooze, sisal fiber, precipitated calcium carbonate, alumina silicate, six are weighed by above-mentioned formula
Sodium metaphosphate, tetrapotassium pyrophosphate, titanium dioxide, temperature become material, thickener, fire retardant, coalescents, anionic additive, activity
Charcoal, distilled water, it is standby；
（2）Temperature is become into material and distilled water is mixed, is placed in reactor, is added calgon and tetrapotassium pyrophosphate, be heated to
55 DEG C, stirred 15 minutes with 250r/min speed, obtain temperature change powder slurry；
（3）To step（2）Obtained temperature, which becomes in slurry, sequentially adds coalescents, precipitated calcium carbonate and alumina silicate, with 400r/
Min speed insulated and stirred 45 minutes, then adds acrylic emulsion and silicone acrylic emulsion, 75 DEG C is heated to, with 1100r/min's
Speed is stirred 15 minutes, is cooled to room temperature；
（4）To step（3）Sisal fiber, diatom ooze, titanium dioxide and activated carbon are sequentially added in the mixture of gained, 20 points are stirred
Clock, then adds thickener, fire retardant and anionic additive, vacuumizes, and stirs 15 minutes, produces the high fire-retardance liquid wall
Paper.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of high fire-retardance liquid wallpaper, it is characterised in that include the raw material of following parts by weight：12~23 parts of acrylic emulsion,
15~25 parts of silicone acrylic emulsion, 10~30 parts of diatom ooze, 5~10 parts of sisal fiber, 8~14 parts of precipitated calcium carbonate, alumina silicate 2~3
Part, 1~3 part of calgon, 1.3~2.5 parts of tetrapotassium pyrophosphate, 2~7 parts of titanium dioxide, temperature become 1~2 part of material, thickener 2
~5 parts, 1~2 part of fire retardant, 1.5~2.5 parts of coalescents, 2~3 parts of anionic additive, 1~2 part of activated carbon, distilled water
20~40 parts.
2. high fire-retardance liquid wallpaper according to claim 1, it is characterised in that include the raw material of following parts by weight：Propylene
15~20 parts of yogurt liquid, 19~22 parts of silicone acrylic emulsion, 18~24 parts of diatom ooze, 6~9 parts of sisal fiber, precipitated calcium carbonate 11~
13 parts, 2.3~2.8 parts of alumina silicate, 1.3~2.8 parts of calgon, 1.7~2.1 parts of tetrapotassium pyrophosphate, 3~6 parts of titanium dioxide,
Temperature becomes 1.2~1.7 parts of material, 3~4 parts of thickener, 1.2~1.8 parts of fire retardant, 1.7~2.2 parts of coalescents, anion and added
Plus 2.4~2.6 parts of agent, 1.3~1.8 parts of activated carbon, 25~33 parts of distilled water.
3. high fire-retardance liquid wallpaper according to claim 1, it is characterised in that include the raw material of following parts by weight：Propylene
18 parts of yogurt liquid, 20 parts of silicone acrylic emulsion, 22 parts of diatom ooze, 7 parts of sisal fiber, 12 parts of precipitated calcium carbonate, 2.7 parts of alumina silicate, six
2.5 parts of sodium metaphosphate, 1.8 parts of tetrapotassium pyrophosphate, 4 parts of titanium dioxide, temperature become 1.5 parts of material, 3.2 parts of thickener, fire retardant 1.6
Part, 2 parts of coalescents, 2.5 parts of anionic additive, 1.6 parts of activated carbon, 28 parts of distilled water.
4. high fire-retardance liquid wallpaper according to claim 1, it is characterised in that the sisal fiber is by following methods system
：By 100 kilograms of sisal leaves, it is added in the sodium hydroxide liquid that 200 kilograms of mass percents are 40%, heating is boiled 30 minutes
Afterwards, pull fibre bundle out, cleaned with clear water, and with mass percent in 2% watery hydrochloric acid and remaining alkali, then, after cleaning
Sisal hemp beam be cut into 5~10 millimeters of chopped fiber, then, chopped fiber is put into water, comb solution of dissociating, as sisal fiber.
5. high fire-retardance liquid wallpaper according to claim 1, it is characterised in that the temperature becomes material and crystallized into microencapsulation
Violet lactone, 25 DEG C of its discoloring temperature.
6. high fire-retardance liquid wallpaper according to claim 1, it is characterised in that the coalescents are selected from propylene glycol phenyl
Ether, alcohol ester-12（2,2,4- trimethyl -1,3- pentanediol mono isobutyrates）In one kind.
7. high fire-retardance liquid wallpaper according to claim 1, it is characterised in that the thickener thickens for polyurethanes
Agent, alkali soluble is swollen any of class thickener, polyethers thickener.
8. a kind of method for preparing any one of the claim 1~7 high fire-retardance liquid wallpaper, it is characterised in that including as follows
Step：
（1）Acrylic emulsion, silicone acrylic emulsion, diatom ooze, sisal fiber, precipitated calcium carbonate, alumina silicate, six are weighed by above-mentioned formula
Sodium metaphosphate, tetrapotassium pyrophosphate, titanium dioxide, temperature become material, thickener, fire retardant, coalescents, anionic additive, activity
Charcoal, distilled water, it is standby；
（2）Temperature is become into material and distilled water is mixed, is placed in reactor, is added calgon and tetrapotassium pyrophosphate, be heated to
50~60 DEG C, stirred 12~17 minutes with 200~300r/min speed, obtain temperature change powder slurry；
（3）To step（2）Obtained temperature, which becomes in slurry, sequentially adds coalescents, precipitated calcium carbonate and alumina silicate, with 300~
500r/min speed insulated and stirred 30~60 minutes, then adds acrylic emulsion and silicone acrylic emulsion, is heated to 70~80 DEG C,
Stirred 10~20 minutes with 1000~1200r/min speed, be cooled to room temperature；
（4）To step（3）Sequentially add sisal fiber, diatom ooze, titanium dioxide and activated carbon in the mixture of gained, stirring 15~
25 minutes, thickener, fire retardant and anionic additive are then added, is vacuumized, stirred 10~20 minutes, produce the high resistant
Burning liquid wallpaper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710644610.9A CN107254229A (en) | 2017-08-01 | 2017-08-01 | A kind of high fire-retardance liquid wallpaper and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710644610.9A CN107254229A (en) | 2017-08-01 | 2017-08-01 | A kind of high fire-retardance liquid wallpaper and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109437817A (en) * | 2019-01-10 | 2019-03-08 | 佛山市山河水家居配套有限公司 | A kind of scrubbable water negative ion diatom ooze formula and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101781485A (en) * | 2010-02-04 | 2010-07-21 | 辽宁胜吉科技发展有限公司 | Production method of fiber grain liquid wallpaper |
| CN102040895A (en) * | 2009-10-15 | 2011-05-04 | 王思力 | Temperature-sensing liquid wall paper |
| CN102199388A (en) * | 2011-03-22 | 2011-09-28 | 广东工业大学 | Water-resistance thermosensitive color-changing liquid wall paper and preparation method thereof |
| CN104530883A (en) * | 2014-12-26 | 2015-04-22 | 青岛佳尚创意文化有限公司 | Environment-friendly odorless latex paint |
| CN106883718A (en) * | 2017-04-06 | 2017-06-23 | 合肥欧克斯新型建材有限公司 | A kind of high fire-retardance liquid wallpaper and preparation method |
-
2017
- 2017-08-01 CN CN201710644610.9A patent/CN107254229A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040895A (en) * | 2009-10-15 | 2011-05-04 | 王思力 | Temperature-sensing liquid wall paper |
| CN101781485A (en) * | 2010-02-04 | 2010-07-21 | 辽宁胜吉科技发展有限公司 | Production method of fiber grain liquid wallpaper |
| CN102199388A (en) * | 2011-03-22 | 2011-09-28 | 广东工业大学 | Water-resistance thermosensitive color-changing liquid wall paper and preparation method thereof |
| CN104530883A (en) * | 2014-12-26 | 2015-04-22 | 青岛佳尚创意文化有限公司 | Environment-friendly odorless latex paint |
| CN106883718A (en) * | 2017-04-06 | 2017-06-23 | 合肥欧克斯新型建材有限公司 | A kind of high fire-retardance liquid wallpaper and preparation method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109437817A (en) * | 2019-01-10 | 2019-03-08 | 佛山市山河水家居配套有限公司 | A kind of scrubbable water negative ion diatom ooze formula and preparation method thereof |
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