CN107254140A - A kind of regeneration wall brick for building and preparation method thereof - Google Patents
A kind of regeneration wall brick for building and preparation method thereof Download PDFInfo
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- CN107254140A CN107254140A CN201710498123.6A CN201710498123A CN107254140A CN 107254140 A CN107254140 A CN 107254140A CN 201710498123 A CN201710498123 A CN 201710498123A CN 107254140 A CN107254140 A CN 107254140A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/16—Ethene-propene or ethene-propene-diene copolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Abstract
The invention discloses a kind of regeneration wall brick for building, include the raw material of following parts by weight：56~74 parts of epoxy resin, 12~18 parts of ethylene propylene diene rubber, 10~18 parts of silica white, 5~10 parts of microcrystalline wax, 20~28 parts of sericite in powder, 2~4 parts of fire retardant, 0.2~0.6 part of vulcanizing agent, 2~4 parts of curing agent, 5~8 parts of foaming agent, 0.6~1 part of nucleating agent, 2~8 parts of colouring agent；Its preparation method includes the preparation of base-material, and silica white and microcrystalline wax and auxiliary agent are mixed into, and the solidification of compound, vulcanization, extrusion and is cooled and shaped.Wall brick anti-wear performance proposed by the present invention is good, and is a kind of high, the safe and environment-friendly renewable construction material of resource utilization with waterproof, heat-resisting and fire resistance, and preparation method is simple, and equipment requirement is low, can be mass produced.
Description
Technical field
The present invention relates to building material technical field, more particularly to a kind of regeneration wall brick for building and preparation method thereof.
Background technology
Wall brick is one of the construction material on basis, and the usage amount in finishing is larger.Such as toilet, kitchen, outdoor sun
The decoration for vertical face of platform.Wall brick be protection metope exempt from water splash, the effective way of greasy dirt.Moreover, for the decoration at skirting
Wall brick, the not only attractive in appearance but also protection wall base is difficult to be made dirty by footwear or table and chair pin；It is not only attractive in appearance but also can be with for the ceramic tile in pond and bathroom
Play a part of water-proof skid-proof.The main material of wall brick of commercial type is in ceramics, and ceramic rigidity is stronger, as wall brick is used
The extension of time, abrasion, cut can be produced on wall brick surface, or even cracking, broken phenomenon occur in use.And
And after second-hand house transaction is carried out, new house-owner would generally remove original decoration, be replaced with new decoration style, at this moment originally
Wall brick will be removed, and fall as garbage disposal.These outcast wall bricks are stacked upon space-consuming, and post processing is again
It is cumbersome.While second-hand house trading volume Continued, the problem of wall brick rubbish is brought is also increasingly severe.
The content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of regeneration wall brick for building proposed
And preparation method thereof.
A kind of regeneration wall brick for building, includes the raw material of following parts by weight：56~74 parts of epoxy resin, ethylene propylene diene rubber
12~18 parts, 10~18 parts of silica white, 5~10 parts of microcrystalline wax, 20~28 parts of sericite in powder, 2~4 parts of fire retardant, vulcanizing agent
0.2~0.6 part, 2~4 parts of curing agent, 5~8 parts of foaming agent, 0.6~1 part of nucleating agent, 2~8 parts of colouring agent.
It is preferred that, a kind of described regeneration wall brick for building includes the raw material of following parts by weight：Epoxy resin 58~70
Part, 14~18 parts of ethylene propylene diene rubber, 12~16 parts of silica white, 6~10 parts of microcrystalline wax, 22~26 parts of sericite in powder is fire-retardant
2~4 parts of agent, 0.2~0.6 part of vulcanizing agent, 2~4 parts of curing agent, 5~8 parts of foaming agent, 0.6~0.8 part of nucleating agent, colouring agent 4
~8 parts.
It is preferred that, a kind of described regeneration wall brick for building includes the raw material of following parts by weight：64 parts of epoxy resin, three
First 16 parts of EP rubbers, 14 parts of silica white, 8 parts of microcrystalline wax, 24 parts of sericite in powder, 3 parts of fire retardant, 0.4 part of vulcanizing agent, solidification
3 parts of agent, 6 parts of foaming agent, 0.7 part of nucleating agent, 6 parts of colouring agent.
It is preferred that, the addition of the ethylene propylene diene rubber is more than the 15% of epoxy resin.
It is preferred that, the granularity of the sericite in powder is the mesh of 45 mesh~300.
It is preferred that, the fire retardant be TDE, eight bromo ether, deca-BDE and, in HBCD
Any one or two kinds.
It is preferred that, the foaming agent is the compounding of azodicarbonamide and phthalic acid, and azodicarbonamide and neighbour
The weight part ratio of phthalic acid is 0.5~2：1~2.
The invention also provides a kind of preparation method of regeneration wall brick for building, comprise the following steps：
S1：Epoxy resin and ethylene propylene diene rubber are added in kneading machine, and the temperature for raising kneading machine makes to 60~80 DEG C
Epoxy resin and ethylene propylene diene rubber mixing are complete, then add into batch mixer the foaming agent of corresponding parts by weight, with 500~
1000r/min speed stirs 5~10min, adds nucleating agent, continues to stir 1~3min, produces base-material；
S2：The silica white and microcrystalline wax of corresponding parts by weight are added into above-mentioned base-material, continues 3~5min of stirring and produces compound
A, fire retardant, colouring agent and sericite in powder are disperseed into compound A, compound B is obtained successively；
S3：Compound B is transferred to fluid bed, while adding vulcanizing agent, in 120~150 DEG C, vulcanizes 90~120min, vulcanization
50~60 DEG C are cooled to after end, the curing agent of corresponding parts by weight is added, 3~10min is reacted, then through screw extruder base
Plinth, cooling and shaping produce regeneration wall brick for building.
Wall brick anti-wear performance proposed by the present invention is good, and is a kind of resource utilization with waterproof, heat-resisting and fire resistance
High, safe and environment-friendly renewable construction material, and preparation method is simple, equipment requirement is low, can be mass produced, should
Wall brick is using epoxy resin and ethylene propylene diene rubber as base-material, with waterproof and heat resistance, and good toughness, it is to avoid glass material is deposited
Fragmentation Phenomena generation, make to produce bubble in wall brick base-material by adding foaming agent and nucleating agent, then in base-material add
Silica white and microcrystalline wax to strengthen the mobility and toughness of base-material, and add auxiliary agent improve base-material fire resistance and color,
Sericite in powder is distributed to improve the anti-wear performance of wall brick in base-material again, finally by solidifying and vulcanizing double action, made
The performance of wall brick is more firm, and the wall brick prepared can be gone back by adhesive with wall strong bonded after dismounting when in use
Can be with recycling, resource utilization is high, environmental protection.
Embodiment
The present invention is made with reference to specific embodiment further to explain.
Embodiment one
A kind of regeneration wall brick for building proposed by the present invention, includes the raw material of following parts by weight：66 parts of epoxy resin, EPDM
16 parts of rubber, 12 parts of silica white, 8 parts of microcrystalline wax, 22 parts of sericite in powder, 3 parts of TDE, 0.4 part of vulcanizing agent, solidification
3 parts of agent, 2 parts of azodicarbonamide, 3 parts of phthalic acid, 0.8 part of nucleating agent, 4 parts of colouring agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin and ethylene propylene diene rubber are added in kneading machine, and the temperature for raising kneading machine makes to 60~80 DEG C
Epoxy resin and ethylene propylene diene rubber mixing are complete, then add into batch mixer the azodicarbonamide and adjacent benzene of corresponding parts by weight
Dioctyl phthalate, 10min is stirred with 500~1000r/min speed, adds nucleating agent, is continued to stir 1~3min, is produced base-material；
S2：The silica white and microcrystalline wax of corresponding parts by weight are added into above-mentioned base-material, continues stirring 5min and produces compound A,
Disperse TDE, colouring agent and sericite in powder successively into compound A, obtain compound B；
S3：Compound B is transferred to fluid bed, while adding vulcanizing agent, in 120 DEG C, vulcanizes 120min, vulcanization cools after terminating
To 50 DEG C, the curing agent of corresponding parts by weight is added, 10min is reacted, then produce and build through screw extruder basis, cooling and shaping
Build with regeneration wall brick.
Embodiment two
A kind of regeneration wall brick for building proposed by the present invention, includes the raw material of following parts by weight：70 parts of epoxy resin, EPDM
14 parts of rubber, 18 parts of silica white, 10 parts of microcrystalline wax, 20 parts of sericite in powder, 3 parts of deca-BDE, 0.6 part of vulcanizing agent, solidification
4 parts of agent, 3 parts of azodicarbonamide, 5 parts of phthalic acid, 0.6 part of nucleating agent, 8 parts of colouring agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin and ethylene propylene diene rubber are added in kneading machine, and the temperature for raising kneading machine makes epoxy to 80 DEG C
Resin and ethylene propylene diene rubber mixing are complete, then add into batch mixer the azodicarbonamide and O-phthalic of corresponding parts by weight
Acid, 8min is stirred with 500r/min speed, adds nucleating agent, is continued to stir 2min, is produced base-material；
S2：The silica white and microcrystalline wax of corresponding parts by weight are added into above-mentioned base-material, continues stirring 5min and produces compound A,
Disperse deca-BDE, colouring agent and sericite in powder successively into compound A, obtain compound B；
S3：Compound B is transferred to fluid bed, while adding vulcanizing agent, in 150 DEG C, vulcanizes 120min, vulcanization cools after terminating
To 60 DEG C, the curing agent of corresponding parts by weight is added, 3min is reacted, then produce and build through screw extruder basis, cooling and shaping
Build with regeneration wall brick.
Embodiment three
A kind of regeneration wall brick for building proposed by the present invention, includes the raw material of following parts by weight：56 parts of epoxy resin, EPDM
12 parts of rubber, 16 parts of silica white, 10 parts of microcrystalline wax, 24 parts of sericite in powder, 3 parts of eight bromo ether, 0.6 part of vulcanizing agent, curing agent 4
Part, 4 parts of azodicarbonamide, 4 parts of phthalic acid, 1 part of nucleating agent, 8 parts of colouring agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin and ethylene propylene diene rubber are added in kneading machine, and the temperature for raising kneading machine makes epoxy to 80 DEG C
Resin and ethylene propylene diene rubber mixing are complete, then add into batch mixer the azodicarbonamide and O-phthalic of corresponding parts by weight
Acid, 5min is stirred with 1000r/min speed, adds nucleating agent, is continued to stir 3min, is produced base-material；
S2：The silica white and microcrystalline wax of corresponding parts by weight are added into above-mentioned base-material, continues stirring 5min and produces compound A,
Disperse eight bromo ether, colouring agent and sericite in powder successively into compound A, obtain compound B；
S3：Compound B is transferred to fluid bed, while adding vulcanizing agent, in 140 DEG C, vulcanizes 120min, vulcanization cools after terminating
To 50 DEG C, the curing agent of corresponding parts by weight is added, 10min is reacted, then produce and build through screw extruder basis, cooling and shaping
Build with regeneration wall brick.
Example IV
A kind of regeneration wall brick for building proposed by the present invention, includes the raw material of following parts by weight：60 parts of epoxy resin, EPDM
15 parts of rubber, 15 parts of silica white, 8 parts of microcrystalline wax, 22 parts of sericite in powder, 3 parts of HBCD, 0.6 part of vulcanizing agent, solidification
4 parts of agent, 3 parts of azodicarbonamide, 4 parts of phthalic acid, 0.8 part of nucleating agent, 4 parts of colouring agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin and ethylene propylene diene rubber are added in kneading machine, and the temperature for raising kneading machine makes epoxy to 70 DEG C
Resin and ethylene propylene diene rubber mixing are complete, then add into batch mixer the azodicarbonamide and O-phthalic of corresponding parts by weight
Acid, 7min is stirred with 800r/min speed, adds nucleating agent, is continued to stir 3min, is produced base-material；
S2：The silica white and microcrystalline wax of corresponding parts by weight are added into above-mentioned base-material, continues stirring 3min and produces compound A,
Disperse HBCD, colouring agent and sericite in powder successively into compound A, obtain compound B；
S3：Compound B is transferred to fluid bed, while adding vulcanizing agent, in 120 DEG C, vulcanizes 120min, vulcanization cools after terminating
To 50 DEG C, the curing agent of corresponding parts by weight is added, 3min is reacted, then produce and build through screw extruder basis, cooling and shaping
Build with regeneration wall brick.
Embodiment five
A kind of regeneration wall brick for building proposed by the present invention, includes the raw material of following parts by weight：66 parts of epoxy resin, EPDM
16 parts of rubber, 16 parts of silica white, 6 parts of microcrystalline wax, 25 parts of sericite in powder, 2 parts of eight bromo ether, deca-BDE, 2 parts, vulcanizing agent
0.4 part, 4 parts of curing agent, azodicarbonamide part 4,4 parts of phthalic acid, 1 part of nucleating agent, 2 parts of colouring agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin and ethylene propylene diene rubber are added in kneading machine, and the temperature for raising kneading machine makes epoxy to 80 DEG C
Resin and ethylene propylene diene rubber mixing are complete, then add into batch mixer the azodicarbonamide and O-phthalic of corresponding parts by weight
Acid, 5min is stirred with 1000r/min speed, adds nucleating agent, is continued to stir 1min, is produced base-material；
S2：The silica white and microcrystalline wax of corresponding parts by weight are added into above-mentioned base-material, continues stirring 3min and produces compound A,
Disperse eight bromo ether, deca-BDE, colouring agent and sericite in powder successively into compound A, obtain compound B；
S3：Compound B is transferred to fluid bed, while adding vulcanizing agent, in 150 DEG C, vulcanizes 90min, vulcanization cools after terminating
To 50 DEG C, the curing agent of corresponding parts by weight is added, 10min is reacted, then produce and build through screw extruder basis, cooling and shaping
Build with regeneration wall brick.
Performance detection is carried out to wall brick prepared by embodiment one~five, testing result is as follows：
Wherein, the condition of heat resistance experiment is：100 DEG C, 24h；Wear-resisting rate computational methods are：Wall brick is rubbed under normal temperature and pressure
Wall brick surface abrasion area accounts for the percentage of total surface area when wiping 200 times.
Test result indicates that, wall brick prepared by embodiment one~five has superior water resistance, heat resistance and anti-wear performance.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (8)
1. a kind of regeneration wall brick for building, it is characterised in that include the raw material of following parts by weight：56~74 parts of epoxy resin, three
First 12~18 parts of EP rubbers, 10~18 parts of silica white, 5~10 parts of microcrystalline wax, 20~28 parts of sericite in powder, fire retardant 2~4
Part, 0.2~0.6 part of vulcanizing agent, 2~4 parts of curing agent, 5~8 parts of foaming agent, 0.6~1 part of nucleating agent, 2~8 parts of colouring agent.
2. a kind of regeneration wall brick for building according to claim 1, it is characterised in that include the raw material of following parts by weight：
58~70 parts of epoxy resin, 14~18 parts of ethylene propylene diene rubber, 12~16 parts of silica white, 6~10 parts of microcrystalline wax, sericite in powder
22~26 parts, 2~4 parts of fire retardant, 0.2~0.6 part of vulcanizing agent, 2~4 parts of curing agent, 5~8 parts of foaming agent, nucleating agent 0.6~
0.8 part, 4~8 parts of colouring agent.
3. a kind of regeneration wall brick for building according to claim 1, it is characterised in that include the raw material of following parts by weight：
64 parts of epoxy resin, 16 parts of ethylene propylene diene rubber, 14 parts of silica white, 8 parts of microcrystalline wax, 24 parts of sericite in powder, 3 parts of fire retardant,
0.4 part of vulcanizing agent, 3 parts of curing agent, 6 parts of foaming agent, 0.7 part of nucleating agent, 6 parts of colouring agent.
4. a kind of regeneration wall brick for building according to claim 1, it is characterised in that the addition of the ethylene propylene diene rubber
Amount is more than the 15% of epoxy resin.
5. a kind of regeneration wall brick for building according to claim 1, it is characterised in that the granularity of the sericite in powder is 45
The mesh of mesh~300.
6. a kind of regeneration wall brick for building according to claim 1, it is characterised in that the fire retardant is decabrominated dipheny second
Alkane, eight bromo ether, deca-BDE and, any one or two kinds in HBCD.
7. a kind of regeneration wall brick for building according to claim 1, it is characterised in that the foaming agent is the formyl of azo two
The compounding of amine and phthalic acid, and the weight part ratio of azodicarbonamide and phthalic acid is 0.5~2：1~2.
8. a kind of preparation method of regeneration wall brick for building, it is characterised in that comprise the following steps：
S1：Epoxy resin and ethylene propylene diene rubber are added in kneading machine, and the temperature for raising kneading machine makes to 60~80 DEG C
Epoxy resin and ethylene propylene diene rubber mixing are complete, then add into batch mixer the foaming agent of corresponding parts by weight, with 500~
1000r/min speed stirs 5~10min, adds nucleating agent, continues to stir 1~3min, produces base-material；
S2：The silica white and microcrystalline wax of corresponding parts by weight are added into above-mentioned base-material, continues 3~5min of stirring and produces compound
A, fire retardant, colouring agent and sericite in powder are disperseed into compound A, compound B is obtained successively；
S3：Compound B is transferred to fluid bed, while adding vulcanizing agent, in 120~150 DEG C, vulcanizes 90~120min, vulcanization
50~60 DEG C are cooled to after end, the curing agent of corresponding parts by weight is added, 3~10min is reacted, then through screw extruder base
Plinth, cooling and shaping produce regeneration wall brick for building.
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| CN201710498123.6A CN107254140A (en) | 2017-06-27 | 2017-06-27 | A kind of regeneration wall brick for building and preparation method thereof |
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| CN201710498123.6A CN107254140A (en) | 2017-06-27 | 2017-06-27 | A kind of regeneration wall brick for building and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108047650A (en) * | 2017-12-12 | 2018-05-18 | 吕玲 | A kind of high-efficiency insulated heat-barrier material for building and preparation method thereof |
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| CN102643481A (en) * | 2012-05-20 | 2012-08-22 | 柳州市海达新型材料科技有限公司 | Polypropylene material for economical automobile decorative apron boards and hold-down strips and preparation method thereof |
| CN102850664A (en) * | 2012-08-31 | 2013-01-02 | 苏州博云塑业有限公司 | Chloroprene rubber thermal-insulation waterproof material |
| CN103740124A (en) * | 2013-12-23 | 2014-04-23 | 苏州宏泉高压电容器有限公司 | Environment-friendly wallboard and preparation method thereof |
| CN105368277A (en) * | 2015-12-04 | 2016-03-02 | 苏州市神龙门窗有限公司 | Corrosion-resistant low-temperature-resistant outdoor building door and window |
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