CN1072403A - Red and blue flashing beads and flashing pieces for fireworks - Google Patents
Red and blue flashing beads and flashing pieces for fireworks Download PDFInfo
- Publication number
- CN1072403A CN1072403A CN 91106849 CN91106849A CN1072403A CN 1072403 A CN1072403 A CN 1072403A CN 91106849 CN91106849 CN 91106849 CN 91106849 A CN91106849 A CN 91106849A CN 1072403 A CN1072403 A CN 1072403A
- Authority
- CN
- China
- Prior art keywords
- red
- blue
- paste
- flashing
- fireworks
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011324 bead Substances 0.000 title claims abstract description 13
- 239000003814 drug Substances 0.000 claims abstract description 17
- 229940079593 drug Drugs 0.000 claims abstract description 8
- 238000005303 weighing Methods 0.000 claims abstract description 8
- 238000005469 granulation Methods 0.000 claims abstract description 7
- 230000003179 granulation Effects 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 3
- 241000695776 Thorichthys aureus Species 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 13
- 210000003205 muscle Anatomy 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
- 239000005864 Sulphur Substances 0.000 claims description 12
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 10
- 229910001051 Magnalium Inorganic materials 0.000 claims description 10
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims description 10
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 10
- 239000004800 polyvinyl chloride Substances 0.000 claims description 10
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims description 10
- 229910052712 strontium Inorganic materials 0.000 claims description 9
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 9
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 9
- 229960004643 cupric oxide Drugs 0.000 claims description 5
- 235000011837 pasties Nutrition 0.000 claims description 5
- 241000233855 Orchidaceae Species 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 9
- 238000001035 drying Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 239000010970 precious metal Substances 0.000 abstract description 3
- 238000005507 spraying Methods 0.000 abstract description 2
- 230000001680 brushing effect Effects 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 4
- 230000005855 radiation Effects 0.000 description 3
- -1 sieve Substances 0.000 description 3
- 159000000008 strontium salts Chemical class 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 241000370738 Chlorion Species 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 101100496858 Mus musculus Colec12 gene Proteins 0.000 description 1
- 241000098700 Sarcocheilichthys parvus Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000012916 chromogenic reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- UFQXGXDIJMBKTC-UHFFFAOYSA-N oxostrontium Chemical compound [Sr]=O UFQXGXDIJMBKTC-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The present invention relates to a red and blue flashing bead and flashing sheet with red and blue flashing effect for fireworks. The method is characterized in that: respectively weighing red glitter and blue glitter medicines for fireworks, sieving and uniformly stirring, adding 1-2% of paste for granulation, controlling the beads to be 8-15 meshes, drying in the sun to obtain red glitter and blue glitter beads or taking the medicines, adding 3-4% of paste, mixing into paste, brushing on strip paper, and drying in the sun to obtain red glitter and blue glitter tablets. The advantages are that: the firework has the red and blue flashing effects, generates a little sound, does not contain rare and precious metals and forbidden materials of fireworks, is safe and non-toxic, has proper cost price, and is suitable for fireworks products with fireworks spraying and high-altitude flashing effects.
Description
The present invention relates to a kind of firework and have red, blue flash effect when burning, producing slightly in luminous, the firework of the sound dodges pearl and flash card with red, orchid.
Though existing firework is colourful, but still can not satisfy human consumer's needs, the flash of light class firework that particularly is loved by the people, only have at present green, white, yellow three kinds, when people see that firework is red, during Lan Liangzhu, just proposed firework naturally with red, blue requirement of dodging pearl and flash card product.According to investigations, it is domestic up till now still blank to send sudden strain of a muscle pearl and flash card red, blue flash of light, does not also have reported in literature in the world.Through Hunan Province's scientific information research institute computer search collection restricted data, 1985～1991 years Chinese patents and relevant periodical and the World Patent Index file351 of U.S. DIALOG system, 350, (1963～1991 years) international online retrieval is not found pertinent literature.
The purpose of this invention is to provide a kind of red, blue flash effect that has, firework blue dodges pearl and flash card with red, and does not contain rare precious metal and fireworks forbidding material, safety non-toxic evil environmentally safe, and cost value is suitable.
To achieve these goals, solution of the present invention is, takes by weighing firework respectively with red, blue flash drug, sieve, mix thoroughly, add the slurry lake granulation of one of dose percentage to 2 percent, the control bead dries at 8～15 orders, red, bluely dodge pearl or get said medicine, add the paste of dose 3 percent to 4 percent, the furnishing pasty state, brush is on paper strip, dry, red, blue flash card.
The pharmaceutical cpd scope (by weight) of this sudden strain of a muscle pearl and flash card is: 1. red sudden strain of a muscle pharmaceutical cpd:
Strontium chloride 10～20%, potassium perchlorate 35～50%, magnalium 15～30%, polyvinyl chloride 5～10%, sulphur 2～8%, JS strontium 20～30%.
2. blue flash drug composition:
Cupric oxide 10～30%, potassium perchlorate 25～40%, magnalium 10～30%, polyvinyl chloride 5～10%, sulphur 5～10%, AF powder 25～35%
Above medicine is the following powder of 100 orders.
Optimum pharmaceutical cpd scope (by weight) is:
1. red sudden strain of a muscle pharmaceutical cpd:
Strontium oxide 10%, potassium perchlorate 35%, magnalium 25%, polyvinyl chloride 5%, sulphur 5%, JS strontium 20%
2. blue flash drug composition:
Cupric oxide 20%, potassium perchlorate 25%, magnalium 20%, polyvinyl chloride 5%, sulphur 5%, AF powder 25%.
This red, blue manufacture method of dodging pearl and flash card:
Take by weighing firework respectively with red, blue flash drug, even by above-mentioned percentage mix, as to sieve, mix thoroughly, add dose 1～2% paste granulation, control bead at 8～15 orders, dry, red, Lan Shanzhu, or take by weighing medicine respectively by above-mentioned per-cent, add the paste of dose 3～4%, the furnishing pasty state, brush is on paper strip, dry, red, blue flash card.
The present invention has following advantage: 1. have red, blue flash effect, produce the sound slightly in luminous, 2. do not contain rare precious metal and fireworks forbidding material, the safety non-toxic evil, environmentally safe, cost value is suitable, 3. is applicable to the firework product of firework spraying decoration class and high-altitude flicker effect.
Embodiment:
1. prepare red sudden strain of a muscle pearl and flash card: get particle less than 100 purpose strontium oxides, 10 grams, potassium perchlorate 35 grams, magnalium 25 grams, polyvinyl chloride 5 grams, sulphur 5 grams, and JS strontium 20 grams mix, 100 orders that sieve are mixed thoroughly, add 2 gram paste granulations, control bead at 8～15 orders, dry, red sudden strain of a muscle pearl, drying in the sun bead and black powder are pressed 4: 6 mixed, fill in the paper web, plug lead-in wire, seal package is red sudden strain of a muscle pearl product, adds paste 4 grams if take by weighing medicine according to the above ratio, the furnishing pasty state, brush dries on paper strip, with black powder 25 grams, fitted tube, plug lead-in wire, seal package is red flash card product.
2. the preparation orchid dodges pearl and flash card: get particle less than 100 purpose cupric oxide, 20 grams, potassium perchlorate 25 grams, magnalium 20 grams, polyvinyl chloride 5 grams, sulphur 5 grams, AF powder 25 grams mix, 100 orders that sieve are mixed thoroughly, add 2 gram paste granulations, control bead at 8～15 orders, dry, Lan Shanzhu, drying in the sun bead and black powder are pressed 4: 6 mixed, fill in the paper web, plug lead-in wire, seal package is the blue pearl product that dodges.If take by weighing medicine according to the above ratio, add paste 4 grams, the furnishing pasty state, brush dries on paper strip, adds black powder 25 grams, and fitted tube is plugged lead-in wire, and seal package is blue flash card product.
3. prepare red, blue dodge pearl and flash card: red, the orchid of preparation dodge pearl and flash card as stated above, mix and place, and fill in the paper web, plug lead-in wire, and seal package is red, blue sudden strain of a muscle pearl or flash card product.
Mechanism of the present invention:
1. red sudden strain of a muscle mechanism: the firework product will produce blushed flame, uses strontium salt more.Strontium salt commonly used has strontium nitrate and Strontium carbonate powder.But the easy moisture absorption of strontium nitrate is of little use.Strontium salt generates strontium oxide (SrO) at high-temp combustion, under the condition that has chlorion to exist, can generate the inferior strontium (SrCl) of oxidation, the former radiation wave band broad, and the highest in 606 nanometers intensity, the latter produces intensive ruddiness bands of a spectrum in 636～688 nanometers.In fact only just constitute the ruddiness agent on the basis of strontium oxide or monochlor(in)ate strontium, wherein the radiation of monochlor(in)ate strontium is much better than.As in flame, there being superfluous free chlorine to exist, make balanced type trend left:
So use chloride compound can improve flame color, in red sudden strain of a muscle, contain a certain amount of active metal powder, when burning in red sudden strain of a muscle pearl (flash card) lining, emit big calorimetric, temperature is sharply raise, according to survey: in the time of 1000 ℃, generate the monochlor(in)ate strontium, produce high light, reach flicker effect.
2. the blue mechanism of dodging: existing blue streak agent generally is to utilize the compound of copper to make the blue look of luminous agent by monochlor(in)ate copper (CuCl) molecular radiation, according to survey: have only flame temperature at 1000～1200 ℃, and when having excess chlorine to exist; The blue coloured light spectrum of monochlor(in)ate copper just can take place in the flame reduction zone preferably, make reaction trend left to:
When adding a certain amount of sulphur in the blue streak agent, can find that the color of flame improves, its former because:
Owing to the generation of monochlor(in)ate copper, increased the concentration of chromogenic reagent, thereby the blue look intensification of flame, on the other hand, sulphur burning itself is blue look flame, also can deepen the blue look of flame.In medicine, contain a certain amount of active metal powder, make it in combustion reactions, form metal oxide and emit a large amount of heat, temperature of charge is improved rapidly, produce high light, reach the effect of flicker.
Claims (2)
1, a kind of firework dodges pearl and flash card with red, orchid.It is characterized in that: take by weighing red, blue flash drug that firework is used respectively, sieve, mix thoroughly, add the paste granulation of dose 1～2%, the control bead is at 8～15 orders, dry, red, Lan Shanzhu, or get said medicine, add the paste of dose 3～4%, the furnishing pasty state, the brush on paper strip, dry, red, blue flash card.
The composition of red sudden strain of a muscle is: strontium oxide 10～20%, potassium perchlorate 35～50%, magnalium 15～30%, polyvinyl chloride 5～10%, sulphur 2～8%, JS strontium 20～30%.
The blue composition that dodges is: cupric oxide 10～30%, potassium perchlorate 25～40%, magnalium 10～30%, polyvinyl chloride 5～10%, sulphur 5～10%, AF powder 25～35%.
2, make red, blue method of dodging pearl and flash card, it is characterized in that:
(1) getting granularity is that following red sudden strain of a muscle medicine (strontium oxide, potassium perchlorate, magnalium, polyvinyl chloride, sulphur, JS strontium) of 100 orders and blue flash drug (cupric oxide, potassium perchlorate, magnalium, polyvinyl chloride, sulphur, AF powder) are even by the described percentage mix of claim 1 respectively, sieve, mix thoroughly, add the paste granulation of dose 1～2%, control bead at 8～15 orders, dry red, Lan Shanzhu.
(2) by the described per-cent of claim 1, take by weighing medicine respectively, add the paste of dose 3～4%, the furnishing pulpous state, brush dries on paper strip, red, blue flash card.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91106849 CN1072403A (en) | 1991-11-18 | 1991-11-18 | Red and blue flashing beads and flashing pieces for fireworks |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91106849 CN1072403A (en) | 1991-11-18 | 1991-11-18 | Red and blue flashing beads and flashing pieces for fireworks |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1072403A true CN1072403A (en) | 1993-05-26 |
Family
ID=4908227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91106849 Pending CN1072403A (en) | 1991-11-18 | 1991-11-18 | Red and blue flashing beads and flashing pieces for fireworks |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1072403A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386558B (en) * | 2008-08-22 | 2012-05-23 | 王贤凤 | Fireworks spraying pyrotechnic compound composition with composite effect |
| CN102506615A (en) * | 2011-11-03 | 2012-06-20 | 雍和平 | Safe color-light firecracker |
| CN110204405A (en) * | 2019-05-10 | 2019-09-06 | 湖南出入境检验检疫局检验检疫技术中心 | A kind of cladding fireworks material, celestial body medicament and its preparation and application |
-
1991
- 1991-11-18 CN CN 91106849 patent/CN1072403A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386558B (en) * | 2008-08-22 | 2012-05-23 | 王贤凤 | Fireworks spraying pyrotechnic compound composition with composite effect |
| CN102506615A (en) * | 2011-11-03 | 2012-06-20 | 雍和平 | Safe color-light firecracker |
| CN110204405A (en) * | 2019-05-10 | 2019-09-06 | 湖南出入境检验检疫局检验检疫技术中心 | A kind of cladding fireworks material, celestial body medicament and its preparation and application |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |