CN107237176B - Novel antiskid flame-retardant material and manufacturing method thereof - Google Patents

Novel antiskid flame-retardant material and manufacturing method thereof Download PDF

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Publication number
CN107237176B
CN107237176B CN201710654785.8A CN201710654785A CN107237176B CN 107237176 B CN107237176 B CN 107237176B CN 201710654785 A CN201710654785 A CN 201710654785A CN 107237176 B CN107237176 B CN 107237176B
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parts
flame
skid
textile fabric
layer
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CN107237176A (en
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屈朝辉
屈志豪
袁小丽
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Chongqing Jin Hao United States Dish Products Co Ltd
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Chongqing Jin Hao United States Dish Products Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/186—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials one of the layers is on one surface of the fibrous web and the other layer is on the other surface of the fibrous web
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D197/00—Coating compositions based on lignin-containing materials
    • C09D197/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/02—Natural macromolecular compounds or derivatives thereof
    • D06N2203/022—Natural rubber
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/106—Roughness, anti-slip, abrasiveness
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/18—Medical, e.g. bandage, prostheses, catheter

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Woven Fabrics (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses a novel anti-skid flame-retardant material which comprises three layers, wherein a surface layer is a novel anti-skid layer, a middle layer is a textile fabric layer, and a bottom layer is a natural rubber layer. The invention also discloses a manufacturing method of the novel anti-skid flame-retardant material. The novel anti-skid flame-retardant material provided by the invention has the advantages of simple manufacturing process, easy raw material, good anti-skid property and good flame retardance, and the manufactured material basically contains environment-friendly substances. The novel anti-skid flame-retardant material is applied to articles for daily use, building articles and automotive interior articles.

Description

novel antiskid flame-retardant material and manufacturing method thereof
Technical Field
the invention relates to the field of textile fabric coating, in particular to a novel anti-skid flame-retardant material and a manufacturing method thereof.
background
in the current textile industry, the traditional printed fabric is mainly used, and the fabric is widely applied because the fabric is low in manufacturing cost, relatively simple to operate and bright in appearance. However, the whole production process of the fabric is full of pollution, which not only has influence on the fabric, but also has quite serious pollution to the land, water source and environment. Meanwhile, in order to fully develop the application range of the textile, other materials are necessary to be combined for integration.
various textile products are continuously appeared in the existing market and are applied to various clothes and the like. The environmental pollution is serious in the finishing stage of spinning, various auxiliaries are used in a large amount in the process of the traditional fabric, the surface of the fabric is improved, but a large amount of pollutants are generated, residues can cause discomfort, allergy and other symptoms to human skin, the active ingredients of a plurality of natural materials are inactivated, the fabric is not ideal for protecting the skin and prolonging the service life of clothes when being worn or used, and the fabric has the problems of flammability and the like.
Disclosure of Invention
The invention aims to provide a novel anti-skid flame-retardant material with environmental protection, flame retardance and skid resistance and a manufacturing method thereof.
In order to solve the problems, the invention adopts the following technical scheme:
The novel anti-skid flame-retardant material comprises three layers, wherein a surface layer is a novel anti-skid layer, a middle layer is a textile fabric layer, and a bottom layer is a natural rubber layer.
The novel anti-skid layer comprises straw, bamboo fiber, a flame retardant, an oxide and an anti-skid agent.
the weight parts of the components are 40-80 parts of straws, 15-30 parts of bamboo fibers, 8-20 parts of flame retardant, 5-12 parts of oxide and 12-18 parts of anti-slip agent.
The straw is one or more of corn straw, wheat straw, rice straw, peanut straw and soybean straw.
The flame retardant is one or more of phenolic resin, polypropylene resin, sodium silicate, calcium nitrate, polystyrene, polyvinyl chloride, polyamide resin and vinyl acetate.
The oxide is one or more of silicon dioxide, zinc oxide, calcium oxide, aluminum oxide, iron oxide, titanium oxide and zirconium oxide.
The anti-slip agent is one or more of anti-slip particles, diatomite and clay.
The preparation method of the novel anti-skid layer comprises the following steps:
a. mixing 40-80 parts of straws, 15-30 parts of bamboo fiber, 8-20 parts of flame retardant and 5-12 parts of oxide in a high-speed mixer for 20-30 min;
b. B, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200-;
c. B, mixing the uniformly mixed powder master batch obtained in the step b with 12-18 parts of the anti-slip agent in a high-speed mixer for 20-30min according to the proportion;
d. and d, placing the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200-.
e. and d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
a manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) Pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) And (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) and (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50-80 ℃;
4) and (3) post-treatment: and (3) washing the textile fabric with hot water of 60-90 ℃, and then drying.
the novel anti-skid flame-retardant material is applied to articles for daily use and medical supplies.
has the following beneficial effects:
the novel anti-skid flame-retardant material disclosed by the invention has good anti-skid and flame-retardant properties, is environment-friendly and has a long service life.
Detailed Description
example 1
the preparation method of the novel anti-skid layer comprises the following steps:
a. mixing 40 parts of corn straws, 15 parts of bamboo fibers, 8 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. b, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. b, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. and c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. And d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
a manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) And (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) and (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) and (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
Example 2
The preparation method of the novel anti-skid layer comprises the following steps:
a. Mixing 80 parts of corn straws, 15 parts of bamboo fibers, 8 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. b, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. B, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. and c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. and d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
A manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) Pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) And (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) and (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) and (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
example 3
the preparation method of the novel anti-skid layer comprises the following steps:
a. Mixing 40 parts of corn straws, 30 parts of bamboo fibers, 8 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. b, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. B, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. And c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. and d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
A manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) Pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) And (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) and (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
example 4
The preparation method of the novel anti-skid layer comprises the following steps:
a. mixing 40 parts of corn straws, 15 parts of bamboo fibers, 20 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. b, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. b, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. and c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. And d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
A manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) And (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) and (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
Example 5
The preparation method of the novel anti-skid layer comprises the following steps:
a. mixing 40 parts of corn straws, 15 parts of bamboo fibers, 8 parts of sodium silicate and 12 parts of silicon dioxide in a high-speed mixer for 30 min;
b. b, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. b, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. and c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. And d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
a manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) And (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) and (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
example 6
the preparation method of the novel anti-skid layer comprises the following steps:
a. mixing 40 parts of corn straws, 15 parts of bamboo fibers, 8 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. B, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. b, mixing the uniformly mixed powder master batch obtained in the step b and 18 parts of anti-skid particles in a high-speed mixer for 30 min;
d. And c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. and d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
a manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) Pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) and (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) and (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
Example 7
the preparation method of the novel anti-skid layer comprises the following steps:
a. mixing 80 parts of corn straws, 30 parts of bamboo fibers, 8 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. B, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. B, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. And c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. And d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
A manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) And (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) and (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) and (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
Example 8
the preparation method of the novel anti-skid layer comprises the following steps:
a. mixing 80 parts of corn straws, 30 parts of bamboo fibers, 20 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. B, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. B, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. And c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. And d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
A manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) and (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) And (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
Example 9
the preparation method of the novel anti-skid layer comprises the following steps:
a. Mixing 80 parts of corn straws, 30 parts of bamboo fibers, 20 parts of sodium silicate and 12 parts of silicon dioxide in a high-speed mixer for 30 min;
b. b, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. b, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. and c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. and d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
a manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) And (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) And (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
example 10
the preparation method of the novel anti-skid layer comprises the following steps:
a. Mixing 80 parts of corn straws, 30 parts of bamboo fibers, 20 parts of sodium silicate and 12 parts of silicon dioxide in a high-speed mixer for 30 min;
b. B, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. b, mixing the uniformly mixed powder master batch obtained in the step b and 18 parts of anti-skid particles in a high-speed mixer for 30 min;
d. And c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. and d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
A manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) Pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) And (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) And (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) And (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
Example 11
the preparation method of the novel anti-skid layer comprises the following steps:
a. mixing 60 parts of corn straws, 20 parts of bamboo fibers, 15 parts of sodium silicate and 8 parts of silicon dioxide in a high-speed mixer for 30 min;
b. b, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. b, mixing the uniformly mixed powder master batch obtained in the step b with 15 parts of anti-skid particles in a high-speed mixer for 30 min;
d. and c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 200 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. And d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
A manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) Pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) and (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) And (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
Example 12
the preparation method of the novel anti-skid layer comprises the following steps:
a. mixing 40 parts of corn straws, 15 parts of bamboo fibers, 8 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. b, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 220 ℃ and the screw rotation speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. B, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. and c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 220 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. and d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
a manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) And (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) and (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
Example 13
the preparation method of the novel anti-skid layer comprises the following steps:
a. Mixing 40 parts of corn straws, 15 parts of bamboo fibers, 8 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. B, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 240 ℃ and the screw rotation speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. b, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. and c, putting the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 240 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties.
e. and d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
a manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) Pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) and (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) And (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
example 14
The preparation method of the novel anti-skid layer comprises the following steps:
a. Mixing 40 parts of corn straws, 15 parts of bamboo fibers, 8 parts of sodium silicate and 5 parts of silicon dioxide in a high-speed mixer for 30 min;
b. B, extruding the uniformly mixed powder obtained in the step a at the extrusion temperature of 260 ℃ and the screw rotating speed of 700 revolutions per minute to obtain uniformly mixed powder master batches;
c. B, mixing the uniformly mixed powder master batch obtained in the step b with 12 parts of anti-skid particles in a high-speed mixer for 30 min;
d. c, placing the uniformly mixed powder obtained in the step c into a double-screw extruder, and extruding and granulating at the temperature of 260 ℃ and the screw rotating speed of 700 revolutions per minute to obtain the material with the antiskid and flame retardant properties;
e. and d, tabletting the antiskid flame-retardant material obtained in the step d on a rolling machine.
a manufacturing method of a novel antiskid flame-retardant material comprises the following steps:
1) Pretreatment: sequentially carrying out desizing, refining, mercerizing and bleaching processes on the textile fabric;
2) and (3) retreatment: steaming, washing and drying the textile fabric subjected to the pretreatment in sequence;
3) And (3) upper die: coating a novel anti-skid layer on one side of the textile fabric, and coating a natural rubber layer on the other side of the textile fabric; the process temperature for coating the novel anti-skid layer and the natural rubber layer is 50 ℃;
4) And (3) post-treatment: and (3) washing the textile fabric with hot water of 60 ℃, and then drying.
the embodiments described above are intended to enable those skilled in the art to make and use the invention. It will be readily apparent to those skilled in the art that various modifications to these embodiments may be made, and the generic principles described herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above embodiments, and those skilled in the art should make improvements and modifications within the scope of the present invention based on the disclosure of the present invention.
Flame retardancy test
The material spread in a plate shape was observed from a flame (flame length: 3 cm) directly contacting the lighter at 2.5cm below the material. The flame is in contact perpendicularly with respect to the block of material.
The evaluation samples were made as follows: the material was compressed by a roller mill to form a plate. From the observation results, flame retardancy was evaluated in the following 4 th order.
A. even if the flame is close to the flame, the flame is in a partially burning state where the flame is in contact with the flame, and further burning is not performed
B. approaching the flame, the flame has several passes on the block surface, and when the flame is taken off, the fire is extinguished
C. when approaching the flame, the flame passes over the block surface, and even if the flame is taken off, the flame can be continuously burnt
D. when approaching flame, the combustion expands
the raw material composition for each example is shown in table 1 below:

Claims (3)

1. a novel anti-skid flame-retardant material is characterized by comprising three layers, wherein the surface layer is a novel anti-skid layer, the middle layer is a textile fabric layer, the bottom layer is a natural rubber layer,
the novel anti-skid layer comprises straws, bamboo fiber, a flame retardant, an oxide and an anti-skid agent,
the weight parts of the components are 40-80 parts of straws, 15-30 parts of bamboo fiber, 8-20 parts of flame retardant, 5-12 parts of oxide and 12-18 parts of anti-slip agent;
the flame retardant is one or more of phenolic resin, polypropylene resin, sodium silicate, calcium nitrate, polystyrene, polyvinyl chloride, polyamide resin and vinyl acetate;
The oxide is one or more of silicon dioxide, zinc oxide, calcium oxide, aluminum oxide, iron oxide, titanium oxide and zirconium oxide;
The anti-slip agent is one or more of anti-slip particles, diatomite and clay.
2. the novel antiskid flame retardant material of claim 1, wherein the straw is one or more of corn straw, wheat straw, rice straw, peanut straw and soybean straw.
3. The use of the novel non-slip flame retardant material of claim 1 in articles for daily use, medical use.
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