CN107236970A - The method for repairing and mending of electrolytic cell sideways furnace wall - Google Patents

The method for repairing and mending of electrolytic cell sideways furnace wall Download PDF

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Publication number
CN107236970A
CN107236970A CN201710398822.3A CN201710398822A CN107236970A CN 107236970 A CN107236970 A CN 107236970A CN 201710398822 A CN201710398822 A CN 201710398822A CN 107236970 A CN107236970 A CN 107236970A
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repairing
furnace wall
repaired
electrolytic cell
anode
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CN201710398822.3A
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CN107236970B (en
Inventor
程仁策
马正清
汤昌廷
李威
王风慧
韩以申
程鸿鹏
周平
李源
徐玉峰
辛涛
王美春
王博
赵俊凤
潘荣凯
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Shandong Nanshan Aluminium Co Ltd
Yantai Nanshan University
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Shandong Nanshan Aluminium Co Ltd
Yantai Nanshan University
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

A kind of method for repairing and mending of electrolytic cell sideways furnace wall, is related to electrolytic cell service technique field, and the method for repairing and mending is that electrolyte first is adjusted into 15~16cm, by the negative electrode that lower section is dropped down onto under the corresponding anode of sideways furnace wall to be repaired;Materials block presses big face, and the pot shell of aluminium water and sideways furnace wall is separated;Silica brick remaining on sideways furnace wall is cleared up, and model is made with aluminium sheet, the gap of position to be repaired is surrounded together with being formed between pot shell in the shell surface of crust layer;Made firm by ramming with to be repaired position of the carbon paste in gap, until by position to be repaired make firm by ramming to other silica brick same level positions;Finally lift anode.This method repair efficiency is good, will not produce gap, and need not take out aluminium water, and the normal operation of electrolytic cell is not influenceed.

Description

The method for repairing and mending of electrolytic cell sideways furnace wall
Technical field
The present invention relates to electrolytic cell service technique field, and more particularly to a kind of method for repairing and mending of electrolytic cell sideways furnace wall.
Background technology
In the past, electrolytic cell local damage or runout do not have any remedial measure, but carry out unplanned property overhaul in advance, This mode has the following disadvantages:Average groove age can substantially be shortened;Increase ton aluminium cost.Later, in order to avoid unnecessary big Repair the influence brought to electrolytic cell, aluminium electroloysis industry is initially formed various carries out light maintenance to electrolytic cell local damage or other problemses Method, but all do not form more specification, reliable technology, the effect of repairing is also not obvious enough.
Wherein, the phenomenon lifted on silica brick occurs in production early stage for partial electrolyte groove, due to no side in being produced in the later stage The protection of portion silica brick, when the consumption of local stove side is thinning, sidepiece pot shell rod iron is stable to be risen, can there is a possibility that it is breakdown, because The local light maintenance of this sideways furnace wall is necessary.Currently the local minor repair method of counter-lateral quadrents stove side is:First, it is determined that needing repairing Position, and materials block presses big face;Secondly, sidepiece is cleaned out;Then, the position for needing to repair is repaired with silica brick, in repairing Before, if aluminium water is too high, in addition it is also necessary to first extract aluminium water out a part.The shortcoming that this method is present is as follows:
When the 1st, pressing big face, material block can enter anode bottom, be likely to result in the long bag of anode;When the 2nd, being repaired with silica brick counter-lateral quadrents, Gap occurs in the side seam of sideways furnace wall and bottom, and when sideways furnace wall consumes thinning, aluminium water can be entered among gap, and then is made Heat emission hole temperature is raised again, influences the stationarity of electrolytic cell;3rd, aluminium water is taken out if desired, then can influence the normal fortune of electrolytic cell OK.
The content of the invention
It is an object of the invention to provide a kind of method for repairing and mending of electrolytic cell sideways furnace wall, the method repair efficiency is good, no Gap can be produced, and aluminium water need not be taken out, the normal operation of electrolytic cell is not influenceed.
The present invention is solved its technical problem and realized using following technical scheme.
The present invention proposes a kind of method for repairing and mending of electrolytic cell sideways furnace wall, and it comprises the following steps:
Electrolyte is adjusted to 15~16cm, the negative electrode of lower section will be dropped down onto under the corresponding anode of sideways furnace wall to be repaired On;
Materials block presses big face, and the pot shell of aluminium water and sideways furnace wall is separated;
Silica brick remaining on sideways furnace wall is cleared up, and model is made with aluminium sheet, is formed between the shell surface and pot shell of crust layer The gap of position to be repaired is surrounded together;
Made firm by ramming with to be repaired position of the carbon paste in gap, until by position to be repaired make firm by ramming to the same water of other silica bricks Prosposition is put;
Lift anode.
Further, in present pre-ferred embodiments, before the anode of whereabouts, anode fixture is opened, with insulation board by sun Pole guide rod and bus are separated, and are lifted after anode, close anode fixture, take out insulation board.
Further, in present pre-ferred embodiments, repairing the specific method of position to be repaired is:With 65~70 DEG C Carbon paste is made firm by ramming in position to be repaired, is often made the carbon paste layer to form a 1.5~3cm of thickness firm by ramming, is spread coal tar on carbon paste layer, then smash Gu next layer of carbon paste layer, until by position to be repaired make firm by ramming to other silica brick same level positions.
Further, in present pre-ferred embodiments, sidepiece silica brick includes pot shell and the silica brick layer in pot shell, treats Repair position and be located at silica brick layer.
Further, in present pre-ferred embodiments, the width in gap is identical with the thickness of silica brick layer, be 10~ 15cm。
Further, in present pre-ferred embodiments, the method for model is made of aluminium sheet is:Aluminium sheet is inserted into crust layer Between shell surface and silica brick layer, and laminating silica brick layer, gap is formed between aluminium sheet and pot shell.
Further, in present pre-ferred embodiments, position to be repaired is completed after repairing, pressure is welded on silica brick layer Plate.
Further, in present pre-ferred embodiments, anode is lifted to initial position, with rake by the bottom of anode The palm strikes off.
Further, in present pre-ferred embodiments, dry completing the repairing position after repairing.
Further, in present pre-ferred embodiments, obtained after material block crust layer is broken.
The beneficial effect of the method for repairing and mending of the electrolytic cell sideways furnace wall of the embodiment of the present invention is:The method for repairing and mending is first by electricity Solution matter is adjusted to 15~16cm, by the negative electrode that lower section is dropped down onto under the corresponding anode of sideways furnace wall to be repaired;Materials block pressure is big Face, the pot shell of aluminium water and sideways furnace wall is separated;Silica brick remaining on sideways furnace wall is cleared up, and model is made with aluminium sheet, in crust The shell surface of layer surrounds the gap of position to be repaired together with being formed between pot shell;Smash with to be repaired position of the carbon paste in gap Gu, until by position to be repaired make firm by ramming to other silica brick same level positions;Finally lift anode.This method repair efficiency It is good, gap will not be produced, and aluminium water need not be taken out, the normal operation of electrolytic cell is not influenceed.
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, below will be attached to what is used required in embodiment Figure is briefly described, it will be appreciated that the following drawings illustrate only certain embodiments of the present invention, therefore is not construed as pair The restriction of scope, for those of ordinary skill in the art, on the premise of not paying creative work, can also be according to this A little accompanying drawings obtain other related accompanying drawings.
Fig. 1 is structural representation of the electrolytic cell before repairing in the embodiment of the present invention;
Fig. 2 is structural representation of the electrolytic cell when repairing sideways furnace wall in the embodiment of the present invention;
Fig. 3 is structural representation of the electrolytic cell when repairing another stage of sideways furnace wall in the embodiment of the present invention;
Fig. 4 completes the structural representation after repairing for electrolytic cell in the embodiment of the present invention.
Icon:110- negative electrodes;120- aluminium water;130- electrolyte;140- anodes;141- anode rods;142- buses;150- Heat-insulation layer;160- crust layers;170- sideways furnace walls;171- silica bricks layer;172- pot shells;181- insulation boards;182- aluminium sheets;183- expects Block.
Embodiment
, below will be in the embodiment of the present invention to make the purpose, technical scheme and advantage of the embodiment of the present invention clearer Technical scheme be clearly and completely described.Unreceipted actual conditions person, builds according to normal condition or manufacturer in embodiment The condition of view is carried out.Agents useful for same or the unreceipted production firm person of instrument, are the conventional production that can be obtained by commercially available purchase Product.
The method for repairing and mending of the electrolytic cell sideways furnace wall of the embodiment of the present invention is specifically described below.
Shown in Figure 1, the concrete structure of electrolytic cell is:Electrolytic cell includes being located at positioned at the pot shell 172 of sidepiece and laminating Silica brick layer 171 in pot shell 172, pot shell 172 and silica brick layer 171 collectively constitute sideways furnace wall 170, and electrolytic cell also includes being located at groove It is interior, and negative electrode 110, aluminium water 120 and the electrolyte 130 being sequentially arranged from the bottom to top, electrolytic cell is also including partly stretching into electrolyte Anode 140 in 130, anode 140 is connected with the anode rod 141 stretched out outside groove, and the top of anode rod 141 is provided with bus 142, crust layer 160 is formed between anode 140 and sideways furnace wall 170, crust layer 160 is generally aluminum oxide, the top of anode 140 Surrounding is covered with heat-insulation layer 150.
In actual production, the damaged part of sideways furnace wall 170 is typically all in silica brick layer 171, therefore, sideways furnace wall 170 position to be repaired is located at silica brick layer 171.
The embodiment of the present invention provides a kind of method for repairing and mending of electrolytic cell sideways furnace wall, and the method for repairing and mending is to said structure Electrolytic cell it is effective, the method for repairing and mending comprises the following steps:
It is S1, shown in Figure 2, electrolyte 130 is adjusted to 15~16cm, typically first anode fixture is opened, with insulation Plate 181 separates anode rod 141 and bus 142, prevents electricity, then by the corresponding anode 140 of sideways furnace wall 170 to be repaired Under drop down onto on the negative electrode 110 of lower section, before whereabouts anode 140, can take out the heat-insulation layer 150 of the top surrounding of anode 140 is broken.
S2, materials block 183 press big face, and the pot shell 172 of aluminium water 120 and the sideways furnace wall 170 is separated, institute's materials block 183 Crust layer 160 is broken to be obtained, and realizes refuse reclamation.
S3, shown in Figure 3, remaining silica brick on cleaning sideways furnace wall 170, that is, silica brick layer 171, by cover to be repaired Put and clean out, be convenient for follow-up patch work;Model is made with aluminium sheet 182, in the shell surface and pot shell 172 of crust layer 160 Between form the gap for surrounding position to be repaired together.
Because position to be repaired is located at silica brick layer 171, therefore, model is set up i.e. around silica brick layer 171 with aluminium sheet 182 Can.The method for making model with aluminium sheet 182 is:Aluminium sheet 182 is inserted between the shell surface of crust layer 160 and silica brick layer 171, and laminating Silica brick layer 171, gap is formed between aluminium sheet 182 and pot shell 172;The width in the gap of formation is identical with the thickness of silica brick layer 171, It is 10~15cm.
S4, made firm by ramming with to be repaired position of the carbon paste in gap, until position to be repaired is made firm by ramming to same with other silica bricks One horizontal level, is completed after repairing, and pressing plate is welded on new silica brick layer 171, can also be blown completing the repairing position after repairing Wind, to accelerate the formation of new sideways furnace wall 170.
Repairing the specific method of position to be repaired is:Made firm by ramming with 65~70 DEG C of carbon pastes in position to be repaired, often make shape firm by ramming Into the carbon paste layer of a 1.5~3cm of thickness, coal tar is spread on carbon paste layer, then makes next layer of carbon paste layer firm by ramming, until by cover to be repaired Put make firm by ramming to other silica brick same level positions.
It is S5, shown in Figure 4, lift after anode 140 to initial position, struck off the bottom of anode 140 with rake, in sun The top surrounding sprinkling alumina powder of pole 140, forms heat-insulation layer 150, accordingly, closes anode fixture, take out insulation board 181, should Anode 140 can normal power-up use.
In the method for repairing and mending of the electrolytic cell sideways furnace wall of the embodiment of the present invention:Using the to be repaired of carbon paste counter-lateral quadrents stove side 170 Cover, which is put, to be repaired, and carbon paste after making firm by ramming layer is through oversintering, hardness rise, and silica brick with surrounding, pot shell 172 is seamless, warp Cross stop plow stove find carbon paste layer sintering it is blocking, without crackle, illustrate that repair efficiency is good.Sideways furnace wall 170 after repairing Temperature can effectively reduce, and the duration is long, by it was verified that the sideways furnace wall 170 after repairing can at least be maintained 1 year Service life.
The method for repairing and mending of the embodiment of the present invention can also farthest reduce the influence to electrolytic cell, during repairing, without taking out Aluminium water 120, it is only necessary to suspend the corresponding energization work of anode 140 in position to be repaired, other anodes 140 in electrolytic cell are not influenceed After the completion of normal work, and repairing, the anode 140 can recover normal power-up work.
The feature and performance to the present invention are described in further detail with reference to embodiments.
Embodiment 1
Shown in Figure 1, the present embodiment provides a kind of method for repairing and mending of electrolytic cell sideways furnace wall, and it comprises the following steps:
S101, electrolyte 130 is adjusted to 15cm, first opens anode fixture, with insulation board 181 by anode rod 141 Separate, taken out the heat-insulation layer 150 of the top surrounding of anode 140 is broken with bus 142, then by sideways furnace wall 170 to be repaired On the negative electrode 110 that lower section is dropped down onto under corresponding anode 140.
S102, materials block 183 press big face, and the crust layer 160 of institute's materials block 183 is broken to be obtained, by aluminium water 120 and the side The pot shell 172 of stove side of portion 170 is separated.
Remaining silica brick on S103, cleaning silica brick layer 171, aluminium sheet 182 is inserted the shell surface and silica brick layer of crust layer 160 Between 171, and laminating silica brick layer 171, gap, width and the silica brick layer in the gap of formation are formed between aluminium sheet 182 and pot shell 172 171 thickness is identical, is 12cm.
S104, made firm by ramming in position to be repaired with 65 DEG C of carbon pastes, the carbon paste layer to form a thickness 2cm is often made firm by ramming, in carbon paste Spread coal tar on layer, then make next layer of carbon paste layer firm by ramming, until by position to be repaired make firm by ramming to other silica brick same level positions, Complete after repairing, pressing plate is welded on new silica brick layer 171, dry completing the repairing position after repairing, to accelerate new sidepiece The formation of stove side 170.
S105, lift after anode 140 to initial position, struck off the bottom of anode 140 with rake, at the top of anode 140 Surrounding sprays alumina powder, forms heat-insulation layer 150, closes anode fixture, takes out insulation board 181, and the anode 140 can just normal open Electricity is used.
Embodiment 2
Shown in Figure 1, the present embodiment provides a kind of method for repairing and mending of electrolytic cell sideways furnace wall, and it comprises the following steps:
S201, electrolyte 130 is adjusted to 16cm, first opens anode fixture, with insulation board 181 by anode rod 141 Separate, taken out the heat-insulation layer 150 of the top surrounding of anode 140 is broken with bus 142, then by sideways furnace wall 170 to be repaired On the negative electrode 110 that lower section is dropped down onto under corresponding anode 140.
S202, materials block 183 press big face, and the crust layer 160 of institute's materials block 183 is broken to be obtained, by aluminium water 120 and the side The pot shell 172 of stove side of portion 170 is separated.
Remaining silica brick on S203, cleaning silica brick layer 171, aluminium sheet 182 is inserted the shell surface and silica brick layer of crust layer 160 Between 171, and laminating silica brick layer 171, gap, width and the silica brick layer in the gap of formation are formed between aluminium sheet 182 and pot shell 172 171 thickness is identical, is 15cm.
S204, made firm by ramming in position to be repaired with 68 DEG C of carbon pastes, the carbon paste layer to form a thickness 1.5cm is often made firm by ramming, in carbon Spread coal tar in paste layer, then make next layer of carbon paste layer firm by ramming, until by position to be repaired make firm by ramming to other silica brick same level positions Put, complete after repairing, pressing plate is welded on new silica brick layer 171, dry completing the repairing position after repairing, to accelerate new side The formation of stove side of portion 170.
S205, lift after anode 140 to initial position, struck off the bottom of anode 140 with rake, at the top of anode 140 Surrounding sprays alumina powder, forms heat-insulation layer 150, closes anode fixture, takes out insulation board 181, and the anode 140 can just normal open Electricity is used.
Embodiment 3
Shown in Figure 1, the present embodiment provides a kind of method for repairing and mending of electrolytic cell sideways furnace wall, and it comprises the following steps:
S301, electrolyte 130 is adjusted to 15.5cm, first opens anode fixture, with insulation board 181 by anode rod 141 and bus 142 separate, take out the heat-insulation layer 150 of the top surrounding of anode 140 is broken, then by sideways furnace wall to be repaired On the negative electrode 110 that lower section is dropped down onto under 170 corresponding anodes 140.
S302, materials block 183 press big face, and the crust layer 160 of institute's materials block 183 is broken to be obtained, by aluminium water 120 and the side The pot shell 172 of stove side of portion 170 is separated.
Remaining silica brick on S303, cleaning silica brick layer 171, aluminium sheet 182 is inserted the shell surface and silica brick layer of crust layer 160 Between 171, and laminating silica brick layer 171, gap, width and the silica brick layer in the gap of formation are formed between aluminium sheet 182 and pot shell 172 171 thickness is identical, is 10cm.
S304, made firm by ramming in position to be repaired with 70 DEG C of carbon pastes, the carbon paste layer to form a thickness 3cm is often made firm by ramming, in carbon paste Spread coal tar on layer, then make next layer of carbon paste layer firm by ramming, until by position to be repaired make firm by ramming to other silica brick same level positions, Complete after repairing, pressing plate is welded on new silica brick layer 171, dry completing the repairing position after repairing, to accelerate new sidepiece The formation of stove side 170.
S305, lift after anode 140 to initial position, struck off the bottom of anode 140 with rake, at the top of anode 140 Surrounding sprays alumina powder, forms heat-insulation layer 150, closes anode fixture, takes out insulation board 181, and the anode 140 can just normal open Electricity is used.
Embodiment 4
Shown in Figure 1, the present embodiment provides a kind of method for repairing and mending of electrolytic cell sideways furnace wall, and it comprises the following steps:
S401, electrolyte 130 is adjusted to 16cm, first opens anode fixture, with insulation board 181 by anode rod 141 Separated with bus 142, then by the negative electrode 110 that lower section is dropped down onto under the corresponding anode 140 of sideways furnace wall 170 to be repaired.
S402, materials block 183 press big face, and the pot shell 172 of aluminium water 120 and the sideways furnace wall 170 is separated.
Remaining silica brick, model is made with aluminium sheet 182 on S403, cleaning silica brick layer 171, in the shell surface and groove of crust layer 160 The gap for surrounding position to be repaired together is formed between shell 172, the width in the gap of formation is identical with the thickness of silica brick layer 171, It is 13cm.
S404, made firm by ramming in position to be repaired with 68 DEG C of carbon pastes, until position to be repaired is made firm by ramming to same with other silica bricks One horizontal level, is completed after repairing, and pressing plate is welded on new silica brick layer 171.
S405, lift after anode 140 to initial position, in the top surrounding sprinkling alumina powder of anode 140, form heat-insulation layer 150, close anode fixture, take out insulation board 181, the anode 140 can normal power-up use.
First, the electrolytic cell after respectively repairing embodiment 1 and embodiment 2 stops plow stove, finds:In embodiment 1 and implementation The repairing position on electrolytic cell sideways furnace wall in example 2, the carbon paste layer sintering of repairing is blocking, and silica brick, pot shell with surrounding 172 is seamless, without crackle, illustrates that repair efficiency is good.
2nd, the electrolytic tank electrolysis production aluminium after persistently being repaired using embodiment 3 and embodiment 4, by it was verified that repairing Sideways furnace wall 170 afterwards can at least maintain the service life of 1 year.
In summary, the repair efficiency of the method for repairing and mending of the electrolytic cell sideways furnace wall of the embodiment of the present invention is good, will not produce Gap, and aluminium water need not be taken out, the normal operation of electrolytic cell is not influenceed.
Embodiments described above is a part of embodiment of the invention, rather than whole embodiments.The reality of the present invention The detailed description for applying example is not intended to limit the scope of claimed invention, but is merely representative of the selected implementation of the present invention Example.Based on the embodiment in the present invention, what those of ordinary skill in the art were obtained under the premise of creative work is not made Every other embodiment, belongs to the scope of protection of the invention.

Claims (10)

1. a kind of method for repairing and mending of electrolytic cell sideways furnace wall, it is characterised in that it comprises the following steps:
Electrolyte is adjusted to 15~16cm, by the negative electrode that lower section is dropped down onto under the corresponding anode of sideways furnace wall to be repaired;
Materials block presses big face, and the pot shell of aluminium water and the sideways furnace wall is separated;
Silica brick remaining on the sideways furnace wall is cleared up, and model is made with aluminium sheet, between the shell surface and the pot shell of crust layer Form the gap for surrounding position to be repaired together;
Made firm by ramming with to be repaired position of the carbon paste in the gap, until by position to be repaired make firm by ramming to the same water of other silica bricks Prosposition is put;
Lift anode.
2. the method for repairing and mending of electrolytic cell sideways furnace wall according to claim 1, it is characterised in that before the anode that falls, Anode fixture is opened, anode rod and bus is separated with insulation board, lifted after the anode, the anode fixture is closed, Take out the insulation board.
3. the method for repairing and mending of electrolytic cell sideways furnace wall according to claim 1, it is characterised in that repairing position to be repaired Specific method is:Made firm by ramming with 65~70 DEG C of carbon pastes in the position to be repaired, often make the carbon to form a 1.5~3cm of thickness firm by ramming Paste layer, coal tar is spread on carbon paste layer, then makes next layer of carbon paste layer firm by ramming, until by position to be repaired make firm by ramming to other silicon Brick same level position.
4. the method for repairing and mending of electrolytic cell sideways furnace wall according to claim 1, it is characterised in that the sidepiece silica brick includes Pot shell and the silica brick layer in the pot shell, the position to be repaired is located at silica brick layer.
5. the method for repairing and mending of electrolytic cell sideways furnace wall according to claim 4, it is characterised in that the width in the gap with The thickness of the silica brick layer is identical, is 10~15cm.
6. the method for repairing and mending of electrolytic cell sideways furnace wall according to claim 4, it is characterised in that the side of model is made of aluminium sheet Method is:Aluminium sheet is inserted between the shell surface of crust layer and silica brick layer, and silica brick layer of fitting, the aluminium sheet and the pot shell it Between form the gap.
7. the method for repairing and mending of electrolytic cell sideways furnace wall according to claim 4, it is characterised in that complete position to be repaired After repairing, pressing plate is welded on silica brick layer.
8. the method for repairing and mending of electrolytic cell sideways furnace wall according to claim 1, it is characterised in that lift anode to initial Behind position, the bottom of the anode is struck off with rake.
9. the method for repairing and mending of electrolytic cell sideways furnace wall according to claim 1, it is characterised in that to completing repairing after repairing Cover puts blowing.
10. the method for repairing and mending of electrolytic cell sideways furnace wall according to claim 1, it is characterised in that the material block is crust Obtained after layer is broken.
CN201710398822.3A 2017-05-31 2017-05-31 The method for repairing and mending of electrolytic cell sideways furnace wall Active CN107236970B (en)

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