CN107236243A - Speculum and preparation method thereof - Google Patents
Speculum and preparation method thereof Download PDFInfo
- Publication number
- CN107236243A CN107236243A CN201710608990.0A CN201710608990A CN107236243A CN 107236243 A CN107236243 A CN 107236243A CN 201710608990 A CN201710608990 A CN 201710608990A CN 107236243 A CN107236243 A CN 107236243A
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- speculum
- acrylonitrile
- plastic grain
- preparation
- butadiene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/132—Phenols containing keto groups, e.g. benzophenones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
Abstract
The invention belongs to photothermal technique field, and in particular to a kind of speculum and preparation method thereof, a kind of speculum, and it includes waste or used plastics, and above-mentioned raw materials are obtained speculum by activator, antiager, light stabilizer, crosslinking agent by hybrid reaction.The present invention is used using regenerated plastics as raw material, the speculum being prepared from, and the production cost of speculum is substantially increased the plasticity of speculum by it, and again plastics can be made to be used for a long time under solar irradiation.The preparation method for the speculum that the present invention is provided, its is environment friendly and pollution-free, simple to operation.
Description
Technical field
The invention belongs to photothermal technique field, and in particular to a kind of speculum and preparation method thereof.
Background technology
Using regenerative resource be people come the embodiment of social development in science and technology, meet the theory of national sustainable development.The sun
Can be that technology is more ripe in current clean energy resource field, most one of novel renewable energy of large-scale development prospect.Closely
Nian Lai, application of solar energy has caused the extensive concern of various countries research staff, and major New Energy Corporation are increased to the sun
The dynamics of investment in energy field, every rapid technological improvement of field of solar energy.At present, the commercialization of widest field of solar energy
Using being photovoltaic generation, but it has a variety of deficiencies, and photovoltaic solar panel energy transformation ratio is low, cost and Final pollution all compared with
Height, does not possess Peak Load Adjustment, is influenceed larger by weather.
Thus, it is rapid that comparison is developed in Solar use photo-thermal power generation direction.Photo-thermal power generation has a Peak Load Adjustment, but cost
High, especially solar thermal collector reflective mirror uses glass material, due to the design of arc, makes reflective mirror cost
It is higher.
Existing conventional plastic recovery process and reclaimer technology content be not high, is only used for part low-end product, such as again
Raw modeling plank.In addition, reflective mirror is used in solar energy optical-thermal field, the requirement to weatherability and ageing resistace is higher.
In order to solve the above problems, the invention provides a kind of speculum and preparation method thereof, by traditional regenerated plastics
As raw material after being modified, the speculum being prepared from not only reduces cost, and causes speculum in solar irradiation
Under can use for a long time.
The content of the invention
In order to solve the above problems, it is an advantage of the invention to provide a kind of speculum, it will be traditional renewable
Plastics be modified after as raw material, reduce the production cost of speculum.
A further object of the present invention is that, there is provided a kind of speculum, it is applied in solar energy optical-thermal field, is greatly carried
The high plasticity of eyeglass.
The present invention's has a purpose to be there is provided a kind of speculum, and its plastics made is under solar irradiation, when can be long
Between use.
It is still another object of the present invention to provide a kind of preparation method of speculum, for preparing speculum, its technique
It is simple to operation, it is environmentally friendly.
In order to realize that there is provided a kind of speculum, including following components in percentage by weight according to object of the present invention：
Acrylonitrile-butadiene-styrene copolymer 82~95%, activator 2~10%, antiager 0.5~3%, light
Stabilizer 0.5~3%, crosslinking agent 0.5~3%.
Preferably, wherein, including following components in percentage by weight：
Acrylonitrile-butadiene-styrene copolymer 88~93%, activator 4~9%, antiager 0.5~1.5%, light
Stabilizer 0.5~1.5%, crosslinking agent 0.5~1.5%.
Preferably, wherein, including following components in percentage by weight：
Acrylonitrile-butadiene-styrene copolymer 91%, activator 6%, antiager 1%, light stabilizer 1%, crosslinking
Agent 1%.
Present invention also offers a kind of preparation method of speculum, comprise the following steps：
Step 1: collecting the waste or used plastics of acrylonitrile-butadiene-styrene copolymer, after pretreatment, propylene is obtained
The plastic grain of nitrile-BS；
Step 2: according to percentage by weights, plastic grain, activator, crosslinking agent being mixed after crosslinking, plasticizing is added
Agent, antiager, light stabilizer hybrid reaction, obtain regenerated plastics；
Step 3: the regenerated plastics are prepared into particle, screening obtains the recycled plastic granules of 60~80 mesh；
It is molded Step 4: the recycled plastic granules are added in injection machine, obtains speculum.
Preferably, wherein, in the step one, after pretreatment, obtain acrylonitrile-butadiene-styrene (ABS) be total to
The plastic grain of polymers is comprised the following steps that：
The waste or used plastics for the acrylonitrile-butadiene-styrene copolymer collected are cleaned with water, after being crushed by pulverizer,
Screening obtains the particle of 60~80 mesh；
By the particle of 60~80 mesh, 10~20min is dried in temperature is 100 DEG C of dryer, dry plastics are obtained
Particle；
Dry plastic grain is cooled to after room temperature, 30~40min of tumbling in vacuum tumbler obtains the modeling of removal of impurities
Expect particle；
The plastic grain of removal of impurities is cleaned again with water, in temperature is 100 DEG C of dryer drying 10~
20min, obtains the plastic grain of secondary removal of impurities；
The plastic grain of secondary removal of impurities is crushed again, screen 100~120 mesh particle, obtain acrylonitrile-butadiene-
The plastic grain of styrol copolymer.
Preferably, wherein, the activator is consisted of the following components in percentage by weight：
Silane coupler 4%, antistatic additive 1%, lubricant 1%.
Preferably, wherein, the crosslinking agent be GDMA.
Preferably, wherein, the plasticiser be ditridecyl phthalate, o-phthalic acid dibutyl ester, phthalic acid
One or more in dibutyl ester.
Preferably, wherein, the antiager is the mixture of bisphenol-A and triphenyl phosphite.
Preferably, wherein, the light stabilizer is the one or two kinds of of benzophenone and benzotriazole.
Beneficial effects of the present invention：
1st, the speculum that provides of the present invention, its traditional recyclable plastic is modified after as raw material, reduce anti-
Penetrate the production cost of mirror.
2nd, the speculum that the present invention is provided, it is applied in solar energy optical-thermal field, substantially increases the plasticity of eyeglass.
3rd, the speculum that the present invention is provided, it causes plastics under solar irradiation, can use for a long time.
4th, the speculum that the present invention is provided, it uses modified plastics as raw material, reduces later stage offal treatment
Pollution.
5th, the preparation method for the speculum that the present invention is provided, it is used to prepare speculum, and technique is simple to operation, Neng Goushi
The standardization that existing speculum makes, and it is environmentally friendly.
Brief description of the drawings
Fig. 1 is the process chart of the preparation method for the speculum that the present invention is provided；
Fig. 2 is the work of the pretreatment for the plastic grain for obtaining acrylonitrile-butadiene-styrene copolymer that the present invention is provided
Skill flow chart.
Embodiment
The present invention is described in further detail below in conjunction with the accompanying drawings, to make those skilled in the art with reference to specification text
Word can be implemented according to this.
It should be appreciated that such as " having ", "comprising" and " comprising " term used herein are not precluded from one or many
The presence or addition of individual other combinations.
The english abbreviation of the acrylonitrile-butadiene-styrene copolymer referred in the present invention is ABS.
Embodiment 1
The present invention provides a kind of speculum, including following components in percentage by weight：
Acrylonitrile-butadiene-styrene copolymer 82%, activator 9%, antiager 3%, light stabilizer 3%, crosslinking
Agent 3%.
Embodiment 2
The present invention provides a kind of speculum, including following components in percentage by weight：
Acrylonitrile-butadiene-styrene copolymer 85%, activator 10%, antiager 1.5%, light stabilizer
1.5%, crosslinking agent 2%.
Embodiment 3
The present invention provides a kind of speculum, including following components in percentage by weight：
Acrylonitrile-butadiene-styrene copolymer 88%, activator 4%, antiager 2.5%, light stabilizer 3% is handed over
Join agent 2.5%.
Embodiment 4
The present invention provides a kind of speculum, includes the component of hundred parts of ratios of following weight：
Acrylonitrile-butadiene-styrene copolymer 91%, activator 6%, antiager 1%, light stabilizer 1%, crosslinking
Agent 1%.
Embodiment 5
The present invention provides a kind of speculum, includes the component of hundred parts of ratios of following weight：
Acrylonitrile-butadiene-styrene copolymer 93%, activator 2%, antiager 1.5%, light stabilizer 2% is handed over
Join agent 1.5%.
Embodiment 6
The present invention provides a kind of speculum, includes the component of hundred parts of ratios of following weight：
Acrylonitrile-butadiene-styrene copolymer 95%, activator 3.5%, antiager 0.5%, light stabilizer
0.5%, crosslinking agent 0.5%.
Embodiment 7
The invention provides a kind of preparation method for the speculum into embodiment 6 for preparing embodiment 1, including following step
Suddenly：
Step 1: collect acrylonitrile-butadiene-styrene copolymer waste or used plastics, clean with water collection acrylonitrile-
The waste or used plastics of BS, after being crushed by pulverizer, screening obtains the particle of 60 mesh；
By the particle of 60 mesh, 10min is dried in temperature is 100 DEG C of dryer, dry plastic grain is obtained；
Dry plastic grain is cooled to after room temperature, the tumbling 30min in vacuum tumbler obtains the plastics of removal of impurities
Grain；
The plastic grain of removal of impurities is cleaned again with water, 10min is dried in temperature is 100 DEG C of dryer, obtains
To the plastic grain of secondary removal of impurities；
The plastic grain of secondary removal of impurities is crushed again, the particle of 110 mesh is screened, obtains acrylonitrile-butadiene-styrene (ABS)
The plastic grain of copolymer；
Step 2: according to percentage by weight, by plastic grain, activator (its by percentage by weight for 4% it is silane coupled
Agent, 1% antistatic additive, 1% lubricant), GDMA (crosslinking agent) mixing crosslinking after, add neighbour
(light is stable for mixture (antiager), the benzophenone of ester (plasticiser), bisphenol-A and triphenyl phosphite
Agent) hybrid reaction, obtain regenerated plastics；
Step 3: the regenerated plastics are prepared into particle, screening obtains the recycled plastic granules of 60 mesh；
It is molded Step 4: the recycled plastic granules are added in injection machine, obtains speculum.
Embodiment 8
The invention provides a kind of preparation method for the speculum into embodiment 6 for preparing embodiment 1, including following step
Suddenly：
Step 1: collect acrylonitrile-butadiene-styrene copolymer waste or used plastics, clean with water collection acrylonitrile-
The waste or used plastics of BS, after being crushed by pulverizer, screening obtains the particle of 70 mesh；
By the particle of 70 mesh, 15min is dried in temperature is 100 DEG C of dryer, dry plastic grain is obtained；
Dry plastic grain is cooled to after room temperature, the tumbling 35min in vacuum tumbler obtains the plastics of removal of impurities
Grain；
The plastic grain of removal of impurities is cleaned again with water, 15min is dried in temperature is 100 DEG C of dryer, obtains
To the plastic grain of secondary removal of impurities；
The plastic grain of secondary removal of impurities is crushed again, the particle of 100 mesh is screened, obtains acrylonitrile-butadiene-styrene (ABS)
The plastic grain of copolymer；
Step 2: according to percentage by weight, by plastic grain, activator (its by percentage by weight for 4% it is silane coupled
Agent, 1% antistatic additive, 1% lubricant), GDMA (crosslinking agent) mixing crosslinking after, add neighbour
The mixture (antiager) of phthalic acid dibutyl ester (plasticiser), bisphenol-A and triphenyl phosphite, (light is steady for benzotriazole
Determine agent) hybrid reaction, obtain regenerated plastics；
Step 3: the regenerated plastics are prepared into particle, screening obtains the recycled plastic granules of 75 mesh；
It is molded Step 4: the recycled plastic granules are added in injection machine, obtains speculum.
Embodiment 9
The invention provides a kind of preparation method for the speculum into embodiment 6 for preparing embodiment 1, including following step
Suddenly：
Step 1: collect acrylonitrile-butadiene-styrene copolymer waste or used plastics, clean with water collection acrylonitrile-
The waste or used plastics of BS, after being crushed by pulverizer, screening obtains the particle of 80 mesh；
By the particle of 80 mesh, 20min is dried in temperature is 100 DEG C of dryer, dry plastic grain is obtained；
Dry plastic grain is cooled to after room temperature, the tumbling 40min in vacuum tumbler obtains the plastics of removal of impurities
Grain；
The plastic grain of removal of impurities is cleaned again with water, 20min is dried in temperature is 100 DEG C of dryer, obtains
To the plastic grain of secondary removal of impurities；
The plastic grain of secondary removal of impurities is crushed again, the particle of 120 mesh is screened, obtains acrylonitrile-butadiene-styrene (ABS)
The plastic grain of copolymer；
Step 2: according to percentage by weight, by plastic grain, activator (its by percentage by weight for 4% it is silane coupled
Agent, 1% antistatic additive, 1% lubricant), GDMA (crosslinking agent) mixing crosslinking after, add neighbour
The mixture (antiager) of dibatyl phithalate (plasticiser), bisphenol-A and triphenyl phosphite, (light is steady for benzophenone
Determine agent) hybrid reaction, obtain regenerated plastics；
Step 3: the regenerated plastics are prepared into particle, screening obtains the recycled plastic granules of 80 mesh；
It is molded Step 4: the recycled plastic granules are added in injection machine, obtains speculum.
By the preparation method of embodiment 7 to embodiment 9, the obtained speculum described in embodiment 1 to embodiment 6, i.e.,
Using the eyeglass of the eyeglass obtained by ABS reworked materials and traditional speculum, difference less, can be with surface smoothness for both
The use requirement of solar energy reflection mirror is fully achieved；Secondly, the weatherability and ageing-resistant performance of speculum of the present invention expire
The replacement cycle of sufficient solar energy reflection mirror；And the cost of speculum can be reduced using ABS reworked materials, improve market competition
Power.
The present invention is that raw material prepare speculum, present conventional plastic recovery process and recovery using recyclable plastic
Equipment and technology content is not high, is only used for part low-end product, such as regeneration modeling plank, in addition, reflective mirror is used in solar energy
Hot field, the requirement to weatherability and ageing resistace is higher, thus the present invention traditional recyclable plastic is modified, with accord with
Close the use requirement under outdoor conditions.
The present invention is used using regenerated plastics as raw material, the speculum being prepared from.Regenerated plastics shown in of the invention
By larger lifting in terms of the plasticity of cost and increase eyeglass is reduced, it can make plastics can be for a long time under solar irradiation again
Use.
Moreover, the preparation method of the speculum of the present invention, can prepare the speculum of function admirable, preparation process environmental protection
Do not pollute.
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With can be applied to various suitable the field of the invention entirely, for those skilled in the art, be easily achieved
Other modification, therefore under the universal limited without departing substantially from claim and equivalency range, the present invention is not limited to spy
Fixed details and shown here as the legend with description.
Claims (10)
1. a kind of speculum, it is characterised in that including following components in percentage by weight：
Acrylonitrile-butadiene-styrene copolymer 82~95%, activator 2~10%, antiager 0.5~3%, light is stable
Agent 0.5~3%, crosslinking agent 0.5~3%.
2. speculum as claimed in claim 1, it is characterised in that including following components in percentage by weight：
Acrylonitrile-butadiene-styrene copolymer 88~93%, activator 4~9%, antiager 0.5~1.5%, light is stable
Agent 0.5~1.5%, crosslinking agent 0.5~1.5%.
3. speculum as claimed in claim 2, it is characterised in that including following components in percentage by weight：
Acrylonitrile-butadiene-styrene copolymer 91%, activator 6%, antiager 1%, light stabilizer 1%, crosslinking agent
1%.
4. the preparation method of a kind of speculum as described in any one in claims 1 to 3, it is characterised in that including following
Step：
Step 1: collect acrylonitrile-butadiene-styrene copolymer waste or used plastics, after pretreatment, obtain acrylonitrile-
The plastic grain of BS；
Step 2: according to percentage by weight, plastic grain, activator, crosslinking agent are mixed after crosslinking, plasticiser is added, resistance to
Aging agent, light stabilizer hybrid reaction, obtain regenerated plastics；
Step 3: the regenerated plastics are prepared into particle, screening obtains the recycled plastic granules of 60~80 mesh；
It is molded Step 4: the recycled plastic granules are added in injection machine, obtains speculum.
5. preparation method as claimed in claim 4, it is characterised in that in the step one, after pretreatment, obtains third
The plastic grain of alkene nitrile-BS is comprised the following steps that：
The waste or used plastics for the acrylonitrile-butadiene-styrene copolymer collected are cleaned with water, after being crushed by pulverizer, screening
Obtain the particle of 60~80 mesh；
By the particle of 60~80 mesh, 10~20min is dried in temperature is 100 DEG C of dryer, dry plastic grain is obtained；
Dry plastic grain is cooled to after room temperature, 30~40min of tumbling in vacuum tumbler obtains the plastics of removal of impurities
Grain；
The plastic grain of removal of impurities is cleaned again with water, 10~20min is dried in temperature is 100 DEG C of dryer, obtains
To the plastic grain of secondary removal of impurities；
The plastic grain of secondary removal of impurities is crushed again, the particle of 100~120 mesh is screened, obtains acrylonitrile-butadiene-benzene second
The plastic grain of alkene copolymer.
6. preparation method as claimed in claim 4, it is characterised in that the activator is by following components in percentage by weight group
Into：
Silane coupler 4%, antistatic additive 1%, lubricant 1%.
7. preparation method as claimed in claim 4, it is characterised in that the crosslinking agent is GDMA.
8. preparation method as claimed in claim 4, it is characterised in that the plasticiser is ditridecyl phthalate, adjacent benzene two
One or more in formic acid dibutyl ester, dibutyl phthalate.
9. the preparation method of speculum as claimed in claim 4, it is characterised in that the antiager is bisphenol-A and phosphorous
The mixture of triphenyl phosphate ester.
10. preparation method as claimed in claim 4, it is characterised in that the light stabilizer is benzophenone and benzo three
The one or two kinds of of azole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710608990.0A CN107236243A (en) | 2017-07-25 | 2017-07-25 | Speculum and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710608990.0A CN107236243A (en) | 2017-07-25 | 2017-07-25 | Speculum and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107236243A true CN107236243A (en) | 2017-10-10 |
Family
ID=59988244
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201710608990.0A Pending CN107236243A (en) | 2017-07-25 | 2017-07-25 | Speculum and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116836515A (en) * | 2023-05-25 | 2023-10-03 | 广东安拓普聚合物科技有限公司 | Anti-aging PCR thermosetting plate for decoration and preparation method thereof |
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|---|---|---|---|---|
| CN103235354A (en) * | 2013-05-15 | 2013-08-07 | 北京化工大学 | Light reflector and preparation method thereof |
| CN104387731A (en) * | 2014-08-28 | 2015-03-04 | 天津市利顺塑料制品有限公司 | Modification recovery method for waste plastic |
| CN105860417A (en) * | 2016-04-28 | 2016-08-17 | 安徽省华晨塑业科技有限公司 | High-performance and environment-friendly modified technology for waste ABS materials |
| CN105885083A (en) * | 2016-03-31 | 2016-08-24 | 界首市华盛塑料机械有限公司 | Waste plastic high-performance environment-friendly regeneration technology |
-
2017
- 2017-07-25 CN CN201710608990.0A patent/CN107236243A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103235354A (en) * | 2013-05-15 | 2013-08-07 | 北京化工大学 | Light reflector and preparation method thereof |
| CN104387731A (en) * | 2014-08-28 | 2015-03-04 | 天津市利顺塑料制品有限公司 | Modification recovery method for waste plastic |
| CN105885083A (en) * | 2016-03-31 | 2016-08-24 | 界首市华盛塑料机械有限公司 | Waste plastic high-performance environment-friendly regeneration technology |
| CN105860417A (en) * | 2016-04-28 | 2016-08-17 | 安徽省华晨塑业科技有限公司 | High-performance and environment-friendly modified technology for waste ABS materials |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116836515A (en) * | 2023-05-25 | 2023-10-03 | 广东安拓普聚合物科技有限公司 | Anti-aging PCR thermosetting plate for decoration and preparation method thereof |
| CN116836515B (en) * | 2023-05-25 | 2023-12-29 | 广东安拓普聚合物科技股份有限公司 | Anti-aging PCR thermosetting plate for decoration and preparation method thereof |
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Application publication date: 20171010 |