CN105885083A - Waste plastic high-performance environment-friendly regeneration technology - Google Patents

Waste plastic high-performance environment-friendly regeneration technology Download PDF

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Publication number
CN105885083A
CN105885083A CN201610203871.2A CN201610203871A CN105885083A CN 105885083 A CN105885083 A CN 105885083A CN 201610203871 A CN201610203871 A CN 201610203871A CN 105885083 A CN105885083 A CN 105885083A
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China
Prior art keywords
plastic
waste
plastic grain
grains
fed
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Pending
Application number
CN201610203871.2A
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Chinese (zh)
Inventor
程德峰
姜曙光
姜妍雅
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JIESHOU HUASHENG PLASTIC MACHINERY CO Ltd
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JIESHOU HUASHENG PLASTIC MACHINERY CO Ltd
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Priority to CN201610203871.2A priority Critical patent/CN105885083A/en
Publication of CN105885083A publication Critical patent/CN105885083A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2400/00Characterised by the use of unspecified polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

A waste plastic high-performance environment-friendly regeneration technology comprises the following steps that firstly, waste plastic is collected and put into a vibrating screen to separate large impurities, then the waste plastic is ground into grains, and the grains are fed into cold air drying equipment; secondly, the plastic grains dried with cold air are fed into a vacuum rolling machine for rolling treatment, vacuum pumping is carried out once every 5-8 min in the rolling process, and rolling is carried out for 5-10 min after each time of vacuum pumping; thirdly, the rolled plastic grains are taken out and sprayed with pure water for washing; fourthly, the sprayed plastic grains are drained to remove moisture and then fed into drying equipment for drying treatment until no moisture exists on the surfaces of the plastic grains; fifthly, the dried plastic grains are fed into low-temperature ring equipment for low-temperature treatment; sixthly, the plastic grains subjected to low-temperature treatment are ground, and the ground plastic grains pass through an 80-mesh screen and then are fed into refrigerating equipment for cold-resistant treatment; seventhly, the plastic grains subjected to cold-resistant treatment are fed into an extruder for extruding granulation, and thus modification of plastic is completed.

Description

Waste or used plastics high-performance environment-friendly regeneration technology
Technical field
The present invention relates to plastics modification technology field, be specifically related to a kind of waste or used plastics high-performance environment-friendly regeneration Technique.
Background technology
Since nineteen thirty modern plastics industry is formed, through more than 80 years develop rapidly, plastics industry was Through becoming the mainstay of light industry.Plastic product wide variety of while, also create huge Plastic pollution, the ecological environment to the whole world causes destruction greatly.Processing method to waste plastic garbage Mainly landfill disposal and burning disposal, but landfill disposal takes up room relatively big due to it, adds soil Ground resource pressure, simultaneously because useless moulding is difficult to degrade, the serious infiltration hampering water and subsoil water circulation, Secondly giving up the additive in moulding also can be to soil reclamation secondary pollution.Burning disposal due to burning produce CO, Polycyclic aromatic compound and heavy metal can be discharged together with incineration residue along with flue dust and cause environment The biggest pollution.Along with the progress of science and technology, start to occur utilizing plastic reclaimed machinery to waste or used plastics Carry out regenerating and modifying, just achieve resources circulation in real consciousness.
For recycling these waste plastics, need it is crushed, clean, separate impurity etc., Traditional recovery process and reclaimer technology content are the highest, and cost recovery is big, the sexual valence attached by recovery Ratio is unsatisfactory.The regenerated plastics quality of preparation is the highest, is only used for part low-end product and uses.Especially Being to use in some special environments, under low temperature environment, environment under high pressure, common reworked material cannot be expired The working environment of foot high intensity, resistance to low temperature is poor, easy embrittlement.And also there is impact strength relatively Low, elastic and that anti-stress cracking performance is poor defect, causes bigger to the development of plastic reclaimed industry Impact.
Summary of the invention
The technical problem to be solved is to provide a kind of physics, stable chemical performance, preparation letter Single waste or used plastics high-performance environment-friendly regeneration technology.
The technical problem to be solved realizes by the following technical solutions:
A kind of waste or used plastics high-performance environment-friendly regeneration technology, it is characterised in that the method step is as follows,
(1) collect waste or used plastics, put into be fallen by big magazins' layout in vibrosieve, mould waste and old the most again Material is ground into graininess, sends into cold wind drying plant, cold air drying 30-35 minute at temperature 50-55 DEG C, Make plastic grain dry tack free, it is simple to follow-up cleaning;
(2) plastic grain after cold air drying is sent into vacuum tumbler and carry out tumbling process, every during tumbling Every 5-8 minute evacuation once, exhaust tumbling 5-10 minute, then vacuum pumping after vacuum every time, so follow Ring 2-4 time so that plastic grain can reach to breathe the effect of massage in tumbling procedure, improves surface and lives Property, make the impurity on surface start to decompose;
(3) plastic grain after tumbling is taken out, carry out cleaning showers with pure water, spray 4-5 continuously Minute, processing owing to have passed through tumbling, the foreign material on plastic grain surface and oil stain are easy to fill to be washed off, Flushing water can be recycled after precipitation process;
(4) plastic grain after spray is drained away the water, send in drying plant and carry out drying and processing, dry Dry temperature controls at 55-60 DEG C, to plastic grain surface without moisture;
(5) plastic grain after drying is sent in low temperature ring apparatus and is carried out K cryogenic treatment, and temperature controls Subzero about 15 DEG C, K cryogenic treatment 20 minutes;The advantage of K cryogenic treatment is to improve the resistance to low of regenerated plastics Warm nature energy;
(6) plastic grain after K cryogenic treatment is pulverized, cross 80 mesh sieves, then the plastics that will pulverize Grain feeding freezing equipment, freezing 40 minutes under subzero 25 DEG C of environment, carry out cold-resistant process;The most effective Improve the dispersion effect of matrix, and send out with ABS under the effect of activator during reactive extrursion Raw reaction, plays the effect of chain extension, improves the mechanical property of waste or used plastics goods.
(7) ratio of the plastic grain after cold-resistant process with activator 1:0.05-0.1 in mass ratio is mixed Close, send into extruder extruding pelletization, i.e. complete modifying plastics.
Described activator is by silane coupler 20g, age resister 10g, procyanidin 10g, antistatic additive 5g, sodium polyphosphate 5g and lubricant 5g make;
Described silane coupler is vinyltrimethoxy silane, VTES, vinyl Triacetoxysilane, vinyl three tert-butoxy silane or γ-(methacryloxypropyl) propyl group trimethoxy The one of base silane.
Owing to waste or used plastics surface exists hydroxyl so that it is be difficult in the base disperse, surface can be relatively big and incline To in reunion, commonly use coupling agent at present and waste or used plastics is carried out surface modification treatment.Used by the present invention Activator in waste or used plastics surface treatment process, there is chemical bonding or thing with waste or used plastics surface Reason adsorption;Such activator is in regeneration process of waste plastics, after waste or used plastics surface is modified, Its surface is become hydrophobicity by hydrophilic, improves the compatibility with matrix, and the mechanical property of product obtains Improve.
The invention has the beneficial effects as follows: the present invention uses waste plastic to be to produce raw material, by plastics Having carried out modification, the plastic grain of preparation may be used for the production of various goods, as food package box, Furniture, container etc.;The product of preparation has higher intensity, nonhazardous, acid and alkali-resistance, anticorrosive, The feature easily reclaimed, is a kind of new green environment protection material.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of waste or used plastics high-performance environment-friendly regeneration technology, it is characterised in that the method step is as follows,
(1) collect waste or used plastics, put into be fallen by big magazins' layout in vibrosieve, mould waste and old the most again Material is ground into graininess, sends into cold wind drying plant, cold air drying 30-35 minute at temperature 50-55 DEG C, Make plastic grain dry tack free, it is simple to follow-up cleaning;
(2) plastic grain after cold air drying is sent into vacuum tumbler and carry out tumbling process, every during tumbling Every 5-8 minute evacuation once, exhaust tumbling 5-10 minute, then vacuum pumping after vacuum every time, so follow Ring 2-4 time so that plastic grain can reach to breathe the effect of massage in tumbling procedure, improves surface and lives Property, make the impurity on surface start to decompose;
(3) plastic grain after tumbling is taken out, carry out cleaning showers with pure water, spray 4-5 continuously Minute, processing owing to have passed through tumbling, the foreign material on plastic grain surface and oil stain are easy to fill to be washed off, Flushing water can be recycled after precipitation process;
(4) plastic grain after spray is drained away the water, send in drying plant and carry out drying and processing, dry Dry temperature controls at 55-60 DEG C, to plastic grain surface without moisture;
(5) plastic grain after drying is sent in low temperature ring apparatus and is carried out K cryogenic treatment, and temperature controls Subzero about 15 DEG C, K cryogenic treatment 20 minutes;The advantage of K cryogenic treatment is to improve the resistance to low of regenerated plastics Warm nature energy;
(6) plastic grain after K cryogenic treatment is pulverized, cross 80 mesh sieves, then the plastics that will pulverize Grain feeding freezing equipment, freezing 40 minutes under subzero 25 DEG C of environment, carry out cold-resistant process;The most effective Improve the dispersion effect of matrix, and send out with ABS under the effect of activator during reactive extrursion Raw reaction, plays the effect of chain extension, improves the mechanical property of waste or used plastics goods.
(7) ratio of the plastic grain after cold-resistant process with activator 1:0.05-0.1 in mass ratio is mixed Close, send into extruder extruding pelletization, i.e. complete modifying plastics.
Described activator is by silane coupler 20g, age resister 10g, procyanidin 10g, antistatic additive 5g, sodium polyphosphate 5g and lubricant 5g make;
Described silane coupler is vinyltrimethoxy silane, VTES, vinyl Triacetoxysilane, vinyl three tert-butoxy silane or γ-(methacryloxypropyl) propyl group trimethoxy The one of base silane.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (3)

1. a waste or used plastics high-performance environment-friendly regeneration technology, it is characterised in that the method step is as follows,
(1) collect waste or used plastics, put into be fallen by big magazins' layout in vibrosieve, mould waste and old the most again Material is ground into graininess, sends into cold wind drying plant, cold air drying 30-35 minute at temperature 50-55 DEG C;
(2) plastic grain after cold air drying is sent into vacuum tumbler and carry out tumbling process, every during tumbling Every 5-8 minute evacuation once, exhaust tumbling 5-10 minute, then vacuum pumping after vacuum every time, so follow Ring 2-4 time;
(3) plastic grain after tumbling is taken out, carry out cleaning showers with pure water, spray 4-5 continuously Minute;
(4) plastic grain after spray is drained away the water, send in drying plant and carry out drying and processing, dry Dry temperature controls at 55-60 DEG C, to plastic grain surface without moisture;
(5) plastic grain after drying is sent in low temperature ring apparatus and is carried out K cryogenic treatment, and temperature controls Subzero about 15 DEG C, K cryogenic treatment 20 minutes;
(6) plastic grain after K cryogenic treatment is pulverized, cross 80 mesh sieves, then the plastics that will pulverize Grain feeding freezing equipment, freezing 40 minutes under subzero 25 DEG C of environment, carry out cold-resistant process;
(7) ratio of the plastic grain after cold-resistant process with activator 1:0.05-0.1 in mass ratio is mixed Close, send into extruder extruding pelletization, i.e. complete modifying plastics.
Waste or used plastics high-performance environment-friendly regeneration technology the most according to claim 1, it is characterised in that Described activator be by silane coupler 20g, age resister 10g, procyanidin 10g, antistatic additive 5g, Sodium polyphosphate 5g and lubricant 5g makes.
Waste or used plastics high-performance environment-friendly regeneration technology the most according to claim 2, it is characterised in that Described silane coupler is vinyltrimethoxy silane, VTES, vinyl three second Acyloxy silane, vinyl three tert-butoxy silane or γ-(methacryloxypropyl) propyl trimethoxy silicon The one of alkane.
CN201610203871.2A 2016-03-31 2016-03-31 Waste plastic high-performance environment-friendly regeneration technology Pending CN105885083A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236243A (en) * 2017-07-25 2017-10-10 陕西路圣里德太阳能研究院有限公司 Speculum and preparation method thereof
CN107418100A (en) * 2017-08-21 2017-12-01 刘子睿 A kind of fascia PVC slush mouldings epidermis tailing reuse method
CN111100472A (en) * 2020-01-03 2020-05-05 扬州市皇宙塑粉有限公司 Composite plastic powder and preparation method thereof
CN112248293A (en) * 2020-08-27 2021-01-22 福建泉州新耀新材料科技有限公司 High-performance environment-friendly regeneration device and regeneration process for waste plastics
CN112300597A (en) * 2020-11-04 2021-02-02 湖南省新基源新材料科技有限公司 Recycled plastic particles and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1646280A (en) * 2002-02-12 2005-07-27 索尼株式会社 Recycle system for used plastics, method of reclaiming used ABS resin and reclaimed ABS resin
CN101914240A (en) * 2010-08-11 2010-12-15 丁飞鹏 Regenerated wire drawing modified material of waste polypropylene woven bags and preparation method thereof
CN104479384A (en) * 2014-11-18 2015-04-01 安徽鸿达塑业科技有限公司 Method for preparing greening fence based on waste plastics and straw
CN104672708A (en) * 2015-02-13 2015-06-03 北京科技大学 Recyclable waste plastic polyvinyl chloride composite material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1646280A (en) * 2002-02-12 2005-07-27 索尼株式会社 Recycle system for used plastics, method of reclaiming used ABS resin and reclaimed ABS resin
CN101914240A (en) * 2010-08-11 2010-12-15 丁飞鹏 Regenerated wire drawing modified material of waste polypropylene woven bags and preparation method thereof
CN104479384A (en) * 2014-11-18 2015-04-01 安徽鸿达塑业科技有限公司 Method for preparing greening fence based on waste plastics and straw
CN104672708A (en) * 2015-02-13 2015-06-03 北京科技大学 Recyclable waste plastic polyvinyl chloride composite material and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236243A (en) * 2017-07-25 2017-10-10 陕西路圣里德太阳能研究院有限公司 Speculum and preparation method thereof
CN107418100A (en) * 2017-08-21 2017-12-01 刘子睿 A kind of fascia PVC slush mouldings epidermis tailing reuse method
CN107418100B (en) * 2017-08-21 2019-09-03 刘子睿 A kind of fascia PVC slush moulding epidermis tailing reuse method
CN111100472A (en) * 2020-01-03 2020-05-05 扬州市皇宙塑粉有限公司 Composite plastic powder and preparation method thereof
CN112248293A (en) * 2020-08-27 2021-01-22 福建泉州新耀新材料科技有限公司 High-performance environment-friendly regeneration device and regeneration process for waste plastics
CN112300597A (en) * 2020-11-04 2021-02-02 湖南省新基源新材料科技有限公司 Recycled plastic particles and preparation method thereof

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Application publication date: 20160824