CN107234828A - A kind of biomass moulding technique and the biomass moulding material as made from the technique - Google Patents

A kind of biomass moulding technique and the biomass moulding material as made from the technique Download PDF

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Publication number
CN107234828A
CN107234828A CN201610186445.2A CN201610186445A CN107234828A CN 107234828 A CN107234828 A CN 107234828A CN 201610186445 A CN201610186445 A CN 201610186445A CN 107234828 A CN107234828 A CN 107234828A
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CN
China
Prior art keywords
biomass
technique
biomass moulding
bundled
moulding material
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Pending
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CN201610186445.2A
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Chinese (zh)
Inventor
林科
杜明来
赵文涛
马芳
白洪彬
刘彦芳
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Beijing SJ Environmental Protection and New Material Co Ltd
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Beijing SJ Environmental Protection and New Material Co Ltd
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Priority to CN201610186445.2A priority Critical patent/CN107234828A/en
Publication of CN107234828A publication Critical patent/CN107234828A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B30PRESSES
    • B30BPRESSES IN GENERAL
    • B30B9/00Presses specially adapted for particular purposes
    • B30B9/28Presses specially adapted for particular purposes for forming shaped articles

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention provides a kind of biomass moulding technique and the biomass moulding material as made from the technique, the technique by biomass material by directly packing bundled, and it is under given conditions that the bundled materials pressing one-time of gained is just plastic, compared with needing to crush biomass with prior art, being just pressed into particulate matter after dedusting, technological operation of the invention is simple and efficient, material handling capacity is small, and the shape of bundled materials and molding mass is easily controllable, it is easy to pile up and transports.Biomass moulding material produced by the present invention can be directly used as the raw material of process for upgrading, without being cooled down again and drying and processing, be conducive to simplifying processing step, it is often more important that the energy consumption of integrated artistic can be also greatly reduced so that technique of the invention has the advantages that simple and efficient to handle, energy consumption is low.

Description

A kind of biomass moulding technique and the biomass moulding material as made from the technique
Technical field
It is applied to the present invention relates to the exploitation field of biomass energy, more particularly to one kind with biomass The biomass moulding technique and the biomass moulding material as made from the technique of upgrading are carried out for raw material.
Background technology
With China's demand for energy increase rapidly and conventional fossil fuel increasingly depleted, coal Will not occur within the following quite a long time as the principal status of public economy of China's production of energy and consumption Sexually revise at all.At present, the utilization for coal is more based on burning, and coal is in combustion The pollutants such as substantial amounts of dust, carbon monoxide, sulphur or nitrogen oxide can be discharged, ecological environment is caused It is continuous worsening, cause increasingly serious environmental problem.Therefore, clean regenerative resource has been developed So turn into the important channel for solving energy crisis and environmental pollution.
Biomass energy is that green plants converts solar energy into chemical energy and is stored in the energy inside biomass Amount, i.e., using biomass as the form of energy of carrier, it directly or indirectly derives from the light of green plants Cooperation is used, and can be converted into conventional solid-state, liquid and fuel gas, inexhaustible, nexhaustible, It is a kind of regenerative resource, while being also a kind of unique reproducible carbon source.Also, biomass energy is also With multi-functionals such as energy substitution, emission reduction environmental protection and promotion rural economys, therefore, from energy security Set out with environmental protection, the exploitation to biomass energy turn into the war of current development regenerative resource Omit emphasis.
However, because the short texture of biological energy raw material, distribution are scattered, space-consuming is big, as Fuel has that energy density is small, directly burn the thermal efficiency is low, transport and storage cost, Cause to be difficult to scale efficiently to utilize, economic benefit is poor, commodity energy is converted into as restriction biomass The key factor in source.The biomass solid shaping technology researched and developed in recent years changes traditional biomass energy Land use systems, highdensity shaped fuel is converted into by loose biomass, is directly burnt or as gas Change, liquefy raw material, a kind of effective way developed as biomass energy, be also to substitute conventional energy The effective ways in source.
Done for example, Chinese patent literature CN102776009A discloses a kind of biomass energy shaping, pyrolysis Industrialization production charcoal, gas, oil, galvanic process are evaporated, is comprised the following steps:Raw material is crushed, removed Sent into after dirt in granulator, be pressed into Φ 6-12 × 20-30 particle, particle to be formed is cooled to room temperature After ± 3 DEG C, then it is 3-5% to be baked to moisture content;Under conditions of completely cutting off air or having a small amount of air, Particle charcoal, gas and liquid are gone out by thermochemical conversion to the shaped granule after drying.Above-mentioned technology has Effect realizes the curing molding of biomass material, by by shaped granule pyrogenation and carbonization, being converted into it With the raw material of industry such as more high-grade high-grade fuel and pyrolkigneous liquid, wood tar, biomass is improved Value.
But above-mentioned technology is needed after crushing, dust removal process, biomass could be pressed into granule The particle in footpath so that the operation of biomass moulding technique is tediously long, crush after also increase the processing of material Measure and be shaped to little particle and be also not easy to pile up and transport.In addition, above-mentioned technology is by shaped granule Before pyrogenation and carbonization, also need to cool down it and drying and processing, by the moisture control of particle In the range of a very little, not only cause the trivial operations of above-mentioned technique, it is often more important that increase The energy consumption of technique.Therefore, the moulding process of biomass how is improved to overcome the upper of prior art presence Defect is stated, the still unsolved technical barrier in this area is still.
The content of the invention
Present invention solves the technical problem that being to overcome the operation present in existing biomass moulding technique Numerous and diverse, treating capacity is big, time-consuming, the defect of high energy consumption, so provide it is a kind of it is simple and efficient to handle, The low biomass moulding technique of energy consumption and the biomass moulding material as made from the technique.
Therefore, the present invention realizes that the technical scheme of above-mentioned purpose is:
A kind of biomass moulding technique, comprises the following steps:
Biomass material is packed bundled, bundled materials are formed;
It is under conditions of 20-100 DEG C, 5-40MPa that the bundled materials are compressing, as biomass Molding mass.
The water content of the biomass material is not more than 20wt%.
The biomass material is stalk and/or wood wastes.
The volume of the bundled materials is not less than 0.5m3
Power is 50-70 DEG C, 15-25MPa under conditions of the compacting.
The ratio between density of the biomass moulding material and the bundled materials is (2-4):1.
The biomass moulding material as made from above-mentioned biomass moulding technique.
The present invention carries out compression process using hydraulic test to above-mentioned bundled materials, according to used mould Shape and size difference, the molding mass with arbitrary shape and size can be made.Preferably, The shape and size of biomass moulding material produced by the present invention and the carbonization chamber of tamping coke furnace match.
The above-mentioned technical proposal of the present invention has the following advantages that:
1st, the biomass moulding technique that the present invention is provided, by the way that biomass material directly is packed into bundled, And it is under given conditions that the bundled materials pressing one-time of gained is just plastic, being needed with prior art will be raw Material, which crushes, can just be pressed into particulate matter after dedusting compares, technological operation of the invention is simple and efficient, Material handling capacity is small, and the shape of bundled materials and molding mass is easily controllable, is easy to pile up and transports.
2nd, the biomass moulding material that the present invention is provided can be directly used as the raw material of process for upgrading, without again Cooled down and drying and processing, be conducive to simplifying processing step, it is often more important that can be also greatly reduced whole The energy consumption of body technology so that technique of the invention has the advantages that simple and efficient to handle, energy consumption is low.And And, biomass moulding material of the invention can obtain the rough coal of appreciable amount through the upgrading processing under specified conditions Gas, tar and carbon residue, it is of the invention compared with the calorific value produced by waiting quality biomass matter to be used as fuel Biomass moulding material possesses higher economic benefit.
Embodiment
Technical scheme will be clearly and completely described below, it is clear that described Embodiment is a part of embodiment of the present invention, rather than whole embodiments.Based in the present invention Embodiment, it is all that those of ordinary skill in the art are obtained under the premise of creative work is not made Other embodiment, belongs to the scope of protection of the invention.In addition, invention described below is different As long as involved technical characteristic does not constitute conflict and can just be combined with each other each other in embodiment.
In the following embodiments, wt% represents weight/mass percentage composition, and " kg/t molding mass " refers to shaping per ton Expect the obtained kilogram number of product, " Nm3/ t molding mass " refers to the body for the raw gas that molding mass per ton is obtained Product is converted into the cubic meter number of 0 DEG C, 1 normal atmosphere pressure.
Embodiment 1
Biomass moulding technique described in the present embodiment, comprises the following steps:
100kg, water content is bundled for 18wt% stalk packing, volume is obtained for 0.5m3It is rectangular Body shape bundled materials;
It is under conditions of 50 DEG C, 15MPa that bundled materials are compressing, biomass moulding material is produced, should The ratio between density of biomass moulding material and bundled materials is 2:1.
Upgrading processing will be carried out in biomass moulding material push-in tamping coke furnace made from the present embodiment, control is carried Matter temperature is 850 DEG C, and the upgrading time is 16 hours, collects the raw gas overflowed, tar, simultaneously To carbon residue.The amount for the raw gas that the present embodiment is obtained is 330Nm3/ t molding mass, the amount of tar is 25kg/t molding mass, the amount of coke is 280kg/t molding mass, in mass, wherein consolidating in coke Body carbon content is not more than 6% not less than 50%, volatile matter content, and particle diameter is in 40mm after coke screening Particle gross mass above is the 10% of coke gross mass, particle gross mass of the particle diameter in more than 25mm For the 20% of coke gross mass.
Embodiment 2
Biomass moulding technique described in the present embodiment, comprises the following steps:
110kg, water content is bundled for 20wt% stalk packing, volume is obtained for 0.5m3It is rectangular Body shape bundled materials;
It is under conditions of 60 DEG C, 25MPa that bundled materials are compressing, biomass moulding material is produced, should The ratio between density of biomass moulding material and bundled materials is 3:1.
Upgrading processing, control will be carried out in biomass moulding material push-in tamping coke furnace made from the present embodiment Upgrading temperature is 850 DEG C, and the upgrading time is 16 hours, collects the raw gas overflowed, tar, simultaneously Obtain carbon residue.The amount for the raw gas that the present embodiment is obtained is 320Nm3/ t molding mass, the amount of tar is 24kg/t molding mass, the amount of carbon residue is 270kg/t molding mass, in mass, wherein consolidating in coke Body carbon content is not more than 6% not less than 50%, volatile matter content, and particle diameter is in 40mm after coke screening Particle gross mass above is the 10% of coke gross mass, particle gross mass of the particle diameter in more than 25mm For the 20% of coke gross mass.
Embodiment 3
Biomass moulding technique described in the present embodiment, comprises the following steps:
90kg, water content is bundled for 16wt% stalk packing, volume is obtained for 0.5m3Cuboid Shape bundled materials;
It is under conditions of 70 DEG C, 35MPa that bundled materials are compressing, biomass moulding material is produced, should The ratio between density of biomass moulding material and bundled materials is 4:1.
Upgrading processing, control will be carried out in biomass moulding material push-in tamping coke furnace made from the present embodiment Upgrading temperature is 850 DEG C, and the upgrading time is 16 hours, collects the raw gas overflowed, tar, simultaneously Obtain carbon residue.The amount for the raw gas that the present embodiment is obtained is 336Nm3/ t molding mass, the amount of tar is 25kg/t molding mass, the amount of carbon residue is 286kg/t molding mass, in mass, wherein consolidating in carbon residue Body carbon content is not more than 6% not less than 50%, volatile matter content, and particle diameter is in 40mm after coke screening Particle gross mass above is the 10% of coke gross mass, particle gross mass of the particle diameter in more than 25mm For the 20% of coke gross mass.
Embodiment 4
Biomass moulding technique described in the present embodiment, comprises the following steps:
100kg, water content is bundled for 18wt% stalk packing, volume is obtained for 0.5m3It is rectangular Body shape bundled materials;
It is under conditions of 20 DEG C, 20MPa that bundled materials are compressing, biomass moulding material is produced, should The ratio between density of biomass moulding material and bundled materials is 2.5:1.
Upgrading processing, control will be carried out in biomass moulding material push-in tamping coke furnace made from the present embodiment Upgrading temperature is 850 DEG C, and the upgrading time is 16 hours, collects the raw gas overflowed, tar, simultaneously Obtain coke.The amount for the raw gas that the present embodiment is obtained is 330Nm3/ t molding mass, the amount of tar is 25kg/t molding mass, the amount of coke is 280kg/t molding mass, in mass, wherein consolidating in coke Body carbon content is not more than 6% not less than 50%, volatile matter content, and particle diameter is in 40mm after coke screening Particle gross mass above is the 10% of coke gross mass, particle gross mass of the particle diameter in more than 25mm For the 20% of coke gross mass.
Obviously, above-described embodiment is only intended to clearly illustrate example, and not to embodiment party The restriction of formula.For those of ordinary skill in the field, may be used also on the basis of the above description To make other changes in different forms.There is no need and unable to give all embodiments With exhaustion.And the obvious changes or variations thus extended out is still in the guarantor of the invention Protect among scope.

Claims (7)

1. a kind of biomass moulding technique, comprises the following steps:
Biomass material is packed bundled, bundled materials are formed;
It is under conditions of 20-100 DEG C, 5-40MPa that the bundled materials are compressing, produce biomass Molding mass.
2. biomass moulding technique according to claim 1, it is characterised in that the biomass The water content of raw material is not more than 20wt%.
3. biomass moulding technique according to claim 1 or 2, it is characterised in that the life Raw material of substance is stalk and/or wood wastes.
4. the biomass moulding technique according to claim any one of 1-3, it is characterised in that institute The volume for stating bundled materials is not less than 0.5m3
5. the biomass moulding technique according to claim any one of 1-4, it is characterised in that institute Power is 50-70 DEG C, 15-25MPa under conditions of stating compacting.
6. the biomass moulding technique according to claim any one of 1-5, it is characterised in that institute It is (2-4) to state the ratio between density of biomass moulding material and the bundled materials:1.
7. the biomass moulding material as made from the biomass moulding technique described in claim any one of 1-6.
CN201610186445.2A 2016-03-29 2016-03-29 A kind of biomass moulding technique and the biomass moulding material as made from the technique Pending CN107234828A (en)

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CN201610186445.2A CN107234828A (en) 2016-03-29 2016-03-29 A kind of biomass moulding technique and the biomass moulding material as made from the technique

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Publication Number Publication Date
CN107234828A true CN107234828A (en) 2017-10-10

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102320068A (en) * 2011-09-21 2012-01-18 南京林业大学 A kind of bamboo of improved high-frequency heating/wood reconstituted material manufacturing approach
CN102745370A (en) * 2012-06-20 2012-10-24 钱尧翎 Biomass bale breaking machine
CN202781894U (en) * 2012-09-05 2013-03-13 贵州航天风华精密设备有限公司 Extrusion device for tobacco packer
CN203496323U (en) * 2013-08-28 2014-03-26 河南奥科新能源发展有限公司 Single-side material discharging mechanism for biomass compact forming machine
US20160082683A1 (en) * 2010-09-22 2016-03-24 Forest Concepts. Llc Engineered Woody Biomass Baling System

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160082683A1 (en) * 2010-09-22 2016-03-24 Forest Concepts. Llc Engineered Woody Biomass Baling System
CN102320068A (en) * 2011-09-21 2012-01-18 南京林业大学 A kind of bamboo of improved high-frequency heating/wood reconstituted material manufacturing approach
CN102745370A (en) * 2012-06-20 2012-10-24 钱尧翎 Biomass bale breaking machine
CN202781894U (en) * 2012-09-05 2013-03-13 贵州航天风华精密设备有限公司 Extrusion device for tobacco packer
CN203496323U (en) * 2013-08-28 2014-03-26 河南奥科新能源发展有限公司 Single-side material discharging mechanism for biomass compact forming machine

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Application publication date: 20171010