CN107230619A - The preparation method of enhancement type gallium nitride transistor - Google Patents

The preparation method of enhancement type gallium nitride transistor Download PDF

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Publication number
CN107230619A
CN107230619A CN201610178136.0A CN201610178136A CN107230619A CN 107230619 A CN107230619 A CN 107230619A CN 201610178136 A CN201610178136 A CN 201610178136A CN 107230619 A CN107230619 A CN 107230619A
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China
Prior art keywords
dielectric layers
gallium nitride
si3n4
algan
enhancement type
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CN201610178136.0A
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Chinese (zh)
Inventor
刘美华
孙辉
林信南
陈建国
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Peking University
Peking University Founder Group Co Ltd
Shenzhen Founder Microelectronics Co Ltd
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Peking University
Peking University Founder Group Co Ltd
Shenzhen Founder Microelectronics Co Ltd
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Priority to CN201610178136.0A priority Critical patent/CN107230619A/en
Publication of CN107230619A publication Critical patent/CN107230619A/en
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    • H01L29/66462
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3205Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
    • H01L21/321After treatment
    • H01L21/3215Doping the layers
    • H01L21/32155Doping polycristalline - or amorphous silicon layers
    • H01L29/0623
    • H01L29/42372

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Junction Field-Effect Transistors (AREA)

Abstract

The embodiment of the present invention provides a kind of preparation method of enhancement type gallium nitride transistor.This method includes:Grow the GaN dielectric layers, aluminium gallium nitride alloy AlGaN dielectric layers and silicon nitride Si3N4 dielectric layers of phosphorus doping successively on the surface of silicon substrate;Si3N4 dielectric layers are performed etching;In the AlGaN dielectric layers exposed and remaining Si3N4 dielectric layers upper surface deposited metal layer;Dry etching is carried out downwards along the presumptive area on the surface of the Si3N4 dielectric layers exposed;SiO2 dielectric layers are deposited in gate contact hole and are used as gate medium.The GaN dielectric layers of phosphorus doping on the surface of silicon substrate of the embodiment of the present invention, reduce the surface field of enhancement type gallium nitride transistor, improve pressure-resistant, in addition, the grid doping of enhancement type gallium nitride transistor has phosphorus, have the compound of electronics and hole so that conducting resistance is reduced, and realizes the smaller and pressure-resistant larger technological requirement of conducting resistance of gallium nitride transistor.

Description

The preparation method of enhancement type gallium nitride transistor
Technical field
The present embodiments relate to semiconductor applications, more particularly to a kind of system of enhancement type gallium nitride transistor Make method.
Background technology
With the increasingly increase of efficiently complete circuit for power conversion and system requirements, with low-power consumption and height The power device of fast characteristic has attracted many concerns recently.Gallium nitride GaN is third generation wide bandgap semiconductor Material, because it has big energy gap (3.4eV), high electron saturation velocities (2e7cm/s), height Breakdown electric field (1e10--3e10V/cm), higher heat-conductivity, corrosion-resistant and radiation resistance, high pressure, There is stronger advantage, it is considered to be research is short under high frequency, high temperature, high-power and Flouride-resistani acid phesphatase environmental condition The optimal material of wavelength optoelectronic and high voltagehigh frequency rate high power device.
At present, aluminium gallium nitride alloy/GaN high electron mobility transistor (AlGaN/GaN High Electron Mobility Transistor, abbreviation AlGaN/GaN HEMT) it is study hotspot in power device, Because AlGaN/GaN suppresses to form high concentration, the two-dimensional electron gas (2DEG) of high mobility at knot, Hetero-junctions has good adjustment effect to 2DEG simultaneously.
The conducting resistance of gallium nitride transistor is bigger, and its is pressure-resistant also bigger, but generally those skilled in the art Wish that the conducting resistance of gallium nitride transistor is smaller, it is as far as possible big that its is pressure-resistant, and existing manufacture craft is difficult The conducting resistance for meeting gallium nitride transistor is smaller and pressure-resistant larger.
The content of the invention
The embodiment of the present invention provides a kind of preparation method of enhancement type gallium nitride transistor, with the conducting of reduction Resistance.
The one side of the embodiment of the present invention is to provide a kind of preparation method of enhancement type gallium nitride transistor, Including:
The GaN dielectric layers of phosphorus doping, aluminium gallium nitride alloy AlGaN is grown successively on the surface of silicon substrate to be situated between Matter layer and silicon nitride Si3N4 dielectric layers;
The first area and second area of the Si3N4 dielectric layers are performed etching, to expose described first Region and the second area distinguish corresponding AlGaN dielectric layers;
In the AlGaN dielectric layers and the remaining Si3N4 dielectric layers upper surface deposited metal exposed Layer;
Photoetching, etching are carried out to the metal level, is connect with exposing the Si3N4 dielectric layers and forming ohm Touched electrode;
Dry etching is carried out downwards along the presumptive area on the surface of the Si3N4 dielectric layers exposed, directly To the AlGaN dielectric layers of etch away sections, the Si3N4 dielectric layers being etched away and part institute State AlGaN dielectric layers formation gate contact hole;
Silica SiO2 dielectric layers are deposited in the gate contact hole as gate medium, and the grid to be situated between The surface of matter is less than surface where the aperture in the gate contact hole;
Adulterated in the upper surface deposit polycrystalline silicon PolySi of the SiO2 dielectric layers, and in the PolySi Phosphorus formation grid, to complete the making of the enhancement type gallium nitride transistor.
The preparation method of enhancement type gallium nitride transistor provided in an embodiment of the present invention, on the surface of silicon substrate The GaN dielectric layers of upper phosphorus doping, reduce the surface field of enhancement type gallium nitride transistor, improve increasing Strong type gallium nitride transistor it is pressure-resistant, in addition, the grid doping of enhancement type gallium nitride transistor has phosphorus, meeting There is the compound of electronics and hole so that conducting resistance is reduced, and realizes the conducting resistance of gallium nitride transistor Smaller and pressure-resistant larger technological requirement.
Brief description of the drawings
Fig. 1 is the preparation method flow chart of enhancement type gallium nitride transistor provided in an embodiment of the present invention;
Fig. 2 illustrates to perform the section of enhancement type gallium nitride transistor in manufacturing process of the embodiment of the present invention Figure;
Fig. 3 illustrates to perform the section of enhancement type gallium nitride transistor in manufacturing process of the embodiment of the present invention Figure;
Fig. 4 illustrates to perform the section of enhancement type gallium nitride transistor in manufacturing process of the embodiment of the present invention Figure;
Fig. 5 illustrates to perform the section of enhancement type gallium nitride transistor in manufacturing process of the embodiment of the present invention Figure;
Fig. 6 illustrates to perform the section of enhancement type gallium nitride transistor in manufacturing process of the embodiment of the present invention Figure;
Fig. 7 illustrates to perform the section of enhancement type gallium nitride transistor in manufacturing process of the embodiment of the present invention Figure;
Fig. 8 illustrates to perform the section of enhancement type gallium nitride transistor in manufacturing process of the embodiment of the present invention Figure.
Embodiment
Fig. 1 is the preparation method flow chart of enhancement type gallium nitride transistor provided in an embodiment of the present invention.For To the method in the present embodiment understand the description of system, Fig. 2-Fig. 8 is performs the embodiment of the present invention The diagrammatic cross-section of enhancement type gallium nitride transistor in procedure, as shown in figure 1, methods described includes:
Step S101, GaN dielectric layers, the aluminium gallium nitride alloy for growing on the surface of silicon substrate phosphorus doping successively AlGaN dielectric layers and silicon nitride Si3N4 dielectric layers;
As shown in Fig. 2 growing GaN dielectric layers, the aluminium nitride of phosphorus doping successively on the surface of silicon substrate Gallium AlGaN dielectric layers and silicon nitride Si3N4 dielectric layers, perform the diagrammatic cross-section after step S101 As shown in Fig. 2 wherein, silicon substrate is represented with 20, the GaN dielectric layers of phosphorus doping are represented with 21, AlGaN Dielectric layer represents that silicon nitride Si3N4 dielectric layers are represented with 23 with 22.
Step S102, the first area to the Si3N4 dielectric layers and second area are performed etching, to reveal Go out the first area and the second area distinguishes corresponding AlGaN dielectric layers;
On the basis of Fig. 2, first area and second area to Si3N4 dielectric layers carry out dry etching, The Si3N4 dielectric layers in first area and second area are etched away by dry etching, and etch away Source contact hole is formed after Si3N4 dielectric layers in one region, the Si3N4 etched away in second area is situated between Drain terminal contact hole is formed after matter layer.
The diagrammatic cross-section after step S102 is performed as shown in figure 3, wherein, etching away in first area Si3N4 dielectric layers after the source contact hole that is formed represented with 24, etch away the Si3N4 in second area The drain terminal contact hole formed after dielectric layer is represented with 25.
Step S103, in the AlGaN dielectric layers and the remaining Si3N4 dielectric layers upper table exposed Face deposited metal layer;
Specifically, in the AlGaN dielectric layers 22 and the remaining Si3N4 dielectric layers 23 exposed Upper surface deposited metal layer, performs the diagrammatic cross-section after step S103 as shown in figure 4, wherein, sinking Long-pending metal level is represented with 26.
In embodiments of the present invention, it is described in the AlGaN dielectric layers exposed and remaining described Before the deposited metal layer of Si3N4 dielectric layers upper surface, in addition to:The AlGaN exposed is situated between Matter layer and the remaining Si3N4 dielectric layers upper surface are cleaned.
Specifically, in the AlGaN dielectric layers and the remaining Si3N4 dielectric layers upper surface that expose Before deposited metal layer, using DHF+SC1+SC2 methods to the AlGaN dielectric layers that expose and surplus The remaining Si3N4 dielectric layers upper surface is cleaned, wherein, DHF expressions are cleaned with dilute hydrogen fluoride acid, SC1 represents standardization first step cleaning, and SC2 represents standardization second step cleaning, the time of three cleanings It is 60s.
It is preferred that, the metal level is Ohmic electrode metal, and the Ohmic electrode metal includes two layer medium, The two layer medium is followed successively by titanium and aluminium according to order from top to bottom.
Specifically, using magnetron sputtering membrane process deposited metal layer, metal level is Ohmic electrode metal, Ohmic electrode metal includes two layers, and first layer is titanium, and the second layer is aluminium, and the deposition of first layer titanium is The deposition of second layer aluminium isAnd order and enhancement type gallium nitride from first layer to the second layer Sequence consensus in the diagrammatic cross-section of transistor from top to bottom.
Step S104, to the metal level carry out photoetching, etching, to expose the Si3N4 dielectric layers simultaneously Form Ohm contact electrode;
A part to metal level 26 carries out photoetching, etching, to expose the Si3N4 dielectric layers, does not carve The metal level 26 of eating away respectively constitutes Ohm contact electrode, and the Ohm contact electrode includes source electrode and drain electrode, The diagrammatic cross-section after step S104 is performed as shown in figure 5, wherein, source electrode is represented with 27, is drained Represented with 28.
It is described that photoetching, etching are carried out to the metal level, to expose the Si3N4 dielectric layers and form Europe After nurse contact electrode, in addition to:Under conditions of 600 DEG C, annealed 10 minutes in N2 atmosphere, To form the metal electrode of good Ohmic contact.
It is described to the metal level carry out photoetching, including:The metal level is carried out successively gluing, exposure, Development.
Step S105, done downwards along the presumptive area on the surface of the Si3N4 dielectric layers exposed Method is etched, until the AlGaN dielectric layers of etch away sections, the Si3N4 media being etched away Layer and part the AlGaN dielectric layers formation gate contact hole;
On the basis of Fig. 5, along the surface of the Si3N4 dielectric layers 23 exposed presumptive area to Lower carry out dry etching, until the AlGaN dielectric layers 22 of etch away sections, the presumptive area is less than The surface region of the Si3N4 dielectric layers 23 exposed, the Si3N4 dielectric layers 23 being etched away, With the part AlGaN dielectric layers 22 formation gate contact hole, perform the section after step S105 and show It is intended to as shown in fig. 6, wherein, gate contact hole is represented with 29.
Step S106, in the gate contact hole deposit silica SiO2 dielectric layers as gate medium, And the surface of the gate medium is less than surface where the aperture in the gate contact hole;
On the basis of Fig. 6, the SiO2 dielectric layers are deposited in gate contact hole 29 as gate medium, The diagrammatic cross-section after step S106 is performed as shown in fig. 7, gate medium is represented with 30, and gate medium 30 surface is less than in Fig. 6 surface, i.e. gate medium 30 where the aperture in gate contact hole 29 not by grid Pole contact hole 29 is filled up.
The silica SiO2 dielectric layers that deposited in the gate contact hole are and described as gate medium Before the surface of gate medium is less than surface where the aperture in the gate contact hole, in addition to:Using HCL Clean the gate contact hole.
Step S107, the upper surface deposit polycrystalline silicon PolySi in the SiO2 dielectric layers, and described Adulterate phosphorus formation grid in PolySi, to complete the making of the enhancement type gallium nitride transistor.
On the basis of Fig. 7, in surface deposit polycrystalline silicon PolySi, the PolySi of gate medium 30, and Adulterate phosphorus formation grid in the PolySi, perform the diagrammatic cross-section after step S107 as shown in figure 8, Grid represents with 31, and structure as shown in Figure 8 is cuing open for the enhancement type gallium nitride transistor that is finally fabricated to Face schematic diagram.
The GaN dielectric layers of phosphorus doping on the surface of silicon substrate of the embodiment of the present invention, reduce enhanced nitrogen Change the surface field of gallium transistor, the pressure-resistant of enhancement type gallium nitride transistor is improved, in addition, enhanced The grid doping of gallium nitride transistor has phosphorus, has the compound of electronics and hole so that conducting resistance is reduced, Realize the smaller and pressure-resistant larger technological requirement of conducting resistance of gallium nitride transistor.
In summary, the GaN dielectric layers of phosphorus doping on the surface of silicon substrate of the embodiment of the present invention, reduce The surface field of enhancement type gallium nitride transistor, improves the pressure-resistant of enhancement type gallium nitride transistor, separately Outside, the grid doping of enhancement type gallium nitride transistor has phosphorus, has the compound of electronics and hole so that lead Be powered resistance reduction, realizes the smaller and pressure-resistant larger technological requirement of conducting resistance of gallium nitride transistor.
In several embodiments provided by the present invention, it should be understood that disclosed apparatus and method, It can realize by another way.For example, device embodiment described above is only schematical, For example, the division of the unit, only a kind of division of logic function, can have in addition when actually realizing Dividing mode, such as multiple units or component can combine or be desirably integrated into another system, or Some features can be ignored, or not perform.It is another, shown or discussed coupling each other or Direct-coupling or communication connection can be the INDIRECT COUPLING or communication link of device or unit by some interfaces Connect, can be electrical, machinery or other forms.
The unit illustrated as separating component can be or may not be it is physically separate, make It can be for the part that unit is shown or may not be physical location, you can with positioned at a place, Or can also be distributed on multiple NEs.Can select according to the actual needs part therein or Person's whole units realize the purpose of this embodiment scheme.
In addition, each functional unit in each embodiment of the invention can be integrated in a processing unit, Can also be that unit is individually physically present, can also two or more units be integrated in a list In member.Above-mentioned integrated unit can both be realized in the form of hardware, it would however also be possible to employ hardware adds software The form of functional unit is realized.
The above-mentioned integrated unit realized in the form of SFU software functional unit, can be stored in a computer In read/write memory medium.Above-mentioned SFU software functional unit is stored in a storage medium, including some fingers Order is to cause a computer equipment (can be personal computer, server, or network equipment etc.) Or processor (processor) performs the part steps of each embodiment methods described of the invention.And it is foregoing Storage medium include:USB flash disk, mobile hard disk, read-only storage (Read-Only Memory, ROM), Random access memory (Random Access Memory, RAM), magnetic disc or CD etc. are various can be with The medium of store program codes.
Those skilled in the art can be understood that, for convenience and simplicity of description, only with above-mentioned each The division progress of functional module is for example, in practical application, as needed can divide above-mentioned functions With by different functional module completions, i.e., the internal structure of device is divided into different functional modules, with Complete all or part of function described above.The specific work process of the device of foregoing description, can be with With reference to the corresponding process in preceding method embodiment, it will not be repeated here.
Finally it should be noted that:Various embodiments above is merely illustrative of the technical solution of the present invention, rather than right It is limited;Although the present invention is described in detail with reference to foregoing embodiments, this area it is common Technical staff should be understood:It can still modify to the technical scheme described in foregoing embodiments, Or equivalent substitution is carried out to which part or all technical characteristic;And these modifications or replacement, and The essence of appropriate technical solution is not set to depart from the scope of various embodiments of the present invention technical scheme.

Claims (6)

1. a kind of preparation method of enhancement type gallium nitride transistor, it is characterised in that including:
The GaN dielectric layers of phosphorus doping, aluminium gallium nitride alloy AlGaN is grown successively on the surface of silicon substrate to be situated between Matter layer and silicon nitride Si3N4 dielectric layers;
The first area and second area of the Si3N4 dielectric layers are performed etching, to expose described first Region and the second area distinguish corresponding AlGaN dielectric layers;
In the AlGaN dielectric layers and the remaining Si3N4 dielectric layers upper surface deposited metal exposed Layer;
Photoetching, etching are carried out to the metal level, is connect with exposing the Si3N4 dielectric layers and forming ohm Touched electrode;
Dry etching is carried out downwards along the presumptive area on the surface of the Si3N4 dielectric layers exposed, directly To the AlGaN dielectric layers of etch away sections, the Si3N4 dielectric layers being etched away and part institute State AlGaN dielectric layers formation gate contact hole;
Silica SiO2 dielectric layers are deposited in the gate contact hole as gate medium, and the grid to be situated between The surface of matter is less than surface where the aperture in the gate contact hole;
Adulterated in the upper surface deposit polycrystalline silicon PolySi of the SiO2 dielectric layers, and in the PolySi Phosphorus formation grid, to complete the making of the enhancement type gallium nitride transistor.
2. according to the method described in claim 1, it is characterised in that described in the AlGaN exposed Before dielectric layer and the remaining Si3N4 dielectric layers upper surface deposited metal layer, in addition to:
The AlGaN dielectric layers exposed and the remaining Si3N4 dielectric layers upper surface are carried out Cleaning.
3. method according to claim 2, it is characterised in that the metal level is Ohmic electrode gold Category, the Ohmic electrode metal include two layer medium, the two layer medium according to order from top to bottom according to Secondary is titanium and aluminium.
4. method according to claim 3, it is characterised in that described that light is carried out to the metal level Carve, etch, to expose the Si3N4 dielectric layers and be formed after Ohm contact electrode, in addition to:
Under conditions of 600 DEG C, annealed 10 minutes in N2 atmosphere.
5. method according to claim 4, it is characterised in that described in the gate contact hole Deposition silica SiO2 dielectric layers connect as gate medium, and the surface of the gate medium less than the grid Before surface where the aperture of contact hole, in addition to:
The gate contact hole is cleaned using HCL.
6. method according to claim 5, it is characterised in that described that light is carried out to the metal level Carve, including:
Carry out gluing, exposure, development successively to the metal level.
CN201610178136.0A 2016-03-25 2016-03-25 The preparation method of enhancement type gallium nitride transistor Pending CN107230619A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108417481A (en) * 2018-03-22 2018-08-17 京东方科技集团股份有限公司 Processing method, thin film transistor (TFT) and the display device of silicon nitride dielectric layer

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102709321A (en) * 2012-04-20 2012-10-03 程凯 Enhanced switch element and production method thereof
CN104821340A (en) * 2014-02-05 2015-08-05 瑞萨电子株式会社 Semiconductor device
CN105047692A (en) * 2015-06-10 2015-11-11 上海新傲科技股份有限公司 Substrate for high-electron-mobility transistor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102709321A (en) * 2012-04-20 2012-10-03 程凯 Enhanced switch element and production method thereof
CN104821340A (en) * 2014-02-05 2015-08-05 瑞萨电子株式会社 Semiconductor device
CN105047692A (en) * 2015-06-10 2015-11-11 上海新傲科技股份有限公司 Substrate for high-electron-mobility transistor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108417481A (en) * 2018-03-22 2018-08-17 京东方科技集团股份有限公司 Processing method, thin film transistor (TFT) and the display device of silicon nitride dielectric layer
CN108417481B (en) * 2018-03-22 2021-02-23 京东方科技集团股份有限公司 Processing method of silicon nitride dielectric layer, thin film transistor and display device

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