A kind of Biofibre facial mask base fabric and Biofibre facial mask
Technical field
The invention belongs to technical field of skin care, and in particular to a kind of Biofibre facial mask base fabric, also relate to one kind
Using the Biofibre facial mask of the mask substrate.
Background technology
Facial mask be apply or spread on human facial skin surface, taken off after a period of time from, clean or retain, play concentration shield
The skin care item of reason or cleaning action;Effect of facial mask mainly has whitening, moisturizing, promotes circulation, tensioning the skin etc..As people disappear
Take the abundant and maturation of theory, facial mask industry obtains rapid growth.
Facial mask can be divided into no base fabric type and base fabric type according to occupation mode.At present, facial mask more than 70% on the market
It is base fabric type, this kind of facial mask is the nutrient solution for being aided with different-effect using fiber base cloth as carrier, improves skin for nutritional ingredient
Infiltration rate and uptake, and rapidly improve skin care effect.Nutrient solution main component is to extract from plant, animal or day
The active ingredients such as right mineral, refine concentration using corresponding technique and technology and form, major function is whitening, moisturizing and provides flesh
Nutrition and moisture required for skin, delay skin aging.
Base fabric type facial mask is more using non-woven cloth as base fabric, and processing technology has hot rolling, spunbond, spun lacing, melt-blown etc., wherein with water
Spunlaced nonwoven application is most, because its feel is soft, quality can people, porosity be high, moisture retention is good, can carry facial mask big
The nutrient solution of amount, it is ensured that skin is fully absorbed.Commercially available non-woven mask substrate it is main with cotton fiber, viscose rayon, CUP,
Wood pulp cellulose is primary raw material, and a small number of products are using cocoon fiber, alginate fibre etc..
With the development of facial mask industry, mask substrate develops from single carrier function towards functionalization direction, and base fabric is fine
The performance of dimension is more good more can promote absorption of nutrient ingredients, and the effect of nutrient solution is got over and can played, and skin circulation also can and then improve.But
It is that existing cotton fiber, viscose rayon, CUP base fabric etc. are developed by clothing fabric, are needed in production process
Using substantial amounts of chemical reagent (such as adhesive), substantially remained in facial mask more;And the pure biological fiber such as tencel fiber exists
It is also required to add substantial amounts of anticorrosive additive when using, the poor biocompatibility of these materials easily causes skin sensitivity, thorn
Pain and redness, contact skin, which is used for a long time, skin is suffered damage.
The content of the invention
It is an object of the invention to provide a kind of Biofibre facial mask base fabric.
Second object of the present invention is to provide a kind of Biofibre facial mask using above-mentioned mask substrate.
To achieve these goals, the technical solution adopted in the present invention is:
A kind of Biofibre facial mask base fabric, is prepared from by the method comprised the following steps:
1) PLA is dissolved in chloroform, the spinning solution that mass concentration is 20%-25% is made;Using the spinning solution
Electrostatic spinning is carried out, acid fiber by polylactic felt is obtained;
2) chitosan solution for being made that mass concentration is 2.0%-2.5% in acetic acid aqueous solution is dissolved chitosan in, after
Mass ratio according to polyvinyl alcohol and chitosan is 0.2-0.3:1 ratio adds polyvinyl alcohol, is heated to 65-70 DEG C of stirring molten
Solution, obtains maceration extract;
Dipping is modified:By step 1) gained acid fiber by polylactic felt immersed in the maceration extract, and negative pressure deaeration 10-20s takes out
Extrusion surplus liquid and drying, obtain composite fibrofelt afterwards;
3) by step 2) gained composite fibrofelt carry out spun lacing reinforcing at room temperature, make its thickness be 0.35-0.45mm, face
Density is 30-40g/m2, produce.
Step 1) in, the parameter of the electrostatic spinning is:Filament mouth is No. 6 or No. 8 syringe needles, and spinning voltage is 15-25kV,
Spinning pole span is 10-15cm, and spinning flow velocity is 0.2-0.5ml/h.
Step 2) in, the mass concentration of acetic acid is 5%-10% in the acetic acid aqueous solution.
Step 2) in, the modified number of times of dipping is at least one times so that step 2) gained composite fibrofelt is relative to poly- breast
The weightening of sour fibrofelt is in 15%-20%.
Step 2) in, the temperature of the drying is 60-65 DEG C, and drying time is 12-24h.
Step 2) in, extrusion surplus liquid refers to carry out jam through roll, and the pick-up of each jam is 70%-80%.
Step 3) in, the spun lacing pressure that the spun lacing is reinforced is 15-20bar, a diameter of 0.08- of liquid drugs injection hole exits
0.12mm。
A kind of Biofibre facial mask using above-mentioned Biofibre facial mask base fabric.
In the Biofibre facial mask base fabric of the present invention, the macromolecular structure of chitosan makes it have antibacterial mite-removing, anti-inflammatory
Purulence, relieve pain, go scar, reduce wound bed fluid separate out and beneficial to wound site healing etc. excellent biocompatibility.But, due to
Chitosan deliquescent limitation in itself, it is difficult to find suitable spin solvent, the spinning difficulty of chitosan in itself is larger;It is simultaneously pure
Chitin fiber mechanical property it is poor, and price is higher, is not suitable for being directly used as facial mask basic.The biological fiber face of the present invention
Film base fabric, by the use of the acid fiber by polylactic obtained by electrostatic spinning as core, utilizes the good processing characteristics of PLA and PLA
Fiber excellent mechanical property and dimensional stability, make it as timbering material, composite is had excellent processing characteristics
And mechanical property;It is modified by impregnating so that polylactic acid fiber surface adheres to the mixed coating of chitosan and polyvinyl alcohol, gained
In composite, chitosan is contacted as surface layer with human skin, can give full play to its biocompatibility and antibiotic property;On a small quantity
Polyvinyl alcohol and chitosan blend, the film forming of chitosan and the hydrophily of chitosan film layer can be further improved, so as to carry
High mask substrate holds liquid energy power;The reinforcing of fibrofelt is carried out by spun lacing method, gained mask substrate is soft, drapability
It is good,
The Biofibre facial mask base fabric of the present invention, is mainly prepared from, chitosan and PLA by chitosan and PLA
Be bio-based macromolecular material, good biocompatibility, gained mask substrate need not add extra chemical preservative, its with
Human skin is in contact, and will not produce allergy, infection and red and swollen reaction, on the contrary using chitosan surface layer have antibacterial, anti-inflammatory,
The performance of analgesic, promotes facial microtrauma healing;Mechanical property is good, there is preferable ultimate strength under dry state and hygrometric state,
It is easy to process and uses;Hold liquid energy power strong, more nutrient solutions can be carried so that the nutritional ingredient of nutrient solution can be more rapid
By percutaneous absorption;Good permeability, the eupnea of face skin is not influenceed, and comfortableness is high.In addition, the mask substrate master of the present invention
It is chitosan and PLA to want composition,, will not be to ring as used disposable mask substrate with good biodegradability
Border produces influence.
Embodiment
With reference to embodiment, the present invention is described further.
In embodiment, PLA used is PLLA, and molecular weight is 3.0-5.0 ten thousand.Chitosan used
Deacetylation is 95%, and molecular weight is 4 × 105-6×105.The alcoholysis degree of polyvinyl alcohol used is 86%, and molecular weight is 1.6-
2.0 ten thousand.
Embodiment 1
The Biofibre facial mask base fabric of the present embodiment, is prepared from by following methods:
1) PLA is dissolved in chloroform, the spinning solution that PLA mass concentration is 20% is made;Using the spinning
Liquid carries out electrostatic spinning, and the parameter of the electrostatic spinning is:Filament mouth is No. 6 syringe needles, and spinning voltage is 20kV, spinning pole span
(distance of receiver board and syringe needle) is 12cm, and spinning flow velocity is 0.3ml/h;It is true under the conditions of 60 DEG C after electrostatic spinning terminates
Sky is dried, and obtains acid fiber by polylactic felt;
After testing, fibre diameter is 100-400nm in gained acid fiber by polylactic felt;
2) acetic acid aqueous solution that mass concentration is 5% is prepared;Dissolve chitosan in acetic acid aqueous solution that quality is made is dense
Spend the chitosan solution for 2.0%, after according to polyvinyl alcohol and chitosan mass ratio be 0.2:1 ratio adds polyethylene
Alcohol, is heated to 65 DEG C of stirring and dissolvings, and standing and defoaming obtains maceration extract;
Dipping is modified:By step 1) gained acid fiber by polylactic felt immersed in the maceration extract, negative pressure deaeration 10s, after taking-up
Carry out jam (extrusion surplus liquid) through roll, the pick-up of the jam is 70%, after 24h is dried under the conditions of 60 DEG C;
Repeat above-mentioned dipping and be modified operation to obtaining weightening of the composite fibrofelt relative to acid fiber by polylactic felt 15%;
3) by step 2) gained composite fibrofelt carries out spun lacing reinforcing at room temperature, and the spun lacing pressure that the spun lacing is reinforced is
15bar, a diameter of 0.08mm of liquid drugs injection hole exits, it is that 0.35mm, surface density are 30g/m to make spun lacing products obtained therefrom thickness2, produce institute
State Biofibre facial mask base fabric.
Embodiment 2
The Biofibre facial mask base fabric of the present embodiment, is prepared from by following methods:
1) PLA is dissolved in chloroform, the spinning solution that PLA mass concentration is 23% is made;Using the spinning
Liquid carries out electrostatic spinning, and the parameter of the electrostatic spinning is:Filament mouth is No. 6 syringe needles, and spinning voltage is 15kV, spinning pole span
(distance of receiver board and syringe needle) is 10cm, and spinning flow velocity is 0.2ml/h;It is true under the conditions of 60 DEG C after electrostatic spinning terminates
Sky is dried, and obtains acid fiber by polylactic felt;
After testing, fibre diameter is 100-400nm in gained acid fiber by polylactic felt;
2) acetic acid aqueous solution that mass concentration is 7% is prepared;Dissolve chitosan in acetic acid aqueous solution that quality is made is dense
Spend the chitosan solution for 2.3%, after according to polyvinyl alcohol and chitosan mass ratio be 0.2:1 ratio adds polyethylene
Alcohol, is heated to 70 DEG C of stirring and dissolvings, and standing and defoaming obtains maceration extract;
Dipping is modified:By step 1) gained acid fiber by polylactic felt immersed in the maceration extract, negative pressure deaeration 15s, after taking-up
Carry out jam (extrusion surplus liquid) through roll, the pick-up of the jam is 80%, after 12h is dried under the conditions of 65 DEG C;
Repeat above-mentioned dipping and be modified operation to obtaining weightening of the composite fibrofelt relative to acid fiber by polylactic felt 17%;
3) by step 2) gained composite fibrofelt carries out spun lacing reinforcing at room temperature, and the spun lacing pressure that the spun lacing is reinforced is
20bar, a diameter of 0.10mm of liquid drugs injection hole exits, it is that 0.40mm, surface density are 35g/m to make spun lacing products obtained therefrom thickness2, produce institute
State Biofibre facial mask base fabric.
Embodiment 3
The Biofibre facial mask base fabric of the present embodiment, is prepared from by following methods:
1) PLA is dissolved in chloroform, the spinning solution that PLA mass concentration is 25% is made;Using the spinning
Liquid carries out electrostatic spinning, and the parameter of the electrostatic spinning is:Filament mouth is No. 8 syringe needles, and spinning voltage is 25kV, spinning pole span
(distance of receiver board and syringe needle) is 15cm, and spinning flow velocity is 0.4ml/h;It is true under the conditions of 60 DEG C after electrostatic spinning terminates
Sky is dried, and obtains acid fiber by polylactic felt;
After testing, fibre diameter is 100-400nm in gained acid fiber by polylactic felt;
2) acetic acid aqueous solution that mass concentration is 10% is prepared;Dissolve chitosan in acetic acid aqueous solution that quality is made is dense
Spend the chitosan solution for 2.5%, after according to polyvinyl alcohol and chitosan mass ratio be 0.3:1 ratio adds polyethylene
Alcohol, is heated to 70 DEG C of stirring and dissolvings, and standing and defoaming obtains maceration extract;
Dipping is modified:By step 1) gained acid fiber by polylactic felt immersed in the maceration extract, negative pressure deaeration 20s, after taking-up
Carry out jam (extrusion surplus liquid) through roll, the pick-up of the jam is 75%, after 18h is dried under the conditions of 60 DEG C;
Repeat above-mentioned dipping and be modified operation to obtaining weightening of the composite fibrofelt relative to acid fiber by polylactic felt 20%;
3) by step 2) gained composite fibrofelt carries out spun lacing reinforcing at room temperature, and the spun lacing pressure that the spun lacing is reinforced is
20bar, a diameter of 0.12mm of liquid drugs injection hole exits, it is that 0.45mm, surface density are 40g/m to make spun lacing products obtained therefrom thickness2, produce institute
State Biofibre facial mask base fabric.
Experimental example 1
Mask substrate requires that mask substrate has in process, it is necessary to cut into face shape by complete coiled material
Certain strength;In use, mask substrate, which soaked, applies after Essence in face, has slight adjustment of pullling, therefore
It is required that the mask substrate under hygrometric state is by certain intensity and elongation.
This experimental example is detected to the mechanical property of Biofibre facial mask base fabric obtained by embodiment 1-3, as a result such as the institute of table 1
Show.
Detection method:Using electronics strength tester, with reference to the fracture under GB/T2428.3-2010 standardized test specimen dry and wet states
Strength and elongation at break;Sample size is 5cm × 30cm (it is 20cm that length, which is more than clamping gauge), and draw speed is 100mm/
min;According to GB/T6529-1008 method by sample damping (hygrometric state).
The mechanics properties testing result of Biofibre facial mask base fabric obtained by the embodiment 1-3 of table 1
Note:Ultimate strength and elongation at break in table 1 are the average value of longitudinal direction and transverse test result.
As it can be seen from table 1 there is good mechanical mechanics property under present invention gained Biofibre facial mask base fabric dry state,
It is easy to machine-shaping;Under hygrometric state, ultimate strength and elongation at break are also maintained at optimal level, and user was using
Tearing in journey, which is gently dragged, will not cause it to rupture or deform, and can maintain its integrality.
Experimental example 2
This experimental example to Biofibre facial mask base fabric obtained by embodiment 1-3 hold fluidity energy and gas permeability is detected, tie
Fruit is as shown in table 2.
Wherein, regain refers to that contained humidity weight in material accounts for the percentage of drying material weight, with reference to GB/T6503-
Regain experimental method is measured in 2008 standards.
Liquid holdup is to hold the mass ratio of the quality with nutrient solution and base fabric by mask substrate to evaluate to hold liquid energy power.Test
Method:It is m by weight1Sample tiling immersion the special Essence of facial mask in, make its fully contact dipping 10s, sample is taken out
Hanging afterwards to place 1min, no liquid drips, weighs and be designated as m2;Calculate liquid holdup (%)=(m2-m1)/m1× 100%.
Gas permeability is to influence the key factor of facial mask comfortableness, and with reference to GB/T5453-2007 tests, pressure is 100Pa, is surveyed
Examination area is 20cm2。
Biofibre facial mask base fabric holds fluidity energy and gas permeability testing result obtained by the embodiment 1-3 of table 2
From table 2 it can be seen that the regain of embodiment 1-3 Biofibre facial mask base fabric holds liquid energy power more than 15%
It is 14-15 times of base fabric quality.The mass ratio of facial mask in the market, base fabric and nutrient solution is 1:In the range of 10-11, this hair
Bright Biofibre facial mask base fabric fully meets above-mentioned requirements;The facial mask good permeability of the present invention, does not influence face during use
The eupnea of portion's skin, will not feel sultry and scratchy, with good patch skin and comfortableness.
Experimental example 3
This experimental example detects that detection method is joined to the anti-microbial property of Biofibre facial mask base fabric obtained by embodiment 1-3
Antibacterial experiment is carried out according to succusion in GB/T20944.3-2008 standards, as a result as shown in table 3.
The bacteriostasis property testing result of Biofibre facial mask base fabric obtained by the embodiment 1-3 of table 3
Bacteriostasis rate (%) |
Embodiment 1 |
Embodiment 2 |
Embodiment 3 |
Staphylococcus aureus |
99.6 |
99.3 |
99.9 |
Escherichia coli |
94.3 |
94.5 |
94.8 |
Candida albicans |
98.4 |
98.0 |
97.9 |
From table 3 it can be seen that embodiment 1-3 Biofibre facial mask base fabric to staphylococcus aureus, Escherichia coli and
The bacteriostasis rate of Candida albicans is more than 94%.Test result indicates that, Biofibre facial mask base fabric of the invention has good
Biocidal property, bacteria breed can be suppressed, so as to increase the anti-microbial property of facial mask, face skin is protected.