CN105644098A - Unidirectional moisture-guiding perspiration fabric and preparation method thereof - Google Patents

Unidirectional moisture-guiding perspiration fabric and preparation method thereof Download PDF

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CN105644098A
CN105644098A CN201610021761.4A CN201610021761A CN105644098A CN 105644098 A CN105644098 A CN 105644098A CN 201610021761 A CN201610021761 A CN 201610021761A CN 105644098 A CN105644098 A CN 105644098A
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sweat
layer
raw material
finishing agent
singly
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CN105644098B (en
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贾右兵
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Shanghai Xiaolanxiang Garment Co ltd
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Shanghai Ximian Garment Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • D06M13/463Compounds containing quaternary nitrogen atoms derived from monoamines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/022 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/73Hydrophobic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/18Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38Polyurethanes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses a unidirectional moisture-guiding perspiration fabric and a preparation method thereof. The unidirectional moisture-guiding perspiration fabric comprises an inner layer and an outer layer, wherein the inner layer is a polypropylene fiber layer, and the outer layer is a perspiration moisture guiding layer. According to the single-guide perspiration fabric, the inner layer is the polypropylene fiber layer, the outer layer is the perspiration moisture guiding layer, and sweat of a human body is directly absorbed by a water absorption point on the outer side of the polypropylene fiber layer in use, is rapidly guided to the inner side of the water absorption point and is rapidly transferred and diffused by virtue of the perspiration moisture guiding layer connected with the inner side of the water absorption point, so that a unidirectional moisture-guiding quick-drying spandex knitted fabric has the efficacies of ventilation, moisture guiding, dryness and the like.

Description

Singly lead sweat absorption fabric and preparation method thereof
Technical field
The present invention relates to a kind of fabric, be specifically related to one and singly lead sweat absorption fabric and preparation method thereof.
Background technology
Moisture absorbing and sweat releasing textile is also known as absorbing fast-drying textile. It is by being directed to fabric appearance from inner textile layer rapidly the sweat on skin, and is dispersed in air, thus keeping base layers to be in dry condition all the time, makes human body sensory comfortable.
Moisture absorbing and sweat releasing textile is mainly used in the dress ornaments such as gym suit, easy dress, underwear. Owing to it can solve sultry and viscous body problem of perspiring, the interior weather of scalable clothing so that clothing have had the characteristic of meeting " breathing ", therefore also have the title of " textile that can breathe ".
Make fabric have moisture absorption sweat discharging functions to be set about by following direction: one is start with from the change of fibrous raw material is structurally-modified, improves its hygroscopicity; Two is structurally-modified by the physical aspect of fibrous material, so as to improve its moisture absorption by capillary effect and lead wet performance, such as the application of the fiber Specializing Techniquess such as hollow, groove, different cross section, surface micropore, fine-denier; Three is designed by rational fabric structure; Four is adopt suitable Final finishing technology (including top finish processing); Also have and just can be by and bibulous fiber blend, be exactly the combination of physical method, chemical method and physico-chemical process in a word.
Coolmax is a kind of functional fiber developed in 1986 by du pont company. Spandex cross section is flat " ten " font, so its surface is the formation of four road grooves, namely 4 perspire pipeline. This four flat groove structures can make adjacent fiber be prone to draw close, and forms the tiny wicking pipeline that many capillary effects are strong, has the function that sweat can drain into rapidly fabric face. Meanwhile, the specific surface area of this fiber is than same fineness typical circular cross-section fibers big 19.8%, thus after sweat drains into this fabric surface, energy rapid evaporation is in ambient atmosphere. The different in nature cross section of this fiber makes to there is very big space between fiber, so having good breathability, therefore this structure of spandex imparts the performance of this fabric wet-guide quick-drying.
Thermocool, is the product of European Company ADVANSA, and in athletic activities or in the weather of sweltering heat, ADVANSAThermoCool relatively other material is compared and can be evaporated wet steam quickly.This fibrous material just have employed the mode increasing surface area at the beginning of design, and the fiber on many fine grooves surface helps dampness rapidly from skin conductance to web surface, and doughnut makes air circulation strengthen and then heat energy is all concentrated consumption in evaporation process, reaches the maximization of evaporative cooling effect whereby. In arctic weather or after being moved through, the fiber of hollow becomes heat rejection medium, and the health of its protection wearer and muscle are to prevent post exercise cold and heat.
This invention address that exploitation is a kind of and brand-new singly lead sweat absorption fabric, meet the present people demand to multifunctional fabric.
Summary of the invention
The technical problem to be solved in the present invention is to provide one and singly leads sweat absorption fabric and preparation method thereof.
For solving the problems referred to above, the present invention adopts the following technical scheme that
One singly leads sweat absorption fabric, is made up of internal layer and two parts of outer layer, and its internal layer is polypropylene layer, and outer layer is Sweat Exhaust & Moisture Conductivity layer.
Preferably,
Described Sweat Exhaust & Moisture Conductivity layer is weaved by the raw material of following weight parts and is formed: 30-45 part Coolmax fiber, 55-70 part cotton fiber, 0.5-4.5 part spandex.
Described Sweat Exhaust & Moisture Conductivity layer is weaved by the raw material of following weight parts and is formed: 30-45 part Coolmax fiber, 55-70 part regenerated celulose fibre, 0.5-4.5 part spandex.
Described Sweat Exhaust & Moisture Conductivity layer is weaved by the raw material of following weight parts and is formed: 30-45 part Thermocool fiber, 55-70 part regenerated celulose fibre, 0.5-4.5 part spandex.
Described regenerated celulose fibre, including CUP, chitin fiber, bamboo fibre, Modal fiber, Tencel fiber etc.
In a word, all fibers again recycled for raw material with cellulose all can be referred to as regenerated celulose fibre. The development of regenerated celulose fibre can be divided into three phases generally, defines three generation products. The first generation was 20 beginnings of the century is solve the common viscose fiber that shortage of cotton emerges. The second filial generation is to start to realize the koplon of industrialized production the 1950's, the Modal fiber of production that its major product includes the toramomen (rear called after Polynosic) of Japan's research and development and the change type high-wet-modulus fibre HWM of American R & D and Lenzin company adopts new technology in the later stage eighties. In the later stage sixties, owing to closing developing rapidly of fine production technology, sufficient raw and with low cost, synthetic fibers have greatly impacted the market position of regenerated celulose fibre. Many research institutions and enterprise have increasingly focused on the development and application of shin-gosen. During this period, the development of world's regenerated celulose fibre tends to stagnating. Third generation product is with the short fine Tencel (tencel) of the release nineties in 20th century, long filament Newcell for representative. Realized, advocate the impact of the factors such as nature by health environment-friendly, regenerated celulose fibre has been had new understanding by people, the physicochemical property of a new generation's regenerated celulose fibre there has also been and is sufficiently improved, and therefore, the application of regenerated celulose fibre has reappeared swift and violent growth.
Tencel fiber is also known as " tencel ", also known as " Lyocell (lyocell) ". It is the wood pulp based on coniferous tree, water and solvent NMMO (4-methyhnorpholine-N-oxide) mixing, heating is to being completely dissolved, will not producing any derivant and chemical action, the direct fabrics through remove impurity in course of dissolution, its molecular structure is simple carbohydrate. Tencel fiber can decompose completely in earth, environmentally safe;It addition, the amine oxide solvent that uses is completely harmless to human body in producing, be almost entirely capable of reclaiming, can Reusability, produce the cellulosic molecule contained by Raw pulp and do not play chemical change, no coupling product, outside without garbage discharge factory, is environmental protection or green fiber. This fabric has good hygroscopicity, comfortableness, drapability and stiffness and dyeability is good, in addition again can with cotton, hair, fiber crops, nitrile, the blending such as wash, it is possible to RING SPINNING, air spinning, cored are spun, and are spun into various cotton and wool type yarn, covering yarn etc. Therefore this fiber can not only apply in the fabric production of underwear, and the fabric for coat ready-made clothes uses also very extensive.
Modal fiber, also known as weaving cellulose modal, Modal fibre, is a kind of brand-new cellulose fibre, and the raw material of Modal fiber comes from the timber of the Nature, can natural degradation after using. Owing to this fibrid is that to adopt native cellulose be raw material, there is biological degradability, and in fiber production process, do not produce the serious environment pollution problem of similar viscose rayon, be the novel environment-friendlyfiber fiber of 21 century. Modal fiber price is the half of Tencel fiber, is second filial generation regenerated celulose fibre. Modal fiber with multiple fiber blend, intertexture, can play the feature of respective fiber, reach effect more preferably. Modal fabric lining moisture pick-up properties, permeability are better than pure cotton fabric, and it is soft, and drapability is good, comfortable and easy to wear, bright in color, are a kind of natural mercerising fabrics. Just because of modal fabric is comfortable, good springiness, the characteristics such as breathability is good, it has been used in underwear production by much well-known underwear brand as seven wolves, fibril bird, top-notch player, next, the Davidarchy of Fu Ni etc., also has increasing domestic consumer to like Modal underwear. But also because these characteristics, it is less that modal fabric is used in ready-made clothes, because it is relatively inaccessible to the effect that sizing is moulding.
Bamboo fibre is the New Regenerated Cellulosic Fibers of the development of China's self-developing industrialization after soybean fiber, and bamboo fibre divides bamboo cellulose fiber and bamboo fiber. Bamboo cellulose fiber is with Phyllostachys pubescens Mazei ex H.de Lebaie for raw material, adds functional aid, process through wet spinning in bamboo pulp. Bamboo fiber is the fiber produced after natural biological preparation processes by Phyllostachys pubescens Mazei ex H.de Lebaie. As the bamboo pulp of spinning material, deriving from the fresh bamboo of short-term training, resource is very abundant. Its garbage soil buries, burn and do not result in environmental pollution, belongs to environmental protection fiber, meets the demand of green consumption. It is similar with viscose rayon that bamboo fibre is performance, and bamboo fiber has good moisture absorption, breathability, and its drapability and dyeability are also relatively good, have the gloss as silkworm silk and feel, and have antibacterial, deodorant, anti-ultraviolet function. These natural characteristics of bamboo fibre make its exclusive seat in the weaving of underclothes fabric. Along with the partially healthy naturalization of consumer spending idea, bamboo fibre receives pursuing of Ge great underwear production firm.
Chitin is widely present in the arthropodan shells such as the aquatic products such as shrimp, Trionyx sinensis Wiegmann and insecticide, exists in the cell wall of mushroom, algae. Viscose chitin fibre is to mix, with chitin, chitosan, the fiber made by conventional wet spinning process with cellulose. It has biological activity, biological degradability and biocompatibility, has excellent moisture-absorbing moisture-keeping function. Adopt chitin fiber to take the function of deodorization with cotton blended fabric, in clothes decoration application and development, have vast potential for future development.
CUP is a kind of regenerated celulose fibre, it is to be dissolved in the liquor ammoniae fortis of Copper hydrate or alkaline cupric salt by natural cellulosic feedstocks such as cotton linters, it is made into spinning liquid, in coagulating bath, CUP element molecular chemistry thing disintegrating and regeneration goes out cellulose, and namely the hydrate cellulose of generation obtains CUP through post-treatment. The cross section of CUP is rounded, and without skin-core structure, fiber can bear high elongation, and prepared monofilament is relatively thin, so fabric is soft, gloss is soft, has silky touch. The hygroscopicity of CUP is close with viscose fiber, and its official regain is 11%, and when general atmosphere, regain can reach 12%--13%, and under identical dyeing condition, the dyeing affinity of CUP is big compared with viscose fiber, paints deeper. The dry strong and viscose fiber of CUP is close, but wet is higher than by force viscose fiber, and wearability is also superior to viscose rayon. Owing to fiber is soft, gloss is suitable for, and commonly uses and makees high-grade silk weaving or knitted fabric. Its wearability is more excellent, good hygroscopicity, great pendency sense, and wearability is similar to silk, meets environmental protection dress ornament trend.
Described Sweat Exhaust & Moisture Conductivity layer raw material obtains through hydrophilizing treatment step.
Described hydrophilizing treatment step is impregnated in hydrophilic finishing agent by described Sweat Exhaust & Moisture Conductivity layer raw material.
Described hydrophilic finishing agent is made up of the raw material of following mass percent: 0.3-0.7% hydrophilic finishing agent, 0.1-0.5% cross-linking agent, 0.1-0.5% penetrating agent, surplus are water.
Preferably, described hydrophilic finishing agent is polyvinylpyrrolidone and/or polyacrylamide.
Preferably, described cross-linking agent is made up of 40-60wt%2,3-dyhydrobutanedioic acid and 40-60wt%3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid.
Preferably, described penetrating agent is made up of 40-60wt% dodecyldimethylammonium hydroxide inner salt and 40-60wt%3-sulfopropyl dodecyldimethylammonium hydroxide inner salt.
Described polypropylene layer is prepared from by polypropylene, and described polypropylene obtains through water-proofing treatment step.
Described water-proofing treatment is by using waterproof finishing agent that polypropylene is carried out water-proofing treatment.
Described waterproof finishing agent is made up of the raw material of following mass percent: 0.5-1.5%1,1,1,3,3,3-hexafluoro-2-propanol, 98.5-99.5% are water.
Present invention also offers the above-mentioned preparation method singly leading sweat absorption fabric, comprise the following steps:
(1) prepare waterproof finishing agent, polypropylene is carried out water-proofing treatment;
(2) prepare hydrophilic finishing agent, Sweat Exhaust & Moisture Conductivity layer raw material is carried out hydrophilic treated;
(3) Sweat Exhaust & Moisture Conductivity layer raw material and polypropylene are weaved, obtain described singly leading sweat absorption fabric.
Preferably, described step (1) is under 100-110 DEG C of condition, and polypropylene impregnates 20-30min in waterproof finishing agent, after dehydration, dries 5-10min under 80-100 DEG C of condition.
Preferably, described step (2) is under 100-110 DEG C of condition, and Sweat Exhaust & Moisture Conductivity layer raw material is impregnated 20-30min in hydrophilic finishing agent, after dehydration, dries 5-10min under 80-100 DEG C of condition.
Preferably, described step (3) singly leads polypropylene layer grammes per square metre in sweat absorption fabric is 50-150g/m2, Sweat Exhaust & Moisture Conductivity layer grammes per square metre is 150-250g/m2��
Concrete, in the present invention:
HFIP, No. CAS: 920-66-1, its structural formula is as follows:
2,3 dihydroxybutanedioic acid, No. CAS: 526-83-0.
3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, No. CAS: 77-92-9.
Dodecyldimethylammonium hydroxide inner salt, No. CAS: 683-10-3.
3-sulfopropyl dodecyldimethylammonium hydroxide inner salt, No. CAS: 14933-08-5.
Polyvinylpyrrolidone, No. CAS: 9003-39-8.
The present invention singly leads sweat absorption fabric, its internal layer is polypropylene layer, outer layer is Sweat Exhaust & Moisture Conductivity layer, suction point outside polypropylene layer will directly absorb the perspiration of human body in use, and perspiration is quickly guided the inner side to suction point, again through the Sweat Exhaust & Moisture Conductivity layer being connected with inner side rapidly by perspiration transfer diffusion so that one-way wet-guide quick-drying spandex knitted fabric have ventilative, lead the effects such as wet, dry and comfortable.
Detailed description of the invention
It is presented herein below and the preferred embodiments of the present invention are described in detail, so that advantages and features of the invention can be easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention being made apparent clear and definite defining.
Polyvinylpyrrolidone, No. CAS: 9003-39-8, adopt the polyvinylpyrrolidone PVPK30 that Jin Ao Chemical Co., Ltd. of Anhui Province provides.
Embodiment 1
The preparation method singly leading sweat absorption fabric, comprises the following steps:
(1) polypropylene (adopting the DTY fine-denier polypropylene silk that specification is 75D/48F that Changzhou Xin Hongji chemical fibre company limited provides) water-proofing treatment: by polypropylene in waterproof finishing agent under 105 DEG C of conditions, dipping 25min, after dehydration, under 90 DEG C of conditions, dry 8min;
Described waterproof finishing agent is made up of the raw material of following mass percent: 1%1,1,1,3,3,3-hexafluoro-2-propanol, 99% for deionized water. HFIP is added to the water mix homogeneously, obtains described waterproof finishing agent.
(2) Sweat Exhaust & Moisture Conductivity layer raw material hydrophilic treated:
Sweat Exhaust & Moisture Conductivity layer raw material (weight portion): 38 parts of Coolmax fiber (INVISTA company Coolmax fibers, 75D), 59 parts of cotton fibers (adopt medium staple cotton, specification: 1.8dtex �� 30mm), 3 parts of spandexs (adopting Du Pont's spandex thread, 70D).
Coolmax fiber, cotton fiber, spandex under 105 DEG C of conditions, are impregnated 25min in hydrophilic finishing agent, after dehydration, under 90 DEG C of conditions, dries 8min;
Described hydrophilic finishing agent raw material (mass percent): 0.5% polyvinylpyrrolidone, 0.1%2,3-dyhydrobutanedioic acid, 0.1%3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, 0.15% dodecyldimethylammonium hydroxide inner salt, 0.15%3-sulfopropyl dodecyldimethylammonium hydroxide inner salt, 99.0% deionized water. Polyvinylpyrrolidone, 2,3 dihydroxybutanedioic acid, 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, dodecyldimethylammonium hydroxide inner salt, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt are added mix homogeneously in deionized water, obtains described hydrophilic finishing agent.
(3) Double-plate machine is used (to adopt the Double-plate machine of moral happy up472 model in Coolmax fiber, cotton fiber, spandex and polypropylene, plane No. 24G syringe, barrel dliameter is 34) and adopt conventional method to weave, what obtain internal layer to be polypropylene layer, outer layer be Sweat Exhaust & Moisture Conductivity layer singly leads sweat absorption fabric. Wherein polypropylene layer grammes per square metre is 100g/m2, Sweat Exhaust & Moisture Conductivity layer grammes per square metre is 200g/m2��
Embodiment 2
Prepare by the method for embodiment 1 and singly lead sweat absorption fabric, differ only in:
Hydrophilic finishing agent raw material (mass percent): 0.5% polyvinylpyrrolidone, 0.2%2,3-dyhydrobutanedioic acid, 0.15% dodecyldimethylammonium hydroxide inner salt, 0.15%3-sulfopropyl dodecyldimethylammonium hydroxide inner salt, 99.0% deionized water. What obtain embodiment 2 singly leads sweat absorption fabric. Polyvinylpyrrolidone, 2,3 dihydroxybutanedioic acid, dodecyldimethylammonium hydroxide inner salt, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt are added mix homogeneously in deionized water, obtains hydrophilic finishing agent.
Embodiment 3
Prepare by the method for embodiment 1 and singly lead sweat absorption fabric, differ only in: hydrophilic finishing agent raw material (mass percent): 0.5% polyvinylpyrrolidone, 0.2%3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, 0.15% dodecyldimethylammonium hydroxide inner salt, 0.15%3-sulfopropyl dodecyldimethylammonium hydroxide inner salt, 99.0% deionized water. Obtain embodiment 3 and singly lead sweat absorption fabric. Polyvinylpyrrolidone, 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, dodecyldimethylammonium hydroxide inner salt, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt are added mix homogeneously in deionized water, obtains hydrophilic finishing agent.
Embodiment 4
Prepare by the method for embodiment 1 and singly lead sweat absorption fabric, differ only in: hydrophilic finishing agent raw material (mass percent): 0.5% polyvinylpyrrolidone, 0.1%2,3-dyhydrobutanedioic acid, 0.1%3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, 0.3% dodecyldimethylammonium hydroxide inner salt, 99.0% deionized water. Obtain embodiment 4 and singly lead sweat absorption fabric. Polyvinylpyrrolidone, 2,3 dihydroxybutanedioic acid, 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, dodecyldimethylammonium hydroxide inner salt are added mix homogeneously in deionized water, obtains hydrophilic finishing agent.
Embodiment 5
Prepare by the method for embodiment 1 and singly lead sweat absorption fabric, differ only in: hydrophilic finishing agent raw material (mass percent): 0.5% polyvinylpyrrolidone, 0.1%2,3-dyhydrobutanedioic acid, 0.1%3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, 0.3%3-sulfopropyl dodecyldimethylammonium hydroxide inner salt, 99.0% deionized water. What obtain embodiment 5 singly leads sweat absorption fabric. Polyvinylpyrrolidone, 2,3 dihydroxybutanedioic acid, 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt are added mix homogeneously in deionized water, obtains hydrophilic finishing agent.
Embodiment 6
Sweat Exhaust & Moisture Conductivity layer raw material (weight portion): 38 parts of Coolmax fibers, 59 parts of bamboo fibre (inner bamboos difficult to understandFiber, Shanghai Lyocell Fibre Research & Development Co., Ltd. produce Lyocell bamboo fiber), 3 parts of spandexs.
Hydrophilic finishing agent raw material (mass percent): 0.5% polyvinylpyrrolidone, 0.1%2,3-dyhydrobutanedioic acid, 0.1%3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, 0.15% dodecyldimethylammonium hydroxide inner salt, 0.15%3-sulfopropyl dodecyldimethylammonium hydroxide inner salt, 99.0% deionized water.
The preparation method singly leading sweat absorption fabric:
(1) HFIP is added to the water mix homogeneously, obtains described waterproof finishing agent, polypropylene under 105 DEG C of conditions, is impregnated 25min in waterproof finishing agent, after dehydration, under 90 DEG C of conditions, dry 8min.
(2) by polyvinylpyrrolidone, 2,3-dyhydrobutanedioic acid, 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, dodecyldimethylammonium hydroxide inner salt, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt add mix homogeneously in deionized water, obtain described hydrophilic finishing agent, by Sweat Exhaust & Moisture Conductivity layer raw material in hydrophilic finishing agent under 105 DEG C of conditions, dipping 25min, after dehydration, under 90 DEG C of conditions, dry 8min.
(3) Sweat Exhaust & Moisture Conductivity layer raw material and polypropylene being weaved, obtain described singly leading sweat absorption fabric, wherein polypropylene layer grammes per square metre is 100g/m2, Sweat Exhaust & Moisture Conductivity layer grammes per square metre is 200g/m2����
Embodiment 7
Sweat Exhaust & Moisture Conductivity layer raw material (weight portion): 38 parts of Thermocool fibers, 59 parts of Modal fibres, 3 parts of spandexs.
Hydrophilic finishing agent raw material (mass percent): 0.5% polyvinylpyrrolidone, 0.1%2,3-dyhydrobutanedioic acid, 0.1%3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, 0.15% dodecyldimethylammonium hydroxide inner salt, 0.15%3-sulfopropyl dodecyldimethylammonium hydroxide inner salt, 99.0% deionized water.
The preparation method singly leading sweat absorption fabric:
(1) HFIP is added to the water mix homogeneously, obtains described waterproof finishing agent, polypropylene layer under 105 DEG C of conditions, is impregnated 25min in waterproof finishing agent, after dehydration, under 90 DEG C of conditions, dry 8min.
(2) by polyvinylpyrrolidone, 2,3-dyhydrobutanedioic acid, 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid, dodecyldimethylammonium hydroxide inner salt, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt add mix homogeneously in deionized water, obtain described hydrophilic finishing agent, by Sweat Exhaust & Moisture Conductivity layer in hydrophilic finishing agent under 105 DEG C of conditions, dipping 25min, after dehydration, under 90 DEG C of conditions, dry 8min.
(3) Sweat Exhaust & Moisture Conductivity layer raw material and polypropylene being weaved, obtain described singly leading sweat absorption fabric, wherein polypropylene layer grammes per square metre is 100g/m2, Sweat Exhaust & Moisture Conductivity layer grammes per square metre is 200g/m2����
Test case 1
Moisture absorption diffusibility is tested:
(1) each sample cuts 5 pieces of samples, and every piece of sample is of a size of 10cm �� 10cm, and sample should be smooth non-wrinkled.
(2) balance that is placed under standard atmosphere condition by sample damping.
(3) lying in sample (to press close to the one of human body skin during use to face up, i.e. internal layer: moisture absorption water repellent layer is upward) on testing stand, the water drawing about 0.2ml drops on sample lightly, and dropper bore test coupon surface should less than 1cm.
(4) examining water droplet spread condition, record water drop contact sample internal layer surface, to complete diffusion (no longer presenting direct reflection) to the required time of outer layer, is accurate to 0.1s. If water droplet diffusion velocity is relatively slow, spread completely not yet after certain time (such as 300s), then can stop test, and record diffusion time for more than setting time (such as 300s).
(5) on average dripping diffusion time (s) of 5 pieces of samples is recorded.
(6) 5 pieces of samples of record are within certain time (300s), and the on average maximum of outer layer soaks diameter (cm), is accurate to mm.
This method very Simple visual, observer can from the complete diffusion in water drop contact sample internal layer surface to outer layer needed for time and the on average maximum diameter that soaks of sample ectonexine to pass judgment on its moisture absorption diffusion. Water droplet is more short for diffusion time, illustrates that its moisture absorption diffusion is more good; It is more little that internal layer soaks diameter, and it is more big that outer layer soaks diameter, illustrates that its unidirectional moisture conducting function is more good; Internal layer soaks diameter when being 0, illustrates that it has one-way wet-guide quick-drying function. Test result is in Table 1.
Table 1: the diffusion time and ectonexine is on average maximum soaks diameter result table of on average dripping of fabric
Comparing embodiment 1-3 and comparative example 1, in embodiment 1-3, waterproof finishing agent on average drips diffusion time and the ectonexine on average maximum diameter that soaks is substantially better than comparative example 1 after using cross-linking agent; Comparing embodiment 1,4-5 and comparative example 2, embodiment 1,4-5 waterproof finishing agent use and on average drip diffusion time after penetrating agent and the ectonexine on average maximum diameter that soaks is substantially better than comparative example 2; Especially, comparing embodiment 1 and enforcement 2-3, (cross-linking agent adopts 2 to embodiment 1,3-dyhydrobutanedioic acid and 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid are composite) diffusion time and the ectonexine on average maximum diameter that soaks that on average drips is substantially better than embodiment 2-3 (cross-linking agent adopts single raw material in 2,3 dihydroxybutanedioic acid and 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid); Comparing embodiment 1 and embodiment 4-5, embodiment 1 (penetrating agent adopt dodecyldimethylammonium hydroxide inner salt, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt composite) on average drips diffusion time and the ectonexine on average maximum diameter that soaks is substantially better than embodiment 4-5 (penetrating agent adopts single raw material in dodecyldimethylammonium hydroxide inner salt, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt).
Test case 2
Wetness guiding perspiration discharging is tested:
Reference standard ISO11092:1993, adopts SDL Sweat Exhaust & Moisture Conductivity instrument to test each embodiment and the thermal resistance of comparative example, dampness. Test result is in Table 2.
Table 2: each embodiment and comparative example thermal resistance, dampness result table
Thermal resistance (10-3km2W-1) Dampness (Pam2W-1)
Embodiment 1 9.218 4.177
Embodiment 2 10.937 5.064
Embodiment 3 10.880 5.053
Embodiment 4 10.370 4.753
Embodiment 5 10.442 4.821
Embodiment 6 9.343 4.223
Embodiment 7 9.317 4.189
Comparing embodiment 1-3 and comparative example 1, in embodiment 1-3, after waterproof finishing agent use cross-linking agent, thermal resistance, dampness are substantially better than comparative example 1; Comparing embodiment 1,4-5 and comparative example 2, after embodiment 1,4-5 waterproof finishing agent use penetrating agent, thermal resistance, dampness are substantially better than comparative example 2; Especially, comparing embodiment 1 and enforcement 2-3, (cross-linking agent adopts 2 to embodiment 1,3-dyhydrobutanedioic acid and 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid are composite) thermal resistance, dampness be substantially better than embodiment 2-3 (cross-linking agent adopts single raw material in 2,3 dihydroxybutanedioic acid and 3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid); Comparing embodiment 1 and embodiment 4-5, embodiment 1 (penetrating agent employing dodecyldimethylammonium hydroxide inner salt, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt are composite) thermal resistance, dampness are substantially better than embodiment 4-5 (penetrating agent adopts single raw material in dodecyldimethylammonium hydroxide inner salt, 3-sulfopropyl dodecyldimethylammonium hydroxide inner salt).
The present invention singly leads sweat absorption fabric, its internal layer is polypropylene layer, outer layer is Sweat Exhaust & Moisture Conductivity layer, suction point outside polypropylene layer will directly absorb the perspiration of human body in use, and perspiration is quickly guided the inner side to suction point, again through the Sweat Exhaust & Moisture Conductivity layer being connected with inner side rapidly by perspiration transfer diffusion so that one-way wet-guide quick-drying spandex knitted fabric have ventilative, lead the effects such as wet, dry and comfortable.

Claims (10)

1. singly lead sweat absorption fabric for one kind, it is characterised in that being made up of internal layer and two parts of outer layer, its internal layer is polypropylene layer, and outer layer is Sweat Exhaust & Moisture Conductivity layer.
2. singly lead sweat absorption fabric as claimed in claim 1, it is characterised in that described Sweat Exhaust & Moisture Conductivity layer is weaved by the raw material of following weight parts and formed: 30-45 part Coolmax fiber, 55-70 part cotton fiber, 0.5-4.5 part spandex.
3. singly lead sweat absorption fabric as claimed in claim 1, it is characterised in that described Sweat Exhaust & Moisture Conductivity layer is weaved by the raw material of following weight parts and formed: 30-45 part Coolmax fiber, 55-70 part regenerated celulose fibre, 0.5-4.5 part spandex.
4. singly lead sweat absorption fabric as claimed in claim 1, it is characterised in that described Sweat Exhaust & Moisture Conductivity layer is weaved by the raw material of following weight parts and formed: 30-45 part Thermocool fiber, 55-70 part regenerated celulose fibre, 0.5-4.5 part spandex.
5. as according to any one of claim 1-4, singly lead sweat absorption fabric, it is characterized in that, described Sweat Exhaust & Moisture Conductivity layer raw material carries out hydrophilic treated by hydrophilic finishing agent, and described hydrophilic finishing agent is made up of the raw material of following mass percent: 0.3-0.7% hydrophilic finishing agent, 0.1-0.5% cross-linking agent, 0.1-0.5% penetrating agent, surplus are water.
6. singly lead sweat absorption fabric as claimed in claim 5, it is characterized in that, described hydrophilic finishing agent is polyvinylpyrrolidone and/or polyacrylamide, and described cross-linking agent is made up of 40-60wt%2,3-dyhydrobutanedioic acid and 40-60wt%3-hydroxyl-3-carboxyl 1,3-propanedicarboxylic acid.
7. singly lead sweat absorption fabric as claimed in claim 5, it is characterised in that described penetrating agent is made up of 40-60wt% dodecyldimethylammonium hydroxide inner salt and 40-60wt%3-sulfopropyl dodecyldimethylammonium hydroxide inner salt.
8. as according to any one of claim 1-4, singly lead sweat absorption fabric, it is characterized in that, described polypropylene layer is prepared from by polypropylene, described polypropylene carries out water-proofing treatment by waterproof finishing agent, and described waterproof finishing agent is made up of the raw material of following mass percent: 0.5-1.5%1, and 1,1,3,3,3-hexafluoro-2-propanol, 98.5-99.5% are water.
9. the preparation method singly leading sweat absorption fabric according to any one of claim 1-8, it is characterised in that comprise the following steps:
(1) prepare waterproof finishing agent, polypropylene is carried out water-proofing treatment;
(2) prepare hydrophilic finishing agent, Sweat Exhaust & Moisture Conductivity layer raw material is carried out hydrophilic treated;
(3) Sweat Exhaust & Moisture Conductivity layer raw material and polypropylene are weaved, obtain described singly leading sweat absorption fabric.
10. the preparation method singly leading sweat absorption fabric according to claim 9, it is characterised in that
Described step (1) is under 100-110 DEG C of condition, and polypropylene impregnates 20-30min in waterproof finishing agent, after dehydration, dries 5-10min under 80-100 DEG C of condition;
Described step (2) is under 100-110 DEG C of condition, and Sweat Exhaust & Moisture Conductivity layer raw material is impregnated 20-30min in hydrophilic finishing agent, after dehydration, dries 5-10min under 80-100 DEG C of condition;
It is 50-150g/m that described step (3) singly leads polypropylene layer grammes per square metre in sweat absorption fabric2, Sweat Exhaust & Moisture Conductivity layer grammes per square metre is 150-250g/m2��
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CN111267428A (en) * 2020-03-13 2020-06-12 福建凤竹纺织科技股份有限公司 Moisture-conducting and sweat-releasing school uniform fabric and preparation method thereof

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CN106835432A (en) * 2017-02-14 2017-06-13 利郎(中国)有限公司 A kind of preparation technology of one-way wet-guide lightweight heat-preserving tatting double-layer fabric
CN106835432B (en) * 2017-02-14 2018-08-07 利郎(中国)有限公司 A kind of preparation process of one-way wet-guide lightweight heat-preserving tatting double-layer fabric
CN107083605A (en) * 2017-06-22 2017-08-22 华懋(厦门)特种材料有限公司 With the shuttle-woven fabric and its production technology for unidirectionally leading suction function
CN107083605B (en) * 2017-06-22 2019-05-17 华懋(厦门)特种材料有限公司 With the shuttle-woven fabric and its production technology for unidirectionally leading suction function
CN107190537A (en) * 2017-06-29 2017-09-22 上海喜眠服饰有限公司 Perspire single guide face material and its preparation technology
CN107190537B (en) * 2017-06-29 2019-04-30 上海喜眠服饰有限公司 Perspire single guide face material and its preparation process
CN107336489A (en) * 2017-07-12 2017-11-10 太仓市天茂化纤有限公司 A kind of two-layer compound weaves thread water absorben perspiring shell fabric
CN108330601A (en) * 2018-02-06 2018-07-27 罗莱生活科技股份有限公司 A kind of absorbing fast-drying knitting fabric and preparation method thereof
CN110682627A (en) * 2019-11-27 2020-01-14 湖南尚珂伊针纺有限公司 Fabric for knitted sports socks
CN111267428A (en) * 2020-03-13 2020-06-12 福建凤竹纺织科技股份有限公司 Moisture-conducting and sweat-releasing school uniform fabric and preparation method thereof
CN111267428B (en) * 2020-03-13 2022-03-18 福建凤竹纺织科技股份有限公司 Moisture-conducting and sweat-releasing school uniform fabric and preparation method thereof

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