CN107201080A - A kind of natural aromatic quick-dry type offset ink and preparation method thereof - Google Patents
A kind of natural aromatic quick-dry type offset ink and preparation method thereof Download PDFInfo
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- CN107201080A CN107201080A CN201710620138.5A CN201710620138A CN107201080A CN 107201080 A CN107201080 A CN 107201080A CN 201710620138 A CN201710620138 A CN 201710620138A CN 107201080 A CN107201080 A CN 107201080A
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- quick
- dry type
- preparation
- natural aromatic
- type offset
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Links
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 18
- 239000002480 mineral oil Substances 0.000 claims abstract description 18
- 241000196324 Embryophyta Species 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000000341 volatile oil Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000000944 linseed oil Substances 0.000 claims abstract description 8
- 235000021388 linseed oil Nutrition 0.000 claims abstract description 8
- 239000002383 tung oil Substances 0.000 claims abstract description 8
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 238000007639 printing Methods 0.000 claims abstract description 6
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 6
- 238000000194 supercritical-fluid extraction Methods 0.000 claims abstract description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 21
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 18
- -1 alkyl phenol Chemical compound 0.000 claims description 17
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 238000000605 extraction Methods 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 235000013824 polyphenols Nutrition 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 238000007873 sieving Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims description 3
- 244000166124 Eucalyptus globulus Species 0.000 claims description 3
- 235000004692 Eucalyptus globulus Nutrition 0.000 claims description 3
- 241000234435 Lilium Species 0.000 claims description 3
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims description 3
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims description 3
- 229940043253 butylated hydroxyanisole Drugs 0.000 claims description 3
- 239000013522 chelant Substances 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 3
- 240000004784 Cymbopogon citratus Species 0.000 claims description 2
- 235000017897 Cymbopogon citratus Nutrition 0.000 claims description 2
- 244000246386 Mentha pulegium Species 0.000 claims description 2
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 2
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 235000001050 hortel pimenta Nutrition 0.000 claims description 2
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 2
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000011230 binding agent Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 238000005096 rolling process Methods 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- 235000013599 spices Nutrition 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical group 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 239000003094 microcapsule Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 235000013355 food flavoring agent Nutrition 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 241000220317 Rosa Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of natural aromatic quick-dry type offset ink and preparation method thereof, the preparation method of the ink is first with after supercritical fluid extraction scent composition, after being modified with rosin and polyalcohol to resin, by linseed oil, tung oil, mineral oil, high performance resin, gel is mixed with link stuff, finally drier will be entered after binder and pigment, plants essential oil mixed rolling, antioxidant obtains natural aromatic quick-dry type offset ink.The inventive method to ink have adhesiveness strong, rapid draing, printing efficiency is high and natural aromatic, will not produce dysgenic advantageous property to human body.
Description
Technical field
The present invention relates to technology of fine chemicals, it is more particularly related to a kind of natural aromatic quick-dry type
Offset ink and preparation method thereof.
Background technology
A kind of functional ink printed as fragrance, fragrant printing ink is mainly by link stuff, colorant, auxiliary agent and the micro- glue of spices
Capsule is constituted.Wherein, the main composition of ink is esters, alcohol or ketone, aromatic hydrocarbons.The main component of spices is alcohol, phenol, ether, aldehyde, ketone
Or ester etc., the two can coexist in general.Fragrant printing ink is in order to keep the stability and persistence of fragrance, by spices system
Into a kind of fragrant microcapsules, then penetrate into ink and printed.During aromatic printed matter use, because of the row such as friction
Fragrance is discharged to rack microcapsules.
At present, the organic components contained in the sufficiently complex and essence of composition of essence be mostly volatile, chemical property not
The materials such as stable alcohol, phenol, ether, aldehyde, ketone or ester.Scattered and disappeared or decomposed metamorphic so can be volatilized unavoidably during using and storing.
At present, to protect essence from the influence of outside environmental elements, and extend it and release the fragrant time limit, traditional technique is by the micro- glue of essence
By with slowly being aoxidized after air contact, constantly discharging fragrance after encapsulated, greatly prolong it and protect fragrant phase, the essence microcapsule also having
Only just can be mutual under the environmental factor catalytic action such as ultraviolet, solar radiation, oxygen air circulation, heating, humidity change
Reaction produces fragrance matter.Although these methods can avoid spices from volatilizing, microencapsulation adds the technology difficulty of ink,
Production cost is added, alcohol, phenol, ether, aldehyde, ketone or ester in addition used in spices are generally artificial synthesized volatile spices, greatly
Some toxic side effects can be produced after after amount absorption.Therefore, exploitation natural aromatic quick-dry type ink has great importance.
The content of the invention
In order to solve the above problems, the invention provides a kind of preparation method of natural aromatic quick-dry type offset ink, bag
Include following steps：
（1）After plant petals or leaf clean dry, 60 mesh sieves are crossed after being crushed using pulverizer, the powder after sieving is placed on
In the extraction kettle of supercritical fluid extraction equipment, in CO2Flow is 1-4kg/h, and temperature is 30-60 DEG C, extracting pressure 8-20MPa
Under conditions of to powder extract 1-3h after, obtain plants essential oil；
（2）After alkyl phenol and formaldehyde are well mixed, add after catalyst and occur under the conditions of 140-200 DEG C, 0.4-1.0Mpa
Low polymer is obtained after phenolic aldehyde polymerisation 0.5-2h, in 150- after then oligomer is well mixed with rosin and polyalcohol
220 DEG C, under the conditions of 0.3-1.0Mpa after phenol aldehyde modified 0.5-1h, obtain high performance resin；
（3）By linseed oil, tung oil, after mineral oil stirring mixing, it is warming up to after 150-180 DEG C, adds after high performance resin,
It is incubated after 20-40 min, cooling adds to be warming up to after gel and is incubated 30 min after 180 DEG C of 150- and adds mineral oil
Link stuff is obtained after uniform；
（4）By obtained binder and pigment, plants essential oil it is well mixed after, be placed on three-roller, 10-20MPa pressure and
2-3 roads are rolled at a temperature of 30-50 DEG C, then three-roller pressure is down to after 3-6 MPa, are added in ground ink
Enter and be well mixed after drier, antioxidant, adjusted with mineral oil after stickiness to setting range, obtain natural aromatic quick-dry type glue
Printing ink.
It is preferred that, step（1）Described in plant petals and leaf be roseleaf, lily petal, Eucalyptus globulus Labill leaf, lemon-grass and peppermint
In one kind；The addition of described plant powder is 200-400g.
It is preferred that, step（2）Described in the mol ratio of alkyl phenol and formaldehyde addition be 1:1.5-2.5；Described urges
Agent is sulfonic acid type strong acid and metal sulfate mixed catalyst；The addition of the catalyst is 0.2-0.5%.
It is preferred that, step（2）Described in polyalcohol ethylene glycol, glycerine, one kind in BDO.
It is preferred that, step（3）Described in linseed oil, tung oil, the ratio of mineral oil is 2:1:0.5；Described
Gel is ethyl acetate base aluminium diisopropyl ester or XP148 aluminum dialkyl chelant thing, and the addition of gel is 0.2-1.0%.
It is preferred that, step（4）Described in drier be the mixture of manganese iso-octoate and cobalt iso-octoate, described drier
Addition be 1.0-2%.
It is preferred that, step（5）Described in antioxidant be Tea Polyphenols, citric acid, butylated hydroxy anisole, dibutyl hydroxyl
One kind in base toluene, the addition of described antioxidant is 1-2%.
It is preferred that, step（5）Described in viscosity be 11-13Pa.s.
The natural aromatic quick-dry type offset ink of the present invention, it is as prepared by above-mentioned preparation method.
A kind of natural aromatic quick-dry type offset ink of the present invention compared with Traditional flavor offset ink preparation method,
Employ supercritical liquid extraction technique and extract natural fragrance of a flower composition as the flavouring agent of ink so that ink has natural virtue
It is fragrant simultaneously, it is to avoid the harmful effect that the artificial flavouring agent added is produced to human body；Resin is carried out using rosin and polyalcohol
Modifying and decorating, can significantly improve the adhesiveness of ink, improve offset printing efficiency；In addition added during ink is prepared and urge dry
Agent so that ink can rapid draing, raising printing efficiency in offset printing.
Embodiment
A kind of natural aromatic quick-dry type offset ink of the present invention is done further below with reference to specific embodiment
Elaboration, with help those skilled in the art to the present invention inventive concept, technical scheme have more complete, accurate and deep
Understand.
Embodiment 1
After lily clean dry, 60 mesh sieves are crossed after being crushed using pulverizer, the powder after sieving is placed on shooting flow
In the extraction kettle of body extraction equipment, in CO2Flow is 3kg/h, and temperature is to powder under conditions of 45 DEG C, extracting pressure 12MPa
Extract after 1.5h, obtain plants essential oil；Alkyl phenol and formaldehyde are pressed 1:After 2.5 mixed in molar ratio are uniform, 0.3% sulfonic acid is added
Type strong acid after occurring phenolic aldehyde polymerisation 1h under the conditions of 0.8Mpa after metal sulfate mixed catalyst with, at 180 DEG C, obtaining low
Polymer, at 170 DEG C after then oligomer is well mixed with rosin and glycerine, under the conditions of 0.6Mpa after phenol aldehyde modified 0.6h,
Obtain high performance resin；By linseed oil, tung oil, mineral oil presses 2:1：After 0.5 stirring mixing, it is warming up to after 170 DEG C, adds
After high performance resin, after insulation 25min, cooling is added to be warming up to after 0.5% ethyl acetate base aluminium diisopropyl ester after 180 DEG C and is incubated
30 min add mineral oil it is uniform after obtain link stuff；Obtained binder and pigment, plants essential oil are well mixed
Afterwards, it is placed on three-roller, rolls 3 roads at a temperature of 15MPa pressure and 40 DEG C, three-roller pressure is then down to 4
After MPa, added in ground ink after the mixture of 1% manganese iso-octoate and cobalt iso-octoate, 1.5% Tea Polyphenols and mix equal
It is even, adjusted with mineral oil after stickiness to 11.4-12.0Pa.s scopes, obtain natural aromatic quick-dry type offset ink.
Embodiment 2
After Eucalyptus globulus Labill leaf clean dry, 60 mesh sieves are crossed after being crushed using pulverizer, the powder after sieving is placed on shooting flow
In the extraction kettle of body extraction equipment, in CO2Flow is 2.7kg/h, and temperature is to powder under conditions of 50 DEG C, extracting pressure 14MPa
After end extraction 1h, plants essential oil is obtained；Alkyl phenol and formaldehyde are pressed 1:After 2 mixed in molar ratio are uniform, 0.5% sulfonic acid type is added
Strong acid after occurring phenolic aldehyde polymerisation 1.5h under the conditions of 0.7Mpa after metal sulfate mixed catalyst with, at 160 DEG C, obtaining low
Polymer, at 180 DEG C after then oligomer is well mixed with rosin and ethylene glycol, phenol aldehyde modified 0.6h under the conditions of 0.7Mpa
Afterwards, high performance resin is obtained；By linseed oil, tung oil, mineral oil presses 2:1：After 0.5 stirring mixing, it is warming up to after 180 DEG C, plus
Enter after high performance resin, after insulation 20min, cooling is added to be warming up to after 0.4% ethyl acetate base aluminium diisopropyl ester after 175 DEG C and protected
35 min of temperature add mineral oil it is uniform after obtain link stuff；Obtained binder and pigment, plants essential oil are mixed equal
After even, it is placed on three-roller, rolls 2 roads at a temperature of 12MPa pressure and 45 DEG C, be then down to three-roller pressure
After 4.5 MPa, added in ground ink after the mixture of 1.5% manganese iso-octoate and cobalt iso-octoate, 1.5% citric acid
It is well mixed, adjusted with mineral oil after stickiness to 11.5-12.5Pa.s scopes, obtain natural aromatic quick-dry type offset ink.
Embodiment 3
After rose clean dry, 60 mesh sieves are crossed after being crushed using pulverizer, the powder after sieving is placed on shooting flow
In the extraction kettle of body extraction equipment, in CO2Flow is 3.5kg/h, and temperature is to powder under conditions of 45 DEG C, extracting pressure 12MPa
After end extraction 1h, plants essential oil is obtained；Alkyl phenol and formaldehyde are pressed 1:After 2.5 mixed in molar ratio are uniform, 0.6% sulfonic acid is added
Type strong acid after occurring phenolic aldehyde polymerisation 1h under the conditions of 0.6Mpa after metal sulfate mixed catalyst with, at 170 DEG C, obtaining low
Polymer, at 170 DEG C after then oligomer is well mixed with rosin and ethylene glycol, phenol aldehyde modified 0.5h under the conditions of 0.7Mpa
Afterwards, high performance resin is obtained；By linseed oil, tung oil, mineral oil presses 2:1：After 0.5 stirring mixing, it is warming up to after 170 DEG C, plus
Enter after high performance resin, after insulation 25min, cooling is warming up to after 175 DEG C after adding 0.35%XP148 aluminum dialkyl chelant thing
Be incubated 30 min add mineral oil it is uniform after obtain link stuff；Obtained binder and pigment, plants essential oil are mixed
After uniform, it is placed on three-roller, rolls 3 roads at a temperature of 15MPa pressure and 40 DEG C, be then down to three-roller pressure
After 5MPa, the mixture of 1.0% manganese iso-octoate and cobalt iso-octoate, 1.5% butylated hydroxy anisole are added in ground ink
After be well mixed, with mineral oil adjust stickiness to 12.0-12.5Pa.s scopes after, obtain natural aromatic quick-dry type offset ink.
For the ordinary skill in the art, simply the present invention is exemplarily described for specific embodiment,
The obvious present invention, which is implemented, to be not subject to the restrictions described above, and is entered as long as employing the inventive concept and technical scheme of the present invention
The improvement of capable various unsubstantialities, or it is not improved by the present invention design and technical scheme directly apply to other occasions
, within protection scope of the present invention.
Claims (9)
1. a kind of preparation method of natural aromatic quick-dry type offset ink, it is characterised in that comprise the following steps：
（1）After plant petals or leaf clean dry, 60 mesh sieves are crossed after being crushed using pulverizer, the powder after sieving is placed on
In the extraction kettle of supercritical fluid extraction equipment, in CO2Flow is 1-4kg/h, and temperature is 30-60 DEG C, extracting pressure 8-20MPa
Under conditions of to powder extract 1-3h after, obtain plants essential oil；
（2）After alkyl phenol and formaldehyde are well mixed, add after catalyst and occur under the conditions of 140-200 DEG C, 0.4-1.0Mpa
Low polymer is obtained after phenolic aldehyde polymerisation 0.5-2h, in 150- after then oligomer is well mixed with rosin and polyalcohol
220 DEG C, under the conditions of 0.3-1.0Mpa after phenol aldehyde modified 0.5-1h, obtain high performance resin；
（3）After linseed oil, tung oil, mineral oil stirring mixing, it is warming up to after 150-180 DEG C, adds the high performance resin
Afterwards, after insulation 20-40 min, cooling is added to be warming up to after 180 DEG C of 150- to be incubated 30 min and add mineral oil after gel and mixed
Link stuff is obtained after closing uniformly；
（4）By obtained link stuff and pigment, plants essential oil it is well mixed after, be placed on three-roller, 10-20MPa pressure and
2-3 roads are rolled at a temperature of 30-50 DEG C, then three-roller pressure is down to after 3-6 MPa, are added in ground ink
Enter and be well mixed after drier, antioxidant, adjusted with mineral oil after stickiness to setting range, obtain natural aromatic quick-dry type glue
Printing ink.
2. a kind of preparation method of natural aromatic quick-dry type offset ink according to claim 1, it is characterised in that step
（1）Described in plant petals and leaf be roseleaf, lily petal, Eucalyptus globulus Labill leaf, lemon-grass and peppermint in one kind；Described
The addition of plant powder is 200-400g.
3. a kind of preparation method of natural aromatic quick-dry type offset ink according to claim 1, it is characterised in that step
（2）Described in the mol ratio of alkyl phenol and formaldehyde addition be 1:1.5-2.5；Described catalyst is sulfonic acid type strong acid and gold
Belong to sulfate mixed catalyst；The addition of the catalyst is 0.2-0.5%.
4. a kind of preparation method of natural aromatic quick-dry type offset ink according to claim 1, it is characterised in that step
（2）Described in polyalcohol ethylene glycol, glycerine, one kind in BDO.
5. a kind of preparation method of natural aromatic quick-dry type offset ink according to claim 1, it is characterised in that step
（3）Described in linseed oil, tung oil, the ratio of mineral oil is 2:1:0.5；Described gel is ethyl acetate base aluminium
The aluminum dialkyl chelant thing of diisopropyl ester or XP148, the addition of gel is 0.2-1.0%.
6. a kind of preparation method of natural aromatic quick-dry type offset ink according to claim 1, it is characterised in that step
（4）Described in drier be the mixture of manganese iso-octoate and cobalt iso-octoate, the addition of described drier is 1.0-2%.
7. a kind of preparation method of natural aromatic quick-dry type offset ink according to claim 1, it is characterised in that step
（5）Described in antioxidant be Tea Polyphenols, one kind in citric acid, butylated hydroxy anisole, dibutyl hydroxy toluene is described
Antioxidant addition be 1-2%.
8. a kind of preparation method of natural aromatic quick-dry type offset ink according to claim 1, it is characterised in that step
（5）Described in viscosity be 11-13Pa.s.
9. a kind of natural aromatic quick-dry type offset ink, it is made as the preparation method any one of claim 1-8
It is standby.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942241A (en) * | 2010-08-16 | 2011-01-12 | 东莞市汇彩印刷材料科技有限公司 | Offset ink binder using pure vegetable oil solvent and preparation method thereof |
| CN102977301A (en) * | 2012-12-07 | 2013-03-20 | 上海华谊（集团）公司 | Preparation method of rosin modified phenolic printing ink resin |
| CN105504961A (en) * | 2014-10-15 | 2016-04-20 | 王萍 | Flower-fragrance environment-friendly printing ink |
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2017
- 2017-07-26 CN CN201710620138.5A patent/CN107201080B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942241A (en) * | 2010-08-16 | 2011-01-12 | 东莞市汇彩印刷材料科技有限公司 | Offset ink binder using pure vegetable oil solvent and preparation method thereof |
| CN102977301A (en) * | 2012-12-07 | 2013-03-20 | 上海华谊（集团）公司 | Preparation method of rosin modified phenolic printing ink resin |
| CN105504961A (en) * | 2014-10-15 | 2016-04-20 | 王萍 | Flower-fragrance environment-friendly printing ink |
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| CN107201080B (en) | 2020-09-11 |
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