TWI355406B - Functional uv paint, construction material using t - Google Patents

Functional uv paint, construction material using t Download PDF

Info

Publication number
TWI355406B
TWI355406B TW095113129A TW95113129A TWI355406B TW I355406 B TWI355406 B TW I355406B TW 095113129 A TW095113129 A TW 095113129A TW 95113129 A TW95113129 A TW 95113129A TW I355406 B TWI355406 B TW I355406B
Authority
TW
Taiwan
Prior art keywords
coating
compound
plant
tea
powder
Prior art date
Application number
TW095113129A
Other languages
Chinese (zh)
Other versions
TW200637895A (en
Inventor
Sunghoon Yue
Minjung Lee
Seoggoo Kang
Il Hong Min
Jae Youl Joung
Original Assignee
Lg Chemical Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lg Chemical Ltd filed Critical Lg Chemical Ltd
Publication of TW200637895A publication Critical patent/TW200637895A/en
Application granted granted Critical
Publication of TWI355406B publication Critical patent/TWI355406B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Description

1355406 ( I9702pif.doc 九、發明說明: 【發明所屬之技術領域】 本發明是關於功能性uv塗料,且更特定言之,是關 於包括乾植物粉或其類似物而非UV固化塗料組份中之添 加劑或顏料填充劑以減少多種揮發性有機化合物(volatiIe organic compounds ’ V〇Cs)並移除曱醛(f〇rmakjehyde,結1355406 ( I9702 pif.doc IX. INSTRUCTIONS: TECHNICAL FIELD OF THE INVENTION The present invention relates to functional uv coatings and, more particularly, to dry plant powders or the like rather than to UV curable coating compositions. Additives or pigment fillers to reduce a variety of volatile organic compounds (volatiIe organic compounds 'V〇Cs) and remove furfural (f〇rmakjehyde, knot

構式為HCH0)藉此提供對環境友好之塗料組合物,且使 塗料所塗覆的建材產生的有害化合物的逸散量降至最低, 藉此改良人類住宅之室内空氣品質的—種uv塗料、使用 此塗料的建材以及製備此塗料的方法。 【先前技術】 在各種影響室内空氣品質的污染物中,v〇Cs&HCH〇 對人類神經系統以及呼吸器官和#環器官具有影響,藉此 ,低周邊神㈣'統_感性且具有致魏力且有如表i —(室=產生之V0Cs及其影響)及表2 ( Η·危害)所 =制因此,此等材料在韓國、美國、日本、歐洲等 表1 1355406 * 19702pif.doc 表2 濃度(ppm) 0.1-5 1或更少 對人體的影響 一'—η 對眼有刺激、導致眼淚'對上呼吸道有刺激 對眼、鼻及頸有刺激 —一 0.25 - 5 1 Λ 對患有支乳官哮喘之人造成嚴重哮喘發作~- ιυ — ZU 亥漱、肺壓迫作用、頭部的沉重感覺、心 迷 Μ) — 100 肺中之體液積累、肺部感染、死亡;當飲酒時, 口腔、頸部及腹部之嚴重不適、呕吐、腹瀉、 暈眩、痙攣、意識不清 至今,藉由將Ti〇2 (光催化劑)、電石(無機材料)、 陰離子、Zn〇_Mn02 (新材料)等等與合成樹脂混合來製 ^的塗料已用於改良室内空氣品質或在住宅或商業建築中 •’ 安裝空氣處理單元來改良室内空氣品質。,然而,由於高成 本和未經證實之效應此等方法不具有高效性。 此外,分解或吸附VOCs與HCilO之效率隨時間而減 小。大多所用之無機材料或合成材料具有有限之化學反應。 鲁 同時’已知天然所得之多紛化合物(p〇lyphen〇i C〇mpound)、類黃酮化合物(flavonoid compound)以及類脂醇 化合物(steroid compound)具有多種功能,包括除臭、對重金 屬及煙鹼之解毒、抗癌效應、抑制環境激素、抗氧化、分 解亞硝酸鹽、兒茶酚組份(catechin components)之殺菌作用 等等。此等化合物目前用於製備具有上述功能之飲料、化 妝品及各種食品。 在韓國專利早期公開第2002-46395、2003-26710及 1355406 ,19702pif.doc • 2003-72152號中揭示包括諸如木粉(wood powder)、糠粉 (chaff powder)及稻草粉(rice-straw powder)之天然材料的塗 料。然而’此等專利的要旨是對塗料提供紋理、遠紅外線 輻射功能等等且其未考慮到VOCs及HCHO。 此外’此等塗料為水性塗料。因而,就技術應用與材 料構成而言,本發明之UV固化塗料基本上與習知之塗料 不同。例如,UV固化塗料不含黏接劑且大體上含有將由 TJV光固化的光引發劑(photoinitiator) ’而習知之塗料大體上 _ 含黏接劑且不含UV抑制劑。 在這點上,要求UV塗料最小化塗料自身的v〇Cs及 HCHO,不影響塗料塗佈的可使用性及塗料膜之物理性 ' 質’且要求移除使用UV塗料產品之VOCs。 ' 因此,存在對能夠滿足上述要求的新功能性UV塗料 的需要。 【發明.内容】 本發明k供對壤境友好的一種功能性uv塗料,其可 Φ 使塗料自身及使用塗料之產品的VOCs及HCHO逸散量降 至最低’而不影響可使用性及塗料膜的物理性質。 本發明亦提供使用功能性UV塗料的建材。 本發明亦提供製備功能性UV塗料的方法。 根據本發明之一態樣,其提供包括多盼化合物、類黃 酮化δ物、類脂醇化合物或其混合物的功能性塗料, 其中化合物之分子量範圍為250至1000。 在UV塗料中,類黃酮化合物或多酚化合物可為至少 7 1355406 I9702pif.doc 一種由下列化合物所構成的族群中選出的化合物:花黃素 (anthoxanthins)、花青素(anthocyanins)、兒茶酚、丹寧酸(tannin) 及咖啡因(caffeine)。 在UV塗料中’類脂醇化合物可為膽固醇(cholesterol)、 皂角苷(saponin)或β-胡蘿蔔素(万_car〇tene;)。 在UV塗料中,類黃酮化合物、多酚化合物或類脂醇 化合物可以塗料總重計包括0.01至2重量%卜1%)。 在UV塗料中,類黃酮化合物或類脂醇化合物可獲自 天然植物。 在UV塗料中’天然植物可為橡樹、紅樹、桃花心木、 金合歡屬樹、柿樹、栗殼、桃、蘋果、葡萄、柿子、綠茶、 紅茶、烏龍茶(oolong tea )、茉莉茶(jasmin tea )、武夷茶 (Wuyi tea)、.鐵械音命(Tie_Guang_Yin tea)、波格茶 (Bongro tea)、尤糸茶(Y〇ubi tea)、首孫茶(Soosun tea)、 奥戈茶(Ogo tea)、白茶、藍茶、粉末狀綠茶、決明子茶 (Gyeolmyeon&ja tea)或煙草葉。 在UV塗料中,類黃酮化合物、多酚化合物或類脂醇 化合物可呈乾植物粉、植物薄片、植物萃取物或粉末分散 液之形式。 在UV塗料中’乾植物粉或植物薄片可具有0 02至125 微米(μηι)之尺寸。 在UV塗料中,乾植物粉或植物薄片可以塗料總重計 以1至5重量%之量添加。 在UV塗料中,乾植物粉或植物薄片可以塗料總重計 8 1355406 I9702pif.doc 以1至2.5重量%之量添加。 在UV塗料中’用於萃取物或分散液之溶劑可為水、 醇、油或樹脂。 UV塗料可用於塗佈諸如門、窗、椅、桌、地板、踏 紙、地面塗層、天花板材料、汽車之内部及外部、衣橋、 電視、冰箱、泡菜冰箱(kimchi refrigerator) '家庭用具、壁 橋材料或地板材料之材料表面。The configuration is HCH0) thereby providing an environmentally friendly coating composition, and minimizing the amount of harmful compounds generated by the building materials coated by the coating, thereby improving the indoor air quality of the human residence. , building materials using the coating, and methods of preparing the coating. [Prior Art] Among various pollutants that affect indoor air quality, v〇Cs&HCH〇 has an effect on the human nervous system as well as the respiratory organs and #loop organs, whereby the low peripheral gods (4) are unified and sensitive. The force is as shown in Table i - (room = generated V0Cs and its effects) and Table 2 (Η · Hazard) = therefore, these materials in Korea, the United States, Japan, Europe, etc. Table 1 1355406 * 19702pif.doc Table 2 Concentration (ppm) 0.1-5 1 or less affects the human body a '-η Irritating to the eye, causing tears 'stimulation of the upper respiratory tract irritation to the eyes, nose and neck — 0.25 - 5 1 Λ A person with breast cancer causes severe asthma attacks~- ιυ — ZU 漱 漱, lung compression, heavy head sensation, heart confusion — — 100 body fluid accumulation in the lungs, lung infection, death; when drinking alcohol, Severe discomfort in the mouth, neck and abdomen, vomiting, diarrhea, dizziness, paralysis, unconsciousness to date, by using Ti〇2 (photocatalyst), calcium carbide (inorganic material), anion, Zn〇_Mn02 (new material) ) and the like, mixed with synthetic resin to make the coating It has been used to improve indoor air quality or • 'install air handling unit to improve indoor air quality in residential or commercial buildings. However, these methods are not efficient due to high cost and unproven effects. In addition, the efficiency of decomposing or adsorbing VOCs and HCilO decreases with time. Most of the inorganic or synthetic materials used have a limited chemical reaction. Lu also knows that 'p〇lyphen〇i C〇mpound, flavonoid compounds and steroid compounds have many functions, including deodorization, heavy metals and smoke. Detoxification, anticancer effects, inhibition of environmental hormones, antioxidants, decomposition of nitrite, bactericidal action of catechin components, etc. These compounds are currently used to prepare beverages, cosmetics, and various foods having the above functions. Including, for example, wood powder, chaff powder, and rice-straw powder are disclosed in Korean Patent Laid-Open Publication Nos. 2002-46395, 2003-26710, and 1355406, 19702 pif. doc, 2003-72152. A coating of natural materials. However, the gist of these patents is to provide texture, far-infrared radiation, etc. to the coating and it does not take into account VOCs and HCHO. In addition, these coatings are waterborne coatings. Thus, the UV curable coating of the present invention is substantially different from conventional coatings in terms of technical application and material composition. For example, UV curable coatings do not contain an adhesive and generally contain a photoinitiator that will be photocured by TJV. Conventional coatings generally contain an adhesive and are free of UV inhibitors. In this regard, UV coatings are required to minimize the coating's own v〇Cs and HCHO, without affecting the applicability of the coating application and the physical properties of the coating film and requiring the removal of VOCs using UV coating products. 'Therefore, there is a need for new functional UV coatings that meet the above requirements. [Invention. Contents] The present invention provides a functional uv coating that is friendly to the soil, which can minimize the VOCs and HCHO emissions of the coating itself and the products using the coating without affecting the usability and coating. The physical properties of the membrane. The invention also provides building materials using functional UV coatings. The invention also provides a method of making a functional UV coating. According to one aspect of the invention, there is provided a functional coating comprising a polypanic compound, a flavonoid delta, a lipohydric alcohol compound or a mixture thereof, wherein the compound has a molecular weight in the range of from 250 to 1000. In UV coatings, the flavonoid compound or polyphenolic compound may be at least 7 1355406 I9702 pif.doc A compound selected from the group consisting of: anthoxanthins, anthocyanins, catechol , tannin and caffeine. In the UV coating, the 'aliphatic alcohol compound can be cholesterol (cholesterol), saponin or beta-carotene (wan_car〇tene;). In the UV coating, the flavonoid compound, the polyphenol compound or the aliphatic alcohol compound may comprise from 0.01 to 2% by weight based on the total weight of the coating. In UV coatings, flavonoid compounds or lipid alcohol compounds can be obtained from natural plants. In UV coatings, 'natural plants can be oak, mangrove, mahogany, acacia, persimmon, chestnut, peach, apple, grape, persimmon, green tea, black tea, oolong tea, jasmine tea ( Jasmin tea ), Wuyi tea, Tie_Guang_Yin tea, Bonro tea, Y〇ubi tea, Sosunc tea, Ogo tea (Ogo tea), white tea, blue tea, powdered green tea, cassia tea (Gyeolmyeon & ja tea) or tobacco leaves. In the UV coating, the flavonoid compound, polyphenol compound or lipid alcohol compound may be in the form of a dry plant powder, a plant flake, a plant extract or a powder dispersion. In dry coatings, 'dry plant powder or plant flakes may have a size of from 0 02 to 125 microns. In the UV coating, the dry vegetable powder or plant flakes may be added in an amount of from 1 to 5% by weight based on the total weight of the coating. In the UV coating, the dry plant powder or plant flakes can be added in an amount of from 1 to 2.5% by weight based on the total weight of the coating 8 1355406 I9702 pif.doc. The solvent used in the extract or dispersion in the UV coating may be water, alcohol, oil or resin. UV coatings can be used for coating such as doors, windows, chairs, tables, floors, treads, floor coatings, ceiling materials, interior and exterior of automobiles, clothing bridges, televisions, refrigerators, kimchi refrigerators, home appliances, The material surface of a wall bridge material or flooring material.

根據本發明之另一態樣,其提供塗有UV塗料之建材。 根據本發明之另一態樣,其提供製備UV塗料之方 法’此方法包括:在粉碎乾植物後篩選粒徑為〇 至 微米的微粒;充分混合包括寡聚物之塗料原料;以及將微 粒以塗料總重計以1至5重量%之量添加和分散於經混合 之塗料原料中。 ° 在所述方法中’可將植物的液體萃取物或微粒的分散 液代替微粒添加至塗料原料中。According to another aspect of the invention, a building material coated with a UV coating is provided. According to another aspect of the present invention, there is provided a method of preparing a UV coating. The method comprises: screening particles having a particle size of 〇 to micrometer after pulverizing the dried plant; thoroughly mixing the coating material including the oligomer; and The total weight of the coating is added and dispersed in the mixed coating material in an amount of from 1 to 5% by weight. ° In the method, a liquid extract of a plant or a dispersion of microparticles may be added to the coating material instead of the microparticles.

不同於習知之UV塗料,所述功能性uv塗料包括具 有吸附力的天然化合物以減少使用塗料的產品之V0CS i 及塗料自身的VOCs與HCH0。 ° 【實施方式】 下文中將更詳細描述本發明。 本發明提供功能性UV塗料,其包括類黃酮化合物、 合物、類輯化合物或其混合物,其中化合 I乾圍為250至1〇〇〇。 為廣泛分佈於植物中之_顏料的类員黃嗣化合物來自 1355406 19702pif.doc —us,其在械財意謂咖色且意指以細作為基本結 ,之植物顏料。在動物中含有相對低量之類黃酮化合物且 黃烷類化合物在植物之葉、花、根、果實及莖中含量豐富。 多酚化合物為在特定植物中分佈之化學物質,起 來澀且苦且具有含有至少一個羥基(_〇H)的諸如苯之芳 族化合物之結構。普遍已知多酚化合物具有藥理學的功 能,諸如抗生素及抗炎作用、使皮膚光滑、降低膽固醇以 及抗過敏作用。 藝具有類脂醇核之類脂醇化合物一般含於激素中。然 而,類脂醇化合物可根據其取代基具有各種結構且其亦存 在於植物中。 在此等化合物中,具有250至1000之分子量的化合物 ,.可用於本發明中。當分子量小於250時,可揮發性不合需 要的高。當分子量大於1〇〇〇時,形成寡聚物,其增加添加 材料之黏度或相對降低對有機材料之吸附力。 一雖然用於本發明之類黃酮化合物或多酚化合物並不特 _ 別受限’但較佳為花黃素、花青素、兒茶盼或丹寧酸 其為兒茶盼或丹寧酸。 兒余酚具有由式1 ((+兒茶酚)所表示之結構及由式 2_( (+)_兒茶酚)所表示之結構且已知多種基於此等結構 衍生物。 1355406 1970lpif.doc 式1Unlike conventional UV coatings, the functional uv coatings include natural compounds with adsorptive power to reduce the V0CS i of the coating product and the VOCs and HCH0 of the coating itself. [Embodiment] Hereinafter, the present invention will be described in more detail. The present invention provides a functional UV coating comprising a flavonoid compound, a compound, a compound or a mixture thereof, wherein the compound I has a dry circumference of from 250 to 1 Torr. The class of the xanthine compound, which is widely distributed in plants, is derived from 1355406 19702pif.doc-us, which means coffee color in the form of machinery and means a plant pigment which is fine as a basic knot. The animal contains relatively low amounts of flavonoid compounds and the flavanoids are abundant in the leaves, flowers, roots, fruits and stems of the plants. The polyphenol compound is a chemical substance distributed in a specific plant, which is a bitter and bitter and has a structure of an aromatic compound such as benzene containing at least one hydroxyl group (-〇H). Polyphenolic compounds are generally known to have pharmacological functions such as antibiotics and anti-inflammatory effects, smoothing the skin, lowering cholesterol, and anti-allergic effects. Aliphatic alcohol compounds having a lipid-like core are generally contained in hormones. However, the lipid alcohol compound may have various structures depending on its substituent and it also exists in plants. Among these compounds, a compound having a molecular weight of from 250 to 1,000, can be used in the present invention. When the molecular weight is less than 250, the volatility is not as high as desired. When the molecular weight is greater than 1 Å, an oligomer is formed which increases the viscosity of the added material or relatively decreases the adsorption of the organic material. Although the flavonoid compound or polyphenol compound used in the present invention is not particularly limited, it is preferably an anthocyanin, anthocyanin, catechin or tannic acid which is a tea or tannic acid. . The phenol has a structure represented by Formula 1 ((+catechol) and a structure represented by Formula 2_((+)_catechol) and is known to be based on such structural derivatives. 1355406 1970lpif.doc Formula 1

式2Equation 2

同樣,兒茶酚為已知具有各種藥理學作用之功能性化 合物。 雖然適用於本發明之類脂醇化合物並不特別受限,但 較佳為膽固醇(cholesterol)、皂角苦(saponin)等等,尤其為 皂角苷。 皂角苷可具有醣連接於類脂醇核(糖苷配基)之結構, 例如由式3及4表示之結構。醣之實例包括D-葡萄糖、D-半乳糖、L-阿拉伯糖(arabinose)及D-鼠李糖(rhamnose)。 1355406 19702pif.doc 式3Also, catechol is a functional compound known to have various pharmacological effects. Although the aliphatic alcohol compound suitable for use in the present invention is not particularly limited, it is preferably cholesterol (cholesterol), saponin or the like, especially saponin. The saponin may have a structure in which a sugar is attached to a lipid alcohol core (aglycone), for example, a structure represented by Formulas 3 and 4. Examples of the sugar include D-glucose, D-galactose, L-arabinose, and D-rhamnose. 1355406 19702pif.doc Equation 3

式4Equation 4

類黃酮化合物、多酚化合物或類脂醇化合物可以塗料 總重計包括0.01至2重量%。當化合物之量小於0.01重量 %時,難於吸附VOCs等等。當化合物之量大於2重量% 時,儘管添加之量增加所得效果仍不明顯且由於化合物之 固有顏色使得用塗料之產品變色。 用於本發明之類黃酮化合物、多酚化合物或類脂醇化 12 19702pif.doc 特別受限,只要其含 金合歡屬樹、柿樹、二貫 紅茶、烏龍茶、茉莉茶'武 葡刼、柿子、綠茶、 碧茶、首孫茶、奥戈茶、白茶觀音茶、波格茶、尤 子茶及煙草葉。類黃輒合物、γι、粉末狀綠茶、決明 物之形式並不特別受限,但可。二化合物或類脂醇化合 物萃取物或粉末分散液之形式钱植物粉、植物薄片或植 例。現將更心崎轉㈣示性實施 綠命之主要成份為兒茶 (〇·㈤。加啡因(2·4% -18/丄、其他類細 (150-250 毫克%)、維,(0.6/〇)、維生素 C *〇3-29 % )、皂㈣、ftX 90-350 Ppm ) ·;广)(刚··毫克 PPm)。綠茶中最豐富之兒茶135-7=帅)及石西(1心 基(-OH)。因此,兒苹齡 ::化予、·、。構中具有多個羥 點上,兒茶盼具有移穩定°在這 肪連同維生素之氧化。此外,化作用並促進脂 對位化學_ 絲在㈣基團之鄰位與 應,且因而-旦發生化學上之多數反應為放熱反 原理捕獲V〇Cs及合物。綠茶粉末以相同 、、录命中之成份與人體中各種有 1355406 • · I9702pif.doc 機化合物反應。 藉由使用水或諸如醇之有機溶劑萃取綠茶或綠茶薄 片在液相中獲知·綠茶或綠茶薄片之萃取物。總揮發性有 機化合物(TV0Cs)意指在ISO 6000-3及6000-6下在 GC/MS分析過程中在己烷與十六烷之間偵測的所有 性有機化合物。 " 同時,乾植物粉或植物薄片尺寸可為〇〇2至125微 米。當乾植物粉或植物薄片尺寸小於〇 〇2微米時,由於粉 塵其難於與塗料混合或複合。當乾植物粉或植物薄片尺寸 大於125微米時,當其與塗料混合時難於將其均勻分散。 乾植物粉或植物薄片之量以塗料總重計較佳為丨至5重量 %,例如且更佳為丨至2.5重量%。當乾植物粉或植物薄片 之董小於1重量%時,由於粉末中有效成份量低難於獲得 所要之效果。當乾植物粉或植物薄片之量大於5重量% 時’儘官添加之量增加所得效果仍不明顯且由於粉末之固 有顏色可使塗料之顏色劣化。 用於製備植物萃取物及粉末分散液之溶劑可為任何用 於萃取有機材料之溶劑,但可為諸如自來水、蒸餾水及超 純水(ultrapure water)之水;諸如曱醇、乙醇、丙醇、丁醇、 異丙醇及己醇之醇類;諸如,例如亞麻子油(linseed oil)、 桐油~〇〇(10丨丨)及紫蘇子油(1^仙&〇][1)之乾性油的油類;諸 如丙烯酸樹脂(acryl resin)、環氧樹脂(epoxy resin)、胺基曱 酸醋樹脂(urethane resin)、g旨樹脂(ester resin)、石夕樹脂(silica resin)、三聚氰錄樹脂(meiamine resin)、紛盤樹脂(phen〇i 1355406 · 19702pif.doc resin)及脲醛樹脂(urea resin)的樹脂類等等。 雖然本實施例之UV塗料並不特別限制其應用,但其 可用於塗佈諸如門、窗、椅、桌、地板、牆紙、地面塗層、 天花板材料、壁櫥材料及地板材料、汽車之内部及外部、 電視、冰箱、泡菜冰箱及家庭用具之材料表面。 本發明亦提供用所述UV塗料塗佈之建材。此建材並 不特別受限,但其可為天花板材料、壁櫥材料或地板材料, 例如加熱地板、地面塗層或究碑。 • 含有綠茶組份之UV固化塗料可用作改良室内或地下 空間空氣品質之塗料。此外’ UV固化塗料可用於塗佈天 花板、地板及牆壁以最小化VOCs及HCHO。 * 現將詳述根據本發明之實施例製備UV塗料之方法。 • · 圖1為根據本發明之實施例的流程圖,其說明製備含 有乾植物粉或植物薄片粉末之UV塗料的製程。製備uv 塗料的方法包括.在粉碎乾植物後篩選粒徑為0 02至125 微米的微粒;充分混合包括募聚物之塗料原料;以及將以 Φ 塗料總重計的1至5重量%之量的微粒添加或分散於經混 合之塗料原料中。圖1為製備含有乾植物粉或植物薄片粉 末的uv塗料之製程圖。製備方法包括處理微粒、混合塗 - 料原料、複合、調節以及檢查。 在處理微粒時,使用粉碎機以高轉速粉碎綠茶葉及 里。粉碎完成後’自粉碎機中排出的空氣及經粉碎之微粒 使用鼓風機根據粒經來分類,且僅選擇及使用粒徑為 至125微米之微粒。 ’ 15 1355406 19702pif.doc 在所述方法中,可將植物之液體萃取物或微粒之分散 液代替微粒添加至塗料原料中。所述粉末可添加至塗料原 料中’但可經有機溶劑萃取以形成液體萃取物或可溶解或 分散於溶劑中。 混合塗料原料為在複合綠茶粉末之前充分混合為uv 固化塗料之主要原料的寡聚物與單體。 一般而言’將所用之UV塗料分為無溶劑UV塗料與 基於溶劑之UV塗料,且其主要組份如表3中所述。The flavonoid compound, polyphenol compound or lipid-like compound may comprise from 0.01 to 2% by weight, based on the total weight of the coating. When the amount of the compound is less than 0.01% by weight, it is difficult to adsorb VOCs and the like. When the amount of the compound is more than 2% by weight, the effect obtained by the increase in the amount of addition is not remarkable and the product of the coating is discolored due to the inherent color of the compound. The flavonoid compound, polyphenol compound or lipid-alcohol 12 19702pif.doc used in the present invention is particularly limited as long as it contains acacia, persimmon, two-dimensional black tea, oolong tea, jasmine tea 'wu bai 刼, persimmon, Green tea, Bicha, First Sun Tea, Ogo Tea, White Tea Guanyin Tea, Bog Tea, Youzi Tea and Tobacco Leaves. The form of the xanthine-like compound, γι, powdered green tea, and cassia is not particularly limited, but it is acceptable. A plant powder, plant flake or plant in the form of a di-compound or a lipool compound extract or a powder dispersion. Now it will be more heart-warming. (IV) The main ingredient of the implementation of green life is catechu (〇·(5). Adding morphine (2.4% -18/丄, other types fine (150-250 mg%), dimension, ( 0.6 / 〇), vitamin C * 〇 3-29%), soap (four), ftX 90-350 Ppm);; wide) (gang · mg PPm). The most abundant tea in green tea is 135-7=handsome) and Shixi (1 heart base (-OH). Therefore, the age of the child is: 化, 、,. The structure has multiple hydroxyl points, tea hope It has a shift stability in this fat together with the oxidation of vitamins. In addition, the chemical action and promote the lipid alignment chemistry _ silk in the ortho position of the (d) group, and thus the chemical reaction of most of the reaction to the exothermic anti-principle capture V 〇Cs and compound. The green tea powder is reacted with various compounds in the human body by the same, and recorded ingredients. The green tea or green tea flakes are extracted in the liquid phase by using water or an organic solvent such as alcohol. Known · Extracts of green tea or green tea flakes. Total Volatile Organic Compounds (TV0Cs) means all detected between hexane and hexadecane during GC/MS analysis under ISO 6000-3 and 6000-6 " At the same time, dry plant powder or plant flakes can range in size from 〇〇2 to 125 microns. When dry plant powder or plant flakes are smaller than 〇〇2 microns, it is difficult to mix or recombine with paint due to dust. Dried plant powder or plant flakes larger than 1 At 25 microns, it is difficult to uniformly disperse it when it is mixed with the coating. The amount of dry vegetable powder or plant flakes is preferably from 丨 to 5% by weight, based on the total weight of the coating, and more preferably from 丨 to 2.5% by weight. When the amount of the plant powder or the plant flakes is less than 1% by weight, it is difficult to obtain the desired effect because the amount of the active ingredient in the powder is low. When the amount of the dry plant powder or the plant flakes is more than 5% by weight, the effect of increasing the amount of the official addition is still It is not obvious and the color of the paint is deteriorated due to the inherent color of the powder. The solvent used for preparing the plant extract and the powder dispersion may be any solvent for extracting the organic material, but may be, for example, tap water, distilled water and ultrapure water ( Ultrapure water; alcohols such as sterols, ethanol, propanol, butanol, isopropanol, and hexanol; such as, for example, linseed oil, tung oil ~ 〇〇 (10 丨丨), and perilla An oil of a dry oil of a sub-oil (1^仙&〇][1); such as an acryl resin, an epoxy resin, an urethane resin, a resin (ester resin), Shixi resin (sili Ca resin), melamine resin, resin (phen 〇 1355406 · 19702 pif. doc resin) and urea resin (such as urea resin), etc. Although the UV coating of this embodiment is not It is particularly limited in its application, but it can be used for coating such as doors, windows, chairs, tables, floors, wallpaper, floor coatings, ceiling materials, closet materials and flooring materials, interior and exterior of automobiles, televisions, refrigerators, kimchi refrigerators and The surface of the material for household appliances. The invention also provides a building material coated with the UV coating. The building material is not particularly limited, but it may be a ceiling material, a closet material or a flooring material such as a heated floor, a floor coating or a monument. • UV-curable coatings containing green tea components can be used as coatings to improve indoor or underground space air quality. In addition, UV curable coatings can be used to coat ceilings, floors and walls to minimize VOCs and HCHO. * A method of preparing a UV coating according to an embodiment of the present invention will now be described in detail. • Figure 1 is a flow diagram illustrating a process for preparing a UV coating containing dry plant powder or plant flake powder, in accordance with an embodiment of the present invention. The method for preparing a uv coating comprises: screening particles having a particle diameter of 0 02 to 125 μm after pulverizing the dried plants; thoroughly mixing the coating material including the polymer; and adding 1 to 5% by weight based on the total weight of the Φ coating The particles are added or dispersed in the mixed coating material. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a process chart for preparing a uv paint containing dried plant powder or plant flake powder. Preparation methods include treating the particles, mixing the coating materials, compounding, conditioning, and inspection. In the treatment of the fine particles, the green tea leaves and the rins are pulverized at a high rotation speed using a pulverizer. After the pulverization is completed, the air discharged from the pulverizer and the pulverized particles are classified according to the granules using a blower, and only particles having a particle diameter of 125 μm are selected and used. ' 15 1355406 19702pif.doc In the method, a liquid extract of a plant or a dispersion of microparticles can be added to the coating material instead of the microparticles. The powder may be added to the coating stock' but may be extracted with an organic solvent to form a liquid extract or may be dissolved or dispersed in a solvent. The mixed coating material is an oligomer and a monomer which are sufficiently mixed as a main raw material of the uv-cured coating before the composite green tea powder. In general, the UV coatings used were classified into solvent-free UV coatings and solvent-based UV coatings, and the main components thereof are as described in Table 3.

表3 基於溶劑的UV塗料 無溶劑的UV塗iliif 60至80重量 物、20至30重量%之^ 體、光引發劑 主要成份 50至60重量%之寡聚 物、30至40重量%之溶 劑(稀釋劑、醇、水)、 光引發劑 次成份 消泡劑、展延顏料 (extender pigment)、添 加劑 單體、消泡劑、 料、添加劑 ^ ,烯酸酯、聚酯丙烯“ ^二丙烯 寡聚物 _ 涵基甲酸酯丙_酸酯、環 氧丙烯酸酯、聚酯丙烯酸 酯、聚矽氧丙烯酸酯 UV塗料中之添加劑為開發功能性 且其實例包括調平劑、消_、阻聚劑、^ 劑。例如,當添加氟樹脂時,抗污染⑽加月 抗此滅 聚石夕氧組份時硬度增加’且#添 二7特突 出遠紅外線。 、斑石(elvan)時韻 當乾植物粉或植物薄片粉末用作添加劑時,可提供具 1355406 , 19702pif.doc 有減少之VOCs及捕獲HCHO的功能性塗料。同樣,當使 用乾植物粉或植物薄片粉末代替作為展延顏料之滑石粉或 CaCCb時,UV塗料中之乾植物粉含量增加,其可更有效 減少VOCs及移除HCHO。 在複合過程中’將作為主要成份之寡聚物、單體及光 引發劑與作為輔助成份之消泡劑、展延顏料及添加劑混合 且複合。在本發明中,添加製備好之乾植物粉或植物薄片 粉末代替展延顏料或添加劑且徹底分散。 鲁乾植物粉或植物薄片粉末之量為所述塗料具有合適之 黏度以維持習知UV塗料之可使用性且不變色之量。因 • ,,乾植物粉或植物薄片粉末之量為以塗料總重計的5重 里j或更少。儘官乾植物粉或植物薄片粉末可添加高至10 'f量% ’但塗料失去其基本顏色且根據植物之顏色而著色。 乾植物粉或植物薄片粉末之粒徑應為125微米或 小’例如,100微米或更小,以不影響uv塗料之分散、 及形狀。當粒徑大於125微米時,乾植:粉 _ 殿。當將含有此粉末之塗料塗佈於產品上時 於均勻塗佈且可使用性差。 、 為改良UV塗料中之乾植物粉或植物薄片粉末的 工可將乾植物粉或植物薄片粉末在溶於或分散於諸 ,子油L桐油及紫蘇子油之乾性油類;水;諸如甲醇 :、二醇、丁醇、異丙醇及己醇之醇類;及諸如丙烯酸樹 二、胺基甲酸醋樹脂、_的合成樹脂後與 1355406 19702pif.doc 節。;寒占度或光澤度需根據UV塗料之用途來調 勃過程令,判斷uv塗料是否符合標準要求,且 八二武及產品適用性測試。經此過程,最終獲得 含有綠余組份之UV塗料。 實例 製備UV固化塗料 實例1 鲁 ❹粉铺Μ轉速粉碎綠茶I在經鼓風機分類之 微粒中僅篩選粒徑為0.02至i25微米之微粒。塗料原料充 分混合後,將綠茶粉末添加至具有如表4之含量的塗料原 料中且分散以獲得UV、塗料。在表4 +,胺基曱酸醋丙稀 • 酸醋與環氧丙烯酸酯用作募聚物(60重量%),包括 DPHA(dipentaerythrytol hexaacrylate)之丙烯酸酯單體或苯 乙缔單體用作單體(25重量%),且使用具有兩個或兩個 以上官能部分之光引發劑(4重量%)'添加劑(1重量0/〇) 鲁 以及展延顏料(8重量%)。塗料原料為AULEX 893FK-HV 且添加No050404綠茶(2重量%)。Table 3 Solvent-Based UV Coatings Solvent-Free UV Coating iliif 60 to 80 Weight, 20 to 30% by Weight, Photoinitiator Main Component 50 to 60% by Weight of Oligomer, 30 to 40% by Weight of Solvent (diluent, alcohol, water), photoinitiator sub-component defoamer, extender pigment, additive monomer, defoamer, material, additive ^, enoate, polyester propylene " ^ dipropylene Additives in oligo _ carbazate propionate, epoxy acrylate, polyester acrylate, polyoxy acrylate UV coatings are developed for functionality and examples include leveling agents, elimination, and resistance For example, when adding a fluororesin, the anti-pollution (10) plus moon increases the hardness when the anti-agglomerate component is increased, and #2 adds a special highlight of far infrared rays. When dry plant powder or plant flake powder is used as an additive, functional coatings with reduced VOCs and HCHO capture of 1355406, 19702 pif.doc are available. Similarly, when dry plant powder or plant flake powder is used instead of as a cast pigment UV coating when talc or CaCCb The content of dried plant powder is increased, which can reduce VOCs and remove HCHO more effectively. In the compounding process, the oligomer, monomer and photoinitiator as main components and defoaming agent as auxiliary component are extended. The pigment and the additive are mixed and compounded. In the present invention, the prepared dry plant powder or plant flake powder is added instead of the extended pigment or additive and thoroughly dispersed. The amount of the Lugan vegetable powder or the vegetable flake powder is suitable for the coating. Viscosity to maintain the usability of conventional UV coatings without discoloration. Because , , the amount of dry vegetable powder or plant flake powder is 5 or less in total weight of the coating. Plant flake powder can be added up to 10 'f%%' but the paint loses its basic color and is colored according to the color of the plant. The dry plant powder or plant flake powder should have a particle size of 125 microns or small 'for example, 100 microns or more. Small, so as not to affect the dispersion and shape of the uv coating. When the particle size is larger than 125 microns, dry: powder _ Hall. When the coating containing the powder is applied to the product, it is evenly coated and can be used. In order to improve the dry plant powder or plant flake powder in the UV coating, the dry plant powder or the plant flake powder may be dissolved or dispersed in the dry oil of the oil, the t-oil and the perilla oil; water; Alcohols such as methanol:, diol, butanol, isopropanol and hexanol; and synthetic resins such as acrylic acid tree II, urethane carboxylic acid resin, _ and 1355406 19702pif.doc section; cold or gloss According to the use of UV coatings, it is necessary to adjust the process order to determine whether the uv coating meets the standard requirements, and the applicability test of the october and the product. After this process, the UV coating containing the green component is finally obtained. EXAMPLES Preparation of UV Curing Coatings Example 1 Lu ❹ powder Μ rpm pulverizing green tea I only particles having a particle diameter of 0.02 to i25 μm were selected in the microparticles classified by the blower. After the coating materials were thoroughly mixed, green tea powder was added to the coating material having the contents as shown in Table 4 and dispersed to obtain UV, paint. In Table 4 +, amino phthalic acid acrylate vinegar and epoxy acrylate are used as a merging polymer (60% by weight), including DPHA (dipentaerythrytol hexaacrylate) acrylate monomer or styrene monomer Monomer (25% by weight), and a photoinitiator (4% by weight) with two or more functional moieties (1 wt%/〇) and a pigment (8 wt%) were used. The coating material was AULEX 893FK-HV and No050404 green tea (2% by weight) was added.

1355406 . 19702pif.doc 實例2 以與實例1相同之方式製備UV塗料,除使用7重量 %之展延顏料及2.5重量%之綠茶粉末之外。 實例3 以與實例1相同之方式製備UV塗料,除使用7重量 %之展延顏料及3重量%之綠茶粉末之外。 實例4 以與實例1相同之方式製備UV塗料,除使用5重量 %之展延顏料及5重量%之綠茶粉末之外。 比較性實例1 以與實例1相同之方式製備UV塗料,除使用10重量 %之展延顏料且不添加綠茶粉末之外。 比較並實例.2 以與實例1相同之方式製備uv塗料,除使用〇.1重 量%之綠茶粉末及9.9重量%之展延顏料之外。 比較性實例3 與實例1相同之方式製備UV塗料,除使用9重量% 之綠茶粉末及1重量%之展延顏料之外。 比較性實例4 以與實例1相同之方式製備UV塗料,除使用5重量 %之展延顏料及使用5重量%之明日葉(學名:Angelica KeiskeiKoidz)代替綠茶粉末之外。 比較性實例5 以與實例1相同之方式製備UV塗料,除使用5重量 19 1355406 19702pif.doc %之展延顏料及使用5重量。/。之羽衣甘藍(kale)代替綠茶粉 末之外。 實驗實例 晉測ΐΐν塗料之tvoc濃座Α逸散率 將在實例I·4及比較性實例1-5中製備的UV塗料各 1.2克以6.32公分x6.32公分面積塗佈於16.5公分xl6.5公 分玻璃上。將此玻璃以線速度10公尺/分鐘以212毫焦/平 方公分之UV燈照射。UV塗料之TVOC的逸散量及逸散 率使用小室(Small Chamber)及FLEC (場及實驗室發射 光電管(field and laboratory emission cell))來量測。所得 結果列於表5中。 表5 濃度(微克/立方 公尺) 逸散率(毫克/ 平方公尺小時) 實例1 171.29 0.057 實例2 160.04 0.053 實例3 159.46 0.053 實例4 120.90 0.040 比較性實例1 326.21~~ 0.11 比較性實例2 310.03 0.10 比較性實例3 229.25 0.07 比較性實例4 406.00^~~ 0.14 比車父性貫例5 236.12 - 0.08 軍測使_龛料之建教^的丁乂〇(::逸散率 將在貫例1-4及比較性實例i_5中製備的uv塗料塗 佈於地板材料上(植物園加熱地板(arb〇retum h_d 20 1355406 19702pif.doc floor),LGChem. Ltd.生產)。TVOC的逸散率使用小室來 置測。所得結果列於表6中。 表6 逸散率(毫克/平方公尺小時) 實例1 0.079 實例2 : 0.077 實例3 - 0.073 實例4 0.072 比較性實例1 0.106 比較性實例2 0.108 一 比較性實例3 0.102 一 比較性實例4 0.128 一 比較性實例5 0.103 ___ . 如表5中所示’在實例1-4中製備的UV塗料的濃度 及TV0C逸散率約為比較性實例1中數值的1/3。其中使 用明日葉及cale來代替綠茶粉末的比較性實例4及5展示 尚TVOC濃度及逸散率。同樣,比較性實例2及3具有比 φ 實例I—4更高之tvoc濃度及逸散率。此等結果表明實例 1-4之綠茶粉末濃度範圍最適合降低TV〇c濃度及逸散 率。因而,證實用於本發明之獲自天然植物之化合物可 效減少TVOC。如表6中所示,甚至當塗覆於建材上時 本發明之U V塗料亦降低τ v 〇 C逸散率。因而不同於習’ 建材,使用本發明之UV塗料之建材可阻撞 乂 物之曈辟。 合 1355406 . I9702pif.doc uv 外觀評估— 估用於TVQC逸散率之地板材料(植物園加熱 地板)的外觀。 圖2A至2C為塗有本發明之uv塗料之建材的照相影 像。參看圖?A至2C,實例i (圖2B)與比較性實例j (圖 2A)展tf類似表面狀態,而由於綠茶導致的顏色變淺,所 以比較性實例3 (圖2〇在外觀上有缺陷。 uv 防水性及防縿多枓#仕 圖3A至3C為展示塗有uv塗料的建材防水性及防變 色性的照相影像。評制於量測TVC)C逸散率的地板材料 (植物,加熱地板)之防水性及防變色性。在將樣本切割 成100毫米(長)X 50毫米(寬)之尺寸後,於25。。下將 樣本浸潰於水巾3公分深處。藉由連频察卜3、5及7 天,與可購得之加熱地板比較來判斷新產品之變色。在可 見光範圍内亮度差異使用Hunter Lab的Labscan XE設備 來比2。圖3D說明塗有UV塗料之建材的亮度。參看圖 3D,貝例1及2,以及比較性實例丨具有相似亮度,而含 有9重置%綠茶的比較性實例3展示亮度差異。 參看圖3A至3C,實例1 (圖3B)與比較性實例1 (圖 3A )具有相似防水性與防變色性’而比較性實例3 (圖3C ) 變成深綠色。 根據本發明實施例的功能性UV塗料可減少使用此塗 料的產品之VOCs以及此塗料自身之v〇Cs及HCHO。 雖然本發明已以較佳實施例揭露如上,然其並非用以 22 1355406.. 19702pif.doc 限定本發明’任何熟習此技藝者,在不脫離本發明之精神 和範圍内’當可作些許之更動與潤飾,因此本發明之保護 範圍當視後附之申請專利範圍所界定者為準。 【圖式簡單說明】 藉由參考附圖詳細描述其例示性實施例,本發明之上 •述及其它特徵及優點將變得更為明顯。 • 圖1為根據本發明之一實施例的流程圖,其說明製備 含有乾植物粉或植物薄片粉末之uv塗料的製程。 鲁 _ 2A至2C為塗有UV塗料的建材的照招影像。 圖3A至3C為展示塗有Uv塗料的建材防水性及防 色性的照相影像。 & 圖3D說明塗有UV塗料的建材的亮度。 -· 【主要元件符號說明】 fe 〇1355406 . 19702pif.doc Example 2 A UV coating was prepared in the same manner as in Example 1, except that 7 wt% of the cast pigment and 2.5% by weight of the green tea powder were used. Example 3 A UV coating was prepared in the same manner as in Example 1, except that 7 wt% of the cast pigment and 3% by weight of the green tea powder were used. Example 4 A UV coating was prepared in the same manner as in Example 1 except that 5% by weight of the pigment and 5% by weight of the green tea powder were used. Comparative Example 1 A UV coating was prepared in the same manner as in Example 1 except that 10% by weight of the pigment was used and no green tea powder was added. Comparative and Example. 2 A uv coating was prepared in the same manner as in Example 1, except that 0.1% by weight of green tea powder and 9.9 % by weight of a cast pigment were used. Comparative Example 3 A UV coating was prepared in the same manner as in Example 1, except that 9% by weight of green tea powder and 1% by weight of a cast pigment were used. Comparative Example 4 A UV coating was prepared in the same manner as in Example 1, except that 5% by weight of a cast pigment was used and 5% by weight of a tomorrow leaf (scientific name: Angelica Keiskei Koidz) was used instead of the green tea powder. Comparative Example 5 A UV coating was prepared in the same manner as in Example 1 except that 5 weights of 19 1355406 19702 pif.doc% of the pigment were used and 5 weights were used. /. Kale replaces green tea powder. Experimental Example: The tvoc-rich Α 散 散 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 涂料 UV UV UV UV UV UV UV UV UV UV UV UV 涂料5 cm on the glass. The glass was irradiated with a UV lamp at a line speed of 10 m/min at 212 mJ/cm. The TVOC dispersion and escape rate of the UV coating were measured using a small chamber and a FLEC (field and laboratory emission cell). The results obtained are shown in Table 5. Table 5 Concentration (μg/m^3) Emission rate (mg/m2h) Example 1 171.29 0.057 Example 2 160.04 0.053 Example 3 159.46 0.053 Example 4 120.90 0.040 Comparative Example 1 326.21~~ 0.11 Comparative Example 2 310.03 0.10 Comparative Example 3 229.25 0.07 Comparative Example 4 406.00^~~ 0.14 than the car father's example 5 236.12 - 0.08 Military test _ 之 之 建 ^ 乂〇 乂〇 : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : 4 and the uv paint prepared in Comparative Example i_5 was applied to the floor material (arbor 〇 heating floor (arb〇retum h_d 20 1355406 19702 pif. doc floor), manufactured by LG Chem. Ltd.). The escape rate of TVOC was set using a small chamber. The results obtained are shown in Table 6. Table 6 Emission rate (mg/m2h) Example 1 0.079 Example 2: 0.077 Example 3 - 0.073 Example 4 0.072 Comparative Example 1 0.106 Comparative Example 2 0.108 A comparative Example 3 0.102 A comparative example 4 0.128 A comparative example 5 0.103 ___ . As shown in Table 5, the concentration of the UV coating prepared in Examples 1-4 and the TV0C dissipation rate were approximately the values in Comparative Example 1. 1/3 Comparative Examples 4 and 5, in which the leaves and cales were used instead of green tea powder, showed the TVOC concentration and the escape rate. Similarly, Comparative Examples 2 and 3 had higher tvoc concentrations and escape rates than φ Examples 1-4. These results indicate that the green tea powder concentration range of Examples 1-4 is most suitable for reducing the TV〇c concentration and the escape rate. Thus, it was confirmed that the compound obtained from the natural plant used in the present invention is effective in reducing TVOC. It is shown that the UV coating of the present invention also reduces the τ v 〇C escape rate even when applied to building materials. Therefore, unlike the building materials, the building materials using the UV coating of the present invention can block the smashing of the sputum. 1355406 . I9702pif.doc uv Appearance Evaluation - Appearance of the floor material (botanical heating floor) used for TVQC escape rate. Figures 2A to 2C are photographic images of building materials coated with the uv paint of the present invention. 2C, Example i (Fig. 2B) and Comparative Example j (Fig. 2A) exhibited a surface state similar to tf, and the color due to green tea became lighter, so Comparative Example 3 (Fig. 2) was defective in appearance. uv Water repellency And 縿 縿 枓 仕 #仕图3A to 3C for the exhibition A photographic image showing the water repellency and anti-coloring properties of building materials coated with uv paint. It is evaluated for the waterproofness and discoloration resistance of floor materials (plants, heated floors) that measure TVC) C dissipation rate. After cutting the sample to a size of 100 mm (length) X 50 mm (width), at 25. . The sample was immersed in a water towel 3 cm deep. The color change of the new product was judged by comparing the available flooring with 3, 5 and 7 days. The difference in brightness over the visible light range was compared to 2 using Hunter Lab's Labscan XE device. Figure 3D illustrates the brightness of a building material coated with a UV coating. Referring to Fig. 3D, Bays 1 and 2, and Comparative Example 丨 have similar brightness, while Comparative Example 3 containing 9% by % green tea shows a difference in brightness. Referring to Figs. 3A to 3C, Example 1 (Fig. 3B) has similar water repellency and discoloration resistance as Comparative Example 1 (Fig. 3A) and Comparative Example 3 (Fig. 3C) became dark green. The functional UV coating according to an embodiment of the present invention can reduce the VOCs of the products using the coating and the v〇Cs and HCHO of the coating itself. Although the present invention has been disclosed in the preferred embodiments as described above, it is not intended to limit the invention to those skilled in the art without departing from the spirit and scope of the invention. The scope of protection of the present invention is defined by the scope of the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Other features and advantages will become more apparent from the detailed description of the embodiments. • Figure 1 is a flow diagram illustrating the preparation of a uv coating containing dry plant flour or plant flake powder, in accordance with an embodiment of the present invention. Lu _ 2A to 2C are photographs of building materials coated with UV coatings. 3A to 3C are photographic images showing the water repellency and color resistance of a building material coated with Uv paint. & Figure 3D illustrates the brightness of building materials coated with UV coatings. -· [Key component symbol description] fe 〇

23twenty three

Claims (1)

19702piD 為第95113129號申文專利範圍無劃線修正本·修正$100年3月1〇日 申請專輿範園: 1.一種uv塗料,包括類項合物、多齡化合物以 及類脂醇化合物或其混合物,以及展延顏料, 其中該化合物之分子量範圍為250至1000, 該類黃_化合物或該多酴化合物為至少一種由下列化 合物所構成的族群中選出的化合物:花黃素、花青素、兒 茶盼、丹寧酸及咖_因, 該類類脂醇化合物為至少一種由下列化合物所構成的 族群中選出的化合物:膽固醇、皂角苷及β_胡蘿蔔素, 以該塗料總重計,該類黃酮化合物、該多酚化合物或 該類脂醇化合物包括0.01至2重量%, 該類黃酮化合物、該多酚化合物或該類脂醇化合物呈 乾植物粉或植物薄片之形式,其中該乾植物粉或該二物薄 片具有0.02至125微米之粒徑, 該乾植物粉或該植物薄片代替一部份的展延顏料,且 以該塗料總重計,該乾植物粉或該植物薄片是以丨至5重 量%的量添加的。 土 2.如申請專利範圍第1項所述之UV塗料,其中該裏 黃酮化合物或該類脂醇化合物取自天然植物。/、 ^ 3.如申請專利範圍第2項所述之爪塗料, =植^為,、紅樹、桃花心木、金合歡屬樹、柿樹= ς ^頻杲、葡萄、柿子、綠茶、紅茶、烏龍苹、茉^ 木、武夷茶、鐵觀音茶、波格茶、尤碧茶、首孫茶、奥? 1355406 19702ρΐβ 為第则129號中文專利範圍無劃線修正本修正日期⑽年〕月則· 才t白茶、藍茶、粉末狀綠茶、決明子茶或煙草葉。 4·如申請專利範圍第!項所述之—塗料,其中以該 塗料總重計’該乾植物粉或該植物薄片是以〗至2 5 %的量添加的。 5·如申請專利範圍第1項所述之uv塗料,其中用於 該萃取物或該分散液之溶劑為至少一種由下列溶^所構成 的族群中選出的溶劑:水、醇、油及樹脂。 6.如申請專利範圍第!至5項中任一項所述之―塗 料,其用於塗佈至少一種由下列各物所構成的族群中選出 φ 的物體表面:門、窗、椅、桌、地板、牆紙、地面塗層、 天化板材料及地板材料。 7·—種建材,是經申請專利範圍第丨至5項中任一項 之UV塗料塗佈的。 、 8· —種製備UV塗料之方法,包括: 在粉碎一乾植物後’篩選粒徑為〇 〇2至125微米的微 粒; 充分混合包括募聚物、單體、光引發劑、添加劑及展 延顏料之UV塗料的一塗料原料;以及 以該塗料總重計,以1至5重量%的量將該些微粒添 加並分散於該經混合之該塗料原料中, 該乾植物包括類黃酮化合物、多酚化合物以及類脂醇 化合物或其混合物, 該類只嗣化合物或該多紛化合物為至少一種由下列化 合物所構成的族群中選出的化合物··花黃素、花青素、兒 ⑨ 25 1355406 19702piB 修正日期:100年3月10曰 為第95113129號中文專利範圍無劃線修正本 茶盼、丹寧酸及咖啡因, 該類類脂ϋ彳b合物為至少-種由下列化合物所構成的 族群中選出的化合物:膽固醇、皂角苷及P_胡蘿蔔素, 其中添加的該乾植物的微粒代替一部份的該展延顏 料。19702piD is the patent scope of No. 95113129. There is no slash correction. Amendment: March 100, 1100. Apply for a special garden: 1. A uv coating, including a class compound, a compound of a compound, and a lipid compound or a mixture thereof, and a cast pigment, wherein the compound has a molecular weight in the range of 250 to 1000, and the yellow compound or the polysaccharide compound is at least one selected from the group consisting of the following compounds: anthocyanin, cyanine a compound selected from the group consisting of cholesterol, saponin and β-carotene, with the total amount of the coating, the catechin, the tannin, and the coffee. The flavonoid compound, the polyphenol compound or the aliphatic alcohol compound comprises 0.01 to 2% by weight, and the flavonoid compound, the polyphenol compound or the aliphatic alcohol compound is in the form of a dry vegetable powder or a plant flake. Wherein the dry vegetable powder or the two-material flakes have a particle size of 0.02 to 125 microns, the dry plant powder or the plant flakes replace a part of the stretched pigment, and the total amount of the paint Meter, the plant dried plant powder or the sheet is Shu to 5 wt% of the amount added. 2. The UV coating of claim 1, wherein the flavonoid compound or the aliphatic alcohol compound is derived from a natural plant. /, ^ 3. For example, the claw coating mentioned in the second paragraph of the patent application, = planting, red, mahogany, acacia, persimmon = ς ^ frequency, grapes, persimmon, green tea, Black tea, Wulongping, Mojimu wood, Wuyi tea, Tieguanyin tea, Boge tea, Youbi tea, first sun tea, Austrian? 1355406 19702ρΐβ is the first Chinese patent range No. 129 No underline correction This correction date (10) year 〕月则· Only t white tea, blue tea, powdered green tea, cassia tea or tobacco leaves. 4. If you apply for a patent scope! The coating material, wherein the dry plant powder or the plant flakes are added in an amount of from 5% to 5% by weight based on the total weight of the coating. 5. The uv coating of claim 1, wherein the solvent for the extract or the dispersion is at least one selected from the group consisting of water, alcohol, oil, and resin. . 6. If you apply for a patent range! A coating according to any one of the items 5, which is used for coating at least one surface of an object selected from the group consisting of: a door, a window, a chair, a table, a floor, a wallpaper, a floor coating , Tianhua board materials and flooring materials. 7·—Building materials are coated with UV coatings according to any of the scopes of the patent application range 丨5 to 5. , a method for preparing a UV coating, comprising: screening a particle having a particle size of 〇〇2 to 125 μm after pulverizing a dry plant; thoroughly mixing the polymer, monomer, photoinitiator, additive, and extension a coating material of the UV coating of the pigment; and adding and dispersing the microparticles in the mixed coating material in an amount of 1 to 5% by weight based on the total weight of the coating, the dried plant comprising a flavonoid compound, a polyphenol compound and a lipool compound or a mixture thereof, the bismuth compound or the compound is at least one compound selected from the group consisting of the following compounds: lutein, anthocyanins, children 9 25 1355406 19702piB Revision date: 100 years March 10th is No. 95113129 Chinese patent scope without underline correction This tea expectant, tannic acid and caffeine, such lipid raft b compounds are at least one kind consisting of the following compounds Compounds selected from the group consisting of cholesterol, saponin and P-carotene, wherein the added dry plant particles replace a portion of the extended pigment. 9.如申請專利範圍第8項所述之製備UV塗料之方 法’其中將植物的液體萃取物或該微粒的分散液代替該微 粒添加至該塗料原料中。9. The method of preparing a UV coating according to claim 8, wherein the liquid extract of the plant or the dispersion of the microparticles is added to the coating material instead of the microparticle. 2626
TW095113129A 2005-04-22 2006-04-13 Functional uv paint, construction material using t TWI355406B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20050033643 2005-04-22
KR1020050115907A KR100768746B1 (en) 2005-04-22 2005-11-30 Functional UV paint, Construction material using the same, and method for preparing the paint

Publications (2)

Publication Number Publication Date
TW200637895A TW200637895A (en) 2006-11-01
TWI355406B true TWI355406B (en) 2012-01-01

Family

ID=37620162

Family Applications (1)

Application Number Title Priority Date Filing Date
TW095113129A TWI355406B (en) 2005-04-22 2006-04-13 Functional uv paint, construction material using t

Country Status (4)

Country Link
JP (1) JP5208728B2 (en)
KR (1) KR100768746B1 (en)
CN (1) CN101163765A (en)
TW (1) TWI355406B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2952067B1 (en) * 2009-11-03 2012-05-25 Saint Gobain Technical Fabrics FILMOGENIC COMPOSITION COMPRISING AN AGENT SUITABLE FOR TRAPPING FORMALDEHYDE
CN102304305B (en) * 2010-12-07 2013-12-18 中山市丽莎涂料有限公司 Persimmon peel extractive, extraction method thereof and formaldehyde-removal coating containing persimmon peel extractive
CN103509387A (en) * 2013-09-10 2014-01-15 马鞍山市金韩涂料制造有限公司 Epoxy resin anticorrosion paint comprising catechol, and preparation method thereof
CN106268166A (en) * 2016-10-31 2017-01-04 史书杰 A kind of remove formaldehyde and the method for benzene homologues in indoor, car
CN107740267A (en) * 2017-09-30 2018-02-27 江苏新瑞贝科技股份有限公司 A kind of uvioresistant finishing agent and preparation method thereof
CN108641446A (en) * 2018-05-31 2018-10-12 天津瑞杰塑料制品有限公司 A kind of special UV coating of PP plastics and preparation method thereof
KR101939707B1 (en) * 2018-09-19 2019-01-17 정원기계산업(주) Eco-friendly complex panel
CN109704641A (en) * 2019-02-26 2019-05-03 广西鼎康科技股份有限公司 A kind of diatomite plate and preparation method thereof that sound insulation effect is good
JP7543553B2 (en) * 2021-09-13 2024-09-02 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング Coating compositions containing sustainable pigments and methods of coating substrates therewith
KR102423141B1 (en) * 2021-09-29 2022-07-20 주식회사 에이스 인더스트리 Functional paint composition for non-flammable and anti-bacterial eco-friendly building finishes and construction method of eco-friendly building finishes using the same

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5318808A (en) 1992-09-25 1994-06-07 Polyset Company, Inc. UV-curable coatings
JP2001226827A (en) * 1999-11-30 2001-08-21 Erubu:Kk Composite formed product and its production method
JP2001286541A (en) * 2000-02-02 2001-10-16 Erubu:Kk Functional composition, functional resin composition and functional holding
KR20010107346A (en) * 2000-05-26 2001-12-07 김상헌 UV-curable coating resin by using used and new vegetable oils
JP2002060693A (en) * 2000-08-21 2002-02-26 Nippe Home Products Co Ltd Natural paint for wood
DE60135383D1 (en) * 2000-11-16 2008-09-25 Fujitsu Ltd LATENT PICTURE PRINT, PRINTER PRODUCT WITH LATENT PICTURE FROM THE PRINTING COLOR, READING PROCEDURE BASED ON DATA PICTURE DATA AND READING DEVICE FOR READING DATA
KR20040012361A (en) * 2002-08-02 2004-02-11 영동특산영농조합법인 Ink-Jet Ink Composition Include Extracted Tannin from Persimmon
KR20040064188A (en) * 2003-01-09 2004-07-16 손영석 Functional paint
US20050080160A1 (en) * 2003-08-14 2005-04-14 Seabrook Samuel G. Paints, coatings and polymers containing phytochemical agents and methods for making and using same
KR20060041368A (en) * 2004-11-08 2006-05-12 강윤식 Nature paint composition and manufacturing process
KR20060083241A (en) * 2005-01-14 2006-07-20 이구호 Wood flooring with natural paint and method of coating thereof

Also Published As

Publication number Publication date
JP2008537003A (en) 2008-09-11
KR100768746B1 (en) 2007-10-19
KR20060111353A (en) 2006-10-27
TW200637895A (en) 2006-11-01
CN101163765A (en) 2008-04-16
JP5208728B2 (en) 2013-06-12

Similar Documents

Publication Publication Date Title
TWI355406B (en) Functional uv paint, construction material using t
EP1871850B1 (en) Functional uv paint, construction material using the same, and method of preparing the paint
CN103055465B (en) A kind of oil-soluble formaldehyde scavenger and preparation method thereof
US20080200593A1 (en) Functional Adhesive, Construction Material Using the Same, and Method For Preparing the Adhesive
CN106310906B (en) A kind of room air eliminating smell agent and preparation method thereof having both sterilizing function
CN102690600A (en) Environment-friendly water-based paint and preparation method thereof
WO2021135722A1 (en) Coating having sterilization function and preparation method therefor and application thereof
US6755904B2 (en) Natural paint and method for manufacturing the same
CN110511631A (en) A kind of health environment-friendly coating and preparation method thereof
CN103965451B (en) The preparation method of the clean taste Synolac of a kind of environment-friendly type low viscosity
KR20100138320A (en) Paint composition for painting
KR20170052727A (en) Open Porous Inorganic-Polymer Hybrid Microspheres and Method Thereof, and Cosmetic Formulations Containing Them
CN104710917B (en) A kind of preparation method of novel, aqueous alkyd resin coating
Compton et al. Starch-encapsulated, soy-based, ultraviolet-absorbing composites with feruloylated monoacyl-and diacylglycerol lipids
KR101181871B1 (en) Paint composition for antifungal function and deodorization comprising phytochemical
KR101548878B1 (en) Wallpaper
CN109401500A (en) A kind of drawing acrylic paints of the pollen containing jasmine and preparation method thereof
CN105176178A (en) UV paint, preparation method and applications thereof
Phuriyakorn et al. Antioxidant and prebiotic gut-microbiota effects of dietary phenolic compounds in Etlingera elatior extracts.
Elsayed et al. Micro-encapsulation of Eugenia supra-auxillaris phenolics Rich Fraction for Its Possible Use as a Natural Food Preservative
ES2173045B2 (en) NEW WATER PAINTS IN WHICH THEIR COLOR IS ASSOCIATED WITH A FRAGRANCE, PROCEDURE FOR PREPARATION AND APPLICATIONS.
CN109135444A (en) A kind of agalloch eaglewood interior wall coating and preparation method thereof
CN105885668A (en) Zero-VOC waterborne soft-feel coating and preparation method thereof
KR100607689B1 (en) Water soluble paint composition for emanating emission of green tea and manufacturing method same
CN105062255A (en) Novel antibacterial fire-proof emulsion paint primer and preparation method thereof

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees