CN105176178A - UV paint, preparation method and applications thereof - Google Patents
UV paint, preparation method and applications thereof Download PDFInfo
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- CN105176178A CN105176178A CN201510526838.9A CN201510526838A CN105176178A CN 105176178 A CN105176178 A CN 105176178A CN 201510526838 A CN201510526838 A CN 201510526838A CN 105176178 A CN105176178 A CN 105176178A
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Abstract
The invention provides a functional UV paint, which comprises flavonoid compounds, steroid compounds, polyphenol compounds, or mixture thereof, and a graphene-metal oxide composite. The molecular weight of the compounds is in a range of 250 to 1000. The provided UV paint can reduce the VOC of products that is covered by the UV paint, moreover, the VOC and HCHO of UV paint are also reduced, the UV paint can absorb harmful gas and is capable of degrading pollutants under certain conditions, and the UV paint can be widely used in home and buildings.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of UV coating, Preparation Method And The Use.
Background technology
Affect in the pollutent of IAQ (indoor air quality) multiple, VOC and HCHO has impact to human nervous system and respiratory organs and causing circulatory, thus reduces the susceptibility of peripheral nervous system and has carciongenic potency and the toxicity as shown in table 1 (VOC of indoor generation and impact thereof) and table 2 (HCHO harm).Therefore, these materials are subject to control in Korea S, the U.S., Japan, Europe etc.
Table 1
Table 2
So far, by by TiO
2(photocatalyst), tourmalinite (inorganic materials), negatively charged ion, ZnO-MnO
2the coating that (novel material) etc. mix with synthetic resins and prepare is for improving IAQ (indoor air quality) or installing air handling unit to improve IAQ (indoor air quality) in house or commercial building.But due to high cost and unverified effect, these methods do not have efficient.
In addition, the efficiency of decomposition or absorption VOC and HCHO reduces in time.
Meanwhile, the polyphenolic substance of known natural gained, flavonoids and steroide have comprise deodorizing, the removing toxic substances of heavy metal and Nicotine, antitumous effect, suppression environmental hormone, anti-oxidant, decompose nitrite, several functions to the germicidal action of catechol component etc.These compounds are at present for the preparation of having the beverage of above-mentioned functions, makeup and numerous food.
In Korean Patent Publication No. 2002-46395,2003-26710 and 2003-72152, disclose the coating of the natural materials comprising such as wood powder (woodpowder), chaff powder (chaffpowder) and rice straw powder (rice-strawpowder).But the object of these patents provides texture, far infrared radiation function etc. to coating and reckons without VOC and HCHO, and described coating is aqueous coating.; CN200680013577.X discloses a kind of functional uv coating, uses the material of construction of this coating and prepare the method for this coating, this UV coating comprises flavonoids, steroide, polyphenolic substance or its mixture, for reducing the volatile quantity of VOC and removing HCHO, and this UV is coating material solidified fundamentally different from conventional coating, such as, UV is coating material solidified does not comprise tackiness agent and substantially containing by the light trigger by UV photocuring, and conventional coating comprises tackiness agent substantially and not containing UV inhibitor.
Although UV coating exists advantage in VOC and HCHO improvement, its performance needs to improve further.Therefore, there are the needs to the new functionalized UV coating that can meet the demand.
Summary of the invention
The invention provides a kind of environment amenable functional uv coating and Preparation method and use, this coating can make coating itself and use VOC and the HCHO dissipation amount of the product of coating to minimize, and can absorb polluted matter, under certain condition by contaminant degradation, and the physical properties of workability and paint film can not be affected.
Present invention provides the material of construction using described functional uv coating.
Present invention also offers the method preparing described functional uv coating.
According to a technical scheme of the present invention, provide the functional uv coating comprising polyphenolic substance, flavonoids, steroide or its mixture and Graphene-metal oxide compounds, wherein the molecular weight ranges of compound is 250 to 1000, as 300,400,500,600,700,800,900 or 950.
Graphene in described Graphene-metal oxide compounds is the Graphene of hydroxyl and/or carboxyl modified, and described metal oxide is titanium dioxide, cerium dioxide, tungstic oxide or ferric oxide.
The amount of described Graphene-metal oxide compounds is the 0.05-1% of coating gross weight, as 0.08%, 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8% or 0.9%.
Graphene has great surface-area, has excellent absorption property.Adding of Graphene-metal oxide compounds makes described UV coating to the significant adsorption as HCHO has of the pollutent in air, and HCHO can degrade by the metal oxide of graphenic surface under the irradiation of UV, therefore Graphene and metal oxide and polyphenolic substance, flavonoids, steroide or its mixture can cooperatively interact, and greatly improve the degradation amount of HCHO.
The granular size of described Graphene-metal oxide compounds is 10-500 nanometer, as 50 nanometers, 100 nanometers, 200 nanometers, 300 nanometers, 400 nanometers, 500 nanometers, 600 nanometers, 700 nanometers, 800 nanometers or 900 nanometers.
In UV coating, described flavonoids or polyphenolic substance can for being selected from the mixture by any one in xantheine, anthocyanidin, catechol, tannin and coffee or at least two kinds.
In UV coating, described steroide can be cholesterol, Saponin/TSM or β-carotene.
In UV coating, the described flavonoids of the 0.01-2wt% of coating based gross weight, polyphenolic substance or steroide can be comprised, as 0.05wt%, 0.08wt%, 0.1wt%, 0.2wt%, 0.3wt%, 0.4wt%, 0.5wt%, 0.6wt%, 0.7wt%, 0.8wt%, 0.9wt%, 1.0wt%, 1.2wt%, 1.4wt%, 1.5wt% or 1.8wt%.
In UV coating, described flavonoids or steroide can be obtained by natural phant.
In UV coating, described natural phant can be Oak Tree, mangrove, mahogany, Acacia tree, persimmon, chestnut shell, peach, apple, grape, persimmon, green tea, black tea, oolong tea, Jasmine tea, bohea (Wuyitea), extra-strong tea, ripple lattice tea (Bongrotea), You Bicha (Youbitea), first grandson's tea (Soosuntea), dagger-axe tea difficult to understand (Ogotea), white tea, blue tea, powdered green tea, cassia-tora tea (Gyeolmyeongjatea) or tobacco leaf.
In UV coating, described flavonoids, polyphenolic substance or steroide can be the forms of dry plant powder, plantflakesare, plant extract or powder dispersion.
In UV coating, described dry plant powder or plantflakesare can have the size of 0.02-125 micron, as 0.5 micron, 1.0 microns, 5.0 microns, 10 microns, 20 microns, 50 microns, 80 microns, 100 microns or 110 microns.
In UV coating, described dry plant powder or plantflakesare can the amount of 1-5wt% of coating based gross weight add, and the amount being preferably 1-2.5wt% as 1.5wt%, 2.0wt%, 2.5wt%, 3.0wt%, 3.5wt%, 4.0wt% or 4.5wt% adds.
In UV coating, the solvent for extract or dispersion can be water, alcohol, oil or resin.
Described UV coating may be used for applying the material surface of the inside of such as door, window, chair, table, floor, wallpaper, flooring material (floorcovering), ceiling tile materials, automobile and outside, wardrobe, TV, refrigerator, kraut refrigerator (kimchirefrigerator), household implements, closet material or flooring material.
According to a further aspect in the invention, the material of construction being coated with described UV coating is provided.
According to another aspect of the invention, provide the method preparing described UV coating, the method comprises: after being pulverized by dry plant, and screening granularity is the particulate of 0.02 to 125 micron; Abundant mixing comprises the coating raw material of oligopolymer; Graphene-the metal oxide compounds of gained particulate and 10-500 nanometer is added and is scattered in the coating raw material of mixing, wherein particulate adds with the amount of the 1-5wt% of coating based gross weight, and Graphene-metal oxide compounds adds with the amount of the 0.05-1% of coating based gross weight.
In the process, can particulate be replaced to join in coating raw material the dispersion of the liquid extract of plant or particulate.
Different from conventional UV coating, described functional uv coating comprise there is adsorptive power natural compounds with VOC and HCHO of the VOC and coating itself that reduce the product using described coating.
Compared with prior art, beneficial effect of the present invention is:
Functional uv coating provided by the invention can reduce use this coating the VOC of product and VOC and HCHO of this coating itself, the HCHO and functional uv coating of the present invention can adsorb and degrade under certain condition, thus reach the object of clean room air.
Accompanying drawing explanation
Fig. 1 is preparation technology's schema of the functional uv coating that the specific embodiment of the invention 1 provides.
Embodiment
Technical scheme of the present invention is further illustrated by embodiment below in conjunction with accompanying drawing.
The invention provides functional uv coating, it comprises flavonoids, polyphenolic substance, steroide or its mixture and Graphene-metal oxide compounds, and wherein the molecular weight ranges of compound is 250 to 1000.
Flavonoid (flavonoid) compound being distributed widely in the amber colour in plant is derived from " flavus ", and its being meant in Greek is amber and mean to have the vegetable pigment of structure based on flavones.Containing the flavonoids of relatively low amounts in animal, and flavonoids is abundant in the leaf of plant, flower, root, fruit and stem.
Polyphenolic substance is tasting the chemical substance distributed in the specified plant of puckery and hardship, and has the structure of the aromatic substance of the such as benzene containing at least one hydroxyl (-OH).Known polyphenolic substance has pharmacotoxicological effect, such as microbiotic and anti-inflammatory action, makes skin smooth, reduces cholesterol and anti-allergic effects.
The steroide with steroid nucleus is contained in hormone usually.But steroide can have various structures according to its substituting group and it is also present in plant.
In these compounds, the compound with the molecular weight of 250 to 1000 can be used in the present invention.When molecular weight is less than 250, volatility is unsatisfactoryly high.When molecular weight is greater than 1000, form oligopolymer, its viscosity increasing adding material or the adsorptive power relatively reduced organic materials.
Be not particularly limited for flavonoids of the present invention or polyphenolic substance, but preferred xantheine, anthocyanidin, catechol or tannin, particularly catechol or tannin.
Catechol has the structure represented by general formula 1 ((-)-catechol) and the structure represented by general formula 2 ((+)-catechol) and known many derivatives based on this structure.
General formula 1
General formula 2
Equally, catechol is the known functional compound with multiple pharmacotoxicological effect.
Be not particularly limited for steroide of the present invention, but preferred cholesterol, Saponin/TSM etc., particularly Saponin/TSM.
Saponin/TSM can have the carbohydrate structure being connected to steroid nucleus (glucoside unit), the structure such as represented by general formula 3 and 4.The example of carbohydrate comprises D-Glucose, D-semi-lactosi, L-arabinose and D-rhamnosyl.
General formula 3
General formula 4
The amount of 0.01-2wt% of coating based gross weight can comprise flavonoids, polyphenolic substance or steroide.When the amount of compound is less than 0.01wt%, be difficult to absorption VOC etc.When the amount of compound is greater than 2wt%, although the amount of adding to increase income effect not obvious, and make the product variable color with coating due to the inherent colour of compound.
Can obtain from natural phant for flavonoids of the present invention, polyphenolic substance or steroide.Described plant is not particularly limited, as long as it contains above-claimed cpd.The example of described plant comprises Oak Tree, mangrove, mahogany, Acacia tree, persimmon, shell, peach, apple, grape, persimmon, green tea, black tea, oolong tea, Jasmine tea, bohea, extra-strong tea, ripple lattice tea, You Bicha, first grandson's tea, dagger-axe tea difficult to understand, white tea, blue tea, powdered green tea, cassia-tora tea and tobacco leaf.The form of described flavonoids, polyphenolic substance or steroide is not particularly limited, but can be the form of dry plant powder, plantflakesare or plant extract or powder dispersion.
Now more detailed description is used the illustrative embodiment of the UV coating of green tea.
The main component of green tea is catechol (10 ~ 18%), other flavonoid (0.6 ~ 0.7%), caffeine (2 ~ 4%), polysaccharide (0.6%), vitamins C (150 ~ 250 milligrams of %), vitamin-E (25 ~ 70 milligrams of %), β-carotene (13 ~ 29 milligrams of %), GABA (γ-aminobutyric acid) (100 ~ 200 milligrams of %), Saponin/TSM, fluorine (90 ~ 350ppm), zinc (35 ~ 75ppm) and selenium (1.0 ~ 1.8ppm).Catechol the abundantest in green tea has multiple hydroxyl (-OH) in its chemical structure.Therefore, catechol can be easy to combine will by stable VOC.In this, catechol has the antioxygenation of active oxygen in removing body and promotes that fat is together with the oxidation of VITAMIN.In addition, catechol is at the ortho position of polyphenol group and contraposition chemisorption HCHO.Majority reaction in polyphenol group is thermopositive reaction, and thus once there is chemical bonding, then described bonding has strong bonding force.Therefore, the material experiencing chemical reaction can not be released again.Saponin/TSM and tristearin, alcohol, phenol etc. combine to form more insoluble molecular compound.Green tea powder, with the same principle with multiple organic compound reaction in composition in green tea and human body, catches VOC and HCHO.
By using organic solvent extraction green tea or the green tea thin slice of water or such as alcohol, obtain the extract of green tea or green tea thin slice in the liquid phase.Total volatile organic compound (TVOC) refers to according to ISO6000-3 and 6000-6, all volatile organic compoundss detected between hexane and n-Hexadecane in GC/MS analytic process.
Meanwhile, the size of dry plant powder or plantflakesare can be 0.02 to 125 micron.When the size of dry plant powder or plantflakesare is less than 0.02 micron, due to dust, it is difficult to mix and compound with coating.When the size of dry plant powder or plantflakesare is greater than 125 microns, be difficult to dispersed when it mixes with coating.The amount of dry plant powder or plantflakesare is preferably 1 to the 5wt% of coating based gross weight, such as, and is more preferably 1 to 2.5wt%.When the amount of dry plant powder or plantflakesare is less than 1wt%, be difficult to obtain required effect because effective constituent amount in powder is low.When the amount of dry plant powder or plantflakesare is greater than 5wt%, although the amount of adding to increase income effect not obvious, and the color deterioration of coating can be made due to the inherent colour of powder.
Solvent for the preparation of plant extract and powder dispersion can be any solvent for extracting organic materials, but can be the water of such as tap water, distilled water and ultrapure water; The such as alcohol of methyl alcohol, ethanol, propyl alcohol, butanols, Virahol and hexanol; Such as, as the oil of the siccative oil of Toenol 1140, tung oil and perilla oil; The such as resin etc. of acryl resin, epoxy resin, urethane resin, ester resin, silica resin, melamine resin, phenol resins and urea element resin.
The application of the UV coating of present embodiment is not particularly limited, but it can be used for applying the surface of inside and outside, TV, refrigerator, kraut refrigerator and household implements of such as door, window, chair, table, floor, wallpaper, flooring material, ceiling tile materials, closet material and flooring material, automobile.
Present invention provides the material of construction with described UV applying coating.Described material of construction is not particularly limited, but it can be ceiling tile materials, closet material or flooring material, such as heating floor, flooring material or ceramic tile.
In order to improve the Air quality in room or the underground space, the UV containing green tea component can be used coating material solidified as coating.And coating material solidified coating top ceiling, floor and the wall of can be used for of described UV minimizes to make VOC and HCHO.
Now in detail the method preparing UV coating according to the embodiment of the present invention will be described.
Fig. 1 comprises the schema of the step of the UV coating of dry plant powder or plantflakesare powder for inventing the preparation provided.Described preparation process comprises particulate process, the mixing of coating raw material, compound, adjustment and inspection.The method preparing UV coating comprises: after being pulverized by dry plant, and screening granularity is the particulate of 0.02 to 125 micron; Abundant mixing comprises the coating raw material of oligopolymer; And the Graphene-metal oxide compounds of the amount of the particulate of the amount of 1 to the 5wt% of coating based gross weight and coating based gross weight 0.05-1wt% is added and is scattered in the coating raw material of mixing, Graphene-metal oxide compounds of the present invention is the raw material that those skilled in the art can be obtained by prior art, and therefore not to repeat here.
In process particulate, pulverizer is used to pulverize green tea and stem with high rotating speed.After pulverizing completes, use gas blower according to granularity by air and the pulverizing microparticle classification of discharging from pulverizer, and only select and use granularity to be the particulate of 0.02 to 125 micron.
In the process, can particulate be replaced to join in coating raw material the dispersion of the liquid extract of plant or particulate.Described powder can join in coating raw material, but organic solvents available carries out extracting to form liquid extract, or solubilized or be scattered in solvent.
Before compound green tea powder, compo raw material fully mixes to make the oligopolymer as the coating material solidified main raw material of UV with monomer.
Normally used UV coating is divided into solvent-free UV coating and the UV coating based on solvent, and its main ingredient is as described in table 3.
Table 3
Additive in UV coating is the material that adds in development functionality product and the example comprises levelling agent, defoamer, stopper, dispersion agent and anti-sludging agent.Such as, when adding fluoro-resin, resistance to crocking increases; When adding particular silicone component, hardness increases; And when adding elvan, send far infrared rays.
When using dry plant powder or plantflakesare powder as additive, the VOC with minimizing and the functional coating of catching HCHO can be provided.Equally, when using dry plant powder or plantflakesare powder to replace talcum powder as pigment extender or CaCO
3time, the dry Plant Powder content in UV coating increases, and it more effectively can reduce VOC and remove HCHO.
In recombination process, mix as the oligopolymer of main component, monomer and light trigger and compound with as the defoamer of ancillary component, pigment extender and additive.In the present invention, add the dry plant powder prepared or plantflakesare powder replacement pigment extender or additive and thoroughly disperse.
The amount of dry plant powder or plantflakesare powder be can make described coating have suitable viscosity with maintain conventional UV coating workability and can not the amount of variable color.Thus, the amount of dry plant powder or plantflakesare powder is the 5wt% of coating based gross weight or less.Although can add dry plant powder or plantflakesare powder is up to 10wt%, coating loses its basic colors and painted according to the color of plant.
The granularity of dry plant powder or plantflakesare powder should be 125 microns or less, such as, 100 microns or less, not affect the described dispersion of UV coating, the formation of paint film and shape.When granularity is greater than 125 microns, dry plant powder agglomeration and precipitating.When the applying coating that will comprise this powder is on product, be difficult to even application and workability is poor.
In order to improve the dispersiveness of dry plant powder in UV coating or plantflakesare powder, be dissolved in or be scattered in the siccative oil of such as Toenol 1140, tung oil and perilla oil; Water; The such as alcohol of methyl alcohol, ethanol, propyl alcohol, butanols, Virahol and hexanol; And after the synthetic resins of such as acryl resin, epoxy resin, urethane resin and ester resin, dry plant powder or plantflakesare powder can be mixed with oligopolymer.
The viscosity of UV coating or gloss need adjust according to the purposes of UV coating.
In checking process, judge the whether conformance with standard requirement of described UV coating, and carry out standardized test and product Operability Testing.Through this process, final acquisition comprises the UV coating of green tea component.
Embodiment 1
UV is coating material solidified in preparation
Pulverizer is used to be pulverized by green tea with high rotating speed.The particulate that granularity is 0.02 to 125 micron is only screened in the particulate of classifying with gas blower.After coating raw material is fully mixed, the Graphene-titanium dioxide compound of green tea powder and 100 nanometers to be joined in the coating raw material with content as shown in table 4 and to carry out disperseing to obtain UV coating.In table 4, use urethaneacrylates and epoxy acrylate as oligopolymer (60wt%), use styrene monomer or comprise double pentaerythritol methacrylate (dipentaerythrytolhexaacrylate) acrylate monomer as monomer (25wt%), and use light trigger (4wt%), additive (1wt%) and the pigment extender (8wt%) with two or more functional moieties.Coating raw material is AULEX893FK-HV and adds No. 050404 green tea (2wt%) and Graphene-titanium dioxide compound (0.8wt%).
Table 4
Embodiment 2
Except using the Graphene-iron oxide composite end of the pigment extender of 7wt%, the green tea powder of 2.5wt% and 1wt%, prepare UV coating in the same manner as example 1.
Embodiment 3
Except using the Graphene-ceria composites of the pigment extender of 7wt%, the green tea powder of 3wt% and 0.5wt%, prepare UV coating in the same manner as example 1.
Embodiment 4
Except using the Graphene-tungstic oxide mixture of the pigment extender of 5wt%, the green tea powder of 5wt% and 0.05wt%, prepare UV coating in the same manner as example 1.
Comparative example 1
Except the use pigment extender of 8wt% and the green tea powder of 2wt%, prepare UV coating in the same manner as example 1.
Comparative example 2
Except the use green tea powder of 2.5wt% and the pigment extender of 7wt%, prepare UV coating in the same manner as example 1.
Comparative example 3
Except the use green tea powder of 3wt% and the pigment extender of 7wt%, prepare UV coating in the same manner as example 1.
Comparative example 4
Except using the pigment extender of 5wt% and using the angelica keiskei koidzumi (AngelicaKeiskeiKoidz) of 5wt% to replace except green tea powder, prepare UV coating in the same manner as example 1.
Comparative example 5
Except using the pigment extender of 5wt% and using the kale (cale) of 5wt% to replace except green tea powder, prepare UV coating in the same manner as example 1.
Experimental example
The TVOC concentration of UV coating and the test of dissipation rate
Each 1.2 grams of the UV coating of preparation in embodiment 1 ~ 4 and comparative example 1 ~ 5 is coated on the glass of 16.5cm × 16.5cm with the area of 6.32cm × 6.32cm.Use 212mj/cm
2uV lamp irradiate this glass with linear velocity 10m/min.Small size building materials space simulation test module (SmallChamber) and FLEC (on-the-spot and testing laboratory's release cell) is used to test dissipation amount and the dissipation rate of the TVOC of UV coating.Acquired results is listed in table 5.
Table 5
Use the test of the TVOC dissipation rate of the material of construction of UV coating
By the UV applying coating of preparation in embodiment 1 ~ 4 and comparative example 1 ~ 5 on flooring material (Botanical gardens heating floor (arboretumheatedfloor), LG Chemical Ltd. produces).Use the dissipation rate of small size building materials space simulation test module test TVOC.Acquired results is listed in table 6.
Table 6
| Dissipation rate (mg/m 2hr) | |
| Embodiment 1 | 0.069 |
| Embodiment 2 | 0.067 |
| Embodiment 3 | 0.063 |
| Embodiment 4 | 0.062 |
| Comparative example 1 | 0.81 |
| Comparative example 2 | 0.76 |
| Comparative example 3 | 0.71 |
| Comparative example 4 | 0.81 |
| Comparative example 5 | 0.79 |
As shown in table 5, concentration and the TVOC dissipation rate of the UV coating prepared in embodiment 1 ~ 4 are about 1/3 of respective value in comparative example 1.Angelica keiskei koidzumi and kale is wherein used to replace the comparative example 4 and 5 of green tea powder to demonstrate high TVOC concentration and dissipation rate.Equally, comparative example 2 and 3 has the TVOC concentration higher than embodiment 1 ~ 4 and dissipation rate.These results show that the concentration range of the green tea powder of embodiment 1 ~ 4 is most suitable for reducing TVOC concentration and dissipation rate.Therefore, can confirm effectively can reduce TVOC for the compound by obtaining from natural phant of the present invention.As shown in table 6, even if when being applied to material of construction, UV coating of the present invention also can reduce TVOC dissipation rate.Therefore, be different from conventional building material, use the material of construction of UV coating of the present invention can serve as the blocking layer of hazardous compound.
The VOC of the product using described coating and VOC and HCHO of this coating itself can be reduced according to the functional uv coating of embodiment of the present invention.
Although with reference to its illustrative embodiments, illustrate and describe the present invention, but it will be apparent to those skilled in the art that when not departing from the spirit and scope of the invention that following claims limit, can to carry out in various ways and change in details.
Industrial usability
Functional uv coating according to the present invention can reduce the VOC of the product using described coating and VOC and HCHO of this coating itself.
Applicant states, the present invention illustrates method detailed of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned method detailed, does not namely mean that the present invention must rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of ancillary component, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (10)
1. a UV coating, is characterized in that, comprises flavonoids, polyphenolic substance and steroide or its mixture and Graphene-metal oxide compounds,
Wherein, the molecular weight ranges of described compound is 250 to 1000.
2. UV coating according to claim 1, is characterized in that, the Graphene in described Graphene-metal oxide compounds is the Graphene of hydroxyl and/or carboxyl modified, and described metal oxide is titanium dioxide, cerium dioxide, tungstic oxide or ferric oxide;
Preferably, the amount of described Graphene-metal oxide compounds is the 0.05-1% of coating gross weight.
3. UV coating according to claim 1 and 2, is characterized in that, the granular size of described Graphene-metal oxide compounds is 10-500 nanometer.
4. according to the UV coating one of claim 1-3 Suo Shu, it is characterized in that, described flavonoids or polyphenolic substance are the mixture be selected from by any one in xantheine, anthocyanidin, catechol, tannin and caffeine or at least two kinds;
Preferably, described steroide is selected from the mixture by any one in cholesterol, Saponin/TSM and β-carotene or at least two kinds.
5. according to the UV coating one of claim 1-4 Suo Shu, it is characterized in that, described UV coating comprises the described flavonoids of the amount of the 0.01-2wt% of coating gross weight, polyphenolic substance or steroide.
6. according to the UV coating one of claim 1-5 Suo Shu, it is characterized in that, described flavonoids, polyphenolic substance or steroide are the form of dry plant powder, plantflakesare, plant extract or powder dispersion;
Preferably, described dry plant powder or plantflakesare have the granularity of 0.02-125 micron;
Preferably, described UV coating adds described dry plant powder or the plantflakesare of the amount of the 1-5wt% of coating based gross weight, is preferably 1-2.5wt%.
7. UV coating according to claim 6, is characterized in that, the solvent that described UV coating is used for extract or dispersion is the mixture of any one or at least two kinds selected in free water, alcohol, oil and resin.
8. according to the purposes of the UV coating one of claim 1-7 Suo Shu, it is characterized in that, this coating selects the surface of free door, window, chair, table, floor, wallpaper, flooring material, ceiling tile materials or flooring material for applying.
9. a material of construction, this material of construction is coated with the UV coating described in claim 1-7 any one.
10. prepare a method for UV coating, the method comprises:
After being pulverized by dry plant, screening granularity is the particulate of 0.02 to 125 micron;
Abundant mixing comprises the coating raw material of oligopolymer; And
With the amount of the 1-5wt% of coating based gross weight described particulate added and be scattered in the coating raw material of mixing.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107740269A (en) * | 2017-09-30 | 2018-02-27 | 江苏新瑞贝科技股份有限公司 | A kind of uvioresistant finishing agent of bafta and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060237687A1 (en) * | 2005-04-22 | 2006-10-26 | Sunghoon Yue | Functional UV paint, construction material using the same, and method of preparing the paint |
| US20120289755A1 (en) * | 2009-11-26 | 2012-11-15 | Nisshinbo Holdings Inc. | Carbon catalyst for decomposition of hazardous substance, hazardous-substance-decomposing material, and method for decomposition of hazardous substance |
| CN103816869A (en) * | 2014-03-11 | 2014-05-28 | 济南大学 | Preparation method for magnetic mesoporous titanium dioxide / graphene oxide adsorbing material |
| CN104693929A (en) * | 2015-03-19 | 2015-06-10 | 济宁利特纳米技术有限责任公司 | Dope being able to absorb formaldehyde and based on graphene composite material and preparation method thereof |
-
2015
- 2015-08-25 CN CN201510526838.9A patent/CN105176178A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060237687A1 (en) * | 2005-04-22 | 2006-10-26 | Sunghoon Yue | Functional UV paint, construction material using the same, and method of preparing the paint |
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