CN107191518A - A kind of composite fibre high-quality friction material and preparation method thereof - Google Patents

A kind of composite fibre high-quality friction material and preparation method thereof Download PDF

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Publication number
CN107191518A
CN107191518A CN201710422674.4A CN201710422674A CN107191518A CN 107191518 A CN107191518 A CN 107191518A CN 201710422674 A CN201710422674 A CN 201710422674A CN 107191518 A CN107191518 A CN 107191518A
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Prior art keywords
composite fibre
fiber
friction material
hours
preparation
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CN107191518B (en
Inventor
张秋萍
杜建华
张银华
李辉
王浩旭
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HANGZHOU XIAOSHAN HONGQI FRICTION MATERIAL CO Ltd
Academy of Armored Forces Engineering of PLA
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HANGZHOU XIAOSHAN HONGQI FRICTION MATERIAL CO Ltd
Academy of Armored Forces Engineering of PLA
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/02Composition of linings ; Methods of manufacturing
    • F16D69/023Composite materials containing carbon and carbon fibres or fibres made of carbonizable material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/14Anti-slip materials; Abrasives
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0004Materials; Production methods therefor metallic
    • F16D2200/0008Ferro
    • F16D2200/0021Steel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0004Materials; Production methods therefor metallic
    • F16D2200/0026Non-ferro
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/006Materials; Production methods therefor containing fibres or particles

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Braking Arrangements (AREA)

Abstract

The present invention relates to a kind of composite fibre high-quality friction material and preparation method thereof, including the bottom sintered by intermediate layer HTHP and upper strata, bottom is steel core flaggy, and intermediate layer is copper fiber layer, and upper strata is annular friction layer.Copper fiber silk is incorporated into by the one side of fiber cloth, impregnated resin baking and curing simultaneously cuts to form upper strata and intermediate layer, with thermally treated, oxide skin, clean and dry after carry out the steel core plate overlapping of plating formation and formed through HTHP sintering.With lighter quality, high specific strength, stable coefficient of friction, the anti-wear performance of superelevation and heat resistance.

Description

A kind of composite fibre high-quality friction material and preparation method thereof
Technical field
The present invention relates to a kind of friction material, more particularly to a kind of composite fibre high-quality friction material and its preparation side Method.
Background technology
Friction pair is machine driving and the significant components of brake portion, and it is related to the reliable of vehicle power transmission and control Property.Friction pair is made up of friction plate and antithesis piece, and the performance of wherein friction pair depends primarily on the friction and wear behavior of friction plate. Existing domestic friction plate has that frictional behaviour is unstable, wear rate is high and the low problem of heat resistance in use, still, The serious performance for constraining the excellent mobility of assembly.Therefore, develop and match with high load capacity, high-energy, high-speed drive system , the Novel friction plate that service life length, reliability are high and friction pair it is very urgent and necessary.
Friction material is the critical material for constituting friction pair, and the high performance grinding under high speed, severe duty is applied at present Material mainly includes:Powder metallurgy friction material, carbon/carbon-carbon friction material, ceramic-based friction material, semimetal friction material and paper Base frication material.
Compared with metal base frication material, non-metal base friction material has excellent tribological property, is current friction One of material important development direction.The current non-metal base friction material mainly applied has carbon/carbon-carbon friction material, ceramic base friction Material and paper friction material.
(1)Carbon/carbon-carbon friction material
Carbon/carbon-carbon friction material due to height than by force than mould, low-density, heat conductivility and frictional behaviour is excellent and high-mechanic energy The outstanding features such as power, long life, than Metal Substrate brake material Mass lost 40%, the longevity is being used as aircraft finance lease 3-5 times of life extension, can be used for big energy brake, with high reliability and maintainability.Therefore, carbon/carbon-carbon friction material is extensive Critical material as aircraft brake system.In the U.S., many military aircrafts use carbon/carbon brake disc, such as F-16, B-1 Deng;Domestic Zhongnan Polytechnic Univ, Northwestern Polytechnical University and Shenyang metal etc. preparation in carbon/carbon brake disc and its frictional behaviour Research in terms of achieve abundant achievement.At present, it is domestic to prepare the process that carbon/carbon-carbon friction material uses and be mainly CVD, haves the shortcomings that production cycle length, the small, cost of batch are high;Technique is prepared also in laboratory preparatory phase, at present still Industrialization can not be formed.Above mentioned problem is to need to solve during carbon/carbon-carbon friction material develops.
(2)Ceramic-based friction material
Ceramic-based friction material can bear high surface temperature, with higher coefficient of friction, higher compression strength and relatively low Thermal coefficient of expansion, slide abrasiveness and corrosion stability be good, is class important materials in Friction Materials field in recent years.Mesh The more ceramic-based friction material of preceding research has Al2O3Base frication material and C/SiC friction materials, and with fiber reinforced ceramic Friction material is important development direction, to solve the brittleness problems of ceramic material.
C/SiC friction materials have the performances such as density is low, intensity is high, high temperature resistant, thermophysical property are good, especially with friction Coefficient is high and stably, and the advantages of influence to environment is insensitive, the advantage with substitution C/C friction materials is rubbed greatly by the U.S. four Wipe Materials Co., Ltd and be set to aircraft friction material of new generation.Meanwhile, because of the friction and wear behavior that C/SiC friction materials are excellent, in height The high energy such as fast train, automobile, aircraft, tank, which carry field, also to have wide practical use, thus C/SiC friction materials turn into current One of focus of high-quality friction material research.Using chemical vapor infiltration(CVI)Association reaction molten liquid forming(RMI)System It is high with kinematics and static friction coefficient for inexpensive, high performance C/SiC aircraft friction materials(Respectively 0.34,0.41), it is wet State is almost undamped(About 2.9%), wear and tear small(About 1.9 μm), the features such as stable friction performance.At present, the crisp of ceramic material is solved Property is the research emphasis of ceramic-based friction material.
(3)Paper friction material
Paper friction material comes across late 1950s, is that yield is maximum in the world today, most widely used wet type is rubbed Wipe one of material.Paper friction material is by cellulose fibre, high-performance fiber, special particle and additive and different viscous Connect agent to be made, be soft and porous material, through-thickness even structure is interconnected between hole.When friction pair is not engaged When, in hole can lubrication oil, when friction pair is engaged, oil flows out from porous material, so as to cool down friction surface.Paper base material Material elasticity is good, can be distributed uniform load on the whole surface by deforming during engagement.But it is due to that it is organic structure, Therefore the thermal conductivity factor of paper friction material, ratio of heat capacities copper base friction material are small.Meanwhile, excessive surface pressing can make material Fiber binder below surface disconnects, and spot occurs in material or large area comes off, and causes material failure.
In summary, the high cost of carbon/carbon-carbon friction material, the fragility of ceramic-based friction material and paper friction material Low-intensity is the bottleneck problem for restricting its large-scale promotion application, thus research has relatively low manufacturing cost, and with stabilization The friction material and its friction pair of coefficient of friction, low wear rate and high-fire resistance energy are the developing direction of non-metal base friction pair.
The content of the invention
The present invention mainly solution the deficiencies in the prior art have there is provided one kind is applied to high-energy-density transmission System condition high and stable coefficient of friction, low wear rate, a kind of high property of composite fibre of high heat-resistance coefficient and high performance-price ratio Energy friction material and preparation method thereof.
The above-mentioned technical problem of the present invention is mainly what is be addressed by following technical proposals:
A kind of composite fibre high-quality friction material, including bottom, intermediate layer and upper strata, the top of described bottom are provided with upper Layer, described bottom is formed with upper strata and intermediate layer by HTHP sintering, and described bottom is steel core flaggy, it is described in Interbed is copper fiber layer, and described upper strata is annular friction layer.
A kind of composite fibre high-quality friction material, is carried out according to the following steps:(1), textile sheet;
(2), the one side of fiber cloth is incorporated into copper fiber silk;
(3), by fiber cloth impregnating resin and baking and curing and cut to form upper strata and intermediate layer;
(4), take thermally treated steel plate, oxide skin, clean and dry after carry out plating formed as bottom steel core flaggy;
(5), upper strata and intermediate layer and steel core flaggy overlap sintered formation friction plate.
Preferably, fiber cloth braiding uses composite fibre, complex fiber material component ratio:
Composition 1:Carbon fiber 100%;
Or,
Composition 2:Carbon fiber 85-90%, aramid fiber 10-15%;
Or,
Composition 3:Carbon fiber 84-90%, aramid fiber 5-8%, glass fibre 5-8%.
Preferably, fiber cloth weaves squarely, with a diameter of 7 μm of composite fibre silk, according to the friction to be woven into Thickness degree puts 0.05mm surpluses and has calculated composite fibre thread number, and squarely fiber cloth is woven on 2.5D multidimensional braiders.
Preferably, during impregnating resin, fiber cloth is strutted, size applicator is sunk to, is vacuumized after size applicator sealing, vacuum It is 0.08Pa, the time vacuumized is 14 minutes, then adds glue, until being impregnated with.
Preferably, modified resin glue and 50% absolute alcohol that the glue in size applicator is 50%, the impregnation time are 2 small When, glue is drained after impregnation, Draining time is 2 hours.
Preferably, after after alcohol completely volatilization, entering back into baking oven and being dried, the temperature of drying is 120 DEG C, to arriving Untill drying.
Preferably, being placed into during solidification in baking oven, the temperature in baking oven rises to 120 degree, and soaking time is 18 minutes, is protected After temperature terminates, the temperature in baking oven is warming up to 150 degree, fibrous layer was opened oven door and put in baking oven inside holding 26 minutes Gas once, is then warming up to 180 degree again, then is incubated 2 hours or 2.5 hours, and insulation is cooled down after terminating.
Preferably, steel plate first rushes inside and outside circle using punch press;Again with excircle orientation, hot-leveling is adjusted according to steel core plate thickness Temperature, temperature carries out hot-leveling at 650 degree, and positive replicate is incubated -2.5 hours 2 hours;Then be heat-treated, harden for HRC35-45;Descale is vibrated again, is cleaned on cleaning machine, surface and oil contaminant is removed, and is dried;Steel core plate is put into plating Immersion plating is carried out in copper groove, solution composition is Cu+225 grams/liter, P2O7 -4(Total amount)175 grams/liter,(NH43C5H6O725 grams/ Litre, H2O surpluses, thickness of coating is 0.005mm.
Preferably, the frictional layer copper fiber the being punched silk side is carried out into frosted polishing, then burnishing surface direction Steel core plate, which is stacked, to be put on the backing plate of sintering stove, and sintering temperature is 850 degree, and pressure is 50kg every square centimeter, during insulation Between be 3 hours, formed friction plate.
After friction plate makes, required according to product drawing, product physical property and physical dimension are tested;According to Gu Visitor requires or enterprise product packing instructions, is packed;The attached quality certification of qualified products handles storage.
Advantage:
1st, the coupling method of traditional fiber-like material and steel core plate is by the gluing on steel core plate, then on vulcanizing press Carry out temperature-pressure and bond to form, the shortcoming of this adhesive method be colloid can not high temperature resistant hyperpyrexia, in the case of high temperature hyperpyrexia, The adhesion strength of colloid can be substantially reduced.It is laminated to fibre frictoin to be incorporated into and we use and steel core plate is electroplated Copper fiber silk, then carries out HTHP sintering, and adhesion strength is high, can high temperature resistant hyperpyrexia.
2nd, traditional fiber friction material is not because by colloid, heatproof is influenceed, and maximum heat-resistance coefficient is general 50000 Up and down, and we use is incorporated into copper fiber silk, the maximum heat-resistance coefficient of method for then carrying out HTHP sintering is more than 70000。
3rd, the fibrage class of traditional in the market is two-dimensional structure, and the number of plies is few.This technique weaves knot using 2.5D multidimensional Structure, not stratified with high damage tolerance, no delamination and the performance characteristics such as anti-shearing.It can have as friction material configuration There are lighter quality, high specific strength, stable coefficient of friction, excellent wearability and heat resistance.
We use carbon fiber plus aramid fiber and glass fibre, so can both improve coefficient of friction to increase Moment of torsion, can make material have certain expansion rate again, improve porosity, reduce noise and stablize coefficient of friction.
Therefore, a kind of composite fiber friction material of the invention and preparation method thereof, with lighter quality, Gao Biqiang Degree, stable coefficient of friction, the anti-wear performance of superelevation and heat resistance.
Embodiment
Below by embodiment, technical scheme is described in further detail.
Embodiment 1:A kind of composite fiber friction material, including bottom, intermediate layer and upper strata, the top of described bottom is set There is upper strata, described bottom is formed with upper strata by intermediate layer HTHP sintering, and described bottom is steel core flaggy, described Intermediate layer is copper fiber layer, and described upper strata is annular friction layer.
A kind of preparation method of composite fibre high-quality friction material, in following processing steps:
(1), composite fiber friction material component ratio:
Carbon fiber 100%;
(2) squarely fiber cloth, is woven:
With a diameter of 7 μm of composite fibre silk, 0.05mm surpluses are put according to the frictional layer thickness to be woven into and have calculated compound fibre Thread number is tieed up, such as friction plate thickness is 0.50mm, and number of share of stock is 4200-4700 strands during braiding, is woven on 2.5D multidimensional braiders Squarely fiber cloth, one side fiber cloth is incorporated into copper fiber silk as intermediate layer, a diameter of 10 μm of copper fiber layer;
(3), impregnating resin:
Square fiber cloth friction plate is separated with wire netting, frock is sunk into size applicator, vacuum is opened in size applicator capping fastening Pumping vacuum, vacuum is 0.08Pa, and the time vacuumized is 14 minutes, then closes the glue that vavuum pump is added in glue, size applicator Liquid is 50% modified resin glue and 50% absolute alcohol, and the impregnation time is 2 hours, until being impregnated with, opens lid, takes out frock control Dry glue liquid, Draining time is 2 hours;
(4), dry:
After after alcohol completely volatilization, enter back into baking oven and dried, the temperature of drying is 120 DEG C, to untill drying;
(5), solidification:
Fibre frictoin layer interfolded is inserted in baking oven, the temperature in baking oven rises to 120 degree, and soaking time is 18 minutes, is protected After temperature terminates, the temperature in baking oven is warming up to 150 degree, fibrous layer was opened oven door and put in baking oven inside holding 26 minutes Gas once, is then warming up to 180 degree again, then is incubated 2 hours or 2.5 hours, after insulation terminates, and opens oven door and takes after cooling Go out fiber frictional layer;
(6), punching:
Internal-and external diameter is fixed in punching machine for the mould of product frictional layer internal-and external diameter, and the composite fibre after solidification is laid Enter bicker and fixation, the annular or fan-shaped frictional layer of size needed for being punched into;
(7), steel core plate make:
Steel plate is taken, first inside and outside circle is rushed using punch press;Again with excircle orientation, the temperature of hot-leveling, temperature are adjusted according to core thickness At 650 degree, hot-leveling is carried out, positive replicate is incubated 2 hours or 2.5 hours;Then it is heat-treated, is hardened for HRC35-45;Again Descale is vibrated, is cleaned on cleaning machine, removes surface and oil contaminant, dried;
(8), plating:
Steel core plate is put into copper plating groove and carries out immersion plating, solution composition is Cu+225 grams/liter, P2O7 -4(Total amount)175 grams/public Rise,(NH43C5H6O725 grams/liter, H2O surpluses, thickness of coating is 0.005mm;
(9), frosted polishing:
The frictional layer copper fiber silk side being punched is subjected to frosted polishing, to increase adhesion strength;
(10), HTHP sintering:
Fibre frictoin layer after the steel core plate of plating and punching frosted polishing is put on the backing plate of sintering stove, sintering temperature For 850 degree, pressure is 50kg every square centimeter, and soaking time is 3 hours, forms friction plate;
(11), eventually inspection:
Required according to product drawing, product physical property and physical dimension are tested;
(12), packaging:
According to customer requirement or enterprise product packing instructions, packed;
(13), storage:
The attached quality certification of qualified products handles storage.
Embodiment 2:
A kind of preparation method of composite fibre high-quality friction material, in following processing steps:
(1), composite fiber friction material component ratio:
Carbon fiber 85%, aramid fiber 15%;
(2) squarely fiber cloth, is woven:
With a diameter of 7 μm of composite fibre silk, 0.05mm surpluses are put according to the frictional layer thickness to be woven into and have calculated compound fibre Thread number is tieed up, such as friction plate thickness is 0.50mm, and number of share of stock is 4200-4700 strands during braiding, is woven on 2.5D multidimensional braiders Squarely fiber cloth, one side fiber cloth is incorporated into copper fiber silk as intermediate layer, a diameter of 10 μm of copper fiber layer;
(3), impregnating resin:
Square fiber cloth friction plate is separated with wire netting, frock is sunk into size applicator, vacuum is opened in size applicator capping fastening Pumping vacuum, vacuum is 0.08Pa, and the time vacuumized is 14 minutes, then closes the glue that vavuum pump is added in glue, size applicator Liquid is 50% modified resin glue and 50% absolute alcohol, and the impregnation time is 2 hours, until being impregnated with, opens lid, takes out frock control Dry glue liquid, Draining time is 2 hours;
(4), dry:
After after alcohol completely volatilization, enter back into baking oven and dried, the temperature of drying is 120 DEG C, to untill drying;
(5), solidification:
Fibre frictoin layer interfolded is inserted in baking oven, the temperature in baking oven rises to 120 degree, and soaking time is 18 minutes, is protected After temperature terminates, the temperature in baking oven is warming up to 150 degree, fibrous layer was opened oven door and put in baking oven inside holding 26 minutes Gas once, is then warming up to 180 degree again, then is incubated 2 hours or 2.5 hours, after insulation terminates, and opens oven door and takes after cooling Go out fiber frictional layer;
(6), punching:
Internal-and external diameter is fixed in punching machine for the mould of product frictional layer internal-and external diameter, and the composite fibre after solidification is laid Enter bicker and fixation, the annular or fan-shaped frictional layer of size needed for being punched into;
(7), steel core plate make:
Steel plate is taken, first inside and outside circle is rushed using punch press;Again with excircle orientation, the temperature of hot-leveling, temperature are adjusted according to core thickness At 650 degree, hot-leveling is carried out, positive replicate is incubated 2 hours or 2.5 hours;Then it is heat-treated, is hardened for HRC35-45;Again Descale is vibrated, is cleaned on cleaning machine, removes surface and oil contaminant, dried;
(8), electroplate:
Steel core plate is put into copper plating groove and carries out immersion plating, solution composition is Cu+225 grams/liter, P2O7 -4(Total amount)175 grams/public Rise,(NH43C5H6O725 grams/liter, H2O surpluses, thickness of coating is 0.005mm;
(9), frosted polishing:
The frictional layer copper fiber silk side being punched is subjected to frosted polishing, to increase adhesion strength;
(10), HTHP sintering:
Fibre frictoin layer after the steel core plate of plating and punching frosted polishing is put on the backing plate of sintering stove, sintering temperature For 850 degree, pressure is 50kg every square centimeter, and soaking time is 3 hours, forms friction plate;
(11), eventually inspection:
Required according to product drawing, product physical property and physical dimension are tested;
(12), packaging:
According to customer requirement or enterprise product packing instructions, packed;
(13), storage:
The attached quality certification of qualified products handles storage.
Embodiment 3:A kind of preparation method of composite fibre high-quality friction material, in following processing steps:
(1), composite fiber friction material component ratio:
Carbon fiber 87%, aramid fiber 13%;
(2) squarely fiber cloth, is woven:
With a diameter of 7 μm of composite fibre silk, 0.05mm surpluses are put according to the frictional layer thickness to be woven into and have calculated compound fibre Thread number is tieed up, such as friction plate thickness is 0.50mm, and number of share of stock is 4200-4700 strands during braiding, is woven on 2.5D multidimensional braiders Squarely fiber cloth, one side fiber cloth is incorporated into copper fiber silk as intermediate layer, a diameter of 10 μm of copper fiber layer;
(3), impregnating resin:
Square fiber cloth friction plate is separated with wire netting, frock is sunk into size applicator, vacuum is opened in size applicator capping fastening Pumping vacuum, vacuum is 0.08Pa, and the time vacuumized is 14 minutes, then closes the glue that vavuum pump is added in glue, size applicator Liquid is 50% modified resin glue and 50% absolute alcohol, and the impregnation time is 2 hours, until being impregnated with, opens lid, takes out frock control Dry glue liquid, Draining time is 2 hours;
(4), dry:
After after alcohol completely volatilization, enter back into baking oven and dried, the temperature of drying is 120 DEG C, to untill drying;
(5), solidification:
Fibre frictoin layer interfolded is inserted in baking oven, the temperature in baking oven rises to 120 degree, and soaking time is 18 minutes, is protected After temperature terminates, the temperature in baking oven is warming up to 150 degree, fibrous layer was opened oven door and put in baking oven inside holding 26 minutes Gas once, is then warming up to 180 degree again, then is incubated 2 hours or 2.5 hours, after insulation terminates, and opens oven door and takes after cooling Go out fiber frictional layer;
(6), punching:
Internal-and external diameter is fixed in punching machine for the mould of product frictional layer internal-and external diameter, and the composite fibre after solidification is laid Enter bicker and fixation, the annular or fan-shaped frictional layer of size needed for being punched into;
(7), steel core plate make:
Steel plate is taken, first inside and outside circle is rushed using punch press;Again with excircle orientation, the temperature of hot-leveling, temperature are adjusted according to core thickness At 650 degree, hot-leveling is carried out, positive replicate is incubated 2 hours or 2.5 hours;Then it is heat-treated, is hardened for HRC35-45;Again Descale is vibrated, is cleaned on cleaning machine, removes surface and oil contaminant, dried;
(8), plating:
Steel core plate is put into copper plating groove and carries out immersion plating, solution composition is Cu+225 grams/liter, P2O7 -4(Total amount)175 grams/public Rise,(NH43C5H6O725 grams/liter, H2O surpluses, thickness of coating is 0.005mm;
(9), frosted polishing:
The frictional layer copper fiber silk side being punched is subjected to frosted polishing, to increase adhesion strength;
(10), HTHP sintering:
Fibre frictoin layer after the steel core plate of plating and punching frosted polishing is put on the backing plate of sintering stove, sintering temperature For 850 degree, pressure is 50kg every square centimeter, and soaking time is 3 hours, forms friction plate;
(11), eventually inspection:
Required according to product drawing, product physical property and physical dimension are tested;
(12), packaging:
According to customer requirement or enterprise product packing instructions, packed;
(13), storage:
The attached quality certification of qualified products handles storage.
Embodiment 4:A kind of preparation method of composite fibre high-quality friction material, in following processing steps:
(1), composite fiber friction material component ratio:
Carbon fiber 90%, aramid fiber 10%;
(2) squarely fiber cloth, is woven:
With a diameter of 7 μm of composite fibre silk, 0.05mm surpluses are put according to the frictional layer thickness to be woven into and have calculated compound fibre Thread number is tieed up, such as friction plate thickness is 0.50mm, and number of share of stock is 4200-4700 strands during braiding, is woven on 2.5D multidimensional braiders Squarely fiber cloth, one side fiber cloth is incorporated into copper fiber silk as intermediate layer, a diameter of 10 μm of copper fiber layer;
(3), impregnating resin:
Square fiber cloth friction plate is separated with wire netting, frock is sunk into size applicator, vacuum is opened in size applicator capping fastening Pumping vacuum, vacuum is 0.08Pa, and the time vacuumized is 14 minutes, then closes the glue that vavuum pump is added in glue, size applicator Liquid is 50% modified resin glue and 50% absolute alcohol, and the impregnation time is 2 hours, until being impregnated with, opens lid, takes out frock control Dry glue liquid, Draining time is 2 hours;
(4), dry:
After after alcohol completely volatilization, enter back into baking oven and dried, the temperature of drying is 120 DEG C, to untill drying;
(5), solidification:
Fibre frictoin layer interfolded is inserted in baking oven, the temperature in baking oven rises to 120 degree, and soaking time is 18 minutes, is protected After temperature terminates, the temperature in baking oven is warming up to 150 degree, fibrous layer was opened oven door and put in baking oven inside holding 26 minutes Gas once, is then warming up to 180 degree again, then is incubated 2 hours or 2.5 hours, after insulation terminates, and opens oven door and takes after cooling Go out fiber frictional layer;
(6), punching:
Internal-and external diameter is fixed in punching machine for the mould of product frictional layer internal-and external diameter, and the composite fibre after solidification is laid Enter bicker and fixation, the annular or fan-shaped frictional layer of size needed for being punched into;
(7), steel core plate make:
Steel plate is taken, first inside and outside circle is rushed using punch press;Again with excircle orientation, the temperature of hot-leveling, temperature are adjusted according to core thickness At 650 degree, hot-leveling is carried out, positive replicate is incubated 2 hours or 2.5 hours;Then it is heat-treated, is hardened for HRC35-45;Again Descale is vibrated, is cleaned on cleaning machine, removes surface and oil contaminant, dried;
(8), plating:
Steel core plate is put into copper plating groove and carries out immersion plating, solution composition is Cu+225 grams/liter, P2O7 -4(Total amount)175 grams/public Rise,(NH43C5H6O725 grams/liter, H2O surpluses, thickness of coating is 0.005mm;
(9), frosted polishing:
The frictional layer copper fiber silk side being punched is subjected to frosted polishing, to increase adhesion strength;
(10), HTHP sintering:
Fibre frictoin layer after the steel core plate of plating and punching frosted polishing is put on the backing plate of sintering stove, sintering temperature For 850 degree, pressure is 50kg every square centimeter, and soaking time is 3 hours, forms friction plate;
(11), eventually inspection:
Required according to product drawing, product physical property and physical dimension are tested;
(12), packaging:
According to customer requirement or enterprise product packing instructions, packed;
(13), storage:
The attached quality certification of qualified products handles storage.
Embodiment 5:A kind of preparation method of composite fibre high-quality friction material, in following processing steps:
(1), composite fiber friction material component ratio:
Carbon fiber 85%, aramid fiber 8%, glass fibre 7%;
(2) squarely fiber cloth, is woven:
With a diameter of 7 μm of composite fibre silk, 0.05mm surpluses are put according to the frictional layer thickness to be woven into and have calculated compound fibre Thread number is tieed up, such as friction plate thickness is 0.50mm, and number of share of stock is 4200-4700 strands during braiding, is woven on 2.5D multidimensional braiders Squarely fiber cloth, one side fiber cloth is incorporated into copper fiber silk as intermediate layer, a diameter of 10 μm of copper fiber layer;
(3), impregnating resin:
Square fiber cloth friction plate is separated with wire netting, frock is sunk into size applicator, vacuum is opened in size applicator capping fastening Pumping vacuum, vacuum is 0.08Pa, and the time vacuumized is 14 minutes, then closes the glue that vavuum pump is added in glue, size applicator Liquid is 50% modified resin glue and 50% absolute alcohol, and the impregnation time is 2 hours, until being impregnated with, opens lid, takes out frock control Dry glue liquid, Draining time is 2 hours;
(4), dry:
After after alcohol completely volatilization, enter back into baking oven and dried, the temperature of drying is 120 DEG C, to untill drying;
(5), solidification:
Fibre frictoin layer interfolded is inserted in baking oven, the temperature in baking oven rises to 120 degree, and soaking time is 18 minutes, is protected After temperature terminates, the temperature in baking oven is warming up to 150 degree, fibrous layer was opened oven door and put in baking oven inside holding 26 minutes Gas once, is then warming up to 180 degree again, then is incubated 2 hours or 2.5 hours, after insulation terminates, and opens oven door and takes after cooling Go out fiber frictional layer;
(6), punching:
Internal-and external diameter is fixed in punching machine for the mould of product frictional layer internal-and external diameter, and the composite fibre after solidification is laid Enter bicker and fixation, the annular or fan-shaped frictional layer of size needed for being punched into;
(7), steel core plate make:
Steel plate is taken, first inside and outside circle is rushed using punch press;Again with excircle orientation, the temperature of hot-leveling, temperature are adjusted according to core thickness At 650 degree, hot-leveling is carried out, positive replicate is incubated 2 hours or 2.5 hours;Then it is heat-treated, is hardened for HRC35-45;Again Descale is vibrated, is cleaned on cleaning machine, removes surface and oil contaminant, dried;
(8), plating:
Steel core plate is put into copper plating groove and carries out immersion plating, solution composition is Cu+225 grams/liter, P2O7 -4(Total amount)175 grams/public Rise,(NH43C5H6O725 grams/liter, H2O surpluses, thickness of coating is 0.005mm;
(9), frosted polishing:
The frictional layer copper fiber silk side being punched is subjected to frosted polishing, to increase adhesion strength;
(10), HTHP sintering:
Fibre frictoin layer after the steel core plate of plating and punching frosted polishing is put on the backing plate of sintering stove, sintering temperature For 850 degree, pressure is 50kg every square centimeter, and soaking time is 3 hours, forms friction plate;
(11), eventually inspection:
Required according to product drawing, product physical property and physical dimension are tested;
(12), packaging:
According to customer requirement or enterprise product packing instructions, packed;
(13), storage:
The attached quality certification of qualified products handles storage.
Embodiment 6:A kind of preparation method of composite fibre high-quality friction material, in following processing steps:
(1), composite fiber friction material component ratio:
Carbon fiber 87%, aramid fiber 5%, glass fibre 8%;
(2) squarely fiber cloth, is woven:
With a diameter of 7 μm of composite fibre silk, 0.05mm surpluses are put according to the frictional layer thickness to be woven into and have calculated compound fibre Thread number is tieed up, such as friction plate thickness is 0.50mm, and number of share of stock is 4200-4700 strands during braiding, is woven on 2.5D multidimensional braiders Squarely fiber cloth, one side fiber cloth is incorporated into copper fiber silk as intermediate layer, a diameter of 10 μm of copper fiber layer;
(3), impregnating resin:
Square fiber cloth friction plate is separated with wire netting, frock is sunk into size applicator, vacuum is opened in size applicator capping fastening Pumping vacuum, vacuum is 0.08Pa, and the time vacuumized is 14 minutes, then closes the glue that vavuum pump is added in glue, size applicator Liquid is 50% modified resin glue and 50% absolute alcohol, and the impregnation time is 2 hours, until being impregnated with, opens lid, takes out frock control Dry glue liquid, Draining time is 2 hours;
(4), dry:
After after alcohol completely volatilization, enter back into baking oven and dried, the temperature of drying is 120 DEG C, to untill drying;
(5), solidification:
Fibre frictoin layer interfolded is inserted in baking oven, the temperature in baking oven rises to 120 degree, and soaking time is 18 minutes, is protected After temperature terminates, the temperature in baking oven is warming up to 150 degree, fibrous layer was opened oven door and put in baking oven inside holding 26 minutes Gas once, is then warming up to 180 degree again, then is incubated 2 hours or 2.5 hours, after insulation terminates, and opens oven door and takes after cooling Go out fiber frictional layer;
(6), punching:
Internal-and external diameter is fixed in punching machine for the mould of product frictional layer internal-and external diameter, and the composite fibre after solidification is laid Enter bicker and fixation, the annular or fan-shaped frictional layer of size needed for being punched into;
(7), steel core plate make:
Steel plate is taken, first inside and outside circle is rushed using punch press;Again with excircle orientation, the temperature of hot-leveling, temperature are adjusted according to core thickness At 650 degree, hot-leveling is carried out, positive replicate is incubated 2 hours or 2.5 hours;Then it is heat-treated, is hardened for HRC35-45;Again Descale is vibrated, is cleaned on cleaning machine, removes surface and oil contaminant, dried;
(8), plating:
Steel core plate is put into copper plating groove and carries out immersion plating, solution composition is Cu+225 grams/liter, P2O7 -4(Total amount)175 grams/public Rise,(NH43C5H6O725 grams/liter, H2O surpluses, thickness of coating is 0.005mm;
(9), frosted polishing:
The frictional layer copper fiber silk side being punched is subjected to frosted polishing, to increase adhesion strength;
(10), HTHP sintering:
Fibre frictoin layer after the steel core plate of plating and punching frosted polishing is put on the backing plate of sintering stove, sintering temperature For 850 degree, pressure is 50kg every square centimeter, and soaking time is 3 hours, forms friction plate;
(11), eventually inspection:
Required according to product drawing, product physical property and physical dimension are tested;
(12), packaging:
According to customer requirement or enterprise product packing instructions, packed;
(13), storage:
The attached quality certification of qualified products handles storage.
Embodiment 7:A kind of preparation method of composite fibre high-quality friction material, in following processing steps:
(1), composite fiber friction material component ratio:
Carbon fiber 90%, aramid fiber 5%, glass fibre 5%;
(2) squarely fiber cloth, is woven:
With a diameter of 7 μm of composite fibre silk, 0.05mm surpluses are put according to the frictional layer thickness to be woven into and have calculated compound fibre Thread number is tieed up, such as friction plate thickness is 0.50mm, and number of share of stock is 4200-4700 strands during braiding, is woven on 2.5D multidimensional braiders Squarely fiber cloth, one side fiber cloth is incorporated into copper fiber silk as intermediate layer, a diameter of 10 μm of copper fiber layer;
(3), impregnating resin:
Square fiber cloth friction plate is separated with wire netting, frock is sunk into size applicator, vacuum is opened in size applicator capping fastening Pumping vacuum, vacuum is 0.08Pa, and the time vacuumized is 14 minutes, then closes the glue that vavuum pump is added in glue, size applicator Liquid is 50% modified resin glue and 50% absolute alcohol, and the impregnation time is 2 hours, until being impregnated with, opens lid, takes out frock control Dry glue liquid, Draining time is 2 hours;
(4), dry:
After after alcohol completely volatilization, enter back into baking oven and dried, the temperature of drying is 120 DEG C, to untill drying;
(5), solidification:
Fibre frictoin layer interfolded is inserted in baking oven, the temperature in baking oven rises to 120 degree, and soaking time is 18 minutes, is protected After temperature terminates, the temperature in baking oven is warming up to 150 degree, fibrous layer was opened oven door and put in baking oven inside holding 26 minutes Gas once, is then warming up to 180 degree again, then is incubated 2 hours or 2.5 hours, after insulation terminates, and opens oven door and takes after cooling Go out fiber frictional layer;
(6), punching:
Internal-and external diameter is fixed in punching machine for the mould of product frictional layer internal-and external diameter, and the composite fibre after solidification is laid Enter bicker and fixation, the annular or fan-shaped frictional layer of size needed for being punched into;
(7), steel core plate make:
Steel plate is taken, first inside and outside circle is rushed using punch press;Again with excircle orientation, the temperature of hot-leveling, temperature are adjusted according to core thickness At 650 degree, hot-leveling is carried out, positive replicate is incubated 2 hours or 2.5 hours;Then it is heat-treated, is hardened for HRC35-45;Again Descale is vibrated, is cleaned on cleaning machine, removes surface and oil contaminant, dried;
(8), plating:
Steel core plate is put into copper plating groove and carries out immersion plating, solution composition is Cu+225 grams/liter, P2O7 -4(Total amount)175 grams/public Rise,(NH43C5H6O725 grams/liter, H2O surpluses, thickness of coating is 0.005mm;
(9), frosted polishing:
The frictional layer copper fiber silk side being punched is subjected to frosted polishing, to increase adhesion strength;
(10), HTHP sintering:
Fibre frictoin layer after the steel core plate of plating and punching frosted polishing is put on the backing plate of sintering stove, sintering temperature For 850 degree, pressure is 50kg every square centimeter, and soaking time is 3 hours, forms friction plate;
(11), eventually inspection:
Required according to product drawing, product physical property and physical dimension are tested;
(12), packaging:
According to customer requirement or enterprise product packing instructions, packed;
(13), storage:
The attached quality certification of qualified products handles storage.

Claims (10)

1. a kind of composite fibre high-quality friction material, it is characterised in that:Including bottom, intermediate layer and upper strata, described bottom Top be provided with upper strata, described bottom is formed with upper strata and intermediate layer by HTHP sintering, and described bottom is steel core Flaggy, described intermediate layer is copper fiber layer, and described upper strata is annular friction layer.
2. a kind of preparation method of composite fibre high-quality friction material according to claim 1, it is characterised in that by with Lower step is carried out:
(1), textile sheet;
(2), the one side of fiber cloth is incorporated into copper fiber silk;
(3), by fiber cloth impregnating resin and baking and curing and cut to form upper strata and intermediate layer;
(4), take thermally treated steel plate, oxide skin, clean and dry after carry out plating formed as bottom steel core flaggy;
(5), upper strata and intermediate layer and steel core flaggy overlap sintered formation friction plate.
3. a kind of preparation method of composite fibre high-quality friction material according to claim 2, it is characterised in that fiber Cloth braiding uses composite fibre, complex fiber material component ratio:
Composition 1:Carbon fiber 100%;
Or,
Composition 2:Carbon fiber 85-90%, aramid fiber 10-15%;
Or,
Composition 3:Carbon fiber 84-90%, aramid fiber 5-8%, glass fibre 5-8%.
4. a kind of preparation method of composite fibre high-quality friction material according to claim 2, it is characterised in that fiber Cloth weaves squarely, with a diameter of 7 μm of composite fibre silk, puts 0.05mm surpluses according to the frictional layer thickness to be woven into and calculates Good composite fibre thread number, weaves squarely fiber cloth on 2.5D multidimensional braiders.
5. a kind of preparation method of composite fibre high-quality friction material according to claim 2, it is characterised in that dipping During resin, fiber cloth is strutted, size applicator is sunk to, is vacuumized after size applicator sealing, vacuum is 0.08Pa, the time vacuumized For 14 minutes, glue is then added, until being impregnated with.
6. a kind of preparation method of composite fibre high-quality friction material according to claim 5, it is characterised in that impregnation Modified resin glue and 50% absolute alcohol that glue in device is 50%, the impregnation time is 2 hours, and glue is drained after impregnation, is dripped The dry time is 2 hours.
7. the preparation method of a kind of composite fibre high-quality friction material according to claim 6, it is characterised in that treat wine After smart volatilization completely, enter back into baking oven and dried, the temperature of drying is 120 DEG C, to untill drying.
8. a kind of preparation method of composite fibre high-quality friction material according to claim 2, it is characterised in that solidification When be placed into baking oven, the temperature in baking oven rises to 120 degree, and soaking time is 18 minutes, after insulation terminates, by the temperature in baking oven Degree is warming up to 150 degree, and fibrous layer was opened oven door and deflated once, 180 are then warming up to again in baking oven inside holding 26 minutes Degree, then it is incubated 2 hours or 2.5 hours, insulation is cooled down after terminating.
9. a kind of preparation method of composite fibre high-quality friction material according to claim 2, it is characterised in that steel plate First inside and outside circle is rushed using punch press;Again with excircle orientation, the temperature of hot-leveling is adjusted according to steel core plate thickness, temperature is entered at 650 degree Row hot-leveling, positive replicate is incubated -2.5 hours 2 hours;Then it is heat-treated, is hardened for HRC35-45;Deoxidation is vibrated again Skin, is cleaned on cleaning machine, removes surface and oil contaminant, is dried;Steel core plate, which is put into copper plating groove, carries out immersion plating, plating solution into It is divided into Cu+225 grams/liter, P2O7 -4(Total amount)175 grams/liter,(NH43C5H6O725 grams/liter, H2O surpluses, thickness of coating For 0.005mm.
10. the preparation method of a kind of composite fibre high-quality friction material according to claim 2, it is characterised in that by The frictional layer copper fiber silk side being punched carries out frosted polishing, and then burnishing surface is stacked towards steel core plate and is put into sintering furnace On the backing plate of son, sintering temperature is 850 degree, and pressure is 50kg every square centimeter, and soaking time is 3 hours, forms friction plate.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107523248A (en) * 2017-09-26 2017-12-29 安徽博耐克摩擦材料有限公司 The glue Nian Jie with brake block liner for disk brake steel back and preparation method
CN109694948A (en) * 2019-02-20 2019-04-30 上海春玉金属热处理有限公司 A kind of planetary gear shaft nickel plating aging technique
CN110529531A (en) * 2018-05-24 2019-12-03 昱程科技股份有限公司 Friction plate structure and its manufacturing method
CN110715006A (en) * 2019-11-14 2020-01-21 杭州临安华龙摩擦材料有限公司 Friction plate for light mechanical brake disc and preparation method thereof
CN111890701A (en) * 2020-07-31 2020-11-06 杭州紫麟科技有限公司 2.5D fiber woven reinforced resin matrix composite material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101178102A (en) * 2007-11-26 2008-05-14 杭州前进齿轮箱集团有限公司 Wet-type copper based powder metallurgy friction wafer and manufacturing method
CN105196651A (en) * 2015-08-24 2015-12-30 杭州萧山红旗摩擦材料有限公司 Multi-dimensional fiber high-performance friction material and preparation method thereof
CN105803637A (en) * 2016-04-13 2016-07-27 江南大学 Curved shallow-crossing linking structure carbon fiber/copper fiber carbon-based friction material and preparation method thereof
JP2016160299A (en) * 2015-02-27 2016-09-05 株式会社アドヴィックス Non-asbestos friction material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101178102A (en) * 2007-11-26 2008-05-14 杭州前进齿轮箱集团有限公司 Wet-type copper based powder metallurgy friction wafer and manufacturing method
JP2016160299A (en) * 2015-02-27 2016-09-05 株式会社アドヴィックス Non-asbestos friction material
CN105196651A (en) * 2015-08-24 2015-12-30 杭州萧山红旗摩擦材料有限公司 Multi-dimensional fiber high-performance friction material and preparation method thereof
CN105803637A (en) * 2016-04-13 2016-07-27 江南大学 Curved shallow-crossing linking structure carbon fiber/copper fiber carbon-based friction material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
龙祥,卢雪峰: "结构变化对碳纤维/铜纤维混编酚醛树脂基摩擦材料弯曲性能的影响", 《化工新型材料》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107523248A (en) * 2017-09-26 2017-12-29 安徽博耐克摩擦材料有限公司 The glue Nian Jie with brake block liner for disk brake steel back and preparation method
CN110529531A (en) * 2018-05-24 2019-12-03 昱程科技股份有限公司 Friction plate structure and its manufacturing method
CN109694948A (en) * 2019-02-20 2019-04-30 上海春玉金属热处理有限公司 A kind of planetary gear shaft nickel plating aging technique
CN110715006A (en) * 2019-11-14 2020-01-21 杭州临安华龙摩擦材料有限公司 Friction plate for light mechanical brake disc and preparation method thereof
CN111890701A (en) * 2020-07-31 2020-11-06 杭州紫麟科技有限公司 2.5D fiber woven reinforced resin matrix composite material and preparation method thereof

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