CN107190504B - 一种提高鞋衬材料透气性的加工方法 - Google Patents

一种提高鞋衬材料透气性的加工方法 Download PDF

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CN107190504B
CN107190504B CN201710422467.9A CN201710422467A CN107190504B CN 107190504 B CN107190504 B CN 107190504B CN 201710422467 A CN201710422467 A CN 201710422467A CN 107190504 B CN107190504 B CN 107190504B
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饶蕊
饶魁
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Jieshou City Shengze Footwear Co Ltd
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Abstract

本发明属于鞋衬材料加工技术领域，具体涉及一种提高鞋衬材料透气性的加工方法，包括坯布制备、精炼、整理剂制备、整理及烘焙。本发明相比现有技术具有以下优点：本发明中以超细纤维为主要原料，通过对浆纱过程条件的控制，所得浆纱回潮率为1.5‑2.0%，使其具有较好的强力和弹性，在满足织轴卷绕的条件下，浆纱伸长率降低到0.5%以下，有效减少织机断头，再配合精炼和整理剂整理，提高超细纤维所织坯布的硬挺度，避免鞋衬由于吸收潮气而使硬挺度降低的问题，同时还能保证所得鞋衬具有较强的透水汽性和透气性，进而能使鞋内汗液快速被蒸发，保持鞋内清爽，在穿着一段时间后，仍能保持鞋面形状，能够提高鞋衬的商品性和使用寿命。

Description

一种提高鞋衬材料透气性的加工方法
技术领域
本发明属于鞋衬材料加工技术领域，具体涉及一种提高鞋衬材料透气性的加工方法。
背景技术
随着生活水平的提高，人们越来越关注身体健康的问题，其中足部健康主要受到鞋子的影响，鞋腔空间狭小，再加上人体新陈代谢所产生的汗液、皮脂、皮屑等蛋白质、脂肪类物质，为病菌的生长繁殖提供了必要的温度、湿度以及营养来源，因此鞋靴的卫生性能逐渐被人们关注，现有解决上述问题的方法，主要为对鞋材进行抗菌处理货提高鞋材的透气、透水汽性能，抗菌处理可能会杀灭与人体共生的菌群，可能会影响人体健康，因此，应当对鞋衬进行进一步改进，提高鞋材的透气、透水汽性能，简单有效的提高鞋靴卫生性能，为了提高鞋衬材料的透气性，会采用超细纤维作为原料，在此情况下容易出现鞋衬硬挺度低，放置一段时间后容易变软收缩，还容易脱胶，鞋衬的使用寿命短，也应吸纳够了鞋子的档次和价格，因此，需要对如何提高鞋衬的透气性进一步研究。
发明内容
本发明的目的是针对现有的问题，提供了一种提高鞋衬材料透气性的加工方法。
本发明是通过以下技术方案实现的：一种提高鞋衬材料透气性的加工方法，包括以下步骤：
（1）在坯布织造前，浆纱选用超细纤维，浆纱工艺中，浆料包含以下重量份的原料：质量浓度为8-10%的甲基丙烯酸乙酯溶液100份、巯基蛋白酶1.6-2.2份、海藻酸钠0.8-1.5份；浆纱的浸浆压力为0.15-0.3MPa，烘房温度为85-95℃，上浆率为12-13%，用剑杆织机进行246根/10cm×252根/10cm织造而成，形成鞋衬坯布；
（2）将上述所得坯布放入精炼机的液缸中进行处理，液缸中温度为65-70℃时，加入助剂，保持15-20分钟后，继续升温至85-90℃，精炼50-60分钟内后，取出，烘干备用；
其中，助剂包括以下原料：苦皮藤素40-50g/L、蓖麻油聚氧乙烯醚15-22g/L、羟基乙叉二膦酸11-16g/L、葡萄糖酸钠4-8g/L；
（3）按重量份，将去离子水100份、无水乙醇25-30份、羧基丁苯胶乳18-22份、硅烷偶联剂2-3份、硫脲1.5-2.4份、端羟基聚二甲基硅氧烷0.7-1.4份、甲苯二异氰酸酯2.2-2.6份、氯化镁0.3-0.6份混合，在28-34℃的条件下水解及聚合反应，反应完成后得到功能整理剂；
（4）将上述制得整理剂以二浸二轧法整理到步骤（2）处理后的坯布内，在温度为85-90℃的条件下，用波长为9-15μm的远红外线照射8-12分钟，然后在120-135℃的条件下烘焙2-3分钟，即得。
作为对上述方案的进一步改进，所述蓖麻油聚氧乙烯醚的羟值为58-68mgKOH/g。
作为对上述方案的进一步改进，所述步骤（3）在反应过程中以搅拌速度200-300转/分钟搅拌。
作为对上述方案的进一步改进，所述二浸二轧的轧余率为55-60%。
本发明相比现有技术具有以下优点：本发明中以超细纤维为主要原料，通过对浆纱过程条件的控制，所得浆纱回潮率为1.5-2.0%，使其具有较好的强力和弹性，在满足织轴卷绕的条件下，浆纱伸长率降低到0.5%以下，有效减少织机断头，再配合精炼和整理剂整理，提高超细纤维所织坯布的硬挺度，避免鞋衬由于吸收潮气而使硬挺度降低的问题，同时还能保证所得鞋衬具有较强的透水汽性和透气性，进而能使鞋内汗液快速被蒸发，保持鞋内清爽，在穿着一段时间后，仍能保持鞋面形状，能够提高鞋衬的商品性和使用寿命。
具体实施方式
实施例1
一种提高鞋衬材料透气性的加工方法，包括以下步骤：
（1）在坯布织造前，浆纱选用超细纤维，浆纱工艺中，浆料包含以下重量份的原料：质量浓度为9%的甲基丙烯酸乙酯溶液100份、巯基蛋白酶1.8份、海藻酸钠0.4份；浆纱的浸浆压力为0.24MPa，烘房温度为90℃，上浆率为12%，用剑杆织机进行246根/10cm×252根/10cm织造而成，形成鞋衬坯布；
（2）将上述所得坯布放入精炼机的液缸中进行处理，液缸中温度为68℃时，加入助剂，保持18分钟后，继续升温至87℃，精炼55分钟内后，取出，烘干备用；
其中，助剂包括以下原料：苦皮藤素45g/L、蓖麻油聚氧乙烯醚18g/L、羟基乙叉二膦酸14g/L、葡萄糖酸钠6g/L；
（3）按重量份，将去离子水100份、无水乙醇28份、羧基丁苯胶乳20份、硅烷偶联剂2.5份、硫脲2.2份、端羟基聚二甲基硅氧烷1.2份、甲苯二异氰酸酯2.4份、氯化镁0.5份混合，在28-34℃的条件下水解及聚合反应，反应完成后得到功能整理剂；
（4）将上述制得整理剂以二浸二轧法整理到步骤（2）处理后的坯布内，在温度为88℃的条件下，用波长为9-15μm的远红外线照射8-12分钟，然后在125℃的条件下烘焙2-3分钟，即得。
其中，所述蓖麻油聚氧乙烯醚的羟值为58-68mgKOH/g；所述步骤（3）在反应过程中以搅拌速度200转/分钟搅拌；所述二浸二轧的轧余率为56%。
本发明中所得鞋衬用H.C费多罗夫皮革透气性测试仪测试，表征超细纤维未经过处理前，其投过100ml空气所用的时间为21.18s，本实施例中，透过100ml空气所用的时间为20.26s；经晶体测试法测试超细纤维，经过24小时，10cm²的面积上透过的水汽为530mg/（10cm²·24h），本实施例中，其透水汽性为594mg/（10cm²·24h），硬挺度比处理前提高了28.6%。
实施例2
一种提高鞋衬材料透气性的加工方法，包括以下步骤：
（1）在坯布织造前，浆纱选用超细纤维，浆纱工艺中，浆料包含以下重量份的原料：质量浓度为8%的甲基丙烯酸乙酯溶液100份、巯基蛋白酶2.2份、海藻酸钠0.9份；浆纱的浸浆压力为0.15MPa，烘房温度为95℃，上浆率为12%，用剑杆织机进行246根/10cm×252根/10cm织造而成，形成鞋衬坯布；
（2）将上述所得坯布放入精炼机的液缸中进行处理，液缸中温度为65℃时，加入助剂，保持20分钟后，继续升温至85℃，精炼60分钟内后，取出，烘干备用；
其中，助剂包括以下原料：苦皮藤素50g/L、蓖麻油聚氧乙烯醚22g/L、羟基乙叉二膦酸11g/L、葡萄糖酸钠5g/L；
（3）按重量份，将去离子水100份、无水乙醇25份、羧基丁苯胶乳22份、硅烷偶联剂3份、硫脲1.5份、端羟基聚二甲基硅氧烷1.4份、甲苯二异氰酸酯2.6份、氯化镁0.3份混合，在34℃的条件下水解及聚合反应，反应完成后得到功能整理剂；
（4）将上述制得整理剂以二浸二轧法整理到步骤（2）处理后的坯布内，在温度为90℃的条件下，用波长为15μm的远红外线照射8分钟，然后在135℃的条件下烘焙2分钟，即得。
其中，所述蓖麻油聚氧乙烯醚的羟值为68mgKOH/g；所述步骤（3）在反应过程中以搅拌速度300转/分钟搅拌；所述二浸二轧的轧余率为55%。
本发明中所得鞋衬用H.C费多罗夫皮革透气性测试仪测试，表征超细纤维未经过处理前，其投过100ml空气所用的时间为21.18s，本实施例中，透过100ml空气所用的时间为20.25s；经晶体测试法测试超细纤维，经过24小时，10cm²的面积上透过的水汽为530mg/（10cm²·24h），本实施例中，其透水汽性为589mg/（10cm²·24h），硬挺度比处理前提高了23.7%。
实施例3
一种提高鞋衬材料透气性的加工方法，包括以下步骤：
（1）在坯布织造前，浆纱选用超细纤维，浆纱工艺中，浆料包含以下重量份的原料：质量浓度为10%的甲基丙烯酸乙酯溶液100份、巯基蛋白酶1.6份、海藻酸钠1.5份；浆纱的浸浆压力为0.3MPa，烘房温度为90℃，上浆率为12%，用剑杆织机进行246根/10cm×252根/10cm织造而成，形成鞋衬坯布；
（2）将上述所得坯布放入精炼机的液缸中进行处理，液缸中温度为65℃时，加入助剂，保持20分钟后，继续升温至85℃，精炼60分钟内后，取出，烘干备用；
其中，助剂包括以下原料：苦皮藤素40g/L、蓖麻油聚氧乙烯醚15g/L、羟基乙叉二膦酸16g/L、葡萄糖酸钠4g/L；
（3）按重量份，将去离子水100份、无水乙醇30份、羧基丁苯胶乳18份、硅烷偶联剂2份、硫脲2.4份、端羟基聚二甲基硅氧烷0.7份、甲苯二异氰酸酯2.6份、氯化镁0.6份混合，在34℃的条件下水解及聚合反应，反应完成后得到功能整理剂；
（4）将上述制得整理剂以二浸二轧法整理到步骤（2）处理后的坯布内，在温度为85℃的条件下，用波长为15μm的远红外线照射12分钟，然后在135℃的条件下烘焙2分钟，即得。
其中，所述蓖麻油聚氧乙烯醚的羟值为62mgKOH/g；所述步骤（3）在反应过程中以搅拌速度300转/分钟搅拌；所述二浸二轧的轧余率为55%。
本发明中所得鞋衬用H.C费多罗夫皮革透气性测试仪测试，表征超细纤维未经过处理前，其投过100ml空气所用的时间为21.18s，本实施例中，透过100ml空气所用的时间为20.14s；经晶体测试法测试超细纤维，经过24小时，10cm²的面积上透过的水汽为530mg/（10cm²·24h），本实施例中，其透水汽性为592mg/（10cm²·24h），硬挺度比处理前提高了35.3%。

Claims (3)

1.一种提高鞋衬材料透气性的加工方法，其特征在于，包括以下步骤：
（1）在坯布织造前，浆纱选用超细纤维，浆纱工艺中，浆料包含以下重量份的原料：质量浓度为8-10%的甲基丙烯酸乙酯溶液100份、巯基蛋白酶1.6-2.2份、海藻酸钠0.8-1.5份；浆纱的浸浆压力为0.15-0.3MPa，烘房温度为85-95℃，上浆率为12-13%，用剑杆织机进行246根/10cm×252根/10cm织造而成，形成鞋衬坯布；
（2）将上述所得坯布放入精炼机的液缸中进行处理，液缸中温度为65-70℃时，加入助剂，保持15-20分钟后，继续升温至85-90℃，精炼50-60分钟内后，取出，烘干备用；
其中，助剂包括以下原料：苦皮藤素40-50g/L、羟值为58-68mgKOH/g的蓖麻油聚氧乙烯醚15-22g/L、羟基乙叉二膦酸11-16g/L、葡萄糖酸钠4-8g/L；
（3）按重量份，将去离子水100份、无水乙醇25-30份、羧基丁苯胶乳18-22份、硅烷偶联剂2-3份、硫脲1.5-2.4份、端羟基聚二甲基硅氧烷0.7-1.4份、甲苯二异氰酸酯2.2-2.6份、氯化镁0.3-0.6份混合，在28-34℃的条件下水解及聚合反应，反应完成后得到功能整理剂；
（4）将上述制得整理剂以二浸二轧法整理到步骤（2）处理后的坯布内，在温度为85-90℃的条件下，用波长为9-15μm的远红外线照射8-12分钟，然后在120-135℃的条件下烘焙2-3分钟，即得。
2.如权利要求1所述一种提高鞋衬材料透气性的加工方法，其特征在于，所述步骤（3）在反应过程中以搅拌速度200-300转/分钟搅拌。
3.如权利要求1所述一种提高鞋衬材料透气性的加工方法，其特征在于，所述二浸二轧的轧余率为55-60%。
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