CN107189688A - A kind of black raw lacquer coating based on natural raw lacquer - Google Patents

A kind of black raw lacquer coating based on natural raw lacquer Download PDF

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Publication number
CN107189688A
CN107189688A CN201710444833.0A CN201710444833A CN107189688A CN 107189688 A CN107189688 A CN 107189688A CN 201710444833 A CN201710444833 A CN 201710444833A CN 107189688 A CN107189688 A CN 107189688A
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CN
China
Prior art keywords
raw lacquer
black
natural raw
natural
preparation
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Pending
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CN201710444833.0A
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Chinese (zh)
Inventor
吴昊
洪克俭
王磊
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HUBEI BAOSHIHUA CRAFTWORK CO Ltd
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HUBEI BAOSHIHUA CRAFTWORK CO Ltd
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Priority to CN201710444833.0A priority Critical patent/CN107189688A/en
Publication of CN107189688A publication Critical patent/CN107189688A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D193/00Coating compositions based on natural resins; Coating compositions based on derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2255Oxides; Hydroxides of metals of molybdenum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of blacking preparation method based on natural raw lacquer.It is to be mixed to be brewed into black material with the method for heating according to certain ratio by the hydroxide of natural raw lacquer and molybdenum first, and then natural raw lacquer and black material are mixed according to specific ratio again and is uniformly dispersed and is made.When boiling black material, the need of the hydroxide of natural raw lacquer and molybdenum press appropriate weight ratio;The weight ratio of black material and natural raw lacquer is 30% -40%.Obtained black paint coating can and large range of temperature humidity under the conditions of rapid draing.Mechanical performance, glossiness, decoration performance, coating performance, heat resistance of paint film etc. are significantly improved, and stably, nontoxic pollution-free, environmental protection, can as synthetic paint substitute, among industrial antisepsis, historical relic reparation, food containers and resident's daily life.

Description

A kind of black raw lacquer coating based on natural raw lacquer
Technical field
The present invention relates to a kind of black raw lacquer coating based on natural raw lacquer.
Background technology
Raw lacquer (Raw laequer) refers to the bast scarfing outflow from lacquer tree (Rhus verniciflua Stokes) Milky white emulsion body.Main component include laccol (60-70%), colloid (5-7%), water-insoluble glycoprotein (- 1%), Rhus Laccase (- 0.24%) and moisture content (20-25%) etc..When connect melt air after, its color and luster because of oxidation from the superficial to the deep, in proper order Dark brown is faded to, a kind of hard paint film is eventually become.Raw lacquer paint film is hard bright, wear-resisting, heat-resisting, corrosion-resistant.It is a kind of Natural paint, in China using existing more than 7000 years usage history, there is the appellation of coating " first ancestor ", politics, warp to China Help, culture life once produced material impact, was the great discovery after four inventions.Use for convenience, improve its decoration Performance and other physics and chemistry combination properties, people take all multi-methods to be modified, compound that many raw lacquer coatings have been made, such as by Asia It is exactly one kind therein that the conventional black that iron ion is chelated and is made with raw lacquer, which pushes away light raw lacquer coating,.The paint film of coating formation It is dark brown, is repeatedly brushed because of it and form thicker paint film, light is reflected and coated article face is become black, this is not Black on essential meaning, and coating is thicker, adds cost, the brushing duration is longer, less efficient.And this technology is achieved The black paint film of real meaning, so as to reduce coating layer thickness, has saved cost, has improved coating efficiency.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of black raw lacquer coating based on natural raw lacquer.
The technical scheme is that:A kind of black raw lacquer coating based on natural raw lacquer, it is characterised in that:It is by day Made by right raw lacquer and black material;Black material be boiled by the hydroxide of natural raw lacquer and molybdenum according to certain proportion Hybrid Heating and Into described natural raw lacquer refers to carve the lacquer tree juice that injury is collected from true lacquertree bark.
A kind of blacking based on natural raw lacquer of the present invention, it is characterised in that described black preparation method for material is:In day The hydroxide Hybrid Heating of addition certain proportion molybdenum, which is boiled, in right raw lacquer liquid forms.
A kind of black raw lacquer coating based on natural raw lacquer of the present invention, it is characterised in that described black preparation method for material is: Natural raw lacquer is mixed with the hydroxide of molybdenum and is uniformly dispersed, is needed in input reaction unit by heating, stirring, be evacuated, take off Hydraulic art process.
A kind of black raw lacquer coating based on natural raw lacquer of the present invention, it is characterised in that described black preparation method for material is Need to reach certain viscosity, then cooling, it is standby kettle.
A kind of preparation method of the black raw lacquer coating based on natural raw lacquer of the present invention, it is characterised in that:By natural raw lacquer Different weight ratios are taken according to different seasons from the black material of preparation, and add quantitative auxiliary agent and stirs and obtains; The constitutional mesh silica flour of pigment 200 is added in coating and auxiliary agent wetting agent S-80, anti-settling agent WA stir as black bottom Paint.
A kind of preparation method of the black raw lacquer coating based on natural raw lacquer of the present invention, it is characterised in that described difference Season natural raw lacquer is spring and summer season 5 with black material composition weight proportioning:5, autumn and winter is 4:6;The auxiliary agent being separately added into is: Wetting agent S-80, concentrate animal gall bladder juice, and dispersed with stirring is uniform.
A kind of preparation method of the black raw lacquer coating based on natural raw lacquer of the present invention, it is characterised in that described is natural Raw lacquer is mixed in proportion with black material needs stirring, then stands certain time again.
A kind of preparation method of the black raw lacquer coating based on natural raw lacquer of the present invention, it is characterised in that described black 0.2% wetting agent S-80 of paint vehicle weight, 2% concentration animal gall bladder juice have been separately added into raw lacquer coating again.
A kind of preparation method of the black raw lacquer coating based on natural raw lacquer of the present invention, it is characterised in that described black The component that raw lacquer coating prepares black primer is wetting agent S-80, the 2% anti-settling agent WA for being separately added into its weight 3% again, 25% 200 mesh silica flours, dispersed with stirring is uniform.
Composition in raw lacquer is laccol, moisture content, laccase, gumminess, nitrogenous thing etc..Laccol is the main film forming in raw lacquer Material, it is that side chain radical is saturation and the mixture of the pyrocatechol series derivates of unsaturated straight chain.Its unsaturated terminal chain can Polyurushiol is oxidative polymerization into, two ortho-phenolic hydroxyls can be with complexing of metal ion.Due to molybdenum ion and laccol reaction generation black Laccol molybdenum, deploy laggard one-step polymerization into the fine and close paint film for stablizing network structure through brushing, therefore, this technology is taken in life The hydroxide of molybdenum is added in paint, is polymerize by thermal dehydration so that laccol is combined with its molybdenum ion is made black material, then again Mixed with undressed natural raw lacquer, so as to obtain bloom black raw lacquer coating.Its preparation method is:
(1) preparation of black material
Filtered natural raw lacquer is put into reactor, by the 2% of the input natural raw lacquer weight hydroxide for adding molybdenum Thing, opens heating, stirring, air extractor, by temperature control between 110 DEG C -130 DEG C, when the complete blackening of paint vehicle, viscosity is At 400 seconds, stop heating immediately, be cooled to 60 DEG C, it is standby to go out kettle while hot, as black material.
(2) modulation of finish paint
Black material is mixed with filtered natural raw lacquer, its weight ratio is spring, summer 5:5, autumn and winter is 4:6;Point Not Jia Ru paint vehicle weight 0.2%S-80,2% concentration animal gall bladder juice, dispersed with stirring is uniform.
(3) preparation of priming paint
A certain amount of finish paint is taken, the 3%S-80 of paint vehicle weight, 2% (WA) anti-settling agent, 25% 200 mesh quartz is added Powder, dispersed with stirring is uniform.
A kind of black raw lacquer coating based on natural raw lacquer of the present invention has the characteristics that:
This method is raw material with natural raw lacquer, adds micro additive modification and takes the bloom black raw lacquer coating of acquisition, Organic solvent-free volatilization, environmental protection in 100%, coating process are up to containing admittedly bright.
It make use of the molybdenum ion in the hydroxide of molybdenum to be combined with laccase, collectively promote the oxidative polymerization of laccol, Make paint liquid energy in large range of humiture environment, Quick Oxidation film forming is dried, the control without heating or adding humiture Measure, easy construction, low-carbon energy-saving.
This technology modulation bloom black raw lacquer coating, not only maintain conventional black push away paint premium properties and Performance is decorated, and also improves some performances, new performance is imparted so that black is more pure, decoration performance is more excellent It is good, add heat resistance, alkaline resistance properties.
The biochemical coating of bloom black of this technology modulation, is comprehensively complete with the most basic difference of other close coating Whole each composition for remaining raw lacquer, directly makes an addition to the related auxiliaries such as four molybdenum hydroxides in raw lacquer, than other methods Its production cost is low, although also someone produced laccol molybdenum with molybdenum compound and obtained black raw lacquer coating, but its method is The laccol in natural raw lacquer is extracted with organic solvent, is then reacted again with molybdenum compound, other compositions is abandoned, ring is polluted Border, causes great waste.
The bloom black raw lacquer coating of this technology modulation, form and aspect are pure, multitudinous Gai Liqiang, can reduce brushing number of times, and reduction is applied Thickness degree, so as to reduce use cost, improves efficiency of construction.
The black material that this technology is produced can also make the natural raw lacquer activity recovery of seasoning hard inactivation and at room temperature nature The effect of drying and forming-film.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely retouched State, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the present invention In embodiment, the every other implementation that those of ordinary skill in the art are obtained under the premise of creative work is not made Example, belongs to the scope of protection of the invention.
Embodiment 1:A kind of black raw lacquer coating based on natural raw lacquer, is 30% by filtered 980 grams of water content Shaanxi Province produce Pingli County natural raw lacquer input ceramic reactor in, add molybdenum 20 grams of hydroxide, open heating, stirring, Air extractor, by temperature control between 110 DEG C -130 DEG C, when the complete blackening of paint vehicle, when viscosity is 400 seconds, stops adding immediately Heat, is cooled to 60 DEG C, and it is standby to go out kettle while hot, as black material.After after its completely cooling, black 489 grams of material is taken, 489 grams of water content are Natural raw lacquer mixing is produced in 30% filtered Shaanxi Province Pingli County, adds 2 grams of S-80 wetting agents, concentrates 20 grams of pig bitter bile, Stirring 2 hours, to stand 3 days be spring, season in summer two with bloom black raw lacquer coating.It is repeated 3 times.
Embodiment 2:A kind of black raw lacquer coating based on natural raw lacquer, by the lake that filtered 970 water content is 22% Bei Sheng is produced Lichuan City in natural raw lacquer input ceramic reactor, adds 30 grams of the hydroxide of molybdenum, and unlatching is heated, stirred, taking out Device of air, by temperature control between 110 DEG C -130 DEG C, when the complete blackening of paint vehicle, when viscosity is 400 seconds, stops adding immediately Heat, is cooled to 60 DEG C, and it is standby to go out kettle while hot, as black material.After after its completely cooling, black 391.2 grams of material is taken, 586.8 grams aqueous Measure and natural raw lacquer mixing is produced by 22% filtered Hubei Province Lichuan City, add 2 grams of S-80 wetting agents, concentrate ox gall bladder juice 20 grams, stir 2 hours, to stand 3 days be autumn, season in winter two with bloom black raw lacquer coating.It is repeated 3 times.
Embodiment 3:A kind of black raw lacquer coating based on natural raw lacquer, by filtered 990 water content for 35% more South is produced in natural raw lacquer input ceramic reactor, adds 10 grams of the hydroxide of molybdenum, opens heating, stirring, air extractor, By temperature control between 110 DEG C -130 DEG C, when the complete blackening of paint vehicle, when viscosity is 400 seconds, stops heating immediately, be cooled to 60 DEG C, it is standby to go out kettle while hot, as black material.After after its completely cooling, taking black 391.2 grams of material, 586.8 grams of water content are 22% Filtered Vietnam produces natural raw lacquer mixing, adds 2 grams of S-80 wetting agents, 20 grams of concentration ox gall bladder juice is stirred 2 hours, quiet Put 5 days is autumn, season in winter two with bloom black raw lacquer coating.It is repeated 3 times.
Embodiment 4:A kind of black raw lacquer coating based on natural raw lacquer, by filtered 960 water content for 22% it is old Change 5 years Hubei Province Lichuan City to produce in natural raw lacquer input ceramic reactor, 40 grams of the hydroxide of addition molybdenum, unlatching heating, Stirring, air extractor, by temperature control between 110 DEG C -130 DEG C, when the complete blackening of paint vehicle, when viscosity is 400 seconds, immediately Stop heating, be cooled to 60 DEG C, it is standby to go out kettle while hot, as black material.After after its completely cooling, black 391.2 grams of material, 586.8 are taken Gram water content produces natural raw lacquer mixing by 22% filtered Vietnam, adds 2 grams of S-80 wetting agents, concentration ox gall bladder juice 20 Gram, stir 2 hours, to stand 3 days be autumn, season in winter two with bloom black raw lacquer coating.It is repeated 3 times.
Embodiment 5:A kind of black raw lacquer coating based on natural raw lacquer, by filtered 975 water content for 28% it is expensive State province is produced Jinsha County in natural raw lacquer input ceramic reactor, adds 25 grams of the hydroxide of molybdenum, and unlatching is heated, stirred, taking out Device of air, by temperature control between 110 DEG C -130 DEG C, when the complete blackening of paint vehicle, when viscosity is 400 seconds, stops adding immediately Heat, is cooled to 60 DEG C, and it is standby to go out kettle while hot, as black material.After after its completely cooling, black 489 grams of material is taken, 489 grams of water content are 22% filtered Vietnam produces natural raw lacquer mixing, adds 2 grams of S-80 wetting agents, and 20 grams of concentration fish gall bladder juice stirs 2 small When, to stand 3 days be spring, season in summer two with bloom black raw lacquer coating.It is repeated 3 times.
Embodiment 6:A kind of black raw lacquer coating based on natural raw lacquer, takes 350 grams of black material, and 350 grams of water content are 30% Hubei Province's Enshi City produce natural raw lacquer mixing, add 30 grams of (S-80) wetting agents, 20 grams of (WA) anti-settling agents, 250 gram 200 It 2 hours is black primer that mesh silica flour, which is stirred,.
Bloom black raw lacquer coating, in surveying drying time on glass plate, is applied in tinplate sheet with 75 μm of thickness film Mechanical performance and heat resistance are surveyed, test result is listed in table 1-3.
The measuring mechanical property result of the bloom blacking dried paint of table 2
The bloom black raw lacquer coating heat resistance of table 3
Embodiment 7:A kind of black raw lacquer coating based on natural raw lacquer, it is as made by natural raw lacquer and black material;Black material To be boiled to form according to certain proportion Hybrid Heating by the hydroxide of natural raw lacquer and molybdenum, described natural raw lacquer refer to from True lacquertree bark carves the lacquer tree juice that injury is collected.Described black preparation method for material is:Certain proportion molybdenum is added in natural raw lacquer liquid Hydroxide Hybrid Heating boil and form.Described black preparation method for material is:Natural raw lacquer is mixed with the hydroxide of molybdenum It is uniformly dispersed, is needed in input reaction unit by heating, stirring, pumping, dewatering process process.Described black material preparation side Method is to need to reach certain viscosity, and then cooling, it is standby kettle.
A kind of preparation method of the black raw lacquer coating based on natural raw lacquer, by natural raw lacquer and the black material foundation of preparation Different seasons takes different weight ratios, and adds quantitative auxiliary agent and stir and obtain;Added in coating constitutional The mesh silica flour of pigment 200 and auxiliary agent wetting agent S-80, anti-settling agent WA stir as black primer.Described Various Seasonal Natural raw lacquer is spring and summer season 5 with black material composition weight proportioning:5, autumn and winter is 4:6;The auxiliary agent being separately added into is:Wetting Agent S-80, concentrate animal gall bladder juice, and dispersed with stirring is uniform.Described natural raw lacquer is mixed in proportion with black material needs stirring, Then certain time is stood again.0.2% wetting agent S- of paint vehicle weight has been separately added into described black raw lacquer coating again 80,2% concentration animal gall bladder juice.
Embodiment 8:A kind of black raw lacquer coating based on natural raw lacquer, it is as made by natural raw lacquer and black material;Black material To be boiled to form according to certain proportion Hybrid Heating by the hydroxide of natural raw lacquer and molybdenum, described natural raw lacquer refer to from True lacquertree bark carves the lacquer tree juice that injury is collected.Described black preparation method for material is:Certain proportion molybdenum is added in natural raw lacquer liquid Hydroxide Hybrid Heating boil and form.Described black preparation method for material is:Natural raw lacquer is mixed with the hydroxide of molybdenum It is uniformly dispersed, is needed in input reaction unit by heating, stirring, pumping, dewatering process process.Described black material preparation side Method is to need to reach certain viscosity, and then cooling, it is standby kettle.
A kind of preparation method of the black raw lacquer coating based on natural raw lacquer, by natural raw lacquer and the black material foundation of preparation Different seasons takes different weight ratios, and adds quantitative auxiliary agent and stir and obtain;Added in coating constitutional The mesh silica flour of pigment 200 and auxiliary agent wetting agent S-80, anti-settling agent WA stir as black primer.Described Various Seasonal Natural raw lacquer is spring and summer season 5 with black material composition weight proportioning:5, autumn and winter is 4:6;The auxiliary agent being separately added into is:Wetting Agent S-80, concentrate animal gall bladder juice, and dispersed with stirring is uniform.Described natural raw lacquer is mixed in proportion with black material needs stirring, Then certain time is stood again.0.2% wetting agent S- of paint vehicle weight has been separately added into described black raw lacquer coating again 80,2% concentration animal gall bladder juice.
A kind of black primer preparation method of the black raw lacquer coating based on natural raw lacquer, described black raw lacquer coating The component for preparing black primer is the wetting agent S-80 for being separately added into its weight 3% again, 2% anti-settling agent WA, the 200 of 25% Mesh silica flour, dispersed with stirring is uniform.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (9)

1. a kind of black raw lacquer coating based on natural raw lacquer, it is characterised in that:It is as made by natural raw lacquer and black material;Black material It is to be boiled to form according to certain proportion Hybrid Heating by the hydroxide of natural raw lacquer and molybdenum, described natural raw lacquer refers to from paint Bark carves the lacquer tree juice that injury is collected.
2. a kind of blacking based on natural raw lacquer according to claim 1, it is characterised in that prepared by described black material Method is:The hydroxide Hybrid Heating of addition certain proportion molybdenum, which is boiled, in natural raw lacquer liquid forms.
3. according to a kind of black raw lacquer coating based on natural raw lacquer of claim 2, it is characterised in that described black material preparation side Method is:Natural raw lacquer is mixed with the hydroxide of molybdenum and is uniformly dispersed, is needed in input reaction unit by heating, stirring, take out Gas, dewatering process process.
4. a kind of black raw lacquer coating based on natural raw lacquer according to claim 3, it is characterised in that described black material Preparation method is to need to reach certain viscosity, and then cooling, it is standby kettle.
5. a kind of preparation method of the black raw lacquer coating based on natural raw lacquer according to claim 1 or 2 or 3 or 4, it is special Levy and be:Natural raw lacquer is taken into different weight ratios according to different seasons from the black material prepared, and adds quantitative auxiliary agent Stir and obtain;The constitutional mesh silica flour of pigment 200 and auxiliary agent wetting agent S-80, anti-settling agent WA stirring are added in coating It is uniformly black primer.
6. a kind of preparation method of black raw lacquer coating based on natural raw lacquer according to claim 5, it is characterised in that Described Various Seasonal natural raw lacquer is spring and summer season 5 with black material composition weight proportioning:5, autumn and winter is 4:6;It is separately added into Auxiliary agent be:Wetting agent S-80, concentrate animal gall bladder juice, and dispersed with stirring is uniform.
7. a kind of preparation method of black raw lacquer coating based on natural raw lacquer according to claim 6, it is characterised in that Described natural raw lacquer is mixed in proportion with black material needs stirring, then stands certain time again.
8. a kind of preparation method of black raw lacquer coating based on natural raw lacquer according to claim 6, it is characterised in that 0.2% wetting agent S-80 of paint vehicle weight, 2% concentration animal gall bladder have been separately added into described black raw lacquer coating again Juice.
9. a kind of preparation method of black raw lacquer coating based on natural raw lacquer according to claim 6, it is characterised in that The component that described black raw lacquer coating prepares black primer is the wetting agent S-80 for being separately added into its weight 3% again, 2% it is anti- Heavy agent WA, 25% 200 mesh silica flours, dispersed with stirring is uniform.
CN201710444833.0A 2017-06-14 2017-06-14 A kind of black raw lacquer coating based on natural raw lacquer Pending CN107189688A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102140311A (en) * 2011-04-08 2011-08-03 来凤县巴风楚韵工贸有限公司 Highlight black raw lacquer coating
CN103965781A (en) * 2014-04-21 2014-08-06 中南林业科技大学 Bio-enzyme modified natural raw lacquer composition and preparation method thereof
JP2014152201A (en) * 2013-02-06 2014-08-25 Kanazawa Inst Of Technology Bright color lacquer having a high lightness and method for manufacturing the same
CN104893574A (en) * 2015-05-23 2015-09-09 张家界娄江生态农业开发有限公司 High-temperature-resistant raw lacquer coating and preparation method thereof
CN105199597A (en) * 2015-10-28 2015-12-30 湖北宝石花工艺品有限公司 Preparation method of highlight black raw lacquer coating
CN105219267A (en) * 2015-10-28 2016-01-06 湖北宝石花工艺品有限公司 A kind of modulator approach of transparent raw lacquer coating

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102140311A (en) * 2011-04-08 2011-08-03 来凤县巴风楚韵工贸有限公司 Highlight black raw lacquer coating
JP2014152201A (en) * 2013-02-06 2014-08-25 Kanazawa Inst Of Technology Bright color lacquer having a high lightness and method for manufacturing the same
CN103965781A (en) * 2014-04-21 2014-08-06 中南林业科技大学 Bio-enzyme modified natural raw lacquer composition and preparation method thereof
CN104893574A (en) * 2015-05-23 2015-09-09 张家界娄江生态农业开发有限公司 High-temperature-resistant raw lacquer coating and preparation method thereof
CN105199597A (en) * 2015-10-28 2015-12-30 湖北宝石花工艺品有限公司 Preparation method of highlight black raw lacquer coating
CN105219267A (en) * 2015-10-28 2016-01-06 湖北宝石花工艺品有限公司 A kind of modulator approach of transparent raw lacquer coating

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Application publication date: 20170922