CN107189649A - A kind of corrosion resistant coating for container - Google Patents
A kind of corrosion resistant coating for container Download PDFInfo
- Publication number
- CN107189649A CN107189649A CN201710396713.8A CN201710396713A CN107189649A CN 107189649 A CN107189649 A CN 107189649A CN 201710396713 A CN201710396713 A CN 201710396713A CN 107189649 A CN107189649 A CN 107189649A
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- CN
- China
- Prior art keywords
- parts
- coating
- container
- corrosion resistant
- resistant coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
Field is protected the present invention relates to container, a kind of corrosion resistant coating for container is disclosed, is characterized in that：It is 35~50 parts of unsaturated polyester resin, 20~30 parts of modified alkyd resin, 9~21 parts of palm kernel ester, 13~21 parts of organosilicon moisture repellent, 30~45 parts of titanium dioxide, 19~32 parts of calcium sulfate, 2~6 parts of epoxy resin, 5~10 parts of fluorine carbon emulsion, 4~8 parts of Lay sulfonic formaldehyde condensation compound sodium salt, 0.2~0.8 part of hydroxypropyl methyl cellulose, 1~5 part of tributyl phosphate, 1~2 part of defoamer, 2.4~3.2 parts of butyl glycol ether by weight ratio.Transport by sea and long-time the exposure processing with container can not be met by solving existing common coating, cause seepage to cause the problem of contents are drenched.
Description
Technical field
Field is protected the present invention relates to container, is concretely a kind of corrosion resistant coating for container.
Background technology
China is the place that container manufacture is most assembled, and 2007 of the period of great prosperity, China's packaging are in manufacturing industry
The annual production of case has just reached 3,750,000 standard containers, accounts for the 96% of whole world case total amount processed, really stands qualified
On the position of " global container first manufactures big country ".
The application of container is quite varied, and especially in international and army, transport be unable to do without transport box and container.Using
Transport box and container can guarantee that institute's freight can not suffer a loss.Such as, wind, rain, snow, hail are met, it is necessary to maintain secrecy
Product be required to transport box and container.Although existing container turns into system substantially, so-called is huge as system
Substantially there is principle type specification in specification.But existing variety of container is various, material is different, because container is needed goods
Transport the whole world, it should with easy handling, protect commercial articles safety, facilitate the characteristics such as privacy of user.
Existing, container surface has fine pore size, and pore and micro-crack are to cause seepage to cause contents to be drenched
Wet basic reason.If capillary porosity duct and micro-crack blocked, it becomes possible to play waterproof, impervious effect, and existing use
In being coated in the coating of container surface in addition to attractive in appearance, also with certain corrosion resistance characteristic, but it is remote with container
Ocean transport and long-time exposure processing, conventional corrosion resistant coating are increasingly difficult to meet demand.
Accordingly, it would be desirable to it is a kind of there is waterproof, it is impervious, solve in the presence of a harsh environment, container surface has crackle and rotten
A kind of corrosion resistant coating for container of erosion problem.
The content of the invention
The present invention can not meet transport by sea and long-time the exposure processing with container for existing common coating, draw
Playing seepage causes the problem of contents are drenched there is provided a kind of corrosion resistant coating for container.
The present invention solves above-mentioned technical problem, and the technical scheme of use is that a kind of corrosion resistant coating for container is applied
Material is constituted by following weight proportion, and 35~50 parts of unsaturated polyester resin, 20~30 parts of modified alkyd resin, palm kernel ester 9~
21 parts, 13~21 parts of organosilicon moisture repellent, 30~45 parts of titanium dioxide, 19~32 parts of calcium sulfate.
Further, a kind of corrosion resistant coating for container, coating is constituted by following weight proportion, unsaturated polyester (UP)
40~45 parts of resin, 22~28 parts of modified alkyd resin, 12~19 parts of palm kernel ester, 15~19 parts of organosilicon moisture repellent, titanium white
34~42 parts of powder, 21~29 parts of calcium sulfate.
Further, a kind of corrosion resistant coating for container, coating is constituted by following weight proportion, unsaturated polyester (UP)
42~44 parts of resin, 24~26 parts of modified alkyd resin, 15~17 parts of palm kernel ester, 16~18 parts of organosilicon moisture repellent, titanium white
38~40 parts of powder, 23~26 parts of calcium sulfate.
Further, a kind of corrosion resistant coating for container, coating is constituted by following weight proportion, unsaturated polyester (UP)
43 parts of resin, 25 parts of modified alkyd resin, 16 parts of palm kernel ester, organosilicon.17 parts of hydrophober, 39 parts of titanium dioxide, calcium sulfate 25
Part.
Optionally, coating also includes the additive by following weight proportion, 2~6 parts of epoxy resin, fluorine carbon emulsion 5~10
Part, 4~8 parts of Lay sulfonic formaldehyde condensation compound sodium salt, 0.2~0.8 part of hydroxypropyl methyl cellulose, 1~5 part of tributyl phosphate, disappear
1~2 part of infusion, 2.4~3.2 parts of butyl glycol ether.
Optionally, coating also includes the additive by following weight proportion, 3~5 parts of epoxy resin, fluorine carbon emulsion 6~8
Part, 5~7 parts of Lay sulfonic formaldehyde condensation compound sodium salt, 0.4~0.6 part of hydroxypropyl methyl cellulose, 2~4 parts of tributyl phosphate, disappear
1.4~1.6 parts of infusion, 2.6~2.9 parts of butyl glycol ether.
Optionally, coating also includes the additive by following weight proportion, 4 parts of epoxy resin, 7 parts of fluorine carbon emulsion, Lay sulphur
Sour 6 parts of formaldehyde condensation products sodium salt, 0.5 part of hydroxypropyl methyl cellulose, 3 parts of tributyl phosphate, 1.5 parts of defoamer, ethylene glycol fourth
2.8 parts of ether.
The purpose so designed is that unsaturated polyester resin, modified alkyd resin are used as the solvent of coating, palm kernel
Ester, titanium dioxide, calcium sulfate with its distinctive active chemistry, using coating inherently chemically and porous, with water
For carrier, by the chemical substance reaction of formation in the osmosis and coating of water, acted along or against hydraulic pressure direction,
Transmit, chemical action occurs again for the composition of incomplete aquation in full, catalytic coatings, formed in coating micropore and capillary
Insoluble complicated and confused shape crystallizes and is combined into entirety with coating, water and other liquid that any direction is come is blocked.Work as structure
When there is no moisture, active ingredient can remains stationary state, but when being contacted again with moisture, above-mentioned chemical action and closed
Journey will repeat to occur, and can be deeper into coating, so as to reach permanent waterproof, protection against the tide, mesh resistant to chemical etching
's.
Pass through again simultaneously, epoxy resin, fluorine carbon emulsion, Lay sulfonic formaldehyde condensation compound sodium salt, hydroxypropyl methyl cellulose, phosphorus
Sour tributyl, defoamer, butyl glycol ether absorb the water in fluorine carbon emulsion based on coating and hardened, the contracting of Lay sulfonic acid and formaldehyde
Compound sodium salt and epoxy resin are combined with coating hardenite, and filling is with the space of coating, making coating have more enhanced water resistance
And toughness.
Hydroxypropyl methyl cellulose, tributyl phosphate, fluorine carbon emulsion are allowed to more antiacid caustic corrosion characteristic.
Beneficial effects of the present invention are at least one below：
1. the solvent of coating, palm kernel ester, titanium dioxide, sulfuric acid are used as by unsaturated polyester resin, modified alkyd resin
Calcium with its distinctive active chemistry, using coating inherently chemically and porous, using water as carrier, by water
Osmosis and the chemical substance reaction of formation in coating, are acted along or against hydraulic pressure direction, in coating micropore and hair
Transmitted in tubule, chemical action occurs again for the composition of incomplete aquation in full, catalytic coatings, forms insoluble complicated and confused shape
Crystallize and be combined into entirety with coating, water and other liquid that any direction is come is blocked.When structure does not have moisture, activity
Composition meeting remains stationary state, but when being contacted again with moisture, above-mentioned chemical action and closed process will repeat to occur,
And can be deeper into coating, so as to reach permanent waterproof, protection against the tide, purpose resistant to chemical etching.
2. pass through, epoxy resin, fluorine carbon emulsion, Lay sulfonic formaldehyde condensation compound sodium salt, hydroxypropyl methyl cellulose, tricresyl phosphate
Butyl ester, defoamer, butyl glycol ether absorb the water in fluorine carbon emulsion based on coating and hardened, Lay sulfonic formaldehyde condensation compound
Sodium salt and epoxy resin are combined with coating hardenite, and filling is with the space of coating, making coating have more enhanced water resistance and tough
Property.
3. more antiacid caustic corrosion characteristic is allowed to by hydroxypropyl methyl cellulose, tributyl phosphate, fluorine carbon emulsion.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments to the present invention
It is described in further detail.It should be appreciated that specific embodiment described herein is used only for explaining the present invention, limit is not used to
The fixed present invention.
Embodiment 1
Container surface is coated in labeled as A groups from common coating, and the 10% concentration dilute sulfuric acid that PH is 5 is sprayed respectively,
Under 1000 lux illumination intensity, place 48 hours, count its surface condition, spray the 10% concentration NaOH that PH is 9,
Under 1000 lux illumination intensity, place 48 hours, count its surface condition.
Embodiment 2
From coating made from following proportioning, coating is constituted by following weight proportion, 43 parts of unsaturated polyester resin, modification
25 parts of alkyd resin, 16 parts of palm kernel ester, 17 parts of organosilicon moisture repellent, 39 parts of calcium sulfate, 25 parts of titanium dioxide.Coating is coated in collection
Vanning surface markers are B groups, and the 10% concentration dilute sulfuric acid that PH is 5 is sprayed respectively, under 1000 lux illumination intensity, place 48
Hour, its surface condition is counted, the 10% concentration NaOH that sprinkling PH is 9 under 1000 lux illumination intensity, places 48 small
When, count its surface condition.
Embodiment 3
From coating made from following proportioning, coating is constituted by following weight proportion, 35 parts of unsaturated polyester resin, modification
20 parts of alkyd resin, 9 parts of palm kernel ester, 13 parts of organosilicon moisture repellent, 30 parts of calcium sulfate, 19 parts of titanium dioxide.Coating is coated in collection
Vanning surface markers are C groups, and the 10% concentration dilute sulfuric acid that PH is 5 is sprayed respectively, under 1000 lux illumination intensity, place 48
Hour, its surface condition is counted, the 10% concentration NaOH that sprinkling PH is 9 under 1000 lux illumination intensity, places 48 small
When, count its surface condition.
Embodiment 4
From coating made from following proportioning, coating is constituted by following weight proportion, 35 parts of unsaturated polyester resin, modification
20 parts of alkyd resin, 9 parts of palm kernel ester, 13 parts of organosilicon moisture repellent, 30 parts of calcium sulfate, 19 parts of titanium dioxide.Coating is coated in collection
Vanning surface markers are D groups, and the 10% concentration dilute sulfuric acid that PH is 5 is sprayed respectively, under 1000 lux illumination intensity, place 48
Hour, its surface condition is counted, the 10% concentration NaOH that sprinkling PH is 9 under 1000 lux illumination intensity, places 48 small
When, count its surface condition.
Embodiment 5
From coating made from following proportioning, coating is constituted by following weight proportion, 43 parts of unsaturated polyester resin, modification
25 parts of alkyd resin, 16 parts of palm kernel ester, 17 parts of organosilicon moisture repellent, 39 parts of calcium sulfate, 25 parts of titanium dioxide.4 parts of epoxy resin,
7 parts of fluorine carbon emulsion, 6 parts of Lay sulfonic formaldehyde condensation compound sodium salt, 0.5 part of hydroxypropyl methyl cellulose, 3 parts of tributyl phosphate, froth breaking
1.5 parts of agent, 2.8 parts of butyl glycol ether.Coating is coated in container surface labeled as E groups, and 10% concentration that PH is 5 is sprayed respectively
Dilute sulfuric acid, under 1000 lux illumination intensity, is placed 48 hours, counts its surface condition, 10% concentration that sprinkling PH is 9
NaOH, under 1000 lux illumination intensity, places 48 hours, counts its surface condition.
Embodiment 6
Contrast marker A~E data, are made following table：
It can be obtained by contrasting 5 groups of experimental datas, the coating provided by the present invention is coated in container surface, sprays respectively
PH is 5 10% concentration dilute sulfuric acid, under 1000 lux illumination intensity, is placed 48 hours, 10% concentration that sprinkling PH is 9
NaOH, under 1000 lux illumination intensity, is placed 48 hours, and coating surface situation is solved existing far better than existing coating
There is common coating can not meet transport by sea and long-time the exposure processing with container, cause seepage to cause contents quilt
The problem of drenching, while coating effect is made more preferably using D groups and E groups.
Claims (7)
1. a kind of corrosion resistant coating for container, it is characterised in that：The coating is constituted by following weight proportion, unsaturated
35~50 parts of polyester resin, 20~30 parts of modified alkyd resin, 9~21 parts of palm kernel ester, 13~21 parts of organosilicon moisture repellent, titanium
30~45 parts of white powder, 19~32 parts of calcium sulfate.
2. a kind of corrosion resistant coating for container according to claim 1, it is characterised in that：The coating is by following
Weight proportion is constituted, and 40~45 parts of unsaturated polyester resin, 22~28 parts of modified alkyd resin, 12~19 parts of palm kernel ester, is had
15~19 parts of machine silicon hydrophober, 34~42 parts of titanium dioxide, 21~29 parts of calcium sulfate.
3. a kind of corrosion resistant coating for container according to claim 1, it is characterised in that：The coating is by following
Weight proportion is constituted, and 42~44 parts of unsaturated polyester resin, 24~26 parts of modified alkyd resin, 15~17 parts of palm kernel ester, is had
16~18 parts of machine silicon hydrophober, 38~40 parts of titanium dioxide, 23~26 parts of calcium sulfate.
4. a kind of corrosion resistant coating for container according to claim 1, it is characterised in that：The coating is by following
Weight proportion is constituted, 43 parts of unsaturated polyester resin, 25 parts of modified alkyd resin, 16 parts of palm kernel ester, organosilicon moisture repellent 17
Part, 39 parts of titanium dioxide, 25 parts of calcium sulfate.
5. a kind of corrosion resistant coating for container according to claim 1, it is characterised in that：The coating also includes
By the additive of following weight proportion, 2~6 parts of epoxy resin, 5~10 parts of fluorine carbon emulsion, Lay sulfonic formaldehyde condensation compound sodium salt 4~
8 parts, 0.2~0.8 part of hydroxypropyl methyl cellulose, 1~5 part of tributyl phosphate, 1~2 part of defoamer, butyl glycol ether 2.4~
3.2 part.
6. a kind of corrosion resistant coating for container according to claim 5, it is characterised in that：The coating also includes
By the additive of following weight proportion, 3~5 parts of epoxy resin, 6~8 parts of fluorine carbon emulsion, Lay sulfonic formaldehyde condensation compound sodium salt 5~7
Part, 0.4~0.6 part of hydroxypropyl methyl cellulose, 2~4 parts of tributyl phosphate, 1.4~1.6 parts of defoamer, butyl glycol ether 2.6
~2.9 parts.
7. a kind of corrosion resistant coating for container according to claim 5, it is characterised in that：The coating also includes
By the additive of following weight proportion, 4 parts of epoxy resin, 7 parts of fluorine carbon emulsion, 6 parts of Lay sulfonic formaldehyde condensation compound sodium salt, hydroxypropyl
0.5 part of methylcellulose, 3 parts of tributyl phosphate, 1.5 parts of defoamer, 2.8 parts of butyl glycol ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710396713.8A CN107189649A (en) | 2017-05-31 | 2017-05-31 | A kind of corrosion resistant coating for container |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710396713.8A CN107189649A (en) | 2017-05-31 | 2017-05-31 | A kind of corrosion resistant coating for container |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107189649A true CN107189649A (en) | 2017-09-22 |
Family
ID=59876295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710396713.8A Pending CN107189649A (en) | 2017-05-31 | 2017-05-31 | A kind of corrosion resistant coating for container |
Country Status (1)
| Country | Link |
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| CN (1) | CN107189649A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4368316A (en) * | 1980-06-02 | 1983-01-11 | Sun Chemical Corporation | Process for the preparation of high-solids rosin-modified polyesters |
| CN1633479A (en) * | 2001-03-15 | 2005-06-29 | 卡伯特公司 | Corrosion-resistant coating composition |
| CN101050322A (en) * | 2006-04-04 | 2007-10-10 | 联合工艺公司 | Chromate free waterborne corrosion resistant primer with non-carcinogenic corrosion inhibiting additive |
| CN101386770A (en) * | 2007-09-14 | 2009-03-18 | 中涂化工（上海）有限公司 | High weather resistant leadless catalyst alkyde resin top-coat |
| CN103992675A (en) * | 2014-06-06 | 2014-08-20 | 厦门大学 | Marine heavy-duty anti-corrosion coating and preparation method thereof |
| CN105255332A (en) * | 2015-10-28 | 2016-01-20 | 苏州赛斯德工程设备有限公司 | Water-based paint for pipeline and preparing method of water-based paint |
| CN105925178A (en) * | 2016-05-13 | 2016-09-07 | 江苏科技大学 | Water-based organic and inorganic hybrid anticorrosive paint composition and preparing method thereof |
| CN105969032A (en) * | 2016-06-03 | 2016-09-28 | 浙江天女集团制漆有限公司 | Water-based alkyd paint and preparation method thereof |
-
2017
- 2017-05-31 CN CN201710396713.8A patent/CN107189649A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4368316A (en) * | 1980-06-02 | 1983-01-11 | Sun Chemical Corporation | Process for the preparation of high-solids rosin-modified polyesters |
| CN1633479A (en) * | 2001-03-15 | 2005-06-29 | 卡伯特公司 | Corrosion-resistant coating composition |
| CN101050322A (en) * | 2006-04-04 | 2007-10-10 | 联合工艺公司 | Chromate free waterborne corrosion resistant primer with non-carcinogenic corrosion inhibiting additive |
| CN101386770A (en) * | 2007-09-14 | 2009-03-18 | 中涂化工（上海）有限公司 | High weather resistant leadless catalyst alkyde resin top-coat |
| CN103992675A (en) * | 2014-06-06 | 2014-08-20 | 厦门大学 | Marine heavy-duty anti-corrosion coating and preparation method thereof |
| CN105255332A (en) * | 2015-10-28 | 2016-01-20 | 苏州赛斯德工程设备有限公司 | Water-based paint for pipeline and preparing method of water-based paint |
| CN105925178A (en) * | 2016-05-13 | 2016-09-07 | 江苏科技大学 | Water-based organic and inorganic hybrid anticorrosive paint composition and preparing method thereof |
| CN105969032A (en) * | 2016-06-03 | 2016-09-28 | 浙江天女集团制漆有限公司 | Water-based alkyd paint and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170922 |
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